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    • 2. 发明授权
    • Method for isomerizing wax to lube base oils
    • 将蜡异构化成润滑油基础油的方法
    • US5059299A
    • 1991-10-22
    • US522275
    • 1990-05-11
    • Ian A. CodyJames D. BellTheodore H. WestWilliam A. WachterBiddanda U. Achia
    • Ian A. CodyJames D. BellTheodore H. WestWilliam A. WachterBiddanda U. Achia
    • C10G67/04
    • C10G67/04
    • Slack waxes and synthetic wax are isomerized and processed into high viscosity index and very low pour point lube base stock oils and blending stocks by the process comprising the steps of hydrotreating the wax, if necessary, to remove heteroatom and polynuclear aromatic compounds and/or deoiling the wax, if necessary, to an oil content between about 5-20% oil, isomerizing the wax over a Group VI-Group VIII on halogenated refractory metal oxide support catalyst, said isomerization being conducted to a level of conversion such that .about.40% and less unconverted wax remains in the 330.degree. C..sup.+, preferably the 370.degree. C..sup.+ fraction sent to the dewaxer. The total isomerate from the isomerization unit is fractionated into a lube oil fraction boiling at 330.degree. C..sup.+, preferably 370.degree.p9 C..sup.+. This oil fraction is solvent dewaxed preferably using MEK/MIBK at 20/80 ratio and unconverted wax is recycled to the isomerization unit. Operating in this manner permits one to obtain isomerate oil of very high VI (in excess of 130) possessing low pours (-21.degree. C., preferably -24.degree. C., most preferably -27.degree. C.).
    • 松散蜡和合成蜡被异构化并加工成高粘度指数和极低倾点润滑油基础油和通过包括以下步骤的混合原料的方法:如果需要,加氢处理蜡以除去杂原子和多核芳族化合物和/或脱油 如果需要,蜡可以含有约5-20%的油,在卤代难熔金属氧化物载体催化剂上使VI族VIII族上的蜡异构化,所述异构化进行到转化水平,使得DIFFERENCE 40% 并且较少未转化的蜡保留在330℃+,优选370℃+馏分送至脱蜡机。 来自异构化单元的总异构体被分馏成沸点在330℃+,优选370°p9℃+的润滑油馏分。 该油馏分优选使用20/80比例的MEK / MIBK进行溶剂脱蜡,未转化的蜡再循环至异构化单元。 以这种方式操作,可以获得具有低倾点(-21℃,优选-24℃,最优选-27℃)的非常高VI(超过130)的异构油。
    • 3. 发明授权
    • Method for isomerizing wax to lube base oils using a sized isomerization
catalyst
    • 使用大小异构化催化剂将蜡异构化成润滑油基础油的方法
    • US4937399A
    • 1990-06-26
    • US283680
    • 1988-12-13
    • William A. WachterIan A. CodyGlen P. Hamner, deceasedBiddanda U. Achia
    • William A. WachterIan A. CodyGlen P. Hamner, deceasedBiddanda U. Achia
    • B01J23/40B01J37/18B01J37/26C10G45/62
    • B01J37/26B01J23/40B01J37/18C10G2400/10
    • The present invention is directed to a process for the catalytic isomerization of waxes to liquid products, particularly to the production of high yields of liquid products boiling in the 370.degree. C..sup.+ range suitable for use as lube oil base stocks or blending stocks, said process employing as the catalyst a material made by depositing a hydrogenation metal component on a refractory metal oxide base, preferably alumina, fluoriding said metal loaded base using aqueous HF and subsequently crushing the fluorided metal loaded base to produce a sized material of 1/32 inch and less its largest cross-sectional dimension. Alternately the catalyst can be made by depositing a hydrogenation metal component on a refractory metal oxide base of 1/32 inch and less across its largest cross-sectional dimension and subsequently fluoriding said sized material using aqueous HF. In either case the catalyst is activated before being used by heating in a hydrogen atmosphere to from 350.degree. C. to 500.degree. C. for from 1 to 48 hours or more.
    • 本发明涉及一种将蜡催化异构化成液体产品的方法,特别是在适用于润滑油基础油或混合原料的370℃+范围内沸腾的高产量液体产物的生产,所述方法 该方法使用通过在难熔金属氧化物基底(优选氧化铝)上沉积氢化金属组分制备的材料,使用HF水溶液氟化所述金属负载的基底,随后粉碎载有氟化金属的基底以产生1/32英寸的尺寸的材料 并且减小其最大横截面尺寸。 或者,催化剂可以通过在其最大横截面尺寸上在1/32英寸以下的难熔金属氧化物基底上沉积加氢金属组分并随后使用HF水溶液氟化所述尺寸的材料来制备。 在任一情况下,催化剂在通过在氢气气氛中加热至350℃至500℃使用1至48小时或更长时间之前被活化。