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1. 发明申请

WO2004104238A3 METHOD FOR EXTRACTING COPPER FROM LEACH SOLUTIONS AT ELEVATED TEMPERATURES 审中-公开
标题翻译：从高温溶液中提取铜的方法
公开(公告)号：WO2004104238A3
公开(公告)日：2005-05-06
申请号：PCT/US2004012907
申请日：2004-04-27
申请人： COGNIS CORP , KORDOSKY GARY A , SUDDERTH R BRANTLEY , VIRNIG MICHAEL J
发明人： KORDOSKY GARY A , SUDDERTH R BRANTLEY , VIRNIG MICHAEL J
IPC分类号： C22B20060101 , C22B3/26 , C22B3/30 , C22B11/00 , C22B15/00
CPC分类号： C22B15/0063 , C22B3/0017 , C22B3/0032 , C22B15/0084 , Y02P10/234 , Y02P10/236
摘要： Copper is extracted from aqueous copper leach solutions wherein the leach solutions have a temperature of at least 30°C. The method comprises contacting the aqueous solution with an extraction reagent of the formula (I) : wherein R is a linear or branched C10-18 alkyl group and R1 is H or CH3. These extraction reagents do not undergo any significant degradation normally encountered with the use of conventional reagents in leach solutions having temperatures equal to or greater than 30°C.
摘要翻译：从浸出溶液中浸出溶液的温度至少为30℃的铜浸出溶液中提取铜。该方法包括使水溶液与式（I）的提取试剂接触：其中R是直链或支链C 10-18烷基，R 1是H或CH 3。这些提取试剂在温度等于或大于30℃的浸出溶液中使用常规试剂时通常不会遇到任何明显的降解。

2. 发明申请

WO2006060305A3 PROCESSES FOR RECOVERING METALS FROM ORES USING ORGANIC SOLVENT EXTRACTION AND AQUEOUS STRIPPING AT SELECTED TEMPERATURE DIFFERENTIALS 审中-公开
标题翻译：使用有机溶剂萃取和选择温度差异的水溶液回收金属的方法
公开(公告)号：WO2006060305A3
公开(公告)日：2007-08-09
申请号：PCT/US2005042875
申请日：2005-11-29
申请人： COGNIS IP MAN GMBH , VIRNIG MICHAEL J , SUDDERTH R BRANTLEY , CRANE PHILIP , NISBETT ANDREW , BOLEY BURREL , GORDON DUSTIN , KORDOSKY GARY A
发明人： VIRNIG MICHAEL J , SUDDERTH R BRANTLEY , CRANE PHILIP , NISBETT ANDREW , BOLEY BURREL , GORDON DUSTIN , KORDOSKY GARY A
IPC分类号： C22B15/00
CPC分类号： C22B3/0017 , C22B15/0071 , C22B15/0084 , Y02P10/234 , Y02P10/236
摘要： The disclosed invention concerns a process comprising: (a) providing a pregnant leach solution comprising copper values; (b) contacting the pregnant leach solution with an organic phase comprising a copper extractant at an extraction temperature, T ext, to form a loaded organic phase comprising the metal values; (c) contacting the loaded organic phase with an aqueous stripping solution at a stripping temperature, T strip, to form a copper-enriched stripping solution; wherein the difference in temperature (?T) between the stripping temperature and the extraction temperature according to equation (I): ?T = T strip - T ext is less than or equal to about 10°C. In other increasingly more preferred embodiments of the invention, the difference in temperature (?T) is less than or equal to about 5°C, less than or equal to about 2.5°C, less than or equal to about 0°C, less than or equal to about -5°C, and less than or equal to about -10°C. Also disclosed are economic means to manipulate the extraction, strip, and electrowinning temperatures to achieve these temperature differentials.
摘要翻译：所公开的发明涉及一种方法，包括：（a）提供包含铜值的怀孕浸出溶液; （b）在提取温度T ext2下使怀孕的浸出溶液与包含铜提取剂的有机相接触以形成包含金属值的负载有机相; （c）在汽提温度T T带下将负载的有机相与含水汽提溶液接触以形成富含铜的汽提溶液; 其中根据等式（I）的剥离温度和提取温度之间的温度差（ΔT）小于或等于（T）等于约10℃。在本发明的其它日益更优选的实施方案中，温度差（ΔT）小于或等于约5℃，小于或等于约2.5℃，小于或等于约0℃，较少大于或等于约-5℃，小于或等于约-10℃。还公开了操作提取，剥离和电解提取温度以实现这些温度差的经济手段。

3. 发明公开

EP1115891A4 PROCESS FOR EXTRACTING AND RECOVERING COPPER 审中-公开
标题翻译：方法拆卸和回收铜
公开(公告)号：EP1115891A4
公开(公告)日：2002-07-03
申请号：EP99969124
申请日：1999-09-14
申请人： COGNIS CORP
发明人： VIRNIG MICHAEL J , GRINSTEIN RUEBEN , SUDDERTH R BRANTLEY , WOLFE GEORGE , OLAFSON STEPHEN
IPC分类号： C22B3/30 , C22B3/40 , C22B15/00
CPC分类号： C22B15/0063 , C22B3/0017 , C22B3/0033 , C22B15/0084 , Y02P10/234 , Y02P10/236
摘要： A process for extracting and recovering copper from an aqueous solution containing copper values comprising: (a) contacting the aqueous copper bearing solution with an organic phase comprising a water insoluble and water immiscible solvent solution of an extraction reagent formulation to extract at least a portion of the copper values into the organic phase; (b) separating the resultant copper pregnant organic phase from the copper baren aqueous phase; and (c) recovering the copper values from the copper pregnant organic phase; wherein the extraction reagent formulation comprises (i) an oxime extractant and (ii) an equilibrium modifier in which the modifier is a linear diester or polyester of an unbranched dicarboxylic acid and an unbranched alcohol.

4. 发明专利

CA2525834A1 METHOD FOR EXTRACTING COPPER FROM LEACH SOLUTIONS AT ELEVATED TEMPERATURES 未知
公开(公告)号：CA2525834A1
公开(公告)日：2004-12-02
申请号：CA2525834
申请日：2004-04-27
申请人： COGNIS CORP
发明人： VIRNIG MICHAEL J , KORDOSKY GARY A , SUDDERTH R BRANTLEY
IPC分类号： C22B15/00 , C22B20060101 , C22B3/26 , C22B3/30 , C22B11/00
摘要： Copper is extracted from aqueous copper leach solutions wherein the leach solutions have a temperature of at least 30~C. The method comprises contacti ng the aqueous solution with an extraction reagent of the formula (I) : wherein R is a linear or branched C10-18 alkyl group and R1 is H or CH3. These extraction reagents do not undergo any significant degradation normally encountered with the use of conventional reagents in leach solutions having temperatures equal to or greater than 30~C.

5. 发明专利

CA2499219A1 LOW VISCOSITY COPPER SOLVENT EXTRACTION REAGENT FORMULATIONS 未知
公开(公告)号：CA2499219A1
公开(公告)日：2004-04-08
申请号：CA2499219
申请日：2003-09-12
申请人： COGNIS CORP
发明人： VIRNIG MICHAEL J , MATTTISON PHILLIP L , OLAFSON STEPHEN M , SUDDERTH R BRANTLEY
IPC分类号： B01D15/04 , C01B31/16 , C22B3/30 , C22B15/00 , C01B31/00 , C07C261/00 , C07C271/00 , C07C275/00
摘要： A low viscosity water insoluble extraction reagent composition according to the invention is comprised of: (a) an extractant selected from the group consisting of an aldoxime, a ketoxime, or a combination thereof; (b) an equilibrium modifier having a Brookdield viscosity of equal to or less than about 5 centapoise at 25~C and a flash point equal to or greater than about 141~F wherein the molar ratio of modifier to extractant is from about 0.05 t o about 2.0 so as to provide a net copper transfer greater than that achieved in the absence of modifier. Such low viscosity extractants afford higher recoveries of copper, permit reduced equipment size such as smaller mixers a nd settlers and the use of reduced amounts of less overall organic inventory.

6. 发明专利

PE20020318A1 PROCEDIMIENTO Y EQUIPO PARA LA REMOCION DEL SEDIMIENTO GRASOSO DESDE LA INTERFASE ENTRE LAS CAPAS ACUOSA Y ORGANICA EN UN DECANTADOR SX 未知
公开(公告)号：PE20020318A1
公开(公告)日：2002-06-08
申请号：PE2001000794
申请日：2001-08-08
申请人： COGNIS CORP
发明人： SUDDERTH R BRANTLEY , DORLAC JEROME P
IPC分类号： B01D11/04 , B01D17/02 , B01D21/24
摘要： EN UN PROCESO DE EXTRACCION POR SOLVENTES PARA LA REFINACION DE UN MINERAL METALICO, QUE COMPRENDE LAS SIGUIENTES ETAPAS: A)COLOCAR UN TALADRO ROTATORIO HORIZONTAL DENTRO DEL DECANTADOR EN O CERCA DE DICHA INTERFASE PARA MOVER EL SEDIMENTO GRASOSO DE MANERA CONTINUA O INTERMITENTE HACIA UN AREA DE RECOLECCION Y REMOCION QUE ES UNA CAJA RECOLECTORA DENTRO DEL DECANTADOR; Y, B)REMOVER EL SEDIMENTO GRASOSO DEL AREA DE RECOLECCION Y REMOCION UTILIZANDO UN SEGUNDO TALADRO O UNA BOMBA. DONDE EL DECANTADOR SX CONSTA DE AL MENOS UN TALADRO ROTATORIO DENTRO DE EL PARA REMOVER EL SEDIMENTO GRASOSO DE LA INTERFASE ENTRE LAS FASES ACUOSA Y ORGANICA CUANDO EL DECANTADOR ESTA EN UN MODO OPERATIVO, Y ES USADO EN LA REFINACION DE UN MINERAL DE COBRE, URANIO,NIQUEL, O ZINC. ADEMAS LA CAJA RECOLECTORA CON AL MENOS UN TALADRO ROTATORIO RECIBIRA EL SEDIMENTO GRASOSO CUANDO DICHO TALADRO COMPUESTO DE PLASTICO DURO SE HACE GIRAR

7. 发明专利

PE06192001A1 METODO PARA SEPARAR COBRE DE HIERRO 未知
公开(公告)号：PE06192001A1
公开(公告)日：2001-06-05
申请号：PE0008192000
申请日：2000-08-11
申请人： COGNIS CORP
发明人： KANG SANG I , MATTISON PHILLIP , WOLFE GEORGE A , VIRNIG MICHAEL J , SUDDERTH R BRANTLEY
IPC分类号： C07C249/06 , C07C251/38 , C22B3/30
摘要： QUE COMPRENDE: i) CONTACTAR UNA SOLUCION DE ALIMENTACION ACUOSA QUE CONTIENE Cu Y Fe DISUELTOS, TAL COMO UN LIXIVIADO DE CONCENTRADO O UNA SOLUCION LIXIVIADA, CON UNA SOLUCION ORGANICA INMISCIBLE EN AGUA QUE TIENE UN DISOLVENTE DE HIDROCARBURO Y UN COMPUESTO DE FORMULA (I), EN DONDE: a) R5 ES ALQUILO LINEAL O RAMIFICADO C1-C22, ARILO C6, ARALQUILO C7-C22, OH o -OR6 SIENDO R6 ALQUILO LINEAL O RAMIFICADO C1-22, ALQUENILO LINEAL O RAMIFICADO C2-C22, ARILO C5, ARALQUILO C7-C22; b) R1 ES H o ALQUILO o ALQUENILO LINEAL O RAMIFICADO C1-22; Y, c) R2, R3 Y R4 SON H, HALOGENO, ALQUILO LINEAL O RAMIFICADO C5-C12 o -OR6; Y, ii) SEPARAR LA FASE ACUOSA FORMADA QUE CONTIENE Fe Y LA FASE ORGANICA FORMADA QUE CONTIENE EL DISOLVENTE DE HIDROCARBURO Y UN COMPLEJO EXTRACTOR DE COBRE SOLUBLE EN DICHO DISOLVENTE

8. 发明专利

AU6764000A Method for separating copper from iron 未知
公开(公告)号：AU6764000A
公开(公告)日：2001-03-13
申请号：AU6764000
申请日：2000-08-10
申请人： COGNIS CORP
发明人： KANG SANG I , MATTISON PHILLIP , VIRNIG MICHAEL J , SUDDERTH R BRANTLEY , WOLFE GEORGE A
IPC分类号： C07C251/24 , C22B3/30 , C22B15/00 , C07C249/06 , C07C251/38
摘要： Copper is preferentially extracted from iron in an aqueous feedstock solution containing dissolved copper and iron values by contacting the feedstock solution with a water-immiscible organic solution comprised of a hydrocarbon solvent and a compound of the formula Iwherein R is a C 1-22 linear or branched alkyl group, a C 2-22 linear or branched alkenyl group, a C 6 aryl group, a C 7-22 aralkyl group, a halogen, OH or -OR wherein R is a C 1-22 linear or branched alkyl group, a C 2-22 linear or branched alkenyl group, a C 6 aryl group, a C 7-22 aralkyl group; R is hydrogen, or a C 1-22 linear or branched alkyl or alkenyl group, a C 6 aryl group or a C 7-22 aralkyl group; R -R is hydrogen, halogen, a linear or branched C 6-12 alkyl group, -OR wherein R is a C 1-22 linear or branched alkyl group, a C 2-22 linear or branched alkenyl group, a C 6 aryl group, or a C 7-22 aralkyl group to form an aqueous phase comprised of iron and an organic phase comprised of the hydrocarbon solvent and a copper-extractant complex wherein the copper-extractant complex is soluble in the hydrocarbon solvent. The R -R groups are chosen so that the copper-extractant complex is soluble in the hydrocarbon solvent. After the extraction stage is completed and the organic and aqueous phases separate, the organic phase is substantially free of iron and/or an iron-extractant complex.

9. 发明专利

PE20040358A1 FORMULACIONES PARA REACTIVOS DE EXTRACCION POR SOLVENTES DEL COBRE DE BAJA VISCOSIDAD 未知
公开(公告)号：PE20040358A1
公开(公告)日：2004-07-26
申请号：PE2003000981
申请日：2003-09-24
申请人： COGNIS CORP
发明人： SUDDERTH R BRANTLEY , MATTISON PHILLIP L , VIRNIG MICHAEL J , OLAFSON STEPHEN M
IPC分类号： B01D15/04 , C01B31/00 , C01B31/16 , C07C261/00 , C07C271/00 , C07C275/00 , C22B3/30 , C22B15/00
摘要： QUE COMPRENDEN: a) UN EXTRACTANTE TAL COMO ALDOXIMA, CETOXIMA O COMBINACION DE ELLOS; b) UN MODIFICADOR DE EQUILIBRIO, SELECCIONADO DE ALCOHOLES, ESTERES DE ACIDO CARBOXILICO, OXIMAS, NITRILOS, CETONAS, AMIDAS, CARBAMATOS, SULFOXIDOS, UREAS Y OXIDOS DE FOSFINO, QUE TIENE UNA VISCOSIDAD DE BROOKFIELD IGUAL A O MENOS DE 5 CENTIPOISES A 25°C Y UN PUNTO DE DESTELLO IGUAL A O MENOS DE 141°F; Y, c) UN ADITIVO CINETICO TAL COMO UNA OXIMA a-HIDROXI, UNA a,b-DIOXIMA O COMBINACION DE ELLOS; EN DONDE LA PROPORCION MOLAR DE (b) PARA (a) ES DE 0,05 A 2 PARA ASI ENTREGAR MAYOR TRASLADO DE COBRE NETO QUE EL LOGRADO EN AUSENCIA DE (b). ADEMAS, SE REFIERE A UN PROCESO PARA RECUPERAR COBRE DESDE UNA SOLUCION ACUOSA QUE CONTIENE VALORES DE COBRE, QUE INCLUYE CONTACTAR DICHA SOLUCION CON UNA FASE ORGANICA QUE COMPRENDE UNA SOLUCION SOLVENTE INMISCIBLE E INSOLUBLE EN AGUA DE DICHAS FORMULACIONES

10. 发明专利

CA2418702A1 CRUD REMOVAL SYSTEM AND METHOD FOR SOLVENT EXTRACTION 未知
公开(公告)号：CA2418702A1
公开(公告)日：2002-02-21
申请号：CA2418702
申请日：2001-07-27
申请人： COGNIS CORP
发明人： DORLAC JEROME P , SUDDERTH R BRANTLEY
IPC分类号： B01D17/02 , B01D21/24 , B01D11/04
摘要： Process and apparatus for the removal of crud from the interface between aqueous and organic layers in settler section (19) in which at least one rotatable auger (28) is positioned at or near the interface to remove crud continuously or intermittently from the interface.

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