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    • 9. 发明授权
    • Solution-based fabrication of photovoltaic cell
    • 光伏电池基于解决方案的制造
    • US08366973B2
    • 2013-02-05
    • US11933357
    • 2007-10-31
    • Dong YuJacqueline FidanzaBrian M. Sager
    • Dong YuJacqueline FidanzaBrian M. Sager
    • H01B1/12
    • H01L31/06B82Y5/00B82Y10/00B82Y30/00C23C18/1204C23C18/1266C23C18/1295H01L31/0322H01L31/0749H01L31/18Y02E10/541Y02P70/521
    • An ink for forming CIGS photovoltaic cell active layers is disclosed along with methods for making the ink, methods for making the active layers and a solar cell made with the active layer. The ink contains a mixture of nanoparticles of elements of groups IB, IIIA and (optionally) VIA. The particles are in a desired particle size range of between about 1 nm and about 500 nm in diameter, where a majority of the mass of the particles comprises particles ranging in size from no more than about 40% above or below an average particle size or, if the average particle size is less than about 5 nanometers, from no more than about 2 nanometers above or below the average particle size. The use of such ink avoids the need to expose the material to an H2Se gas during the construction of a photovoltaic cell and allows more uniform melting during film annealing, more uniform intermixing of nanoparticles, and allows higher quality absorber films to be formed.
    • 公开了一种用于形成CIGS光伏电池有源层的墨水以及用于制备墨水的方法,制备活性层的方法和由活性层制成的太阳能电池。 油墨含有IB,IIIA和(任选地)VIA组分的纳米颗粒的混合物。 颗粒的直径在约1nm至约500nm之间的所需粒度范围,其中大部分颗粒的质量包括尺寸不超过平均粒度的约40%或以下的颗粒,或 如果平均粒度小于约5纳米,高于或低于平均粒度的不超过约2纳米。 使用这种墨水避免了在构建光伏电池期间将材料暴露于H 2 Se气体的需要,并且允许在膜退火期间更均匀的熔融,更均匀的纳米颗粒的混合,并且允许形成更高质量的吸收膜。