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1. 发明申请

WO2005059022A1 COUPLING AGENTS BETWEEN FILLER AND ELASTOMER 审中-公开
标题翻译：填充剂和弹性体之间的联接剂
公开(公告)号：WO2005059022A1
公开(公告)日：2005-06-30
申请号：PCT/EP2004/053273
申请日：2004-12-06
申请人： CIBA SPECIALTY CHEMICALS HOLDING INC. , FUSO, Francesco , GERSTER, Michèle , KNOBLOCH, Gerrit , ROTA-GRAZIOSI, Pierre
发明人： FUSO, Francesco , GERSTER, Michèle , KNOBLOCH, Gerrit , ROTA-GRAZIOSI, Pierre
IPC分类号： C08K9/00
CPC分类号： C08K9/06 , C08K5/005 , C08K5/548 , C08L21/00
摘要： The invention describes a composition comprising a) a naturally occurring or synthetic elastomer susceptible to oxidative, thermal, dynamic, light-induced and/or ozone-induced degradation, b) a white reinforcing filler, and c) as coupling agent, at least one compound of the formula (I) wherein the general symbols are as defined in daim 1, or an oligomeric hydrolysis product of the compound of the formula (I).
摘要翻译：本发明描述了一种组合物，其包含a）对氧化，热，动态，光诱导和/或臭氧诱导的降解敏感的天然存在或合成的弹性体，b）白色增强填料，和c）作为偶联剂，至少一种通式（I）的化合物，其中一般符号如本文所定义，或式（I）化合物的低聚水解产物。

2. 发明申请

WO2007039416A1 FILLED RUBBER COMPOUNDS WITH IMPROVED PROCESSABILITY 审中-公开
标题翻译：填充橡胶化合物具有改进的可加工性
公开(公告)号：WO2007039416A1
公开(公告)日：2007-04-12
申请号：PCT/EP2006/066261
申请日：2006-09-12
申请人： CIBA SPECIALTY CHEMICALS HOLDING INC. , GERSTER, Michèle , KNOBLOCH, Gerrit , ROTA-GRAZIOSI, Pierre , FUSO, Francesco
发明人： GERSTER, Michèle , KNOBLOCH, Gerrit , ROTA-GRAZIOSI, Pierre , FUSO, Francesco
IPC分类号： C07F7/18 , C08K5/00 , C08K5/548 , C08K9/06
CPC分类号： C08K3/36 , C07F7/1836 , C08K5/548 , C08K9/06 , C08L21/00
摘要： The invention describes a process for the manufacture of a filled rubber compound with improved processability which comprises mixing in one-step a) a rubber, b) a white reinforcing filler, and c) a coupling agent of the Formula (I), wherein the general symbols are as defined in claim 1, or an oligomeric hydrolysis product of the compound of the Formula (I).
摘要翻译：本发明描述了一种制备具有改进的加工性能的填充橡胶化合物的方法，其包括在一步a）橡胶，b）白色增强填料和c）式（I）的偶联剂中混合，其中一般符号如权利要求1所定义，或式（I）化合物的低聚水解产物。

3. 发明申请

WO2007042418A3 NON-STAINING ANTIDEGRADANTS FOR VULCANIZED ELASTOMERS 审中-公开
公开(公告)号：WO2007042418A3
公开(公告)日：2007-04-19
申请号：PCT/EP2006/066953
申请日：2006-10-02
申请人： CIBA SPECIALTY CHEMICALS HOLDING INC. , GERSTER, Michèle , MEIER, Hans-Rudolf , KNOBLOCH, Gerrit , ROTA-GRAZIOSI, Pierre
发明人： GERSTER, Michèle , MEIER, Hans-Rudolf , KNOBLOCH, Gerrit , ROTA-GRAZIOSI, Pierre
IPC分类号： C08K5/00 , C08K5/42 , C08K5/372 , C07C317/48 , C07C323/52
摘要： The instant invention discloses a process for preventing contact discoloration of substrates coming into contact with elastomers and stabilizing elastomers to prevent oxidative, thermal, dynamic, light-induced and/or ozone-induced degradation, which comprises incorporating into the elastomers, or applying to these, at least a compound of the formula (I) wherein R 1 is C 1 -C 12 alkyl, R 2 is C 1 -C 12 alkyl, or R 1 and R 2 together with the carbon atom to which they are attached form an unsubstituted or with C 1 -C 4 alkyl substituted C 5 -C 12 cycloalkyl ring; R 3 is hydrogen or -CH 2 -S(O) m -R 5 , R 4 and R 5 independently of each other are unsubstituted or with cyano substituted C 5 -C 18 - alkyl; C 7 -C 9 phenylalkyl, unsubstituted or with halogen, hydroxyl, cyano or C 1 -C 4 alkyl substi- tuted phenyl or naphthyl; benzothiazolyl or -R 6 -CO 2 -R 7 , R 6 is C 1 -C 18 alkylene, R 7 is C 1 -C 18 alkyl, and m is 0, 1 or 2. The instant invention discloses also novel compounds of the formula (I), new mixtures of compounds of the formula (I) and compositions thereof in elastomers.

4. 发明申请

WO2002081432A3 SULFOXIDES OR SULFONES GRAFTED ONTO POLYMERS 审中-公开
公开(公告)号：WO2002081432A3
公开(公告)日：2002-10-17
申请号：PCT/EP2002/003381
申请日：2002-03-26
申请人： CIBA SPECIALTY CHEMICALS HOLDING INC. , MEIER, Hans-Rudolf , KNOBLOCH, Gerrit , ROTA-GRAZIOSI, Pierre , EVANS, Samuel , DUBS, Paul , GERSTER, Michèle
发明人： MEIER, Hans-Rudolf , KNOBLOCH, Gerrit , ROTA-GRAZIOSI, Pierre , EVANS, Samuel , DUBS, Paul , GERSTER, Michèle
IPC分类号： C07C317/00
摘要： Polymers grafted with a compount of formula I, formula (I) wherein the general symbols are as defined in claim 1, have outstanding stability against oxidative, thermal, dynamic, light-induced and/or ozone-induced degradation.

5. 发明申请

WO2002081432A2 SULFOXIDES OR SULFONES GRAFTED ONTO POLYMERS 审中-公开
标题翻译：硫化物或硫磺被吸收到聚合物上
公开(公告)号：WO2002081432A2
公开(公告)日：2002-10-17
申请号：PCT/EP2002/003381
申请日：2002-03-26
申请人： CIBA SPECIALTY CHEMICALS HOLDING INC. , MEIER, Hans-Rudolf , KNOBLOCH, Gerrit , ROTA-GRAZIOSI, Pierre , EVANS, Samuel , DUBS, Paul , GERSTER, Michèle
发明人： MEIER, Hans-Rudolf , KNOBLOCH, Gerrit , ROTA-GRAZIOSI, Pierre , EVANS, Samuel , DUBS, Paul , GERSTER, Michèle
IPC分类号： C07C317/00
CPC分类号： C07D303/22 , C07C317/04 , C07C317/10 , C07C317/18 , C07C317/44 , C07C323/12 , C07C323/25 , C07C323/52 , C07C323/65 , C07C2601/14 , C07D303/16 , C07D405/12 , C07F7/1836 , C08C19/20 , C08C19/22 , C08K5/36
摘要： Polymers grafted with a compount of formula I, formula (I) wherein the general symbols are as defined in claim 1, have outstanding stability against oxidative, thermal, dynamic, light-induced and/or ozone-induced degradation.
摘要翻译：用式I表示的通式（I）的聚合物，其中通式符号如权利要求1所定义，具有优异的抗氧化，热，动态，光诱导和/或臭氧诱导的降解的稳定性。

6. 发明申请

WO2006003092A1 STABILIZATION OF POLYETHER POLYOL, POLYESTER POLYOL OR POLYURETHANE COMPOSITIONS 审中-公开
标题翻译：聚醚多元醇，聚酯多元醇或聚氨酯组合物的稳定性
公开(公告)号：WO2006003092A1
公开(公告)日：2006-01-12
申请号：PCT/EP2005/052843
申请日：2005-06-20
申请人： CIBA SPECIALTY CHEMICALS HOLDING INC. , MÄDER, Dietmar , ROTA-GRAZIOSI, Pierre
发明人： MÄDER, Dietmar , ROTA-GRAZIOSI, Pierre
IPC分类号： C08K5/13
CPC分类号： C08L75/04 , C08K5/005 , C08K5/13 , C08K5/1345 , C08K5/20 , C08K5/3435
摘要： The present invention pertains to compositions comprising (a) a polyether polyol, a polyester polyol or a polyurethane, (b) a UV-absorber of formula (I) and/or a hindered amine light stabilizer of formula (II) wherein R 1 , and R 2 are each independently C 1 -C 4 alkyl or C 1 -C 4 alkyoxy, and (c) at least one further UV-absorber and/or hindered amine light stabilizer if only one of the components (I) and (II) is present with the proviso that component (c) is not a compound of formula (A)-(D) as defined in claim 1.
摘要翻译：本发明涉及包含（a）聚醚多元醇，聚酯多元醇或聚氨酯的组合物，（b）式（I）的UV吸收剂和/或式（II）的受阻胺光稳定剂，其中R

7. 发明申请

WO2007031450A1 POLYURETHANE FLAME RETARDANT COMPOSITIONS 审中-公开
标题翻译：聚氨酯阻燃剂组合物
公开(公告)号：WO2007031450A1
公开(公告)日：2007-03-22
申请号：PCT/EP2006/066045
申请日：2006-09-06
申请人： CIBA SPECIALTY CHEMICALS HOLDING INC. , MÄDER, Dietmar , ROTA-GRAZIOSI, Pierre
发明人： MÄDER, Dietmar , ROTA-GRAZIOSI, Pierre
IPC分类号： C08K5/524 , C08K5/3492 , C08K5/5393 , C08K5/5313
CPC分类号： C08K5/34928 , C08K3/32 , C08K5/51 , C08L75/04
摘要： The invention relates to a flame retardant composition, which comprises a) At least one ester of a phosphorus containing oxo acid selected from the group consisting of phosphonous and phosphorous acid; b) At least one flame retardant component based on a nitrogen compound; particularly melamine cyanurate, and c) A polyurethane polymer base.
摘要翻译：本发明涉及一种阻燃组合物，其包含a）至少一种选自磷酸和亚磷酸的含磷酸的酯; b）至少一种基于氮化合物的阻燃组分; 特别是氰尿酸三聚氰胺，和c）聚氨酯聚合物基料。

8. 发明申请

WO2008113702A1 PROCESSING STABILIZERS FOR RUBBER COMPOUNDING 审中-公开
标题翻译：用于橡胶混合物的加工稳定剂
公开(公告)号：WO2008113702A1
公开(公告)日：2008-09-25
申请号：PCT/EP2008/052801
申请日：2008-03-10
申请人： CIBA HOLDING INC. , KNOBLOCH, Gerrit , PEREGI, Eva , ROTA-GRAZIOSI, Pierre
发明人： KNOBLOCH, Gerrit , PEREGI, Eva , ROTA-GRAZIOSI, Pierre
IPC分类号： C08K5/375 , C08K5/103 , C08L21/00
CPC分类号： C08K5/103 , C08K5/0016 , C08K5/005 , C08K5/375 , C08L21/00
摘要： The invention describes an improved method for the preparation of rubber compounds which comprises compounding the rubber and the components at 125 - 200°C in the presence of an amount of 0.1 - 2% based on the weight of the rubber of a processing stabilizer of the formula (I) wherein R 1 is hydrogen, C 1 -C 20 alkyl, styryl, α-methyl-styryl or -CH 2 -S-R 3 ; or C 1 -C 20 alkyl substituted with C 2- C 20 alkenyl, C 3 -C 20 alkinyl, C 5 -C 9 cycloalkyl, phenyl or tolyl; R 2 is C 1 -C 20 alkyl or -CH 2 -S-R 3 , R 3 is C 1 -C 20 alkyl; with phenyl, hydroxyl, cyano, formyl, acetyl or -O-CO-R 5 substituted C 1 -C 20 alkyl; C 2 -C 20 alkenyl, C 3 -C 20 alkinyl, C 5 -C 9 cycloalkyl; or with hydroxyl, phenyl, 4-chloro-phenyl, 2-methoxycarbonylphenyl, p-tolyl, 1,3-benzthiazol-2-yl, -(CHR 5 ) n COOR 6 or -(CHR 5 ) n CONR 7 R 8 substituted C 5 -C 9 cycloalkyl; R 4 is hydrogen or methyl, R 5 is hydrogen or C 1 -C 6 alkyl, R 6 is C 1 -C 20 alkyl; with oxygen or sulfur interrupted C 3 -C 20 alkyl; C 5 -C 9 cycloalkyl, phenyl, benzyl or tolyl, R 7 and R 8 are independently of each other hydrogen or C 1 -C 6 alkyl, and n is 1 or 2.
摘要翻译：本发明描述了一种用于制备橡胶化合物的改进方法，其包括在125-200℃下，以0.1-2％（重量）的加工稳定剂的橡胶重量的量，使橡胶和组分混合，式（I）其中R 1是氢，C 1 -C 20烷基，苯乙烯基，α-甲基苯乙烯基或-CH _{2 -SR _{3 ; 或被C 2 -C 20链烯基取代的C 1 -C 20烷基，C 3 - 苯基或甲苯基; C 1 -C 20烷基，C 5 -C 9环烷基，苯基或甲苯基; R 2是C 1 -C 20烷基或-CH 2 -SR 3 N / N R 3是C 1 -C 20烷基; R 3是C 1 -C 20烷基; 苯基，羟基，氰基，甲酰基，乙酰基或-O-CO-R 5取代的C 1 -C 20烷基; C 2 -C 20链烯基，C 3 -C 20炔基，C 5 -C 15 > -C _{9 环烷基; 或与羟基，苯基，4-氯 - 苯基，2-甲氧基羰基苯基，对甲苯基，1,3-苯并噻唑-2-基， - （CHR 5 N） COR 6或 - （CHR 5 N）N CONR 7 R 8取代的C _{5 -C _{9 环烷基; R 4是氢或甲基，R 5是氢或C 1 -C 6烷基，R SUB > 6是C 1 -C 20烷基; 与氧或硫中断C 3 -C 20烷基; C 5 -C 9环烷基，苯基，苄基或甲苯基，R 7和R 8各自独立地为其它氢或C 1 -C 6烷基，n为1或2。}}}}}

9. 发明申请

WO2009138342A1 BASIC STABILISATION SYSTEMS FOR EMULSION POLYMERISED RUBBERS 审中-公开
标题翻译：用于乳液聚合橡胶的基本稳定系统
公开(公告)号：WO2009138342A1
公开(公告)日：2009-11-19
申请号：PCT/EP2009/055460
申请日：2009-05-06
申请人： BASF SE , KNOBLOCH, Gerrit , ROTA-GRAZIOSI, Pierre
发明人： KNOBLOCH, Gerrit , ROTA-GRAZIOSI, Pierre
IPC分类号： C08K5/36 , C08K5/18 , C08L9/00
CPC分类号： C08K5/18 , C08K3/01 , C08K5/0008 , C08K5/375 , C08L21/00
摘要： There are described compositions comprising a) an emulsion crude rubber, synthetic latex or natural rubber latex subject to oxidative, thermal, dynamic and/or light-induced degradation, b) a compound of the formula (I) wherein R 1 is C 8 -C 12 alkyl, R 2 is hydrogen, C 1 -C 12 alkyl, cyclohexyl, 1-methylcyclohexyl, benzyl, α-methylbenzyl, α,α-dimethylbenzyl or -CH 2 -S-R 1 , R 3 is C 1 -C 12 alkyl, benzyl, α-methylbenzyl, α, α-dimethylbenzyl or -CH 2 -S-R 1 , R 4 is hydrogen or methyl, and c) a styrenated diphenylamine of the formula (II).
摘要翻译：描述的组合物包含a）经受氧化，热，动态和/或光诱导降解的乳液粗橡胶，合成胶乳或天然橡胶胶乳，b）式（I）化合物，其中R 1是C 8 -C 12烷基，R 2是氢，C 1 -C 12烷基，环己基，1-甲基环己基，苄基，α-甲基苄基，a，α-二甲基苄基或-CH 2 -S-R 1，R 3是C 1 -C 12烷基，苄基，α-甲基苄基， - 二甲基苄基或-CH 2 -S-R 1，R 4是氢或甲基，和c）式（II）的苯乙烯化二苯胺。

10. 发明公开

EP1727858A1 COUPLING AGENTS BETWEEN FILLER AND ELASTOMER 有权转让
标题翻译：离合器装置之间的填充剂和弹性体
公开(公告)号：EP1727858A1
公开(公告)日：2006-12-06
申请号：EP04804681.7
申请日：2004-12-06
申请人： Ciba Specialty Chemicals Holding Inc.
发明人： FUSO, Francesco , GERSTER, Michèle , KNOBLOCH, Gerrit , ROTA-GRAZIOSI, Pierre
IPC分类号： C08K9/00 , C08K5/00 , C08K9/06 , C08K5/548
CPC分类号： C08K9/06 , C08K5/005 , C08K5/548 , C08L21/00
摘要： The invention describes a composition comprising a) a naturally occurring or synthetic elastomer susceptible to oxidative, thermal, dynamic, light-induced and/or ozone-induced degradation, b) a white reinforcing filler, and c) as coupling agent, at least one compound of the formula (I) wherein the general symbols are as defined in daim 1, or an oligomeric hydrolysis product of the compound of the formula (I).

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