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1. 发明专利

DE69217184D1 未知
公开(公告)号：DE69217184D1
公开(公告)日：1997-03-13
申请号：DE69217184
申请日：1992-11-27
申请人： MITSUBISHI HEAVY IND LTD , CHUBU ELECTRIC POWER
发明人： SAKAI MATSUSHIGE , SAJI AKIRA , NODA HIDETOMO , HONDOH TAKEO , TANII TADAAKI , ISHIBASHI MASARU , NEGORO MASAAKI , KAWATA YUTAKA , MURAKAMI TAKEFUMI , KITAMURA HIKARU , KAMATA TOSHIHIRO
IPC分类号： B01D53/62 , B01J3/04 , B01J19/00 , C01B32/50 , C01B31/20
摘要： A carbon dioxide clathrate having a lump diameter enough to precipitate on a desired abyssal position of the sea without being drifted by a seawater flow of the abyss can be produced by bringing an aqueous solution into contact with carbon dioxide with the interposition of an interface in a reactor and retaining this contact; adjusting the pressure in the reactor to 13 atm or more, the temperature of the aqueous solution to a level of more than 5 DEG C to 10 DEG C, the temperature of the interface to a level of more than 10 DEG C to 15 DEG C and the temperature of a lug inserted into the aqueous solution to a level of more than 0 DEG C to 5 DEG C; producing/growing the carbon dioxide clathrate on the lug; and then heating the lug to a temperaturte of more than 10 DEG C to 30 DEG C to separate/drop the carbon dioxide clathrate therefrom.

2. 发明专利

DE69217184T2 未知
公开(公告)号：DE69217184T2
公开(公告)日：1997-05-15
申请号：DE69217184
申请日：1992-11-27
申请人： MITSUBISHI HEAVY IND LTD , CHUBU ELECTRIC POWER
发明人： SAKAI MATSUSHIGE , SAJI AKIRA , NODA HIDETOMO , HONDOH TAKEO , TANII TADAAKI , ISHIBASHI MASARU , NEGORO MASAAKI , KAWATA YUTAKA , MURAKAMI TAKEFUMI , KITAMURA HIKARU , KAMATA TOSHIHIRO
IPC分类号： B01D53/62 , B01J3/04 , B01J19/00 , C01B32/50 , C01B31/20
摘要： A carbon dioxide clathrate having a lump diameter enough to precipitate on a desired abyssal position of the sea without being drifted by a seawater flow of the abyss can be produced by bringing an aqueous solution into contact with carbon dioxide with the interposition of an interface in a reactor and retaining this contact; adjusting the pressure in the reactor to 13 atm or more, the temperature of the aqueous solution to a level of more than 5 DEG C to 10 DEG C, the temperature of the interface to a level of more than 10 DEG C to 15 DEG C and the temperature of a lug inserted into the aqueous solution to a level of more than 0 DEG C to 5 DEG C; producing/growing the carbon dioxide clathrate on the lug; and then heating the lug to a temperaturte of more than 10 DEG C to 30 DEG C to separate/drop the carbon dioxide clathrate therefrom.

3. 发明专利

JPH04324253A FUEL CELL 失效
公开(公告)号：JPH04324253A
公开(公告)日：1992-11-13
申请号：JP9524491
申请日：1991-04-25
申请人： CHUBU ELECTRIC POWER , MITSUBISHI HEAVY IND LTD
发明人： YOSHIDA HIROSHI , INOUE TOSHIO , EZAKI YOSHIMI , HATTORI MASATOSHI , SUMI MASAO , MIYAMOTO HITOSHI , ISHIBASHI MASARU , HANEDA TOSHIO , TAKENOBU KOICHI
IPC分类号： H01M8/04 , H01M8/12
摘要： PURPOSE:To prevent deterioration of a fuel pole of a fuel cell. CONSTITUTION:At the time of increasing/decreasing temperature of a fuel cell where no generation is performed by the fuel cell and at the time of holding a high temperature where the fuel cell is in a standby condition, by supplying nitrogen gas, mixed with reducing gas, to a fuel flow path 7 of the fuel cell from a reducing gas-mixed nitrogen supply device 9, a fuel pole side is held in the reducing atmosphere even in the case whatever it may be, so that a fuel cell 3 can be prevented from deteriorating without oxidizing a nickel metal.

4. 发明专利

JPH05146637A METHOD FOR FORMING CARBON DIOXIDE CLATHRATE 失效
公开(公告)号：JPH05146637A
公开(公告)日：1993-06-15
申请号：JP31773591
申请日：1991-12-02
申请人： CHUBU ELECTRIC POWER , MITSUBISHI HEAVY IND LTD
发明人： SAKAI MATSUNARI , SAJI AKIRA , NODA HIDETOMO , HONDO TAKEO , TANII TADAAKI , ISHIBASHI MASARU , NEGORO MASAAKI , KAWADA YUTAKA , MURAKAMI TAKEFUMI , KITAMURA HIKARI , KAMATA TOSHIHIRO
IPC分类号： B01D53/62 , B01J3/04 , B01J19/00 , C01B32/50
摘要： PURPOSE:To form a carbon dioxide clathrate having a predetermined particle size settled to a predetermined place of the bottom of the sea in a very deep region without being allowed to flow by a deep-sea stream. CONSTITUTION:An aqueous solution 2 and carbon dioxide 3 are held in a reaction container 1 so as to be brought to a contact state at an interface 4 and the pressure in the reaction container 1 is set to 13 atm or higher and the temp. of the aqueous solution 2 is set to the range of 5-10 deg.C while the temp. of the interface 4 is set to the range of 10-15 deg.C and the temp. of the projection part inserted in the aqueous solution 2 is set to the range of 0-5 deg.C to form and grow a carbon dioxide clathrate 20. Thereafter, the projection part is heated to the temp. range of 10-30 deg.C to separate the carbon dioxide clathrate 20 to allow the same to fall.

5. 发明专利

DE69103455D1 未知
公开(公告)号：DE69103455D1
公开(公告)日：1994-09-22
申请号：DE69103455
申请日：1991-03-08
申请人： MITSUBISHI HEAVY IND LTD
发明人： IRINO MITSUHIRO , ISHIBASHI MASARU , SATAKE TOKUKI , SAKAI HIROSHI , FUNATSU MASAYUKI , HANEDA HISAO , TAKENOBU KOICHI , WATANABE KIYOSHI , OKURA KAZUMI , OKURA SHIGERU
IPC分类号： H01M8/04 , H01M8/12 , H01M8/24
摘要： A power generation system with flat fuel cells of solid electrolyte of simple construction permissible of building up a large capacity system, which comprises a train of pile units (5) of flat fuel cells of solid electrolyte disposed in a horizontally extending fuel gas duct (1) adapted to supply said train of pile units of flat fuel cells with the fuel gas (103). each of said pile units of flat fuel cells having, on the one hand, horizontal flat flow paths for the fuel gas each disposed above each fuel-side porous electrode sheet and opening freely at both path ends on the opposing side faces of the pile unit and, on the other hand, horizontal flat flow paths for the oxidant gas each disposed beneath each oxygen-side porous electrode sheet separately from the fuel gas flow paths and each connected at both path ends to either a supply line (109) or to an exhaust line (L) for the oxidant gas, an after-burning region (125) disposed downstream of said train of pile units of flat fuel cells for burning at least a part of the spent fuel gas which has passed through the fuel cell using at least a part of the spent oxidant gas which has passed through the fuel cell, for generating a heat of combustion for use for preheating at least either one of the feed gases to be supplied to the fuel cell.

6. 发明专利

DE69103455T2 未知
公开(公告)号：DE69103455T2
公开(公告)日：1994-11-24
申请号：DE69103455
申请日：1991-03-08
申请人： MITSUBISHI HEAVY IND LTD
发明人： IRINO MITSUHIRO , ISHIBASHI MASARU , SATAKE TOKUKI , SAKAI HIROSHI , FUNATSU MASAYUKI , HANEDA HISAO , TAKENOBU KOICHI , WATANABE KIYOSHI , OKURA KAZUMI , OKURA SHIGERU
IPC分类号： H01M8/04 , H01M8/12 , H01M8/24
摘要： A power generation system with flat fuel cells of solid electrolyte of simple construction permissible of building up a large capacity system, which comprises a train of pile units (5) of flat fuel cells of solid electrolyte disposed in a horizontally extending fuel gas duct (1) adapted to supply said train of pile units of flat fuel cells with the fuel gas (103). each of said pile units of flat fuel cells having, on the one hand, horizontal flat flow paths for the fuel gas each disposed above each fuel-side porous electrode sheet and opening freely at both path ends on the opposing side faces of the pile unit and, on the other hand, horizontal flat flow paths for the oxidant gas each disposed beneath each oxygen-side porous electrode sheet separately from the fuel gas flow paths and each connected at both path ends to either a supply line (109) or to an exhaust line (L) for the oxidant gas, an after-burning region (125) disposed downstream of said train of pile units of flat fuel cells for burning at least a part of the spent fuel gas which has passed through the fuel cell using at least a part of the spent oxidant gas which has passed through the fuel cell, for generating a heat of combustion for use for preheating at least either one of the feed gases to be supplied to the fuel cell.

7. 发明专利

AU7279291A POWER GENERATION SYSTEM WITH FLAT FUEL CELLS OF SOLID ELECTROLYTE 未知
公开(公告)号：AU7279291A
公开(公告)日：1991-09-19
申请号：AU7279291
申请日：1991-03-08
申请人： MITSUBISHI HEAVY IND LTD
发明人： IRINO MITSUHIRO , ISHIBASHI MASARU , TOKUKI SATAKE , SAKAI HIROSHI , FUNATSU MASAYUKI , HANEDA HISAO , TAKENOBU KOICHI , WATANBE KIYOSHI , OGURA KAZUMI , OKURA SHIGERU
IPC分类号： H01M8/04 , H01M8/12 , H01M8/24 , H01M8/06
摘要： A power generation system with flat fuel cells of solid electrolyte of simple construction permissible of building up a large capacity system, which comprises a train of pile units (5) of flat fuel cells of solid electrolyte disposed in a horizontally extending fuel gas duct (1) adapted to supply said train of pile units of flat fuel cells with the fuel gas (103). each of said pile units of flat fuel cells having, on the one hand, horizontal flat flow paths for the fuel gas each disposed above each fuel-side porous electrode sheet and opening freely at both path ends on the opposing side faces of the pile unit and, on the other hand, horizontal flat flow paths for the oxidant gas each disposed beneath each oxygen-side porous electrode sheet separately from the fuel gas flow paths and each connected at both path ends to either a supply line (109) or to an exhaust line (L) for the oxidant gas, an after-burning region (125) disposed downstream of said train of pile units of flat fuel cells for burning at least a part of the spent fuel gas which has passed through the fuel cell using at least a part of the spent oxidant gas which has passed through the fuel cell, for generating a heat of combustion for use for preheating at least either one of the feed gases to be supplied to the fuel cell.

8. 发明专利

JP2004243154A Flying ash treatment method and flying ash 审中-公开
公开(公告)号：JP2004243154A
公开(公告)日：2004-09-02
申请号：JP2003032666
申请日：2003-02-10
申请人： Mitsubishi Heavy Ind Ltd , Taiheiyo Cement Corp , 三菱重工業株式会社 , 太平洋セメント株式会社
发明人： KATO MASAHIRO , ITO MITSUHIRO , SHINODA YUTAKA , KOJIMA KATSUHISA , ISHIBASHI MASARU
IPC分类号： F23G7/00 , B03C7/02 , B03C7/12 , B07B4/02 , B07B7/08 , B07B7/083 , C04B18/08 , F23J1/00
CPC分类号： Y02W30/92
摘要： PROBLEM TO BE SOLVED: To provide a flying ash treatment method which can remove not only unburned carbon but also trace elements from flying ash, and the flying ash. SOLUTION: In the flying ash treatment method, the flying ash containing unburned carbon particles and ash particles, after being charged into a fly ash hopper 1, is supplied into electrified piping 3 by a fly ash supply part 2 and transported to an electrostatic separation part 4 by compressed air. By friction electrification by the collision of the unburned carbon particles and the ash particles with the inner wall surface of the electrified piping 3 or the collision between the unburned carbon particles and the ash particles, the ash particles are charged negatively and the unburned carbon particles are charged positively. The unburned carbon particles and the ash particles receive force in the opposite direction respectively from an electric field when they pass through the electrostatic separation part 4 so that their flows are biased. In this way, low unburned carbon ash of at least 40% unburned carbon removal rate and high unburned carbon ash of a high unburned carbon content are recovered. COPYRIGHT: (C)2004,JPO&NCIPI

9. 发明专利

JP2003080025A Reduction apparatus and denitrification apparatus 有权
标题翻译：减少装置和破坏装置
公开(公告)号：JP2003080025A
公开(公告)日：2003-03-18
申请号：JP2001274341
申请日：2001-09-10
申请人： Mitsubishi Heavy Ind Ltd , Akira Mizuno , 三菱重工業株式会社 , 彰水野
发明人： IWABUCHI HIROYUKI , UEDA YASUTOSHI , KAGAMI MORIO , MIZUNO AKIRA , ISHIBASHI MASARU
IPC分类号： F01N3/08 , B01D53/56 , B01D53/81 , B01D53/86 , B01J19/08 , B01J19/12 , B01J35/02 , F01N3/10
CPC分类号： Y02A50/2345
摘要： PROBLEM TO BE SOLVED: To decrease the use quantity of a reduction gas in a reducing reaction in a denitrification step.
SOLUTION: When a treating gas containing nitrogen oxide flows from the upstream side A of a denitrification apparatus 106 to be supplied to the denitrifrication apparatus 106, corona discharge is produced by AC voltage applied between an electrode 35 and a wire like electrode 24 to form a non- equilibrium plasma atmosphere. NO in the treating gas is oxidized in the atmosphere to be changed to NO
2 . The NO
2 is adsorbed by an alkali adsorbing material 64 made of Ba(OH)
2 coming out from holes 35a provided on the electrode 35 to be turned to Ba(NO
3 )
2 to and stored. Because DC voltage is also applied to the electrode 35 and the wire like electrode 24 from a DC power source 213, NO
3
- in the alkali adsorbing material 64 moves toward a positive electrode (the electrode 35) to be decomposed into N
2 and O
2 .
COPYRIGHT: (C)2003,JPO
摘要翻译：要解决的问题：减少脱氮步骤中的还原反应中的还原气体的使用量。解决方案：当含氮氧化物的处理气体从反硝化设备106的上游侧A流入供给到脱氮装置106时，通过施加在电极35和线状电极24之间的交流电压产生电晕放电，形成非平衡等离子体气氛。处理气体中的NO在大气中被氧化而变为NO2。 NO2被从由设置在电极35上的孔35a出来的Ba（OH）2制成的碱吸附材料64吸附以转变为Ba（NO 3）2并被储存。由于直流电压也从直流电源213向电极35和线状电极24施加，碱吸附材料64中的NO 3 - 向正极（电极35）移动，分解成N2和O2 。

10. 发明专利

JP2001170445A WASTE GAS DENITRATION METHOD AND SYSTEM 失效
公开(公告)号：JP2001170445A
公开(公告)日：2001-06-26
申请号：JP35328999
申请日：1999-12-13
申请人： MITSUBISHI HEAVY IND LTD
发明人： IWABUCHI HIROYUKI , ISHIBASHI MASARU , UEDA YASUTOSHI , TOMIMATSU KAZUTAKA , KAGAMI MORIO
IPC分类号： B01D53/56 , B01D53/32 , B01D53/34 , B01D53/74
摘要： PROBLEM TO BE SOLVED: To provide a denitration method capable of simplifying the device and treatment after denitration by executing denitration treatment in the absence of a catalyst and capable of improving gas turbine operation efficiency by lessening pressure drop for low temperature combustion waste gas, especially gas turbine waste gas. SOLUTION: In the denitration method for the combustion waste gas containing nitrogen oxide, the denitration treatment of the waste gas is executed at a specified temperature region in the absence of the catalyst after injecting ammonia or methane to the waste gas. In the denitration system of the waste gas, an injecting means for supplying the ammonia or the methane is provided downstream of a gas turbine discharging waste gas by burning fuel gas, and a denitration device is provided just after the injecting means.

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