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1. 发明公开

US20230145404A1 H2O2 WITHOUT DIBC FOR PO PRODUCTION 审中-公开
公开(公告)号：US20230145404A1
公开(公告)日：2023-05-11
申请号：US17911673
申请日：2021-03-22
申请人： BASF SE , Dow Global Technologies LLC
发明人： Dominic RIEDEL , Joaquim Henrique TELES , Jaroslaw Michael MORMUL , Andrei-Nicolae PARVULESCU , Meinolf WEIDENBACH , Franciscus Johannes Robertus VAN NEER
IPC分类号： C07D301/12
CPC分类号： C07D301/12
摘要： The invention relates in a first aspect to a process for the preparation of propylene oxide, comprising: (i) providing a reaction mixture comprising propylene, water, organic solvent, and hydrogen peroxide; (ii) contacting the reaction mixture provided in (i) in an epoxidation zone with an epoxidation catalyst comprising a zeolitic material having a framework structure comprising Si, O, and Ti, and subjecting the reaction mixture to epoxidation reaction conditions in the epoxidation zone, obtaining, in the epoxidation zone, a mixture comprising propylene oxide, water, and organic solvent; (iii) removing an effluent stream from the epoxidation zone, the effluent stream comprising propylene oxide, water, and organic solvent; wherein the reaction mixture provided in (i) and subjected to (ii) contains in an amount of at most 500 mg per kg hydrogen peroxide comprised in said reaction mixture at least one aliphatic oxygen containing compound having 8 to 10 carbon atoms. The invention further relates in a second aspect to a reaction mixture for preparing propylene oxide, comprising propylene, water, organic solvent, and hydrogen peroxide, wherein the reaction mixture comprises at least one aliphatic oxygen containing compound having 8 to 10 carbon atoms in an amount of at most 500 mg per kg hydrogen peroxide comprised in the reaction mixture. In a third aspect, the invention relates to a system comprising an epoxidation catalyst comprising a zeolitic material having a framework structure comprising Si, O, and Ti, and further comprising the reaction mixture comprising propylene, water, and organic solvent according to the second aspect. In a fourth aspect, the invention relates to the use of an aqueous hydrogen peroxide solution as epoxidation agent for preparing propylene oxide in the presence of an organic solvent and an epoxidation catalyst comprising a zeolitic material having a framework structure comprising Si, O, and Ti, wherein the aqueous hydrogen peroxide solution comprises at least one aliphatic oxygen containing compound having 8 to 10 carbon atoms in an amount of at most 500 mg per kg hydrogen peroxide comprised in the aqueous hydrogen peroxide solution.

2. 发明申请

US20200070134A1 EXTRUDABLE COMPOSITION COMPRISING A TITANIUM-CONTAINING ZEOLITIC MATERIAL HAVING FRAMEWORK TYPE MWW 审中-公开
公开(公告)号：US20200070134A1
公开(公告)日：2020-03-05
申请号：US16461134
申请日：2017-12-20
申请人： BASF SE
发明人： Andrei-Nicolae PARVULESCU , Ulrich MUELLER , Hans-Juergen LUETZEL , Georg UHL , Joaquim Henrique TELES , Dominic RIEDEL , Daniel URBANCZYK , Ulrike WEGERLE , Markus WEBER , Nicolai Tonio WOERZ , Christian MUELLER
IPC分类号： B01J29/89 , B01J37/00 , B01J35/10 , C01B37/00
摘要： A process for preparing an extrudable composition comprising a titanium-containing zeo-litic material having framework type MWW, the process comprising providing a titanium-containing zeolitic material having framework type MWW, having a water absorption ca-pacity of at least 11 weight-%, subjecting the titanium-containing zeolitic material having framework type MWW an acid treatment, optionally incorporating zinc in the acid-treated titanium-containing zeolitic material having framework type MWW; preparing a composi-tion comprising the titanium-containing zeolitic material having framework type MWW obtained from (ii) or (iii), a precursor of a silica binder, water, and a kneading agent, wherein the composition does not comprise a polyethylene oxide.

3. 发明申请

US20180215694A1 PREPARATION OF 2,6- AND 2,7-DISUBSTITUTED ANTHRAQUINONE DERIVATES 审中-公开
公开(公告)号：US20180215694A1
公开(公告)日：2018-08-02
申请号：US15315143
申请日：2015-05-28
申请人： BASF SE
发明人： Dominic RIEDEL , Joaquim Henrique TELES , Thomas WURM
IPC分类号： C07C46/08 , C07C50/20 , C07C50/18 , B01D11/04 , B01D9/00
CPC分类号： C07C46/08 , B01D9/00 , B01D11/0492 , C01B15/023 , C07C37/14 , C07C46/00 , C07C50/18 , C07C50/20 , C07C2521/02 , C07C2521/06 , C07C2523/04 , C07C2523/06 , C07C2523/42 , C07C2523/44 , C07C2523/72 , C07C2603/22 , Y02P20/582 , C07C39/23
摘要： A composition comprising a compound of formula (Va) wherein n is 1 or 2 and wherein m is 1 or 2, with n and m preferably both being 1 or both being 2, more preferably both being 1, and/or, preferably and, a compound of formula, wherein n is 1 or 2 and wherein m is 1 or 2, with n and m preferably both being 1 or both being 2, more preferably both being 1, and wherein at least 90 weight-% of the composition consist of compounds of formula (Va) and formula (Vb).

4. 发明申请

US20170246620A1 PROCESS FOR THE PREPARATION OF AN MWW ZEOLITIC MATERIAL COMPRISING BORON AND TITANIUM 审中-公开
公开(公告)号：US20170246620A1
公开(公告)日：2017-08-31
申请号：US15509527
申请日：2015-09-08
申请人： BASF SE
发明人： Andrei-Nicolae PARVULESCU , Ulrich MUELLER , Georg UHL , Joaquim Henrique TELES , Dominic RIEDEL
IPC分类号： B01J29/89 , B01J37/04 , B01J37/08 , B01J37/10 , B01J37/06 , C01B39/00 , B01J37/00
CPC分类号： B01J29/89 , B01J37/0009 , B01J37/0018 , B01J37/009 , B01J37/04 , B01J37/06 , B01J37/086 , B01J37/10 , C01B39/00 , C01B39/085 , C01B39/12 , C01B39/48 , C01P2002/72 , C01P2002/82 , C01P2002/86
摘要： A process for the preparation of a zeolitic material having an MWW framework structure and comprising boron and titanium, the process comprising (i) providing an aqueous synthesis mixture comprising a silica source, a boron source, a titanium source, and an MWW templating agent; (ii) heating the aqueous synthesis mixture to a temperature in the range of from 160 to 190° C.; (iii) subjecting the synthesis mixture (ii) to hydrothermal synthesis conditions, obtaining, in its mother liquor, a precursor of the zeolitic material; (iv) separating the precursor from its mother liquor; (v) calcining the separated precursor, obtaining the zeolitic material having an MWW framework structure and comprising boron and titanium.

5. 发明申请

US20170197830A1 PREPARATION OF 2,6- AND 2,7-DISUBSTITUTED ANTHRAQUINONE DERIVATIVES 有权
公开(公告)号：US20170197830A1
公开(公告)日：2017-07-13
申请号：US15314560
申请日：2015-05-28
申请人： BASF SE
发明人： Dominic RIEDEL , Joaquim Henrique TELES , Thomas WURM
IPC分类号： C01B15/023 , C07C46/00 , C07C50/18
CPC分类号： C01B15/023 , C07B2200/13 , C07C45/62 , C07C46/00 , C07C46/08 , C07C50/18
摘要： The present invention relates to novel anthraquinone derivatives, 2,6-diisohexylanthracene-9,10-dione and 2,7-diisohexyl-anthracene-9,10-dione, preferably to be used for the preparation of hydrogen peroxide, and to a process for the preparation of these anthraquinone derivatives.

6. 发明申请

US20160185741A1 PROCESS FOR THE PREPARATION OF PROPYLENE OXIDE 有权
标题翻译：制备丙烯氧化物的方法
公开(公告)号：US20160185741A1
公开(公告)日：2016-06-30
申请号：US14906852
申请日：2014-07-16
申请人： BASF SE , DOW GLOBAL TECHNOLOGIES LLC
发明人： Joaquim TELES , Bianca SEELIG , Dominic RIEDEL , Philip KAMPE , Daniel URBANCZYK , Markus WEBER , Ulrich MUELLER , Andrei-Nicolae PARVULESCU , Alexander SCHROEDER , Meinolf WEIDENBACH , Werner WITZL
IPC分类号： C07D301/36 , C07D301/12 , B01J35/00 , B01J29/70 , B01J27/18
CPC分类号： C07D301/36 , B01J23/06 , B01J27/18 , B01J29/7088 , B01J29/89 , B01J35/00 , B01J35/0006 , B01J35/023 , B01J35/026 , B01J37/0009 , B01J37/0045 , B01J37/0201 , B01J37/10 , B01J2229/186 , B01J2229/42 , C07D301/12 , C07D303/04 , Y02P20/52
摘要： A continuous process for the preparation of propylene oxide, comprising (i) providing a liquid feed stream comprising propene, hydrogen peroxide, acetonitrile, water, dissolved potassium dihydrogen phosphate, and optionally propane; (ii) passing the liquid feed stream provided in (i) into an epoxidation reactor comprising a catalyst comprising a titanium zeolite of structure type MWW, and subjecting the liquid feed stream to epoxidation reaction conditions; (iii) removing an effluent stream from the epoxidation reactor; wherein the concentration of the dissolved potassium dihydrogen phosphate in the liquid feed stream is at least 10% of the solubility limit of the potassium dihydrogen phosphate in the liquid feed stream.
摘要翻译：一种用于制备环氧丙烷的连续方法，包括（i）提供包含丙烯，过氧化氢，乙腈，水，溶解的磷酸二氢钾和任选的丙烷的液体进料流; （ii）将（i）中提供的液体进料流送入包含包含结构类型MWW的钛沸石的催化剂的环氧化反应器中，并使液体进料流进行环氧化反应条件; （iii）从环氧化反应器中除去流出物流; 其中所述液体进料流中溶解的磷酸二氢钾的浓度为所述液体进料流中磷酸二氢钾的溶解度极限的至少10％。

7. 发明公开

US20240294483A1 PROCESS FOR THE PREPARATION OF A LIQUID MIXTURE COMPRISING METHANOL, WATER AND HYDROGEN PEROXIDE 审中-公开
公开(公告)号：US20240294483A1
公开(公告)日：2024-09-05
申请号：US18572209
申请日：2022-06-22
申请人： BASF SE , Dow Global Technologies LLC
发明人： Andrei-Nicolae PARVULESCU , Joaquim Henrique TELES , Dominic RIEDEL , Dylan SEGERS , Massimo BERGAMO , Franciscus Johannes Robertus VAN NEER , Meinolf WEIDENBACH
IPC分类号： C07D301/12
CPC分类号： C07D301/12
摘要： The present invention relates in a first aspect to a process for the preparation of a liquid mixture comprising methanol, water and hydrogen peroxide, the process comprising: (i) providing a feed stream comprising methanol, and a feed stream comprising an aqueous hydrogen peroxide solution; (ii) combining the feed stream comprising the methanol and the feed stream comprising the aqueous hydrogen peroxide solution provided according to (i) at a point in time t1, so that a combined stream comprising methanol, hydrogen peroxide and water is obtained; (iii) filtrating the combined stream obtained according to (ii) at a point in time t2, through a filtration device, thereby obtaining a liquid mixture comprising methanol, hydrogen peroxide and water; wherein the period of time between t1 and t2 is at least 8 seconds. In a second aspect, the invention relates to the use of a liquid mixture obtained or obtainable from the process of the first aspect for the preparation of propylene oxide. A third aspect of the invention is directed to a method for the preparation of propylene oxide comprising: (i) providing a feed stream comprising methanol, a feed stream comprising an aqueous hydrogen peroxide solution and a feed stream comprising propylene; (ii) combining the feed stream comprising the methanol and the feed stream comprising the aqueous hydrogen peroxide solution provided according to (i) at a point in time t1, so that a combined stream comprising methanol, hydrogen peroxide and water is obtained; (iii) filtrating the combined stream obtained according to (ii) at a point in time t2, through a filtration device, thereby obtaining a liquid mixture comprising methanol, hydrogen peroxide and water; (iv) combining the feed stream comprising propylene either with the combined stream obtained in (ii) or with the liquid mixture obtained in (iii), thereby obtaining a liquid mixture comprising methanol, hydrogen peroxide, water and propylene; (v) bringing the liquid mixture obtained according to (iv) in an epoxidation zone in contact with an epoxidation catalyst comprising a zeolitic material having a framework structure comprising Si, O, and Ti under epoxidation reaction conditions, thereby obtaining in the epoxidation zone a mixture comprising propylene oxide, methanol and water; wherein the period of time between t1 and t2 are at least 8 seconds. In a fourth aspect, the invention relates to propylene oxide, obtained or obtainable from the method according to the third aspect.

8. 发明公开

US20230406798A1 METHOXYPROPANOLS SEPARATION COMBINING MEMBRANE SEPARATION AND DISTILLATION 审中-公开
公开(公告)号：US20230406798A1
公开(公告)日：2023-12-21
申请号：US18032668
申请日：2021-10-28
申请人： BASF SE , Dow Global Technologies LLC
发明人： Dominic RIEDEL , Maria Angel SAN PIO BORDEJE , Dylan SEGERS , Joaquim Henrique TELES , Emiel Jan KAPPERT , Ana Luiza DE OLIVEIRA , Meinolf WEIDENBACH , Franciscus Johannes Robertus VAN NEER
IPC分类号： C07C43/13
CPC分类号： C07C43/13
摘要： A first aspect of the invention relates to a process for separating 1-methoxypropan-2-ol from an aqueous stream comprising 1-methoxypropan-2-ol and 2-methoxypropan-1-ol, wherein the process comprises providing a stream SO comprising 1-methoxypropan-2-ol, 2-methoxypropan-1-ol and water, and having a molar ratio of 1-methoxypropan-2-ol:2-methoxypropan-1-ol in the range of from 1:5 to 5:1; wherein the final stream S5 comprises ≥95 weight-% 1-methoxypropan-2-ol based on the total weight of S5. In a second aspect, the invention relates to 1-methoxypropan-2-ol or a mixture of 1-methoxypropan-2-ol and 2-methoxypropan-1-ol obtained or obtainable from the process of the first aspect.

9. 发明申请

US20190322634A1 A PROCESS FOR PURIFYING PROPYLENE OXIDE 审中-公开
公开(公告)号：US20190322634A1
公开(公告)日：2019-10-24
申请号：US16315345
申请日：2017-07-19
申请人： BASF SE , Dow Global Technologies LLC
发明人： Joaquim Henrique TELES , Marvin KRAMP , Christian MUELLER , Nicolai Tonio WOERZ , Bernd METZEN , Tobias KELLER , Dominic RIEDEL , Heiner SCHELLING , Markus WEBER , Daniel URBANCZYK , Andrei-Nicolae PARVULESCU , Ulrike WEGERLE , Ulrich MUELLER , Meinolf WEIDENBACH , Werner J. WITZI
IPC分类号： C07D301/32 , C07D303/04 , B01D3/14
摘要： Disclosed is a process for purifying propylene oxide. A stream S0 containing propylene oxide, acetonitrile, water, and an organic compound containing one or more of acetone and propionaldehyde is provided. Propylene oxide is separated from S0 by subjecting S0 to distillation in a first distillation unit, obtaining a gaseous top stream S1c enriched in propylene oxide, a liquid bottom stream S1a enriched in acetonitrile and water, and a side stream S1b containing propylene oxide and enriched in the carbonyl compound; reacting the carbonyl compound in S1b with an organic compound containing an amino group to obtain a reaction product; separating propylene oxide from the reaction product in a second distillation unit, obtaining a gaseous top stream S3a enriched in propylene oxide and a liquid bottoms stream S3b enriched in the reaction product; and introducing stream S3a into the first distillation unit.

10. 发明申请

US20190077779A1 A PROCESS FOR THE PREPARATION OF PROPYLENE OXIDE 审中-公开
公开(公告)号：US20190077779A1
公开(公告)日：2019-03-14
申请号：US16076600
申请日：2017-02-16
申请人： BASF SE
发明人： Dominic RIEDEL , Joaquim Henrique TELES , Heiner SCHELLING , Ulrike WEGERLE , Ulrich MUELLER , Andrei-Nicolae PARVULESCU , Jochen MANNWEILER , Timo HENN , Thomas LUEDERITZ , Nicolai Tonio WOERZ , Christian MUELLER , Markus WEBER , Daniel URBANCZYK
IPC分类号： C07D301/12 , C07D301/36 , B01J29/70 , B01J19/00
CPC分类号： C07D301/12 , B01J19/0013 , B01J29/7088 , B01J2219/00033 , B01J2219/00051 , B01J2219/00162 , B01J2219/00166 , C07D301/36 , C07D303/04
摘要： A continuous process for the preparation of propylene oxide, comprising a start-up stage and normal run stage, wherein the normal run stage comprises (i) continuously providing a liquid feed stream comprising propene, hydrogen peroxide, acetonitrile, a formate salt, water and optionally propane, wherein in the liquid feed stream, the molar amount of the formate salt relative to the molar amount of hydrogen peroxide at a given point of time during the normal run stage is aN(Fo/H2O2); (ii) continuously passing the liquid feed stream provided in (i) into an epoxidation zone comprising a catalyst comprising a titanium zeolite having framework type MWW, and subjecting the liquid feed stream to epoxidation reaction conditions in the epoxidation zone, obtaining a reaction mixture comprising propylene oxide, acetonitrile, water, the formate salt, optionally propene, and optionally propane; (iii) continuously removing an effluent stream from the epoxidation zone, the effluent stream comprising propylene oxide, acetonitrile, water, at least a portion of the formate salt, optionally propene, and optionally propane; wherein the normal run stage is characterized in an average rate of change of aN(Fo/H2O2) of less than 0 h−1.

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