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1. 发明申请

WO2012150549A1 DISULFIDE DYES 审中-公开
标题翻译： DISIFFIDE DYES
公开(公告)号：WO2012150549A1
公开(公告)日：2012-11-08
申请号：PCT/IB2012/052178
申请日：2012-05-02
申请人： BASF SE , MARQUAIS-BIENEWALD, Sophie , CREMER, Christian , FRÖHLING, Beate , BASF (CHINA) COMPANY LIMITED
发明人： MARQUAIS-BIENEWALD, Sophie , CREMER, Christian , FRÖHLING, Beate
IPC分类号： C09B49/06 , A61K8/49 , A61K8/46 , C09B49/00
CPC分类号： A61K8/4986 , A61K8/49 , A61K2800/884 , A61Q5/04 , A61Q5/065 , A61Q5/10 , C09B26/04 , C09B29/081 , C09B29/3691 , C09B43/18 , C09B43/44 , C09B44/10 , C09B49/00 , C09B62/78 , C09D15/00
摘要： Disclosed are compounds of formula (1) or formula (2). The compounds are useful for the dyeing of organic materials, such as keratin fibers, wool, leather, silk, cellulose or polyamides, especially keratin- containing fibers, cotton or nylon, and preferably hair, more preferably human hair. (1) (2).
摘要翻译：公开了式（1）或式（2）的化合物。这些化合物可用于染色有机材料，例如角蛋白纤维，羊毛，皮革，丝绸，纤维素或聚酰胺，特别是含角蛋白纤维，棉或尼龙，优选毛发，更优选人发。（1）（2）。

2. 发明申请

WO2012022709A1 DISULFIDE OR THIOL POLYMERIC HAIR DYES 审中-公开
标题翻译： DISOLFIDE或THIOL POLYMERIC HAIR DYES
公开(公告)号：WO2012022709A1
公开(公告)日：2012-02-23
申请号：PCT/EP2011/064022
申请日：2011-08-15
申请人： BASF SE , MARQUAIS-BIENEWALD, Sophie , CREMER, Christian , FRÖHLING, Beate
发明人： MARQUAIS-BIENEWALD, Sophie , CREMER, Christian , FRÖHLING, Beate
IPC分类号： C09B62/78 , C09B69/10 , A61Q5/10
CPC分类号： C09B67/0063 , A61K8/817 , A61K8/84 , A61K8/91 , A61Q5/10 , C09B62/78 , C09B69/101 , C09B69/106
摘要： The present invention relates to the reaction product of (A) a polymeric backbone with (B) A chromophore; and with (C) at least one sulfide containing compound. Very good dyeing results are obtained with this new technology.
摘要翻译：本发明涉及（A）聚合物主链与（B）A发色团的反应产物; 和（C）至少一种含硫化物的化合物。使用这种新技术可以获得非常好的染色结果。

3. 发明申请

WO2009090125A1 POLYMERIC HAIR DYES 审中-公开
标题翻译：聚合物染发剂
公开(公告)号：WO2009090125A1
公开(公告)日：2009-07-23
申请号：PCT/EP2009/050098
申请日：2009-01-07
申请人： CIBA HOLDING INC. , MARQUAIS-BIENEWALD, Sophie , CREMER, Christian , WALLQUIST, Olof , FRÖHLING, Beate
发明人： MARQUAIS-BIENEWALD, Sophie , CREMER, Christian , WALLQUIST, Olof , FRÖHLING, Beate
IPC分类号： C09B69/10 , A61K8/72 , A61Q5/00
CPC分类号： C09B69/106 , A61K8/8152 , A61K8/817 , A61K8/84 , A61K2800/4322 , A61Q5/065 , C09B69/107
摘要： Disclosed are olymeric dye of formula (1a), (1b), (1c), A and B, independently from each other represent a polymer backbone; X 1 and X 2 independently from each other are a linkage group selected from -C 1 -C 30 alkylene- or -C 2 -C 12 alkenylene-, which is interrupted and/or terminated at one or both ends by one or more than one -S-, -N-, -N=-, -N(R 5 )-, -S(O)-, -SO 2 -, -(CH 2 CH 2 -O) 1-5 -, -(CH 2 CH 2 CH 2 -O) 1-5 -, -C(O)-, -C(O)O-, -OCO-, (II), -CON(R 1 )-, -C(NR 1 R 2 ) 2 -, -(R 1 )NC(O)-, -C(S)R 1 -; or an optionally substituted, saturated or unsaturated, fused or non-fused aromatic or nonaromatic (heterocyclic) bivalent radical optionally comprising at least one heteroatom; a saturated or unsaturated, fused or non-fused aromatic or nonaromatic bivalent radical comprising at least one heteroatom, which is optionally substituted by C 1 -C 30 alkyl, C 1 -C 30 alkoxy, C 2 -C 12 alkenyl, C 5 -C 10 aryl, C 5 -C 10 cycloalkyl, C 1 -C 10 alkyl(C 5 -C 10 arylene), hydroxy or halogen; R 1 and R 2 independently from each other are hydrogen; unsubstituted or substituted, straight-chain or branched, monocyclic or polycyclic, interrupted or uninterrupted C 1 - C 14 alkyl; C 2 -C 14 alkenyl; C 6 -C 10 aryl; C 6 -C 10 aryl-C 1 -C 10 alkyl; or C 5 -C 10 alkyl(C 5 -C 10 aryl); Y 1 and Y 2 independently from each other are a residue of an organic dye; or hydrogen; wherein at least one of Y 1 and Y 2 is a residue of an organic dye; An 1 , An 2 and An 3 , independently from each other are an anion; a and b independently from each other are a number from 1 to 3; m is a number from 0 to 5000; n is a number from 0 to 5000; and p is a number from 1 to 5000; wherein the sum of m + n + p ≥ 3. The dyes are distinguished by their depth of shade and their good fastness properties to washing, such as, for example, fastness to light, shampooing and rubbing.
摘要翻译：公开了式（1a），（1b），（1c），A和B的聚合染料，彼此独立地表示聚合物主链; X 1和X 2彼此独立地是选自-C 1 -C 30亚烷基或-C 2 -C 12亚烯基的连接基团，其在一个或两个末端被一个或多个-S-，-N- ，-N = - ， - N（R 5） - ， - S（O） - ， - SO 2 - ， - （CH 2 CH 2 -O）1-5 - ， - （CH 2 CH 2 CH 2 -O）） - ， - （R）NC（O） - ， - C（O）O-， - OCO-，（II） - ; 或任选包含至少一个杂原子的任选取代的，饱和或不饱和的稠合或非稠合芳族或非芳族（杂环）二价基团; 饱和或不饱和的，稠合或非稠合的芳族或非芳族二价基团，其包含至少一个杂原子，其任选被C 1 -C 30烷基，C 1 -C 30烷氧基，C 2 -C 12链烯基，C 5 -C 10芳基，C 5 -C 10环烷基，C 1 -C 10烷基（ C5-C10亚芳基），羟基或卤素; R1和R2彼此独立地是氢; 未取代或取代的直链或支链，单环或多环，中断或不间断C 1 -C 14烷基; C2-C14alkenyl; C6-C10芳基; C6-C10芳基，C1-C10烷基; 或C 5 -C 10烷基（C 5 -C 10芳基）; Y1和Y2彼此独立地是有机染料的残基; 或氢; 其中Y 1和Y 2中的至少一个是有机染料的残基; An1，An2和An3彼此独立地为阴离子; a和b彼此独立，为1-3; m是从0到5000的数字; n是从0到5000的数字; p是从1到5000的数字; 其中m + n + p = 3的总和。这些染料的特征在于它们的色调深度和它们对洗涤的良好牢度性质，例如，耐光牢度，洗发剂和摩擦性。

4. 发明申请

WO2008009579A1 POLYMERIC HAIR DYES 审中-公开
标题翻译：聚合物染发剂
公开(公告)号：WO2008009579A1
公开(公告)日：2008-01-24
申请号：PCT/EP2007/056945
申请日：2007-07-09
申请人： CIBA SPECIALTY CHEMICALS HOLDING INC. , MARQUAIS-BIENEWALD, Sophie , WALLQUIST, Olof , CREMER, Christian , FRÖHLING, Beate , MÖCK, Andreas
发明人： MARQUAIS-BIENEWALD, Sophie , WALLQUIST, Olof , CREMER, Christian , FRÖHLING, Beate , MÖCK, Andreas
IPC分类号： C09B69/10 , A61K8/72
CPC分类号： A61K8/84 , A61K8/8152 , A61K8/8158 , A61K8/86 , A61K8/898 , A61K2800/43 , A61K2800/5426 , A61K2800/57 , A61K2800/594 , A61Q5/02 , A61Q5/065 , A61Q5/12 , C09B69/105 , C09B69/106 , C09B69/107 , C09B69/109
摘要： Disclosed are polymeric dyes of formula (1a); (1b); or (1c); wherein A and B, independently from each other represent a polymer backbone; X 1 and X 2 independently from each other are a linkage group selected from -C 1 -C 10 alkylene-; -C 2 -C 12 alkenylene-; -C 5 -C 10 cycloalkylene-; C 5 -C 10 arylene; -C 5 -C 10 arylene-(C 1 -C 10 alkylene)-; -C(O)-; -(CH 2 CH 2 -O) 1-5 -; -C(O)O-; -OCO-; -N(R 1 )-; -CON(R 1 )-; -(R 1 )NC(O)-; -0-; -S-; -S(O)-; -S(O) 2 -; -S(O) 2 -N(R 1 R 2 ); or the direct bond; R 1 and R 2 independently from each other are hydrogen; or unsubstituted or substituted, straight-chain or branched, monocyclic or polycyclic, interrupted or uninterrupted C 1 - C 14 alkyl; C 2 -C 14 alkenyl; C 6 -C 10 aryl; C 6 -C 10 aryl-C 1 -C 10 alkyl; or C 5 -C 10 alky(C 5 -C 10 aryl); Y 1 and Y 2 independently from each other are a residue of an organic dye; or hydrogen; wherein at least one of Y 1 and Y 2 is a residue of an organic dye; An 1 , An 2 and An 3 , independently from each other are an anion; a and b independently from each other are a number from 1 to 3; m is a number from O to 1000; n is a number from O to 1000; and p is a number from 1 to 1000; wherein the sum of m + n + p ≥ 3.
摘要翻译：公开了式（1a）的聚合染料; （1B）; 或（1c）; 其中A和B彼此独立地表示聚合物主链; X 1和X 2彼此独立地是选自-C 1 -C 10亚烷基的连接基团 - ; -C _{2 -C _{12 烯基 - ; -C _{5 -C _{10 环亚烷基; ç_{5 -C _{10 亚芳基; -C _{5 -C _{10 亚芳基 - （C _{1 -C _{10 亚烷基） - ; -C（O） - ; - （CH _{2 CH _{2 -O）_{1-5 - ; -C（O）O-; -OCO-; -N（R _{1 ） - ; -CON（R _{1 ） - ; - （R _{1 ）NC（O） - ; -0-; -S-; -所以）-; -S（O）_{2 - ; -S（O）_{2 -N（R _{1 - [R _{2 ）; 或直接债券; R 1和R 2彼此独立地是氢; 或未取代或取代的直链或支链单环或多环，间断或不间断C 1 -C 14烷基; ç_{2 -C _{14 烯基; ç_{6 -C _{10 芳基; ç_{6 -C _{10 芳基-C _{1 -C _{10 烷基; 或C 5 -C 10烷基（C 5 -C 10芳基）;或C 5 -C 10烷基（C 5 -C 10 - 芳基）; Y 1和Y 2彼此独立地是有机染料的残基; 或氢; 其中Y 1和Y 2 2中的至少一个是有机染料的残基; 1个，2个和3个独立地是阴离子; a和b彼此独立，为1-3; m是从0到1000的数字; n是从0到1000的数字; p是从1到1000的数字; 其中m + n + p = 3的和。}}}}}}}}}}}}}}}}}}}}}}}}}}}}

5. 发明申请

WO2009090124A1 BLUE POLYMERIC HAIR DYES 审中-公开
标题翻译：蓝色聚合物染发剂
公开(公告)号：WO2009090124A1
公开(公告)日：2009-07-23
申请号：PCT/EP2009/050096
申请日：2009-01-07
申请人： CIBA HOLDING INC. , CREMER, Christian , MARQUAIS-BIENEWALD, Sophie , WALLQUIST, Olof , FRÖHLING, Beate
发明人： CREMER, Christian , MARQUAIS-BIENEWALD, Sophie , WALLQUIST, Olof , FRÖHLING, Beate
IPC分类号： C09B69/10 , A61K8/72 , A61Q5/00
CPC分类号： C09B69/10 , A61K8/8152 , A61K8/817 , A61K8/84 , A61K2800/4322 , A61Q5/065 , C09B69/101 , C09B69/106
摘要： Disclosed are cationic polymeric dye with a hue value of h = 210° to 330° comprising: a) a polymer backbone, b) a residue of an organic dye, and c) optionally colorless organic groups, wherein (b) and (c) are covalently bound to the polymer backbone (a), and wherein the cationic charges can independently be part of the dye or the colorless organic groups. The dyes are distinguished by their depth of shade and their good fastness properties to washing, such as, for example, fastness to light, shampooing and rubbing.
摘要翻译：公开了具有h = 210°至330°的色相值为h = 210°至330°的阳离子聚合物染料，其包含：a）聚合物主链，b）有机染料的残基，和c）任选无色的有机基团，其中（b）和（c）共价结合到聚合物主链（a），并且其中阳离子电荷可以独立地是染料或无色有机基团的一部分。这些染料的特征在于它们的色调深度和它们对洗涤性能的良好牢度，例如耐光牢度，洗发剂和摩擦性。

6. 发明申请

WO2011006946A9 POLYMERIC HAIR DYES 审中-公开
公开(公告)号：WO2011006946A9
公开(公告)日：2011-01-20
申请号：PCT/EP2010/060175
申请日：2010-07-15
申请人： BASF SE , CREMER, Christian , BECHERER, Oliver , FRÖHLING, Beate
发明人： CREMER, Christian , BECHERER, Oliver , FRÖHLING, Beate
IPC分类号： C09B26/04 , C09B69/10 , A61Q5/00
摘要： Disclosed are polymeric dyes of formula (1a), (1b), or (1c); wherein A and B, independently from each other represent a polymer backbone; X 1 and X 2 independently from each other are a linkage group selected from -S-, -S-S-, -N-, - N=-, -N(R 5 )-, -S(O)-, -SO 2 -, -(CH 2 CH 2 -O) 1-5 -, -(CH 2 CH 2 CH 2 -O) 1-5 -, -C(O)-, -C(O)O-,-OCO-, (formula II) -CON(R 1 )-, -C(NR 1 R 2 ) 2 -, -(R 1 )NC(O)-, -C(S)R 1 -; which may be interrupted and/or terminated at one or both ends by one or more than one -C 1 C 30 alkylene- or -C 2 -C 12 alkenylene-; or an optionally substituted, saturated or unsaturated, fused or non-fused aromatic or nonaromatic (heterocyclic) bivalent radical optionally comprising at least one heteroatom; a saturated or unsaturated, fused or non-fused aromatic or nonaromatic bivalent radical comprising at least one heteroatom, which is optionally substituted by C 1 -C 30 alkyl, C 1 -C 30 alkoxy, C 2 -C 12 alkenyl, C 5 -C 10 aryl, C 5 -C 10 cycloalkyl, C 1 - C 10 alkyl(C 5 -C 10 arylene), hydroxy or halogen; R 1 and R 2 independently from each other are hydrogen; unsubstituted or substituted, straight-chain or branched, monocyclic or polycyclic, interrupted or uninterrupted C 1 - C 14 alkyl; C 2 -C 14 alkenyl; C 6 -C 10 aryl; C 6 -C 10 aryl- C 1 -C 10 alkyl; or C 5 -C 10 alkyl(C 5 -C 10 aryl); Y 1 and Y 2 independently from each other are a residue of an organic dye selected from hydrazone dyes of formula (1d), wherein Z 1 , Z 2 and Z 3 , independently from each other are -CR 8 - or -NR 9 +-; and at least one of Z 1 , Z 2 or Z 3 is -NR 9 +-; wherein at least one of Y 1 and Y 2 is a residue of an organic dye; R, R 3 , R 4 , R 5 , R 6 , R 7 , R 8 and R 9 independently from each other are hydrogen; hydroxy; C 1 - C 5 alkyl; hydroxy-C 1 C 5 alkyl; C 1 C 5 alkoxy; -NO 2 ; -Cl; -Br; -COOH; -SO 3 H; -CN; NH 2 ; or CH 3 -CO-NH-; An 1 , An 2 and An 3 , independently from each other are an anion; a and b independently from each other are a number from 1 to 3; m is a number from 0 to 5000; n is a number from 0 to 5000; and p is a number from 1 to 5000; wherein the sum of m + n + p ≥ 3. The dyes are distinguished by their depth of shade and their good fastness properties to washing, such as, for example, fastness to light, shampooing and rubbing.

7. 发明申请

WO2008138726A2 POLYMERIC DYES 审中-公开
标题翻译：聚合染料
公开(公告)号：WO2008138726A2
公开(公告)日：2008-11-20
申请号：PCT/EP2008/055038
申请日：2008-04-25
申请人： CIBA HOLDING INC. , CREMER, Christian , RIGGS, Richard Lewis , FRÖHLING, Beate , MÜLLER, Martin
发明人： CREMER, Christian , RIGGS, Richard Lewis , FRÖHLING, Beate , MÜLLER, Martin
IPC分类号： C08G77/22 , C09B69/10
CPC分类号： C08G77/26 , A61K8/11 , A61K8/26 , A61K8/898 , A61K2800/413 , A61K2800/43 , A61K2800/434 , A61Q5/065 , B82Y5/00 , C07F7/1836 , C08G77/22 , C08L83/08 , C09B69/008 , C09B69/101 , C09B69/103 , C09B69/106 , C09B69/107 , C09B69/109 , D06P1/0052 , D06P3/145 , Y10T428/29
摘要： A highly crosslinked polysiloxane dye comprising at least 10 Si atoms, including at least one moiety of the formula (I) whose open Si-bonds each are linked to an oxygen atom and open O-bond is linked to a silicon atom in the rest of the polysiloxane, and wherein T is a direct bond or an organic spacer group such as C 1 -C 18 alkylene, C 2 -C 12 alkenylene, C 5 -C 10 cycloalkylene, C 5 -C 10 arylene, -C 5 -C 10 arylene-(C 1 -C 10 alkylene)-, each of which may be end-capped towards the linkage to Dye by CO, COO, NR 1 , CONR 1 , NR 1 CONR 1 , CS, CSS, CSNR 1 , NR 1 CSNR 1 , O, S, SO, SO 2 , C 5 -C 10 cycloalkylene, C 5 -C 10 arylene; or T is C 3 -C 18 alkylene interrupted, and optionally end- capped towards the linkage to Dye, by CO, COO, NR 1 , CONR 1 , NR 1 CONR 1 , CS, CSS, CSNR 1 , NR 1 CSNR 1 , O, S, SO, -SO 2 -, C 5 -C 10 cycloalkylene, C 5 -C 10 arylene; or is CO; (CH 2 CH 2 -O) 1-5 ; COO; N(R 1 ); CON(R 1 ); O; S; SO; SO 2 ; R 1 is hydrogen; unsubstituted or substituted, straight-chain or branched, monocyclic or polycyclic, interrupted or uninterrupted C 1 -C 14 alkyl; C 2 -C 14 alkenyl; C 6 -C 10 aryl; C 6 -C 10 aryl-C 1 - C 10 alkyl; or C 5 -C 10 alkyl(C 5 -C 10 aryl); and Dye is a residue of an organic dye, is useful for dyeing of organic materials, such as keratin-containing fibers, wool, leather, silk, cellulose or polyamides.
摘要翻译：包含至少10个Si原子的高度交联的聚硅氧烷染料，包括至少一个式（I）的部分，其开放的Si键各自连接到氧原子和开放的O形键，其余部分与硅原子连接聚硅氧烷，其中T是直接键或有机间隔基团，例如C 1 -C 18亚烷基，C 2 -C 3烷基，亚烷基亚烷基，C 5 -C 10亚环烷基，C 5 -C 10亚芳基，-C 5 -C 10亚芳基 - （C 1 -C 10亚烷基） - ，其各自为可以通过CO，COO，NR 1，CONR 1，NR 1和CON 1连接到染料上， / SUP>，CS，CSS，CSNR ，NR 1，CSNR 1，O，S，SO，SO 2， C 1 -C 5亚烷基，C 5 -C 10亚芳基，C 5 -C 10亚环烷基，C 5 -C 10亚芳基，或T是C 3 -C 18亚烷基中断，并且任选地通过CO，COO，NR 1至H 2连接到Dye的连接上。，CONR 1，NR 1，...，CS，CSS，CSNR 1，NR 1， O，S，SO，-SO 2 - ，C 5 -C 10 - ， - C 1 -C 6烷基，亚环烷基，C 5 -C 10亚芳基; 或是CO; （CH _{2 CH _{2 -O）_{1-5 ; COO; N（R ^{1 ）; CON（R ^{1 ）; O; S; 所以; SO _{2 ; R 1是氢; 未取代或取代的直链或支链单环或多环，间断或不间断的C 1 -C 14烷基; ç_{2 -C _{14 烯基; ç_{6 -C _{10 芳基; C 6 -C 10芳基-C 1 -C 10烷基; C 1 -C 6烷基; 或C 5 -C 10烷基（C 5 -C 10芳基）; 染料是有机染料的残留物，可用于染色有机材料，如含角蛋白的纤维，羊毛，皮革，丝绸，纤维素或聚酰胺。}}}}}}}}}}

8. 发明申请

WO2007048722A2 PROCESS FOR HAIR DYEING 审中-公开
标题翻译：头发染色工艺
公开(公告)号：WO2007048722A2
公开(公告)日：2007-05-03
申请号：PCT/EP2006/067417
申请日：2006-10-16
申请人： CIBA SPECIALTY CHEMICALS HOLDING INC. , CREMER, Christian , MÜHLEBACH, Andreas , WALLQUIST, Olof , GIESENBERG, Thomas , FRÖHLING, Beate , RIGGS, Richard Lewis
发明人： CREMER, Christian , MÜHLEBACH, Andreas , WALLQUIST, Olof , GIESENBERG, Thomas , FRÖHLING, Beate , RIGGS, Richard Lewis
CPC分类号： C09C1/407 , A61K8/25 , A61K8/355 , A61Q5/065 , A61Q5/10 , B82Y30/00 , C01P2002/88 , C01P2004/62 , C01P2004/64 , C09C1/3063 , C09C1/3081 , C09C1/309 , C09C3/12
摘要： Disclosed is a process for dyeing of keratin-containing fibers comprising treating the fibers with at least one functionalized particle comprising on the surface an organic chromophore which is bound via a bridge member, wherein the particles are based on SiO 2 , Al 2 O 3 or mixtures thereof, and the functionalized particles carry a positive charge.
摘要翻译：公开了一种用于染色含角蛋白的纤维的方法，包括用至少一种官能化颗粒处理纤维，所述官能化颗粒在表面上包含通过桥构件结合的有机发色团，其中所述颗粒是基于SiO 2 >，Al 2 O 3或其混合物，并且官能化颗粒携带正电荷。

9. 发明申请

WO2010097338A2 HAIR DYEING COMPOSITION 审中-公开
标题翻译：头发染色组合物
公开(公告)号：WO2010097338A2
公开(公告)日：2010-09-02
申请号：PCT/EP2010/052097
申请日：2010-02-19
申请人： BASF SE , FRÖHLING, Beate
发明人： FRÖHLING, Beate
IPC分类号： A61K8/49 , A61K8/41 , A61Q5/10
CPC分类号： A61K8/49 , A61K8/416 , A61K8/4926 , A61K8/494 , A61K8/4946 , A61K2800/4322 , A61K2800/4324 , A61Q5/065 , A61Q5/10
摘要： Hair dyeing composition comprising (a) a dye of formula (1) (b) at least one dye selected from the compounds of formulae (2) (3) (4) wherein D is the radical of a diazo component of the formula (2a) (2b) (2c) (2d) K is the radical of a coupling component selected from aniline derivatives; phenol derivatives; naphthalene derivative; X is -CH= -O-; -S-; or -N(R 7 )-; R 1 , R 2 , R 3 end R 4 independently from each other are hydrogen; or C 1 -C 4 alkyl; R 5 and R 6 independently from each other are hydrogen; C 1 -C 4 alkyl; or C 1 -C 4 alkoxy; R 7 and R 9 independently from each other are unsubstituted or OH-, C 1 -C 4 alkoxy-, halogen-, amino-, C 1 -C 4 -mono or -dialkylamino-substituted C 1 -C 4 alkyl; or phenyl; R 8 is hydrogen; C 1 -C 4 alkyl; Cl; or nitro; R 10 is hydrogen; C 1 -C 4 alkyl; Cl; nitro; amino; or C 1 -C 4 mono- or C 1 -C 4 dialkylamino; R 11 is hydrogen; C 1 -C 4 alkyl; or CN; R 12 is unsubstituted or OH- or CN-substituted C 1 -C 4 alkyl; R 13 is hydrogen; or C 1 -C 4 alkyl; R 14 and R 15 independently from each other are hydrogen; C 1 -C 4 alkyl; or C 1 -C 4 alkoxy; or R 14 and R 15 together with the nitrogen and carbon atoms joining them together form a 5- or 6- membered ring; R 16 and R 20 independently from each other are hydrogen; C 1 -C 4 alkyl; hydroxy; Cl; nitro; amino, C 1 -C 4 mono- or dialkylamino; R 17 , R 18 , R 19 , R 21 , R 22 and R 23 independently from each other are hydrogen; or C 1 -C 4 alkyl; R 24 is hydrogen; or C 1 -C 4 alkyl; and An - is a colorless anion.
摘要翻译：（a）式（1）的染料，（b）至少一种选自式（2）（3）（4）的化合物的染料，其中D为式（2a）（2b）（2c）（2d）K的重氮组分K是选自苯胺衍生物的偶合组分的基团; 酚衍生物; 萘衍生物; X是-CH = -O-; -S-; 或-N（R 7） - ; R 1，R 2，R 3，R 4，R 4彼此独立地为氢; R 1，R 2，R 3，R 4，或C 1 -C 4烷基; R 5和R 6彼此独立地为氢; ç<子> 1 -C <子> 4 烷基; 或C 1 -C 4烷氧基; R 7和R 9彼此独立地是未取代的或OH-，C 1 -C 4 - 烷氧基 - ，卤素 - ，氨基 - ，C 1 -C 4 - 单 - 或二 - 烷基氨基 - 取代的C 1 -C 4 - 子>烷基; 或苯基; R 8是氢; ç<子> 1 -C <子> 4 烷基; 氯; 或硝基; R 10是氢; ç<子> 1 -C <子> 4 烷基; 氯; 硝基; 氨基; 或C 1 -C 4 - 单 - 或C 1 -C 4二烷基氨基; R 11是氢; ç<子> 1 -C <子> 4 烷基; 或CN; R 12是未取代的或OH-或CN-取代的C 1 -C 4烷基; R 13是氢; 或C 1 -C 4烷基; R 14和R 15彼此独立地为氢; ç<子> 1 -C <子> 4 烷基; 或C 1 -C 4烷氧基; 或者R 14和R 15与连接它们的氮和碳原子一起形成5-或6-元环; R 16和R 20彼此独立地为氢; ç<子> 1 -C <子> 4 烷基; 羟基; 氯; 硝基; 氨基，C 1 -C 4 - 单或二烷基氨基; R 17，R 18，R 19，R 21，R 22和 R 23彼此独立地为氢; 或C 1 -C 4烷基; R 24是氢; 或C 1 -C 4烷基; An ^{- 是无色的阴离子。}

10. 发明申请

WO2010097339A2 HAIR DYEING COMPOSITION 审中-公开
标题翻译：头发染色组合物
公开(公告)号：WO2010097339A2
公开(公告)日：2010-09-02
申请号：PCT/EP2010/052099
申请日：2010-02-19
申请人： BASF SE , FRÖHLING, Beate
发明人： FRÖHLING, Beate
IPC分类号： A61K8/41 , A61K8/49 , A61Q5/10
CPC分类号： A61K8/49 , A61K8/4926 , A61K8/4946 , A61Q5/10
摘要： Disclosed is a hair dyeing composition comprising (a)a dye of formula (1); (b)at least one dye selected from the compounds of formulae (2); wherein D is the radical of a diazo component of the formula (2a); K is the radical of a coupling component selected from aniline derivatives; phenol derivatives; and a radical of a heterocyclic coupling component; X is O-; -S-; or N(R 8 )-; Y is CH=; -CR 15 =; or N=; R 1 , R 2 , R 3 and R 4 independently from each other are hydrogen; or C 1 -C 4 alkyl; R 5 and R 6 independently from each other are hydrogen; C 1 -C 4 alkyl; or C 1 -C 4 alkoxy; R 7 and R 9 independently from each other are unsubstituted or OH-, C 1 -C 4 alkoxy-, halogen-, amino-, C 1 -C 4 -mono or -dialkylamino-substituted C 1 -C 4 alkyl; R 8 is hydrogen; or C 1 -C 4 alkyl; R 10 is hydrogen; C 1 -C 4 alkyl; or CN; R 11 is unsubstituted or OH- or CN-substituted C 1 -C 4 alkyl; R 12 is hydrogen; or C 1 -C 4 alkyl; R 13 and R 14 independently from each other are hydrogen; C 1 -C 4 alkyl; or C 1 -C 4 alkoxy; or R 13 and R 14 together with the nitrogen and carbon atoms joining them together form a 5- or 6- membered ring; R 15 is hydrogen; or C 1 -C 4 alkyl; and An 1 - is a colorless anion; and (c) a quaternary ammonium salt.
摘要翻译：公开了一种染发组合物，其包含（a）式（1）的染料; （b）至少一种选自式（2）的化合物的染料; 其中D是式（2a）的重氮组分的基团; K是选自苯胺衍生物的偶联组分的基团; 苯酚衍生物; 和杂环结合组分的基团; X为O-; -S-; 或N（R 8） - ; Y为CH = -CR 15 =; 或N =; R1，R2，R3和R4彼此独立地是氢; 或C 1 -C 4烷基; R5和R6彼此独立地是氢; C1-C4烷基; 或C 1 -C 4烷氧基; R 7和R 9彼此独立地是未取代的或OH-，C 1 -C 4烷氧基 - ，卤素 - ，氨基 - ，C 1 -C 4 - 单或二烷基氨基取代的C 1 -C 4烷基; R8是氢; 或C 1 -C 4烷基; R10是氢; C1-C4烷基; 或CN; R11是未取代的或OH-或CN-取代的C1-C4烷基; R12是氢; 或C 1 -C 4烷基; R 13和R 14彼此独立地是氢; C1-C4烷基; 或C 1 -C 4烷氧基; 或R 13和R 14与连接在一起的氮原子和碳原子一起形成5-或6-元环; R15是氢; 或C 1 -C 4烷基; 和An1-无色阴离子; 和（c）季铵盐。

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