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1. 发明申请

US20050121068A1 PHOTOVOLTAIC DEVICES FABRICATED BY GROWTH FROM POROUS TEMPLATE 失效
标题翻译：由多孔模板生长制成的光伏器件
公开(公告)号：US20050121068A1
公开(公告)日：2005-06-09
申请号：US10443456
申请日：2003-05-21
申请人： Brian Sager , Martin Roscheisen , Klus Petritsch , Karl Pichler , Jacqueline Fidanza , Dong Yu
发明人： Brian Sager , Martin Roscheisen , Klus Petritsch , Karl Pichler , Jacqueline Fidanza , Dong Yu
IPC分类号： H01L20060101 , H01L31/00 , H01L31/0256 , H01L31/0352 , H01L31/042 , H01L31/18
CPC分类号： H01L51/4213 , H01L51/0036 , H01L51/0037 , H01L51/422 , H01L51/4253 , H01L51/447 , Y02E10/549 , Y02P70/521
摘要： Photovoltaic devices, such as solar cells, and methods for their manufacture are disclosed. A device may be characterized by an architecture where two more materials having different electron affinities are regularly arrayed such that their presence alternates within distances of between about 1 nm and about 100 nm. The materials are present in a matrix based on a porous template with an array of template pores. The porous template is formed by anodizing a layer of metal. A photovoltaic device may include such a porous template disposed between a base electrode and a transparent conducting electrode. A first charge-transfer material fills the template pores, A second (complementary) charge-transfer material fills additional space not occupied by the first charge-transfer material.
摘要翻译：公开了太阳能电池等光伏器件及其制造方法。器件的特征可以在于其中两个具有不同电子亲和力的材料被规则排列的结构，使得它们的存在在约1nm和约100nm之间的距离内交替。该材料基于具有模板孔阵列的多孔模板存在于基质中。通过阳极氧化一层金属形成多孔模板。光伏器件可以包括设置在基极和透明导电电极之间的这种多孔模板。第一电荷转移材料填充模板孔。第二（互补）电荷转移材料填充未被第一电荷转移材料占据的附加空间。

2. 发明授权

US06946597B2 Photovoltaic devices fabricated by growth from porous template 失效
标题翻译：通过从多孔模板生长制造的光伏器件
公开(公告)号：US06946597B2
公开(公告)日：2005-09-20
申请号：US10443456
申请日：2003-05-21
申请人： Brian M. Sager , Martin R. Roscheisen , Klus Petritsch , Karl Pichler , Jacqueline Fidanza , Dong Yu
发明人： Brian M. Sager , Martin R. Roscheisen , Klus Petritsch , Karl Pichler , Jacqueline Fidanza , Dong Yu
IPC分类号： H01L20060101 , H01L31/00 , H01L31/0256 , H01L31/0352 , H01L31/042 , H01L31/18
CPC分类号： H01L51/4213 , H01L51/0036 , H01L51/0037 , H01L51/422 , H01L51/4253 , H01L51/447 , Y02E10/549 , Y02P70/521
摘要： Photovoltaic devices, such as solar cells, and methods for their manufacture are disclosed. A device may be characterized by an architecture where two more materials having different electron affinities are regularly arrayed such that their presence alternates within distances of between about 1 nm and about 100 nm. The materials are present in a matrix based on a porous template with an array of template pores. The porous template is formed by anodizing a layer of metal. A photovoltaic device may include such a porous template disposed between a base electrode and a transparent conducting electrode. A first charge-transfer material fills the template pores, A second (complementary) charge-transfer material fills additional space not occupied by the first charge-transfer material.
摘要翻译：公开了太阳能电池等光伏器件及其制造方法。器件的特征可以在于其中两个具有不同电子亲和力的材料被规则排列的结构，使得它们的存在在约1nm和约100nm之间的距离内交替。该材料基于具有模板孔阵列的多孔模板存在于基质中。通过阳极氧化一层金属形成多孔模板。光伏器件可以包括设置在基极和透明导电电极之间的这种多孔模板。第一电荷转移材料填充模板孔。第二（互补）电荷转移材料填充未被第一电荷转移材料占据的附加空间。

3. 发明申请

US20070181177A9 Optoelectronic device and fabrication method 有权
标题翻译：光电器件及其制造方法
公开(公告)号：US20070181177A9
公开(公告)日：2007-08-09
申请号：US10290119
申请日：2002-11-05
申请人： Brian Sager , Martin Roscheisen , Klaus Petritsch , Greg Smestad , Jacqueline Fidanza , Gregory Miller , Dong Yu
发明人： Brian Sager , Martin Roscheisen , Klaus Petritsch , Greg Smestad , Jacqueline Fidanza , Gregory Miller , Dong Yu
IPC分类号： H01L31/00
CPC分类号： H01L51/4226 , H01L51/0034 , H01L51/0035 , H01L51/0036 , H01L51/0038 , H01L51/0052 , H01L51/0053 , H01L51/0064 , H01L51/0078 , H01L51/4253 , Y02E10/549 , Y02P70/521
摘要： Charge-splitting networks, optoelectronic devices, methods for making optoelectronic devices, power generation systems utilizing such devices and method for making charge-splitting networks are disclosed. An optoelectronic device may include a porous nano-architected (e.g., surfactant-templated) film having interconnected pores that are accessible from both the underlying and overlying layers. A pore-filling material substantially fills the pores. The interconnected pores have diameters of about 1-100 nm and are distributed in a substantially uniform fashion with neighboring pores separated by a distance of about 1-100 nm. The nano-architected porous film and the pore-filling, material have complementary charge-transfer properties with respect to each other, i.e., one is an electron-acceptor and the other is a hole-acceptor. The nano-architected porous, film may be formed on a substrate by a surfactant temptation technique such as evaporation-induced self-assembly. A solar power generation system may include an array of such optoelectronic devices in the form of photovoltaic cells with one or more cells in the array having one or more porous charge-splitting networks disposed between an electron-accepting electrode and a hole-accepting electrode.
摘要翻译：公开了电荷分解网络，光电子器件，制造光电器件的方法，利用这种器件的发电系统以及用于制造电荷分解网络的方法。光电子器件可以包括具有互连孔的多孔纳米结构（例如，表面活性剂模板化）膜，其可以从下面的层和上层两者接近。孔填充材料基本上填充孔。相互连通的孔具有大约1-100nm的直径，并以基本上均匀的方式分布，其中相邻的孔分开约1-100nm的距离。纳米结构的多孔膜和孔填充材料相对于彼此具有互补的电荷转移性质，即一个是电子受体，另一个是空穴受体。纳米结构的多孔膜可以通过表面活性剂诱导技术如蒸发诱导的自组装形成在基底上。太阳能发电系统可以包括光伏电池形式的这种光电子器件的阵列，阵列中的一个或多个电池具有设置在电子接受电极和空穴接受电极之间的一个或多个多孔电荷分解网络。

4. 发明申请

US20060174934A1 Optoelectronic device and frabrication method 审中-公开
标题翻译：光电器件及其制造方法
公开(公告)号：US20060174934A1
公开(公告)日：2006-08-10
申请号：US11375413
申请日：2006-03-13
申请人： Brian Sager , Martin Roscheisen , Klaus Petristsch , Greg Smestad , Jacqueline Fidanza , Gregory Miller , Dong Yu
发明人： Brian Sager , Martin Roscheisen , Klaus Petristsch , Greg Smestad , Jacqueline Fidanza , Gregory Miller , Dong Yu
IPC分类号： H01L31/042 , H01L31/00
CPC分类号： H01L51/4226 , H01L51/0034 , H01L51/0035 , H01L51/0036 , H01L51/0038 , H01L51/0052 , H01L51/0053 , H01L51/0064 , H01L51/0078 , H01L51/4253 , Y02E10/549 , Y02P70/521
摘要： Charge-splitting networks, optoelectronic devices, methods for making optoelectronic devices, power generation systems utilizing such devices and method for making charge-splitting networks are disclosed. An optoelectronic device may include a porous nano-architected (e.g., surfactant-templated) film having interconnected pores that are accessible from both the underlying and overlying layers. A pore-filling material substantially fills the pores. The interconnected pores have diameters of about 1-100 nm and are distributed in a substantially uniform fashion with neighboring pores separated by a distance of about 1-100 nm. The nano-architected porous film and the pore-filling material have complementary charge-transfer properties with respect to each other, i.e., one is an electron-acceptor and the other is a hole-acceptor. The nano-architected porous, film may be formed on a substrate by a surfactant temptation technique such as evaporation-induced self-assembly. A solar power generation system may include an array of such optoelectronic devices in the form of photovoltaic cells with one or more cells in the array having one or more porous charge-splitting networks disposed between an electron-accepting electrode and a hole-accepting electrode.
摘要翻译：公开了电荷分解网络，光电子器件，制造光电器件的方法，利用这种器件的发电系统以及用于制造电荷分解网络的方法。光电子器件可以包括具有互连孔的多孔纳米结构（例如，表面活性剂模板化）膜，其可以从下面的层和上层两者接近。孔填充材料基本上填充孔。相互连通的孔具有大约1-100nm的直径，并以基本上均匀的方式分布，其中相邻的孔分开约1-100nm的距离。纳米构造的多孔膜和孔隙填充材料相互之间具有互补的电荷转移性质，即一个是电子受体，另一个是空穴受体。纳米结构的多孔膜可以通过表面活性剂诱导技术如蒸发诱导的自组装形成在基底上。太阳能发电系统可以包括光伏电池形式的这种光电子器件的阵列，阵列中的一个或多个电池具有设置在电子接受电极和空穴接受电极之间的一个或多个多孔电荷分解网络。

5. 发明申请

US20050183767A1 Solution-based fabrication of photovoltaic cell 失效
标题翻译：光伏电池基于解决方案的制造
公开(公告)号：US20050183767A1
公开(公告)日：2005-08-25
申请号：US10782017
申请日：2004-02-19
申请人： Dong Yu , Jacqueline Fidanza , Martin Roscheisen , Brian Sager
发明人： Dong Yu , Jacqueline Fidanza , Martin Roscheisen , Brian Sager
IPC分类号： A61K9/16 , A61K9/50 , B82B3/00 , H01L21/00 , H01L31/00 , H01L31/0256 , H01L31/0392 , H01L31/18
CPC分类号： H01L31/06 , B82Y5/00 , B82Y10/00 , B82Y30/00 , C23C18/1204 , C23C18/1266 , C23C18/1295 , H01L31/0322 , H01L31/0749 , H01L31/18 , Y02E10/541 , Y02P70/521
摘要： An ink for forming CIGS photovoltaic cell active layers is disclosed along with methods for making the ink, methods for making the active layers and a solar cell made with the active layer. The ink contains a mixture of nanoparticles of elements of groups IB, IIIA and (optionally) VIA. The particles are in a desired particle size range of between about 1 nm and about 500 nm in diameter, where a majority of the mass of the particles comprises particles ranging in size from no more than about 40% above or below an average particle size or, if the average particle size is less than about 5 nanometers, from no more than about 2 nanometers above or below the average particle size. The use of such ink avoids the need to expose the material to an H2Se gas during the construction of a photovoltaic cell and allows more uniform melting during film annealing, more uniform intermixing of nanoparticles, and allows higher quality absorber films to be formed.
摘要翻译：公开了一种用于形成CIGS光伏电池有源层的墨水以及用于制造墨水的方法，制备活性层的方法和由活性层制成的太阳能电池。油墨含有IB，IIIA和（任选地）VIA组分的纳米颗粒的混合物。颗粒的直径在约1nm至约500nm之间的所需粒度范围，其中大部分颗粒的质量包括尺寸不超过平均粒度的约40％或以下的颗粒，或如果平均粒度小于约5纳米，高于或低于平均粒度的不超过约2纳米。使用这种墨水避免了在构建光伏电池期间将材料暴露于H 2 S 2 Se气体，并且允许在膜退火期间更均匀的熔融，更均匀的纳米颗粒的混合，并且允许更高的要形成的质量吸收膜。

6. 发明授权

US08366973B2 Solution-based fabrication of photovoltaic cell 失效
标题翻译：光伏电池基于解决方案的制造
公开(公告)号：US08366973B2
公开(公告)日：2013-02-05
申请号：US11933357
申请日：2007-10-31
申请人： Dong Yu , Jacqueline Fidanza , Brian M. Sager
发明人： Dong Yu , Jacqueline Fidanza , Brian M. Sager
IPC分类号： H01B1/12
CPC分类号： H01L31/06 , B82Y5/00 , B82Y10/00 , B82Y30/00 , C23C18/1204 , C23C18/1266 , C23C18/1295 , H01L31/0322 , H01L31/0749 , H01L31/18 , Y02E10/541 , Y02P70/521
摘要： An ink for forming CIGS photovoltaic cell active layers is disclosed along with methods for making the ink, methods for making the active layers and a solar cell made with the active layer. The ink contains a mixture of nanoparticles of elements of groups IB, IIIA and (optionally) VIA. The particles are in a desired particle size range of between about 1 nm and about 500 nm in diameter, where a majority of the mass of the particles comprises particles ranging in size from no more than about 40% above or below an average particle size or, if the average particle size is less than about 5 nanometers, from no more than about 2 nanometers above or below the average particle size. The use of such ink avoids the need to expose the material to an H2Se gas during the construction of a photovoltaic cell and allows more uniform melting during film annealing, more uniform intermixing of nanoparticles, and allows higher quality absorber films to be formed.
摘要翻译：公开了一种用于形成CIGS光伏电池有源层的墨水以及用于制备墨水的方法，制备活性层的方法和由活性层制成的太阳能电池。油墨含有IB，IIIA和（任选地）VIA组分的纳米颗粒的混合物。颗粒的直径在约1nm至约500nm之间的所需粒度范围，其中大部分颗粒的质量包括尺寸不超过平均粒度的约40％或以下的颗粒，或如果平均粒度小于约5纳米，高于或低于平均粒度的不超过约2纳米。使用这种墨水避免了在构建光伏电池期间将材料暴露于H 2 Se气体的需要，并且允许在膜退火期间更均匀的熔融，更均匀的纳米颗粒的混合，并且允许形成更高质量的吸收膜。

7. 发明授权

US08206616B2 Solution-based fabrication of photovoltaic cell 失效
公开(公告)号：US08206616B2
公开(公告)日：2012-06-26
申请号：US11933285
申请日：2007-10-31
申请人： Dong Yu , Jacqueline Fidanza , Brian M. Sager
发明人： Dong Yu , Jacqueline Fidanza , Brian M. Sager
IPC分类号： H01B1/12 , B05D7/00
CPC分类号： H01L31/06 , B82Y5/00 , B82Y10/00 , B82Y30/00 , C23C18/1204 , C23C18/1266 , C23C18/1295 , H01L31/0322 , H01L31/0749 , H01L31/18 , Y02E10/541 , Y02P70/521
摘要： An ink for forming CIGS photovoltaic cell active layers is disclosed along with methods for making the ink, methods for making the active layers and a solar cell made with the active layer. The ink contains a mixture of nanoparticles of elements of groups IB, IIIA and (optionally) VIA. The particles are in a desired particle size range of between about 1 nm and about 500 nm in diameter, where a majority of the mass of the particles comprises particles ranging in size from no more than about 40% above or below an average particle size or, if the average particle size is less than about 5 nanometers, from no more than about 2 nanometers above or below the average particle size. The use of such ink avoids the need to expose the material to an H2Se gas during the construction of a photovoltaic cell and allows more uniform melting during film annealing, more uniform intermixing of nanoparticles, and allows higher quality absorber films to be formed.

8. 发明授权

US08168089B2 Solution-based fabrication of photovoltaic cell 失效
公开(公告)号：US08168089B2
公开(公告)日：2012-05-01
申请号：US11933322
申请日：2007-10-31
申请人： Dong Yu , Jacqueline Fidanza , Brian M. Sager
发明人： Dong Yu , Jacqueline Fidanza , Brian M. Sager
IPC分类号： H01B1/02 , H01L31/04 , B05D7/00
CPC分类号： H01L31/06 , B82Y5/00 , B82Y10/00 , B82Y30/00 , C23C18/1204 , C23C18/1266 , C23C18/1295 , H01L31/0322 , H01L31/0749 , H01L31/18 , Y02E10/541 , Y02P70/521
摘要： An ink for forming CIGS photovoltaic cell active layers is disclosed along with methods for making the ink, methods for making the active layers and a solar cell made with the active layer. The ink contains a mixture of nanoparticles of elements of groups IB, IIIA and (optionally) VIA. The particles are in a desired particle size range of between about 1 nm and about 500 nm in diameter, where a majority of the mass of the particles comprises particles ranging in size from no more than about 40% above or below an average particle size or, if the average particle size is less than about 5 nanometers, from no more than about 2 nanometers above or below the average particle size. The use of such ink avoids the need to expose the material to an H2Se gas during the construction of a photovoltaic cell and allows more uniform melting during film annealing, more uniform intermixing of nanoparticles, and allows higher quality absorber films to be formed.

9. 发明申请

US20080135099A1 SOLUTION-BASED FABRICATION OF PHOTOVOLTAIC CELL 审中-公开
公开(公告)号：US20080135099A1
公开(公告)日：2008-06-12
申请号：US11933407
申请日：2007-10-31
申请人： Dong Yu , Jacqueline Fidanza , Brian M. Sager
发明人： Dong Yu , Jacqueline Fidanza , Brian M. Sager
IPC分类号： H01L31/0216
CPC分类号： H01L31/06 , B82Y5/00 , B82Y10/00 , B82Y30/00 , C23C18/1204 , C23C18/1266 , C23C18/1295 , H01L31/0322 , H01L31/0749 , H01L31/18 , Y02E10/541 , Y02P70/521
摘要： An ink for forming CIGS photovoltaic cell active layers is disclosed along with methods for making the ink, methods for making the active layers and a solar cell made with the active layer. The ink contains a mixture of nanoparticles of elements of groups IB, IIIA and (optionally) VIA. The particles are in a desired particle size range of between about 1 nm and about 500 nm in diameter, where a majority of the mass of the particles comprises particles ranging in size from no more than about 40% above or below an average particle size or, if the average particle size is less than about 5 nanometers, from no more than about 2 nanometers above or below the average particle size. The use of such ink avoids the need to expose the material to an H2Se gas during the construction of a photovoltaic cell and allows more uniform melting during film annealing, more uniform intermixing of nanoparticles, and allows higher quality absorber films to be formed.

10. 发明授权

US08088309B2 Solution-based fabrication of photovoltaic cell 有权
标题翻译：光伏电池基于解决方案的制造
公开(公告)号：US08088309B2
公开(公告)日：2012-01-03
申请号：US11933400
申请日：2007-10-31
申请人： Dong Yu , Jacqueline Fidanza , Brian M. Sager
发明人： Dong Yu , Jacqueline Fidanza , Brian M. Sager
IPC分类号： H01B1/22 , B05D5/12
CPC分类号： H01L31/06 , B82Y5/00 , B82Y10/00 , B82Y30/00 , C23C18/1204 , C23C18/1266 , C23C18/1295 , H01L31/0322 , H01L31/0749 , H01L31/18 , Y02E10/541 , Y02P70/521
摘要： An ink for forming CIGS photovoltaic cell active layers is disclosed along with methods for making the ink, methods for making the active layers and a solar cell made with the active layer. The ink contains a mixture of nanoparticles of elements of groups IB, IIIA and (optionally) VIA. The particles are in a desired particle size range of between about 1 nm and about 500 nm in diameter, where a majority of the mass of the particles comprises particles ranging in size from no more than about 40% above or below an average particle size or, if the average particle size is less than about 5 nanometers, from no more than about 2 nanometers above or below the average particle size. The use of such ink avoids the need to expose the material to an H2Se gas during the construction of a photovoltaic cell and allows more uniform melting during film annealing, more uniform intermixing of nanoparticles, and allows higher quality absorber films to be formed.
摘要翻译：公开了一种用于形成CIGS光伏电池有源层的墨水以及用于制备墨水的方法，制备活性层的方法和由活性层制成的太阳能电池。油墨含有IB，IIIA和（任选地）VIA组分的纳米颗粒的混合物。颗粒的直径在约1nm至约500nm之间的所需粒度范围，其中大部分颗粒的质量包括尺寸不超过平均粒度的约40％或以下的颗粒，或如果平均粒度小于约5纳米，高于或低于平均粒度的不超过约2纳米。使用这种墨水避免了在构建光伏电池期间将材料暴露于H 2 Se气体的需要，并且允许在膜退火期间更均匀的熔融，更均匀的纳米颗粒的混合，并且允许形成更高质量的吸收膜。

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