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1. 发明申请

WO2010006889A2 COUPLING AGENTS FOR FILLED RUBBERS 审中-公开
标题翻译：填充橡胶的偶联剂
公开(公告)号：WO2010006889A2
公开(公告)日：2010-01-21
申请号：PCT/EP2009/057753
申请日：2009-06-23
申请人： BASF SE , GERSTER, Michèle , PEREGI, Eva
发明人： GERSTER, Michèle , PEREGI, Eva
IPC分类号： C08K5/00 , C08K5/11 , C08K5/548 , C08K3/36 , C08L21/00
CPC分类号： C08K3/36 , C08K5/0016 , C08K5/11 , C08K5/548 , C08L21/00
摘要： The invention describes a composition comprising a) a naturally occurring or synthetic rubber susceptible to oxidative, thermal, dynamic, light-induced and/or ozone-induced degradation, b) a white reinforcing filler, c) a coupling agent selected from the group consisting of organofunctionalized silanes, polysulfide silanes, blocked mercaptosilanes, thio substituted silanes, sulfoxide or sulfone substituted silane coupling agents, and oligomeric hydrolysis product thereof, and d) a coupling agent regulator selected from the group consisting of cyclic or acyclic 1,2-disubstituted alkenes bearing two electron-withdrawing groups, cyclic or acyclic 1,2-disubstituted alkenes bearing one electron-withdrawing group and one electron-donating group, cyclic or acyclic 1,1-disubstituted alkenes bearing two electron-withdrawing groups, cyclic or acyclic 1,1-disubstituted alkenes bearing one electron-withdrawing group and one electron-donating group, and cyclic or acyclic trisubstituted alkenes bearing at least two electron-withdrawing groups.
摘要翻译：本发明描述了一种组合物，其包含a）对氧化，热，动态，光诱导和/或臭氧诱导的降解敏感的天然或合成橡胶，b）白色增强填料，c）选自有机官能化硅烷，多硫化物硅烷，封端巯基硅烷，硫代取代硅烷，亚砜或砜取代硅烷偶联剂，以及它们的低聚物水解产物的偶联剂，以及d）偶联剂调节剂，其选自：环状或带有两个吸电子基团的无环1,2-二取代烯烃，带有一个吸电子基团和一个给电子基团的环状或无环1,2-二取代烯烃，带有两个吸电子基团的环状或无环1,1-二取代烯烃，带有一个吸电子基团和一个给电子基团的环状或无环1,1-二取代烯烃，以及环状或无环三取代 d烯烃带有至少两个吸电子基团。

2. 发明申请

WO2007144283A1 S-PERFLUOROALKYL SUBSTITUTED HYDROXYBENZYLTHIOETHERS AND DERIVATIVES AS SURFACE MODIFIERS 审中-公开
标题翻译：作为表面改性剂的S-全氟烷基取代的羟基苯甲酸酯和衍生物
公开(公告)号：WO2007144283A1
公开(公告)日：2007-12-21
申请号：PCT/EP2007/055451
申请日：2007-06-04
申请人： CIBA SPECIALTY CHEMICALS HOLDING INC. , GERSTER, Michèle , MIHALIC, Manuel
发明人： GERSTER, Michèle , MIHALIC, Manuel
IPC分类号： C08K5/36 , C08K5/13
CPC分类号： C08K5/42
摘要： The invention describes a process for reducing the surface energy of organic materials such as for example increasing the oil and water repellency and stain release of organic materials, which comprises treating the organic material with at least a compound of the formula I wherein the general symbols are as defined in claim 1; especially wherein at least one of the radicals R 2 , R 3 or R 4 is -CH(R 11 )-S(O) p -R 12 ; R 11 is hydrogen, C 1 -C 8 alkyl, unsubstituted or with C 1 -C 4 alkyl substituted phenyl; R 12 is a monovalent perfluorinated alkyl or alkenyl, linear or branched organic radical having four to twenty fully fluorinated carbon atoms, and p is 0, 1 or 2.
摘要翻译：本发明描述了一种减少有机材料的表面能的方法，例如增加有机材料的防水和防水性和污迹释放，其包括用至少一种式I化合物处理有机材料，其中通式为如权利要求1所定义; 特别是其中R 2，R 3或R 4中的至少一个为-CH（R 11））-S（O）_{p -R _{12 ; R 11是氢，C 1 -C 8烷基，未取代的或C 1 -C 3烷基， 4烷基取代的苯基; R 12是具有四至二十个完全氟化的碳原子的一价全氟化烷基或烯基，直链或支链有机基团，p是0,1或2。}}

3. 发明申请

WO2005059022A1 COUPLING AGENTS BETWEEN FILLER AND ELASTOMER 审中-公开
标题翻译：填充剂和弹性体之间的联接剂
公开(公告)号：WO2005059022A1
公开(公告)日：2005-06-30
申请号：PCT/EP2004/053273
申请日：2004-12-06
申请人： CIBA SPECIALTY CHEMICALS HOLDING INC. , FUSO, Francesco , GERSTER, Michèle , KNOBLOCH, Gerrit , ROTA-GRAZIOSI, Pierre
发明人： FUSO, Francesco , GERSTER, Michèle , KNOBLOCH, Gerrit , ROTA-GRAZIOSI, Pierre
IPC分类号： C08K9/00
CPC分类号： C08K9/06 , C08K5/005 , C08K5/548 , C08L21/00
摘要： The invention describes a composition comprising a) a naturally occurring or synthetic elastomer susceptible to oxidative, thermal, dynamic, light-induced and/or ozone-induced degradation, b) a white reinforcing filler, and c) as coupling agent, at least one compound of the formula (I) wherein the general symbols are as defined in daim 1, or an oligomeric hydrolysis product of the compound of the formula (I).
摘要翻译：本发明描述了一种组合物，其包含a）对氧化，热，动态，光诱导和/或臭氧诱导的降解敏感的天然存在或合成的弹性体，b）白色增强填料，和c）作为偶联剂，至少一种通式（I）的化合物，其中一般符号如本文所定义，或式（I）化合物的低聚水解产物。

4. 发明申请

WO2009127514A1 STABILIZATION AND SURFACE MODIFICATION OF ORGANIC MATERIALS 审中-公开
标题翻译：有机材料的稳定和表面改性
公开(公告)号：WO2009127514A1
公开(公告)日：2009-10-22
申请号：PCT/EP2009/053770
申请日：2009-03-31
申请人： BASF SE , GERSTER, Michèle , MIHALIC, Manuel
发明人： GERSTER, Michèle , MIHALIC, Manuel
IPC分类号： C07D327/06 , C07C323/15 , C07C323/52 , C07B63/04 , C09K15/00
CPC分类号： C07D327/06 , C07B63/04 , C07C323/16 , C07C323/52
摘要： Organic materials which possess outstanding stability to oxidative, thermal or light-induced degradation and/or are able to reduce the surface energy of organic materials comprise at least one compound of the formula (I) wherein the general symbols are as defined in claim 1.
摘要翻译：具有优异的氧化，热或光诱导降解稳定性和/或能够降低有机材料表面能的有机材料包含至少一种式（I）化合物，其中通式如权利要求1所定义。

5. 发明申请

WO2009095328A1 ADDITIVE MIXTURES FOR STYRENIC POLYMERS 审中-公开
标题翻译：苯乙烯聚合物的添加剂混合物
公开(公告)号：WO2009095328A1
公开(公告)日：2009-08-06
申请号：PCT/EP2009/050539
申请日：2009-01-19
申请人： CIBA HOLDING INC. , WEGMANN, Alex , KIM, SungHee , GERSTER, Michèle
发明人： WEGMANN, Alex , KIM, SungHee , GERSTER, Michèle
IPC分类号： C08K5/00 , C08L25/06 , C08J3/22 , C08K5/372 , C08K5/134 , C08K5/1539
CPC分类号： C08F6/006 , C08J3/226 , C08J2425/00 , C08K5/005 , C08K5/375 , C08L25/04
摘要： The invention describes a process for reducing the amount of saturated or unsaturated monomers and oligomers during production and processing of styrenic polymers comprising a mixture of at least two components selected from the group consisting of a) phenol thioethers, b) phenol acrylates, c) 3-arylbenzofuran-2-ones and d) 1,1-di-substituted ethylenes or tri-substituted ethylenes.
摘要翻译：本发明描述了在生产和加工苯乙烯聚合物期间减少饱和或不饱和单体和低聚物的量的方法，其包含选自以下的至少两种组分的混合物：a）苯酚硫醚，b）苯酚丙烯酸酯，c）3 芳基苯并呋喃-2-酮和d）1,1-二取代的乙烯或三取代的乙烯。

6. 发明申请

WO2006134045A1 OLIGO- AND POLY-CARBONATES TERMINATED WITH SILICON CONTAINING GROUPS AS SURFACE MODIFIERS 审中-公开
标题翻译：用含表面改性剂的硅烷封端的聚碳酸酯和聚碳酸酯
公开(公告)号：WO2006134045A1
公开(公告)日：2006-12-21
申请号：PCT/EP2006/062954
申请日：2006-06-07
申请人： CIBA SPECIALTY CHEMICALS HOLDING INC. , BRAND, Fabien Jean , DESAI, Archana Kishore , GERSTER, Michèle , HINDALEKAR, Shrirang Bhikaji , SAHASRABUDHE, Suhas Dattatraya , THANKI, Paragkumar Nathalal , TINKL, Michael , PREUSS, Andrea , WIETHAN, Jürgen , KUMBHAR, Kishor Prabhakar
发明人： BRAND, Fabien Jean , DESAI, Archana Kishore , GERSTER, Michèle , HINDALEKAR, Shrirang Bhikaji , SAHASRABUDHE, Suhas Dattatraya , THANKI, Paragkumar Nathalal , TINKL, Michael , PREUSS, Andrea , WIETHAN, Jürgen , KUMBHAR, Kishor Prabhakar
IPC分类号： C08G64/08 , C08G64/14 , C08G64/18 , C08G77/448 , C08G77/46
CPC分类号： C08G64/14 , C08G64/085 , C08G77/448 , C08L67/00 , C08L69/00 , C08L2666/18
摘要： The instant invention relates to new compounds of the formula I wherein the general symbols are as defined in claim 1 and R 1 and R 2 are each independently of the other a silicon containing group. These new compounds of the formula I are useful as reducers of surface energy for organic materials such as polycarbonates, polyesters or polyketones or their mixtures, blends or alloys. Polymers with such a reduced surface energy possess an "easy to clean", "self-cleaning" "antisoiling", "soil-release" "antigraffiti", "oil resistance", "solvent resistance", "chemical resistance", "self lubricating", "scratch resistance", "low moisture absorption", "dirt pickup resistance", "slip properties" and "hydrophobic surface"; and antiadhesion properties against proteins and against microorganism such as for example bacteria, fungi and algae.
摘要翻译：本发明涉及新的式I化合物，其中一般符号如权利要求1中所定义，R 1和R 2各自独立地为另一个含硅的组。式I的这些新化合物可用作有机材料如聚碳酸酯，聚酯或聚酮或其混合物，共混物或合金的表面能的还原剂。具有这种表面能降低的聚合物具有“易清洁”，“自清洁”，“防污”，“释放”“防泼溅”，“耐油性”，“耐溶剂性”，“耐化学性” 润滑性“，”耐刮擦性“，”低吸湿性“，”吸尘性“，”滑爽性“，”疏水性表面“等。和抗蛋白质和抗微生物（例如细菌，真菌和藻类）的抗粘附性质。

7. 发明申请

WO2004106311A2 AMINOARYL TRIAZINES 审中-公开
标题翻译： AMINOARYL-1-3-5 TRIAZINES及其作为紫外线吸收剂的用途
公开(公告)号：WO2004106311A2
公开(公告)日：2004-12-09
申请号：PCT/EP2004/050818
申请日：2004-05-17
申请人： CIBA SPECIALTY CHEMICALS HOLDING INC. , SCHÄFER, Thomas , WENDEBORN, Frédérique , GERSTER, Michèle , HAYOZ, Pascal , SCHMIDHALTER, Beat , BUDRY, Jean-Luc
发明人： SCHÄFER, Thomas , WENDEBORN, Frédérique , GERSTER, Michèle , HAYOZ, Pascal , SCHMIDHALTER, Beat , BUDRY, Jean-Luc
IPC分类号： C07D251/22
CPC分类号： C08K5/3492 , C07D251/22 , C07D251/24
摘要： A novel process for preparing a aminophenyltriazines of the formula (I’), comprises reacting a corresponding halogenophenyltriazine of the formula (I’’), with an amine of the formula (IX), H-NR' 2 R' 3 , wherein X is chloro or preferably fluoro and the symbols A, A', R' 2 , R' 3 and R 44 are organic residues as defined in claim 1. Products of this process and derivatives thereof are useful as stabilizers and UV absorbers for protecting an organic material against damage by light, oxygen and/or heat, or as recording dye in an optical recording medium, especially for writing or reading digital information in a recording layer using laser radiation of wavelength less than 450 nm.
摘要翻译：制备式（I'）的氨基苯基三嗪的新方法包括使相应的式（I“）的卤代苯基三嗪与式（IX）的胺，H-NR'2R'3反应，其中X为氯或优选氟，符号A，A'，R'2，R'3和R44是如权利要求1中定义的有机残基。该方法的产物及其衍生物可用作稳定剂和用于保护有机材料的UV吸收剂光，氧和/或热的损害，或作为光记录介质中的记录染料，特别是使用波长小于450nm的激光辐射在记录层中写入或读取数字信息。

8. 发明申请

WO2009034016A1 SILANE COUPLING AGENTS FOR FILLED RUBBERS 审中-公开
标题翻译：用于填充橡胶的硅烷偶联剂
公开(公告)号：WO2009034016A1
公开(公告)日：2009-03-19
申请号：PCT/EP2008/061723
申请日：2008-09-05
申请人： CIBA HOLDING INC. , GERSTER, Michèle , MIHALIC, Manuel
发明人： GERSTER, Michèle , MIHALIC, Manuel
IPC分类号： C08K5/00 , C08K5/548 , C08K3/36 , C08K9/06
CPC分类号： C08K5/548 , C08L21/00
摘要： The invention describes a composition comprising a) a naturally occurring or synthetic rubber susceptible to oxidative, thermal, dynamic, light-induced and/or ozone-induced degradation, b) a white reinforcing filler, and c) as coupling agent, at least one compound of the formula I wherein the general symbols are as defined in claim 1, or an oligomeric hydrolysis product of the compound of the formula I.
摘要翻译：本发明描述了一种组合物，其包含a）对氧化，热，动态，光诱导和/或臭氧诱导的降解敏感的天然存在或合成橡胶，b）白色增强填料，和c）作为偶联剂，至少一种式I化合物，其中通式如权利要求1所定义，或式I化合物的低聚水解产物。

9. 发明申请

WO2007134997A1 N-SUBSTITUTED PERFLUOROALKYLATED PYRROLIDINES AS SURFACE MODIFIERS 审中-公开
标题翻译：作为表面改性剂的N-取代的全氟烷基吡咯烷
公开(公告)号：WO2007134997A1
公开(公告)日：2007-11-29
申请号：PCT/EP2007/054615
申请日：2007-05-14
申请人： CIBA SPECIALTY CHEMICALS HOLDING INC. , GERSTER, Michèle , THORAND, Stephan
发明人： GERSTER, Michèle , THORAND, Stephan
IPC分类号： C08K5/3415
CPC分类号： C08K5/3415
摘要： The invention describes a composition comprising comprising a) a natural, semi-synthetic or synthetic polymer which is susceptible to oxidative, ther- mal or light-induced degradation, and b) a compound of the formula (I) wherein R F , R, Q and q are as defined herein, and are prepared from diallylamine, a perfluoroalkyl iodide and an amino-reactive compound selected from the group of carboxylic acids, anhydrides, acid chlorides, oxiranes, haloalkanes, isocyanates and ureas. The compounds of the formula I are useful as reducers of surface energy for natural, semi- synthetic or synthetic polymers, for example, for increasing the oil and water repellency and stain release of natural, semi-synthetic or synthetic polymers.
摘要翻译：本发明描述了一种组合物，其包含a）天然的，半合成的或合成的聚合物，其易于氧化，热或光诱导的降解，和b）式（I）的化合物，其中R R，Q和q如本文所定义，并且由二烯丙基胺，全氟烷基碘和选自羧酸，酸酐，酰氯，环氧乙烷，卤代烷烃，异氰酸酯和脲的氨基反应性化合物制备。式I的化合物可用作天然的，半合成的或合成的聚合物的表面能的还原剂，例如用于增加天然的，半合成的或合成的聚合物的拒水拒油和污渍释放。

10. 发明申请

WO2007042418A3 NON-STAINING ANTIDEGRADANTS FOR VULCANIZED ELASTOMERS 审中-公开
公开(公告)号：WO2007042418A3
公开(公告)日：2007-04-19
申请号：PCT/EP2006/066953
申请日：2006-10-02
申请人： CIBA SPECIALTY CHEMICALS HOLDING INC. , GERSTER, Michèle , MEIER, Hans-Rudolf , KNOBLOCH, Gerrit , ROTA-GRAZIOSI, Pierre
发明人： GERSTER, Michèle , MEIER, Hans-Rudolf , KNOBLOCH, Gerrit , ROTA-GRAZIOSI, Pierre
IPC分类号： C08K5/00 , C08K5/42 , C08K5/372 , C07C317/48 , C07C323/52
摘要： The instant invention discloses a process for preventing contact discoloration of substrates coming into contact with elastomers and stabilizing elastomers to prevent oxidative, thermal, dynamic, light-induced and/or ozone-induced degradation, which comprises incorporating into the elastomers, or applying to these, at least a compound of the formula (I) wherein R 1 is C 1 -C 12 alkyl, R 2 is C 1 -C 12 alkyl, or R 1 and R 2 together with the carbon atom to which they are attached form an unsubstituted or with C 1 -C 4 alkyl substituted C 5 -C 12 cycloalkyl ring; R 3 is hydrogen or -CH 2 -S(O) m -R 5 , R 4 and R 5 independently of each other are unsubstituted or with cyano substituted C 5 -C 18 - alkyl; C 7 -C 9 phenylalkyl, unsubstituted or with halogen, hydroxyl, cyano or C 1 -C 4 alkyl substi- tuted phenyl or naphthyl; benzothiazolyl or -R 6 -CO 2 -R 7 , R 6 is C 1 -C 18 alkylene, R 7 is C 1 -C 18 alkyl, and m is 0, 1 or 2. The instant invention discloses also novel compounds of the formula (I), new mixtures of compounds of the formula (I) and compositions thereof in elastomers.

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