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    • 1. 发明授权
    • Atmospheres for heat treating non-ferrous metals and alloys
    • 用于热处理有色金属和合金的气氛
    • US5298090A
    • 1994-03-29
    • US995617
    • 1992-12-22
    • Diwakar GargBrian B. BonnerDonald P. EichelbergerKerry R. Berger
    • Diwakar GargBrian B. BonnerDonald P. EichelbergerKerry R. Berger
    • C21D1/76F27D7/06F27D23/00C21D1/00
    • F27D7/06C21D1/763
    • A process for producing low-cost atmospheres suitable for annealing, brazing, and sintering non-ferrous metals and alloys from non-cryogenically produced nitrogen containing up to 5%, residual oxygen is disclosed. According to the process, suitable atmospheres are produced by 1) pre-heating the non-cryogenically produced nitrogen stream containing residual oxygen to a desired temperature, 2) mixing it with more than a stoichiometric amount a hydrocarbon gas, 3) passing it through a reactor packed with a platinum group of metal catalyst to reduce the residual oxygen to very low levels and convert it to a mixture of moisture and carbon dioxide, and 4) using the reactor effluent stream for annealing, brazing, and sintering non-ferrous metals and alloys in a furnace. The key features of the disclosed process include 1) pre-heating the non-cryogenically produced nitrogen containing residual oxygen to a certain minimum temperature, 2) adding more than a stoichiometric amount of a hydrocarbon gas to the pre-heated nitrogen stream, and 3) using a platinum group of metal catalyst to initiate and sustain the reaction between oxygen and the hydrocarbon gas.
    • 公开了一种用于生产低成本气氛的方法,该方法适用于从含低至5%残留氧的非低温法生产的氮中退火,钎焊和烧结有色金属和合金。 根据该方法,通过以下方式产生合适的气氛:1)将含有残余氧气的非低温生成氮气流预热至所需温度,2)将其与多于化学计量的烃气体混合,3)将其通过 反应器用铂族金属催化剂填充,将残余氧气降低至非常低的水平,并将其转化为水分和二氧化碳的混合物,以及4)使用反应器流出物流进行退火,钎焊和烧结有色金属, 合金在炉中。 所公开的方法的主要特征包括:1)将非低温法生产的含氮残留氧预加热到一定的最低温度; 2)向预热的氮气流中加入多于化学计量的烃类气体; 3) )使用铂族金属催化剂引发和维持氧气和烃气体之间的反应。
    • 2. 发明授权
    • Heat treating atmospheres
    • 热处理环境
    • US5417774A
    • 1995-05-23
    • US995624
    • 1992-12-22
    • Diwakar GargBrian B. BonnerDonald P. EichelbergerKerry R. Berger
    • Diwakar GargBrian B. BonnerDonald P. EichelbergerKerry R. Berger
    • B22F3/10B23K35/38C21D1/76C21D1/00C21D9/00
    • B22F3/1007C21D1/763B23K35/38
    • A process for producing low-cost atmospheres suitable for annealing, brazing, and sintering ferrous and non-ferrous metals and alloys, neutral hardening low, medium, and high carbon steels, sintering ceramic powders, and sealing glass to metal from non-cryogenically produced nitrogen containing up to 5% residual oxygen is disclosed. According to the process, suitable atmospheres are produced by 1) pre-heating the non-cryogenically produced nitrogen stream containing residual oxygen to a desired temperature, 2) mixing it with more than a stoichiometric amount a hydrocarbon gas, 3) passing it through a reactor packed with a platinum group of metal catalyst to reduce the residual oxygen to very low levels and convert it to a mixture of moisture and carbon dioxide, and 4) introducing the reactor effluent stream into the heating zone of a furnace and converting in-situ a portion of both moisture and carbon dioxide with a hydrocarbon gas to a mixture of carbon monoxide and hydrogen. The key features of the disclosed process include 1) pre-heating the non-cryogenically produced nitrogen containing residual oxygen to a certain minimum temperature, 2) adding more than a stoichiometric amount of a hydrocarbon gas to the pre-heated nitrogen stream, 3) using a platinum group of metal catalyst to initiate and sustain the reaction between oxygen and the hydrocarbon gas, and 4) converting in-situ a portion of both moisture and carbon dioxide with a hydrocarbon gas to a mixture of carbon monoxide and hydrogen in the heating zone of a furnace.
    • 一种生产低成本气氛的方法,适用于退火,钎焊和烧结黑色和有色金属和合金,中性硬化低,中,高碳钢,烧结陶瓷粉末,以及将玻璃与非低温生产密封在一起 公开了含有高达5%残余氧的氮。 根据该方法,通过以下方式产生合适的气氛:1)将含有残余氧气的非低温生成氮气流预热至所需温度,2)将其与多于化学计量的烃气体混合,3)将其通过 用铂族金属催化剂填充的反应器将残余氧气减少至非常低的水平,并将其转化为水分和二氧化碳的混合物,以及4)将反应器流出物流引入炉的加热区并原位转化 一部分水分和二氧化碳与烃气体混合到一氧化碳和氢气中。 所公开的方法的主要特征包括:1)将非低温法生产的含氮残留氧预加热到一定的最低温度; 2)向预热的氮气流中加入多于化学计量的烃气体; 3) 使用铂族金属催化剂引发和维持氧气和烃类气体之间的反应,以及4)在加热中将一部分水分和二氧化碳与烃气体原位转化为一氧化碳和氢气的混合物 炉区。
    • 4. 发明授权
    • Moisture-free atmosphere brazing of ferrous metals
    • 黑色金属无水环境钎焊
    • US5531372A
    • 1996-07-02
    • US298004
    • 1994-08-30
    • Brian B. BonnerDiwakar GargKerry R. Berger
    • Brian B. BonnerDiwakar GargKerry R. Berger
    • B23K1/00B23K1/008B23K1/19B23K31/02B23K35/38
    • B23K35/383B23K1/008B23K1/00
    • The present invention discloses a novel, moisture-free atmosphere for brazing carbon steels that provides good braze flow and brazed joint quality with minimum or no formation of soot on brazed joints. According to the present invention, carbon steels are brazed in continuous furnaces using a moisture-free atmosphere containing a mixture of three gases including nitrogen, hydrogen, and carbon dioxide. The key features of the invention involve (1) formation of moisture, which is needed to facilitate braze flow and to minimize formation of soot on brazed joints, in-situ in the heating zone of the furnace by the reaction between hydrogen and carbon dioxide and (2) reduction in the overall amount of a reducing gas required for brazing carbon steels by keeping moisture out of the cooling zone. The use of a moisture-free three gas atmosphere has been unexpectedly found to (1) eliminate the need of an expensive and difficult to control external humidification system, (2) provide flexibility in adjusting moisture content of the atmosphere in the heating zone of the furnace simply by adjusting the flow rate of hydrogen or carbon dioxide or both, and (3) facilitate rapid conditioning of the furnace by keeping moisture out of the cooling zone. The moisture-free atmosphere has also been unexpectedly found to provide good braze flow, fillet formation, and brazed joint quality while minimizing or eliminating formation of soot on brazed joints.
    • 本发明公开了一种用于钎焊碳钢的新型无水气氛,其在钎焊接头上具有最少或不形成烟灰的情况下提供良好的钎焊流动和钎焊接头质量。 根据本发明,使用含有三种气体(包括氮气,氢气和二氧化碳)的混合物的无湿气氛将碳钢钎焊在连续炉中。 本发明的主要特征包括(1)通过氢气和二氧化碳之间的反应在炉的加热区中原位形成水分,其是促进钎焊流动并且最小化钎焊接头上的烟灰形成所需要的;以及 (2)通过将水分从冷却区域中除去而使碳钢钎焊所需的还原气体总量减少。 已经意外地发现使用无湿气的三种气体气氛(1)消除了昂贵且难以控制的外部加湿系统的需要,(2)提供调节加热区中的气氛中的含水量的灵活性 炉子简单地通过调节氢气或二氧化碳或两者的流量,和(3)通过将水分从冷却区域中除去来促进炉子的快速调节。 也意外地发现无湿度的气氛提供良好的钎焊流动,圆角形成和钎焊接头质量,同时最小化或消除钎焊接头上的烟灰形成。