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    • 3. 发明申请
    • ß CRYSTALINE POLYPROPYLENES
    • ß晶体聚丙烯
    • WO2003102069A1
    • 2003-12-11
    • PCT/EP2003/005374
    • 2003-05-22
    • CIBA SPECIALTY CHEMICALS HOLDING INC.MÄDER, DietmarHOFFMANN, KurtSCHMIDT, Hans-Werner
    • MÄDER, DietmarHOFFMANN, KurtSCHMIDT, Hans-Werner
    • C08K5/20
    • C08K5/20C08L23/10
    • A composition containing (1) a crystalline polypropylene resin and (2) one or more ß-nucleating agents of the formula (I), wherein R 1 , R 2 and R 3 , independently of one another, are C 1 -C 20 alkyl, C 2 -Calkyl substituted by C 1 -C, 1o alkylamino, di(C 1 -C 1o alkyl)amino, C 1 -C lo alkyloxy or hydroxy; C 3 -C 2o alkenyl, C 5 -C 12 cycloalkyl, C 5 -C 12 Cycloalkyl substituted by 1, 2 or 3 C 1 -C 10 alkyl; cyclohexylmethyl; cyclohexylmethyl substituted by 1, 2 or 3 C 1 -C 1o alkyl; C 5 -C 9 cycloalkenyl, C 5 -C 9 cycloalkenyl substituted by 1, 2 or 3 C 1 -C 10 alkyl; phenyl substituted by 1, 2 or 3 radicals selected from the group consisting of C 1 -C 10 -oalkyl, C 1 -C 10 alkyloxy, hydroxy, halogen, trihalogenmethyl, trihalogenmethoxy, benzoyl, phenylamino, acylamino and phenylazo; C 7 -C 9 phenylalkyl, C 7 -C 9 phenylalkyl which is substituted on the phenyl by 1, 2 or 3 radicals selected from the group consisting of C 1 -C lo alkyl, C 1 -C 10 alkoxy and hydroxy; naphthyl, naphthyl substituted by C 1 C 1o alkyl, adamantyl, or a 5 to 6 membered heterocyclic group; characterized in that the polypropylene resin has a content of ß-form crystals of at least 10 % calculated by means of the following equation ß-form crystal content (%) = 100 x P ß1 ,/(P a1 + P a2 + P a3 + P ß1 ) where P a1 to P a3 are respective peak heights (maxima) of the a-form and P ß1 is a peak height (maximum) of the ß-form determined by wide angle X-ray scattering.
    • 一种组合物,其包含(1)结晶聚丙烯树脂和(2)一种或多种式(I)的β-成核剂,其中R 1,R 2和R 3彼此独立地为C 1 -C 20烷基,被C 1 -C 20烷基取代的C 2 -C 8烷基 C 1 -C 10烷基氨基,二(C 1 -C 10烷基)氨基,C 1 - 烷氧基或羟基; C 3 -C 20烯基,C 5 -C 12环烷基,被1,2或3个C 1 -C 10烷基取代的C 5 -C 12环烷基; 环己基甲基; 被1,2或3个C 1 -C 10烷基取代的环己基甲基; C5-C9环烯基,被1,2或3个C1-C10烷基取代的C5-C9环烯基; 被选自C1-C10-烷基,C1-C10烷氧基,羟基,卤素,三卤代甲基,三卤代甲氧基,苯甲酰基,苯基氨基,酰基氨基和苯基偶氮基的1,2或3个基团取代的苯基; C7-C9苯基烷基,在苯基上被1,2或3个选自C1-C10烷基,C1-C10烷氧基和羟基的基团取代的C7-C9苯基烷基; 萘基,被C 1 -C 10烷基取代的萘基,金刚烷基或5至6元杂环基; 其特征在于,所述聚丙烯树脂的β-型结晶含量通过以下方程计算为至少10%β型晶体含量(%)= 100×Pβ1,/(Pa1 + Pa2 + Pa3 +Pβ1)其中 Pa1至Pa3分别为α型的峰高(最大值),Pβ1为通过广角X射线散射确定的β型的峰高(最大值)。