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1. 发明申请

WO2006120133A2 COLORING KERATIN FIBERS WITH METAL COMPLEXES 审中-公开
标题翻译：具有金属复合物的着色金属纤维
公开(公告)号：WO2006120133A2
公开(公告)日：2006-11-16
申请号：PCT/EP2006/061990
申请日：2006-05-03
申请人： CIBA SPECIALTY CHEMICALS HOLDING INC. , END, Nicole , SCHÖNING, Kai-Uwe , FRÖHLING, Beate
发明人： END, Nicole , SCHÖNING, Kai-Uwe , FRÖHLING, Beate
IPC分类号： A61K8/49 , A61Q5/10 , C07D213/74 , C07D249/08 , C07D249/10 , C07D251/12 , C07D285/08 , C07D271/06 , A61Q5/12 , C07D471/04 , C07F15/02 , C07F13/00
CPC分类号： C07D271/06 , A61K8/19 , A61K8/40 , A61K8/49 , A61K8/4926 , A61K8/496 , A61K8/4966 , A61K2800/58 , A61Q5/065 , C07D213/74 , C07D249/08 , C07D285/08 , C07D471/04 , C09B55/006 , C09B57/00 , C09B57/10
摘要： The present invention concerns coloring keratin fibers, especially human hair, with colored metal complexes.
摘要翻译：本发明涉及用着色金属络合物着色角蛋白纤维，特别是人类头发。

2. 发明申请

WO2005095522A2 2,5-DIAMINO SUBSTITUTED AZO DYES 审中-公开
标题翻译： 2,5-DIAMINO取代的AZO染料
公开(公告)号：WO2005095522A2
公开(公告)日：2005-10-13
申请号：PCT/EP2005/051323
申请日：2005-03-23
申请人： CIBA SPECIALTY CHEMICALS HOLDING INC. , ELIU, Victor Paul , SAUDER, Thomas , KAUFFMANN, Dominique , FRÖHLING, Beate
发明人： ELIU, Victor Paul , SAUDER, Thomas , KAUFFMANN, Dominique , FRÖHLING, Beate
IPC分类号： C09B44/16
CPC分类号： C09B44/16
摘要： Disclosed are azo dyes of formula (1) , wherein R 1 is hydrogen; C 1 -C 14 alkyl; hydroxy- C 1 -C 14 alkyl; C 2 -C 14 alkenyl; a radical of formula (1a) -(CH 2 ) n1 -O-(CH 2 ) n2 -CH 3 ; a radical of formula (1b) C 10 aryl; or C 6 -C 10 aryl-C 1 -C 6 alkyl; R3 is hydrogen; C 1 -C 14 alkyl; C 2 -C 14 alkenyl; C 6 -C 10 aryl; C 6 -C 1 0aryl-C 1 -C 6 alkyl; or CO-R 6 ; R 4 is CO-R 6 ; R 5 is C 1 -C 14 alkyl; C 2 -C 14 alkenyl; C 6 -C 10 aryl; or C 6 -C 10 aryl-C 1 -C 6 alkyl; R 6 is hydrogen; C 1 -C 14 alkyl; C 2 -C 14 alkenyl; or C 6 -C 10 aryl; R 7 , R 8 , R 9 and R 10 , independently from each other are hydrogen; or C 1 -C 5 alkyl; m is 1; or 2; An - is an anion; If m = 1, R 2 is hydrogen; C 1 -C 14 alkyl; C 2 -C 14 alkenyl; a radical of formula (1a); a radical of formula (1b) ; C 6 -C 10 aryl; or C 6 -C 10 aryl-C 1 -C 6 alkyl; If m = 2, R 2 is the direct bond; or C 1 -C 14 alkylene, which is optionally substituted by one or more C 1 -C 4 alkyl, or which is optionally interrupted by C 5 -C 10 arylene, -O- or -NR 9 R 10 -; R 9 and R 10 , independently from each other are hydrogen; or C 1 -C 5 alkyl; and n1, n2, n3 and n4, independently from each other are a number from 0 to 5. The compounds are useful for the dyeing of organic material, preferably human hair.
摘要翻译：公开了式（1）的偶氮染料，其中R 1是氢; ç<子> 1 -C <子> 14 烷基; 羟基-C 1 -C 14 - 烷基; ç<子> 2 -C <子> 14 烯基; 式（1a） - （CH 2）n1 -O-（CH 2）n2 -n- CH <子> 3 ; 式（1b）C10芳基的基团; 或C 6 -C 10芳基-C 1 -C 6烷基;或C 6 -C 10芳基-C 1 -C 6烷基。 R3是氢; ç<子> 1 -C <子> 14 烷基; ç<子> 2 -C <子> 14 烯基; ç<子> 6 -C <子> 10 芳基; ç<子> 6 -C <子> 1 0aryl-C <子> 1 -C <子> 6 烷基; 或CO-R 6; R 4是CO-R 6; R 5是C 1 -C 14烷基; R 5是C 1 -C 14烷基。 ç<子> 2 -C <子> 14 烯基; ç<子> 6 -C <子> 10 芳基; 或C 6 -C 10芳基-C 1 -C 6烷基;或C 6 -C 10芳基-C 1 -C 6烷基。 R 6是氢; ç<子> 1 -C <子> 14 烷基; ç<子> 2 -C <子> 14 烯基; 或C≡C-C10芳基; R 7，R 8，R 9和R 10彼此独立地为氢; R 7，R 8，R 9和R 10彼此独立地为氢; 或C 1 -C 5烷基; m是1; 或2; An ^{- 是一个阴离子; 如果m = 1，则R 2是氢; ç<子> 1 -C <子> 14 烷基; ç<子> 2 -C <子> 14 烯基; 式（1a）的基团; 式（1b）的基团; ç<子> 6 -C <子> 10 芳基; 或C 6 -C 10芳基-C 1 -C 6烷基;或C 6 -C 10芳基-C 1 -C 6烷基。如果m = 2，则R 2是直接键; 或C 1 -C 14亚烷基，其任选被一个或多个C 1 -C 4烷基，或者任选地被C 5 -C 10亚芳基，-O-或-NR 9 R 10取代的亚苯基， > - ; R 9和R 10彼此独立地为氢; 或C 1 -C 5烷基; 并且n1，n2，n3和n4彼此独立地为0-5的数。所述化合物可用于染色有机材料，优选人发。}

3. 发明申请

WO2005012437A1 CATIONIC DIRECT DYES 审中-公开
标题翻译：阳光直射
公开(公告)号：WO2005012437A1
公开(公告)日：2005-02-10
申请号：PCT/EP2004/051481
申请日：2004-07-14
申请人： CIBA SPECIALTY CHEMICALS HOLDING INC. , ELIU, Victor, Paul , FRÖHLING, Beate
发明人： ELIU, Victor, Paul , FRÖHLING, Beate
IPC分类号： C09B44/16
CPC分类号： C09B44/16
摘要： The present invention relates to novel the cationic dyes of formula (1) wherein R 1 is an unsubstituted or substituted C 1 -C 14 alkyl or an aryl radical; X - is an anion; R 3 is an unsubstituted or substituted C 1 -C 14 alkyl, aryl radical, C 1 -C 6 alkoxy, cyanid, nitro or halide; n is 1 or 2; and if n is 1, then R 2 is hydrogen, unsubstituted or substituted C 1 -C 14 alkyl; or if n is 2, then R 2 is an unsubstituted or substituted C 1 -C 14 alkylen. Further, the present invention relates to compositions thereof, especially comprising other dyes, to processes for the preparation thereof and to the use thereof in the dyeing of organic material, such as keratin, wool, leather, silk, paper, cellulose or polyamides, and preferably human hair.
摘要翻译：本发明涉及式（1）的阳离子染料，其中R 1是未取代或取代的C 1 -C 14烷基或芳基; X - 是阴离子; R 3是未取代或取代的C 1 -C 14烷基，芳基，C 1 -C 6烷氧基，氰基，硝基或卤素; n为1或2; 如果n为1，则R2为氢，未取代或取代的C 1 -C 14烷基; 或者如果n为2，则R2为未取代或取代的C1-C14亚烷基。此外，本发明涉及其组合物，特别是其它染料，其制备方法及其在染色有机材料如角蛋白，羊毛，皮革，丝，纸，纤维素或聚酰胺中的用途，以及优选人发。

4. 发明申请

WO2004076564A1 CATIONIC DYES, THEIR PRODUCTION AND USE 审中-公开
标题翻译：阳光染色体，其生产和使用
公开(公告)号：WO2004076564A1
公开(公告)日：2004-09-10
申请号：PCT/EP2004/050132
申请日：2004-02-16
申请人： CIBA SPECIALTY CHEMICALS HOLDING INC. , ELIU, Victor Paul , FRÖHLING, Beate
发明人： ELIU, Victor Paul , FRÖHLING, Beate
IPC分类号： C09B69/06
CPC分类号： C09B69/065 , A61K8/4946 , A61Q5/065 , C09B44/103
摘要： The present invention relates to novel cationic dye of formula (1) wherein R 1 and R 7 are each independently of the other hydrogen, hydroxyl; unsubstituted or substituted C 1 -C 6 alkyl, aryl radical or C 1 I-C 6 alkoxy; or -NR 3 R 4 , wherein R 3 and R 4 are each independently of the other hydrogen, unsubstituted or substituted aryl radical or C 1 -C 6 alkyl, and R 2 is hydrogen, hydroxyl, unsubstituted or substituted C 1 C 6 alkyl, aryl radical or C 1 -C 6 alkoxy, - NR3R4 , or an organic radical of formula (2) wherein R 5 is hydrogen, unsubstituted or substituted aryl radical or C 1 -C 6 alkyl, and X is an anion. Further, the present invention relates to compositions thereof, especially comprising other dyes, to processes for the preparation thereof and to the use thereof in the dyeing of organic material, such as keratin, wool, leather, silk, cellulose or polyamides, and preferably human hair.
摘要翻译：本发明涉及式（1）的新型阳离子染料，其中R 1和R 7各自独立地为氢，羟基; 未取代或取代的C 1 -C 6烷基，芳基或C 1 -C 6烷氧基; 或-NR 3 R 4，其中R 3和R 4各自独立地为氢，未取代或取代的芳基或C 1 -C 6烷基，且R 2为氢，羟基，未取代或取代的C 1 -C 6烷基，芳基或C 1 -C 6烷氧基，-NR 3 R 4或式（2）的有机基团，其中R 5是氢，未取代或取代的芳基或C 1 -C 6烷基，X是阴离子。此外，本发明涉及其组合物，特别是其它染料，其制备方法及其在染色有机材料如角蛋白，羊毛，皮革，丝，纤维素或聚酰胺，优选人头发。

5. 发明申请

WO2011006946A9 POLYMERIC HAIR DYES 审中-公开
公开(公告)号：WO2011006946A9
公开(公告)日：2011-01-20
申请号：PCT/EP2010/060175
申请日：2010-07-15
申请人： BASF SE , CREMER, Christian , BECHERER, Oliver , FRÖHLING, Beate
发明人： CREMER, Christian , BECHERER, Oliver , FRÖHLING, Beate
IPC分类号： C09B26/04 , C09B69/10 , A61Q5/00
摘要： Disclosed are polymeric dyes of formula (1a), (1b), or (1c); wherein A and B, independently from each other represent a polymer backbone; X 1 and X 2 independently from each other are a linkage group selected from -S-, -S-S-, -N-, - N=-, -N(R 5 )-, -S(O)-, -SO 2 -, -(CH 2 CH 2 -O) 1-5 -, -(CH 2 CH 2 CH 2 -O) 1-5 -, -C(O)-, -C(O)O-,-OCO-, (formula II) -CON(R 1 )-, -C(NR 1 R 2 ) 2 -, -(R 1 )NC(O)-, -C(S)R 1 -; which may be interrupted and/or terminated at one or both ends by one or more than one -C 1 C 30 alkylene- or -C 2 -C 12 alkenylene-; or an optionally substituted, saturated or unsaturated, fused or non-fused aromatic or nonaromatic (heterocyclic) bivalent radical optionally comprising at least one heteroatom; a saturated or unsaturated, fused or non-fused aromatic or nonaromatic bivalent radical comprising at least one heteroatom, which is optionally substituted by C 1 -C 30 alkyl, C 1 -C 30 alkoxy, C 2 -C 12 alkenyl, C 5 -C 10 aryl, C 5 -C 10 cycloalkyl, C 1 - C 10 alkyl(C 5 -C 10 arylene), hydroxy or halogen; R 1 and R 2 independently from each other are hydrogen; unsubstituted or substituted, straight-chain or branched, monocyclic or polycyclic, interrupted or uninterrupted C 1 - C 14 alkyl; C 2 -C 14 alkenyl; C 6 -C 10 aryl; C 6 -C 10 aryl- C 1 -C 10 alkyl; or C 5 -C 10 alkyl(C 5 -C 10 aryl); Y 1 and Y 2 independently from each other are a residue of an organic dye selected from hydrazone dyes of formula (1d), wherein Z 1 , Z 2 and Z 3 , independently from each other are -CR 8 - or -NR 9 +-; and at least one of Z 1 , Z 2 or Z 3 is -NR 9 +-; wherein at least one of Y 1 and Y 2 is a residue of an organic dye; R, R 3 , R 4 , R 5 , R 6 , R 7 , R 8 and R 9 independently from each other are hydrogen; hydroxy; C 1 - C 5 alkyl; hydroxy-C 1 C 5 alkyl; C 1 C 5 alkoxy; -NO 2 ; -Cl; -Br; -COOH; -SO 3 H; -CN; NH 2 ; or CH 3 -CO-NH-; An 1 , An 2 and An 3 , independently from each other are an anion; a and b independently from each other are a number from 1 to 3; m is a number from 0 to 5000; n is a number from 0 to 5000; and p is a number from 1 to 5000; wherein the sum of m + n + p ≥ 3. The dyes are distinguished by their depth of shade and their good fastness properties to washing, such as, for example, fastness to light, shampooing and rubbing.

6. 发明申请

WO2010097338A2 HAIR DYEING COMPOSITION 审中-公开
标题翻译：头发染色组合物
公开(公告)号：WO2010097338A2
公开(公告)日：2010-09-02
申请号：PCT/EP2010/052097
申请日：2010-02-19
申请人： BASF SE , FRÖHLING, Beate
发明人： FRÖHLING, Beate
IPC分类号： A61K8/49 , A61K8/41 , A61Q5/10
CPC分类号： A61K8/49 , A61K8/416 , A61K8/4926 , A61K8/494 , A61K8/4946 , A61K2800/4322 , A61K2800/4324 , A61Q5/065 , A61Q5/10
摘要： Hair dyeing composition comprising (a) a dye of formula (1) (b) at least one dye selected from the compounds of formulae (2) (3) (4) wherein D is the radical of a diazo component of the formula (2a) (2b) (2c) (2d) K is the radical of a coupling component selected from aniline derivatives; phenol derivatives; naphthalene derivative; X is -CH= -O-; -S-; or -N(R 7 )-; R 1 , R 2 , R 3 end R 4 independently from each other are hydrogen; or C 1 -C 4 alkyl; R 5 and R 6 independently from each other are hydrogen; C 1 -C 4 alkyl; or C 1 -C 4 alkoxy; R 7 and R 9 independently from each other are unsubstituted or OH-, C 1 -C 4 alkoxy-, halogen-, amino-, C 1 -C 4 -mono or -dialkylamino-substituted C 1 -C 4 alkyl; or phenyl; R 8 is hydrogen; C 1 -C 4 alkyl; Cl; or nitro; R 10 is hydrogen; C 1 -C 4 alkyl; Cl; nitro; amino; or C 1 -C 4 mono- or C 1 -C 4 dialkylamino; R 11 is hydrogen; C 1 -C 4 alkyl; or CN; R 12 is unsubstituted or OH- or CN-substituted C 1 -C 4 alkyl; R 13 is hydrogen; or C 1 -C 4 alkyl; R 14 and R 15 independently from each other are hydrogen; C 1 -C 4 alkyl; or C 1 -C 4 alkoxy; or R 14 and R 15 together with the nitrogen and carbon atoms joining them together form a 5- or 6- membered ring; R 16 and R 20 independently from each other are hydrogen; C 1 -C 4 alkyl; hydroxy; Cl; nitro; amino, C 1 -C 4 mono- or dialkylamino; R 17 , R 18 , R 19 , R 21 , R 22 and R 23 independently from each other are hydrogen; or C 1 -C 4 alkyl; R 24 is hydrogen; or C 1 -C 4 alkyl; and An - is a colorless anion.
摘要翻译：（a）式（1）的染料，（b）至少一种选自式（2）（3）（4）的化合物的染料，其中D为式（2a）（2b）（2c）（2d）K的重氮组分K是选自苯胺衍生物的偶合组分的基团; 酚衍生物; 萘衍生物; X是-CH = -O-; -S-; 或-N（R 7） - ; R 1，R 2，R 3，R 4，R 4彼此独立地为氢; R 1，R 2，R 3，R 4，或C 1 -C 4烷基; R 5和R 6彼此独立地为氢; ç<子> 1 -C <子> 4 烷基; 或C 1 -C 4烷氧基; R 7和R 9彼此独立地是未取代的或OH-，C 1 -C 4 - 烷氧基 - ，卤素 - ，氨基 - ，C 1 -C 4 - 单 - 或二 - 烷基氨基 - 取代的C 1 -C 4 - 子>烷基; 或苯基; R 8是氢; ç<子> 1 -C <子> 4 烷基; 氯; 或硝基; R 10是氢; ç<子> 1 -C <子> 4 烷基; 氯; 硝基; 氨基; 或C 1 -C 4 - 单 - 或C 1 -C 4二烷基氨基; R 11是氢; ç<子> 1 -C <子> 4 烷基; 或CN; R 12是未取代的或OH-或CN-取代的C 1 -C 4烷基; R 13是氢; 或C 1 -C 4烷基; R 14和R 15彼此独立地为氢; ç<子> 1 -C <子> 4 烷基; 或C 1 -C 4烷氧基; 或者R 14和R 15与连接它们的氮和碳原子一起形成5-或6-元环; R 16和R 20彼此独立地为氢; ç<子> 1 -C <子> 4 烷基; 羟基; 氯; 硝基; 氨基，C 1 -C 4 - 单或二烷基氨基; R 17，R 18，R 19，R 21，R 22和 R 23彼此独立地为氢; 或C 1 -C 4烷基; R 24是氢; 或C 1 -C 4烷基; An ^{- 是无色的阴离子。}

7. 发明申请

WO2006136617A2 MIXTURE OF SULFIDE DYES 审中-公开
标题翻译：硫酸染料混合物
公开(公告)号：WO2006136617A2
公开(公告)日：2006-12-28
申请号：PCT/EP2006/066325
申请日：2006-09-13
申请人： CIBA SPECIALTY CHEMICALS HOLDING INC. , FRÖHLING, Beate , CREMER, Christian , ELIU, Victor, Paul , WALLQUIST, Olof
发明人： CREMER, Christian , ELIU, Victor, Paul , WALLQUIST, Olof
CPC分类号： A61Q5/10 , A61K8/46 , A61K8/49 , A61K8/492 , A61K8/4926 , A61K8/4946 , A61K8/496 , A61K8/498 , C09B67/0033 , C09B67/0034
摘要： Disclosed are mixtures of sulfide dyes and dyeing compositions comprising mixtures of sulfide dyes. The dye mixtures are useful for the dyeing of organic materials, such as keratin fibers, preferably human hair.
摘要翻译：公开了硫化染料和包含硫化染料混合物的染色组合物的混合物。染料混合物可用于染色有机材料，例如角蛋白纤维，优选人发。

8. 发明申请

WO2003060015A1 YELLOW CATIONIC DYES FOR DYING OF ORGANIC MATERIAL 审中-公开
标题翻译：用于染色有机物的黄色阳离子染料
公开(公告)号：WO2003060015A1
公开(公告)日：2003-07-24
申请号：PCT/EP2003/000068
申请日：2003-01-07
申请人： CIBA SPECIALITY CHEMICALS HOLDING INC. , ELIU, Victor Paul , FRÖHLING, Beate , HAUSER, Julia
发明人： ELIU, Victor Paul , FRÖHLING, Beate , HAUSER, Julia
IPC分类号： C09B26/04
CPC分类号： C09B26/04
摘要： The present invention relates to novel cationic yellow dyes of formula (1) wherein R 1 and R 2 are each independently of the other a C 1 -C 8 alkyl radical or an unsubstituted or substituted benzyl radical, R 3 is hydrogen, C 1 -C 8 alkyl, C 1 -C 8 alkoxy, cyanide or halide, preferably hydrogen and X is an anion, with the proviso that at least one of the substitutents R 1 is a benzyl radical and R 2 is a methyl radical, R 2 is not hydrogen, also to compositions therof, especially comprising other dyes, to processes for the preparation therof and to the use therof in the dyeing of organic material, such as keratin, wool, leather, silk, cellulose or polyamides, especially keratin-containging fibres, cotton or nylon, and preferably human hair.
摘要翻译：本发明涉及式（1）的新型阳离子黄色染料，其中R1和R2各自独立地为C1-C8烷基或未取代或取代的苄基，R3为氢，C1-C8烷基，C1-C8烷氧基，氰化物或卤化物，优选氢，X是阴离子，条件是至少一个取代基R 1是苄基，R 2是甲基，R 2不是氢，也包括其它染料的组合物，特别是其它染料用于制备和用于染色有机材料如角蛋白，羊毛，皮革，丝绸，纤维素或聚酰胺，特别是含角蛋白的纤维，棉或尼龙，优选人发的用途。

9. 发明申请

WO2003006554A1 A METHOD OF COLORING HAIR USING CATIONIC DYES 审中-公开
标题翻译：使用阳离子染色染发剂的方法
公开(公告)号：WO2003006554A1
公开(公告)日：2003-01-23
申请号：PCT/EP2001/008032
申请日：2001-07-11
申请人： CIBA SPECIALTY CHEMICALS HOLDING INC. , MÖCKLI, Peter , FRÖHLING, Beate, Susanne
发明人： MÖCKLI, Peter , FRÖHLING, Beate, Susanne
IPC分类号： C09B44/16
CPC分类号： A61Q5/10 , A61K8/494 , C09B44/16
摘要： The cationic dyes of formula (1) specified in claim 1 are suitable especially for colouring keratin-containing fibres, more especially for colouring hair.
摘要翻译：权利要求1中规定的式（1）的阳离子染料特别适用于着色含角蛋白的纤维，更特别适用于着色毛发。

10. 发明申请

WO2002069920A1 METHOD OF COLOURING POROUS MATERIAL 审中-公开
标题翻译：多孔材料着色方法
公开(公告)号：WO2002069920A1
公开(公告)日：2002-09-12
申请号：PCT/EP2002/002146
申请日：2002-02-28
申请人： CIBA SPECIALTY CHEMICALS HOLDING INC. , ADAM, Jean-Marie , YOUSAF, Taher , FRÖHLING, Beate
发明人： ADAM, Jean-Marie , YOUSAF, Taher , FRÖHLING, Beate
IPC分类号： A61K7/13
CPC分类号： C09B67/0079 , C07C245/24
摘要： A method of colouring porous material, especially human hair, is described, which method comprises applying to the material being coloured, in any desired order successively, or simultaneously, a) a capped diazonium compound and b) a water-soluble coupling component under conditions such that, initially, coupling does not take place, and then causing the capped diazonium compound present on the material to react with the coupling component.
摘要翻译：描述了多孔材料，特别是人发的着色方法，该方法包括以任何所需的顺序依次或同时施用着色的材料a）封端的重氮化合物和b）在条件下的水溶性偶联组分使得最初不发生偶合，然后使存在于材料上的封端重氮化合物与偶联组分反应。

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