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    • 1. 发明申请
    • AN ORIENTED,SEMI-CRYSTALLINE POLYMER PRODUCT AND METHOD AND APPARATUS FOR PRODUCING SUCH PRODUCT
    • 面向对象的半结晶聚合物产品及其生产方法和装置
    • WO1980000550A1
    • 1980-04-03
    • PCT/US1979000637
    • 1979-08-17
    • BETHLEHEM STEEL CORP
    • BETHLEHEM STEEL CORPAUSTEN AHUMPHRIES D
    • B32B05/16
    • F16L9/12B29C47/0004B29C47/0023
    • A thick-walled, seamless, rigid non-porous conduit (Y) having a substantially uniform wall thikkness which is not less than about 0.5 percent of the outside diameter consisting essentially of an oriented crystalline thermoplastic polymer characterized by a structure comprised of radially compressed discrete, platelet-like spherulitic crystalline aggregates (A!) and having a combination of good ultimate tensile strength and low temperature tensile impact strength. The conduit is fabricated by solid state hydrostatic extrusion of a substantially non-oriented semi-crystalline thermoplastic polymer preform (X) which may contain up to about60 weight percent filler. The polymer is substantially simultaneously elongated in both circumferential and axial directions by compressive forces with the circumferential elongation being at least 100 percent. The apparatus used to produce the product is a hydrostatic extrusion press which includes an annular orifice in which the thermoplastic polymer is elongated substantially simultaneously circumferentially and axially with the circumferential elongation being at least 100 percent. Means for maintaining the rigidity of tooling and the hydrostatic extrusion fluid pressure while providing a film of the fluid on the preform for lubricity are provided in the apparatus. A sheet (F) substantially uniform in thickness and having substantially the microstructure and properties of the conduit and excellent drawability may be made from the conduit by slitting and heat deformation. Articles of manufacture may be made by solid state deformation processing of the conduit or the sheet, such as vacuum drawing.
    • 厚壁,无缝,刚性的无孔导管(Y)具有基本均匀的壁膨胀度,其不小于外径的约0.5%,其基本上由定向结晶热塑性聚合物组成,其特征在于包括径向压缩的离散 ,血小板样球状晶体聚集体(A!),并且具有良好的极限拉伸强度和低温拉伸冲击强度的组合。 导管通过基本上无取向的半结晶热塑性聚合物预制件(X)的固态静压挤出制造,其可以含有高达约60重量%的填料。 聚合物通过压缩力在周向和轴向方向上基本上同时伸长,圆周伸长率至少为100%。 用于生产产品的装置是一种静液压挤压机,其包括环形孔口,其中热塑性聚合物基本上同时沿周向和轴向延伸,周向延伸率至少为100%。 在设备中提供了用于在为预制件提供流体的薄膜以提供润滑性的同时保持模具刚性和静压挤出流体压力的手段。 厚度基本均匀且具有基本上导管的微结构和性质的片材(F),并且可以通过切割和热变形从导管获得优异的可拉伸性。 可以通过导管或片材的固态变形处理(例如真空拉拔)来制造制品。