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    • 1. 发明公开
    • SHUTDOWN METHOD FOR A PROCESS FOR PREPARING AN OLEFIN OXIDE
    • US20240279194A1
    • 2024-08-22
    • US18569645
    • 2022-06-14
    • BASF SEDow Global Technologies LLC
    • Dominic RIEDELMaria Angel SAN PIO BORDEJEJoaquim Henrique TELESAndrei-Nicolae PARVULESCUDylan SEGERSMeinolf WEIDENBACHFranciscus Johannes Robertus VAN NEERMassimo BERGAMO
    • C07D303/04
    • C07D303/04
    • In a first aspect, the present invention relates to a shutdown method for a process for preparing an olefin oxide comprising a normal run stage, wherein the normal run stage comprises providing olefin, hydrogen peroxide and organic solvent into an epoxidation zone comprising an heterogeneous epoxidation catalyst, so that a reaction mixture comprising olefin, hydrogen peroxide and organic solvent is formed and subjecting the reaction mixture to epoxidation reaction conditions in the epoxidation zone, thereby obtaining a mixture comprising olefin oxide and organic solvent; wherein the shutdown method comprises (a) providing olefin and organic solvent for a period of time t1 to the epoxidation zone, so that a mixture is formed, which is essentially free of hydrogen peroxide; (b) contacting the mixture from (a) over t1 under epoxidation reaction conditions in the epoxidation zone with the heterogeneous epoxidation catalyst; (c) removing during t1 an effluent stream from the epoxidation zone, the effluent stream comprising olefin and organic solvent. In a second aspect, the present invention relates to a process for preparing an olefin oxide comprising a normal run stage and a shutdown stage, wherein the normal run stage comprises (A) providing olefin, hydrogen peroxide, water and organic solvent into an epoxidation zone comprising an heterogeneous epoxidation catalyst, so that a reaction mixture comprising olefin, hydrogen peroxide, water and organic solvent is formed; (B) subjecting the reaction mixture from (I) to epoxidation reaction conditions in the epoxidation zone, thereby obtaining a mixture comprising olefin oxide, water and organic solvent; (C) removing an effluent stream from the epoxidation zone, comprising olefin oxide, water and organic solvent; wherein the shutdown stage comprises steps (a), (b) and (c) as described with respect to the first aspect.
    • 4. 发明申请
    • PART-STREAM DISTILLATION
    • US20160115140A1
    • 2016-04-28
    • US14787956
    • 2014-04-28
    • BASF SEDOW GLOBAL TECHNOLOGIES LLC
    • Joaquim H. TELESDominic RIEDELBianca SEELIGPhilip KAMPEDaniel URBANCZYKMarkus WEBERAlexander SCHROEDERAndrei-Nicolae PARVULESCUUlrich MUELLERMeinolf WEIDENBACHWerner WITZLHolger BAER
    • C07D301/12B01D3/14C07D301/32
    • C07D301/12B01D3/143C07D301/32
    • A continuous process for the preparation of propylene oxide, comprising (a) reacting propene, optionally admixed with propane, with hydrogen peroxide in a reaction apparatus in the presence of acetonitrile as solvent, obtaining a stream S0 containing propylene oxide, acetonitrile, water, at least one further component B, optionally propene and optionally propane, wherein the normal boiling point of the at least one component B is higher than the normal boiling point of acetonitrile and wherein the decadic logarithm of the octanol-water partition coefficient (log Kow) of the at least one component B is greater than zero; (b) separating propylene oxide from S0, obtaining a stream S1 containing acetonitrile, water and the at least one further component B; (c) dividing S1 into two streams S2 and S3; (d) subjecting S3 to a vapor-liquid fractionation in a fractionation unit, obtaining a vapor fraction stream S4 being depleted of the at least one component B; (e) recycling at least a portion of S4, optionally after work-up, to (a).
    • 一种用于制备环氧丙烷的连续方法,包括(a)在乙腈作为溶剂的存在下,在反应装置中将丙烯任选与丙烷混合,与过氧化氢反应,得到含有环氧丙烷,乙腈,水的流S0 至少一种另外的组分B,任选的丙烯和任选的丙烷,其中至少一种组分B的标准沸点高于乙腈的标准沸点,其中辛醇 - 水分配系数(log Kow)的十进制对数 所述至少一个组分B大于零; (b)从S0分离环氧丙烷,得到含有乙腈,水和至少一种其它组分B的料流S1; (c)将S1划分成两个流S2和S3; (d)使S3在分馏装置中进行汽 - 液分馏,得到耗尽至少一种B成分的蒸汽馏分流S4; (e)将至少一部分S4,任选地在后处理之后再循环至(a)。
    • 5. 发明公开
    • H2O2 WITHOUT DIBC FOR PO PRODUCTION
    • US20230145404A1
    • 2023-05-11
    • US17911673
    • 2021-03-22
    • BASF SEDow Global Technologies LLC
    • Dominic RIEDELJoaquim Henrique TELESJaroslaw Michael MORMULAndrei-Nicolae PARVULESCUMeinolf WEIDENBACHFranciscus Johannes Robertus VAN NEER
    • C07D301/12
    • C07D301/12
    • The invention relates in a first aspect to a process for the preparation of propylene oxide, comprising: (i) providing a reaction mixture comprising propylene, water, organic solvent, and hydrogen peroxide; (ii) contacting the reaction mixture provided in (i) in an epoxidation zone with an epoxidation catalyst comprising a zeolitic material having a framework structure comprising Si, O, and Ti, and subjecting the reaction mixture to epoxidation reaction conditions in the epoxidation zone, obtaining, in the epoxidation zone, a mixture comprising propylene oxide, water, and organic solvent; (iii) removing an effluent stream from the epoxidation zone, the effluent stream comprising propylene oxide, water, and organic solvent; wherein the reaction mixture provided in (i) and subjected to (ii) contains in an amount of at most 500 mg per kg hydrogen peroxide comprised in said reaction mixture at least one aliphatic oxygen containing compound having 8 to 10 carbon atoms. The invention further relates in a second aspect to a reaction mixture for preparing propylene oxide, comprising propylene, water, organic solvent, and hydrogen peroxide, wherein the reaction mixture comprises at least one aliphatic oxygen containing compound having 8 to 10 carbon atoms in an amount of at most 500 mg per kg hydrogen peroxide comprised in the reaction mixture. In a third aspect, the invention relates to a system comprising an epoxidation catalyst comprising a zeolitic material having a framework structure comprising Si, O, and Ti, and further comprising the reaction mixture comprising propylene, water, and organic solvent according to the second aspect. In a fourth aspect, the invention relates to the use of an aqueous hydrogen peroxide solution as epoxidation agent for preparing propylene oxide in the presence of an organic solvent and an epoxidation catalyst comprising a zeolitic material having a framework structure comprising Si, O, and Ti, wherein the aqueous hydrogen peroxide solution comprises at least one aliphatic oxygen containing compound having 8 to 10 carbon atoms in an amount of at most 500 mg per kg hydrogen peroxide comprised in the aqueous hydrogen peroxide solution.
    • 7. 发明公开
    • PROCESS FOR THE PREPARATION OF A LIQUID MIXTURE COMPRISING METHANOL, WATER AND HYDROGEN PEROXIDE
    • US20240294483A1
    • 2024-09-05
    • US18572209
    • 2022-06-22
    • BASF SEDow Global Technologies LLC
    • Andrei-Nicolae PARVULESCUJoaquim Henrique TELESDominic RIEDELDylan SEGERSMassimo BERGAMOFranciscus Johannes Robertus VAN NEERMeinolf WEIDENBACH
    • C07D301/12
    • C07D301/12
    • The present invention relates in a first aspect to a process for the preparation of a liquid mixture comprising methanol, water and hydrogen peroxide, the process comprising: (i) providing a feed stream comprising methanol, and a feed stream comprising an aqueous hydrogen peroxide solution; (ii) combining the feed stream comprising the methanol and the feed stream comprising the aqueous hydrogen peroxide solution provided according to (i) at a point in time t1, so that a combined stream comprising methanol, hydrogen peroxide and water is obtained; (iii) filtrating the combined stream obtained according to (ii) at a point in time t2, through a filtration device, thereby obtaining a liquid mixture comprising methanol, hydrogen peroxide and water; wherein the period of time between t1 and t2 is at least 8 seconds. In a second aspect, the invention relates to the use of a liquid mixture obtained or obtainable from the process of the first aspect for the preparation of propylene oxide. A third aspect of the invention is directed to a method for the preparation of propylene oxide comprising: (i) providing a feed stream comprising methanol, a feed stream comprising an aqueous hydrogen peroxide solution and a feed stream comprising propylene; (ii) combining the feed stream comprising the methanol and the feed stream comprising the aqueous hydrogen peroxide solution provided according to (i) at a point in time t1, so that a combined stream comprising methanol, hydrogen peroxide and water is obtained; (iii) filtrating the combined stream obtained according to (ii) at a point in time t2, through a filtration device, thereby obtaining a liquid mixture comprising methanol, hydrogen peroxide and water; (iv) combining the feed stream comprising propylene either with the combined stream obtained in (ii) or with the liquid mixture obtained in (iii), thereby obtaining a liquid mixture comprising methanol, hydrogen peroxide, water and propylene; (v) bringing the liquid mixture obtained according to (iv) in an epoxidation zone in contact with an epoxidation catalyst comprising a zeolitic material having a framework structure comprising Si, O, and Ti under epoxidation reaction conditions, thereby obtaining in the epoxidation zone a mixture comprising propylene oxide, methanol and water; wherein the period of time between t1 and t2 are at least 8 seconds. In a fourth aspect, the invention relates to propylene oxide, obtained or obtainable from the method according to the third aspect.