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1. 发明申请

WO2006042585A8 COATING AGENTS CONTAINING ADDUCTS HAVING AN ALKOXYSILANE FUNCTIONALITY 审中-公开
标题翻译：涂层剂含有烷氧基硅烷加合物
公开(公告)号：WO2006042585A8
公开(公告)日：2007-05-24
申请号：PCT/EP2005009495
申请日：2005-09-03
申请人： BASF COATINGS AG , POPPE ANDREAS , WESTHOFF ELKE , STUEBBE WILFRIED , NIEMEIER MANUELA , MIKOLAJETZ DUNJA , HESENER SIMONE , BROSSEIT ANDRE , WERMELT KARIN , KLEIN GUENTER , MOELLERS MARTINA
发明人： POPPE ANDREAS , WESTHOFF ELKE , STUEBBE WILFRIED , NIEMEIER MANUELA , MIKOLAJETZ DUNJA , HESENER SIMONE , BROSSEIT ANDRE , WERMELT KARIN , KLEIN GUENTER , MOELLERS MARTINA
IPC分类号： C09D175/04 , B05D1/36 , C08G18/80
CPC分类号： C08G18/792 , C08G18/222 , C08G18/809 , C09D175/00
摘要： The invention relates to coating agents that contain (A) at least 50 % by weight, based on the content in nonvolatile substances in the coating agent, of at least one compound (A1) having at least one reactive group of formula (I) -NR-C(O)-N-(X-SiR"x(OR')3-x)n(X'-SiR"y(OR')3-y)m (I), wherein R = hydrogen, alkyl, cycloalkyl, aryl or aralkyl, whereby the carbon chain may be interrupted by non-vicinal oxygen, sulfur or Nra groups, with Ra = alkyl, cycloalkyl, aryl or aralkyl, R'= hydrogen, alkyl, cycloalkyl, aryl or aralkyl, whereby the carbon chain may be interrupted by non-vicinal oxygen, sulfur or Nra groups, X,X' = linear and/or branched alkylene or cycloalkylene group having 2 to 20 carbon atoms, R" = alkyl, cycloalkyl, aryl, or aralkyl, whereby the carbon chain may be interrupted by non-vicinal oxygen, sulfur or Nra groups, n = 0 to 2, m = 0 to 2, m+n = 2, and x,y = 0 to 2, (B) a catalyst for cross-linking the -Si(OR')3-x(y) units, and (C) an aprotic solvent or a mixture of aprotic solvents.
摘要翻译：本发明涉及包含涂料组合物（A）至少50重量％，基于非挥发性物质在涂层组合物具有式（I）中的至少一个反应性基团的量，至少一种化合物（A1）-NR-C（O） - N-（X-SIR “×（OR“）3-X）N（X'-SIR” Y（OR'）3-Y）M（I）其中R =氢，烷基，环烷基，芳基或芳烷基，所述碳链可被不相邻的氧，硫或NR a的基团间隔，其中R a =烷基，环烷基，芳基或芳烷基，R“=氢，烷基，环烷基，芳基或芳烷基，不相邻的氧碳链，硫或NR a的基团可以被中断，X，X“=直链和/或支链亚烷基或亚环烷基的碳原子数2〜20，R“=烷基，环烷基，芳基，或芳烷基，不相邻的氧碳链，可以是硫或NR a的基团中断，n = 0至2，m = 0至2，M + N = 2，并且x，y = 0到 2，（B）为-Si（OR“）3-X（Y）单元，和（C）的非质子性溶剂或非质子溶剂的混合物的交联的催化剂。

2. 发明申请

WO2006042584A8 HIGHLY SCRATCH-RESISTANT AND HIGHLY ELASTIC COATING AGENTS BASED ON ALKOXYSILANE-FUNCTIONAL COMPONENTS 审中-公开
标题翻译：高防刮和高弹性涂层剂的基于烷氧基硅烷的功能组件
公开(公告)号：WO2006042584A8
公开(公告)日：2007-05-03
申请号：PCT/EP2005009494
申请日：2005-09-03
申请人： BASF COATINGS AG , POPPE ANDREAS , KLEIN GUENTER , BROSSEIT ANDRE , WERMELT KARIN , MOELLERS MARTINA
发明人： POPPE ANDREAS , KLEIN GUENTER , BROSSEIT ANDRE , WERMELT KARIN , MOELLERS MARTINA
IPC分类号： C09D175/04 , B05D1/36 , C08G18/28
CPC分类号： C08G18/284 , C08G18/631 , C08G18/706 , C08L2666/02 , C09D175/06 , C09J133/04 , Y10T428/31663
摘要： The invention relates to thermally curing coating agents which comprise (A) at least 50 % by weight, based on the content in nonvolatile substances in the coating agent, of (A1) 0 to 50 % by weight, based on the total of components (A1) and (A2), of a polymethacrylate copolymer which comprises more than 50 % by weight, based on the total of comonomers in copolymer (A1), of a radically polymerizable, ethylenically unsaturated compounds (a1) having at least one reactive group of formula (I) -X-SiR"x(OR')3-x (I), and (A2) 50 to 100 % by weight, based on the total of components (A1) and (A2), of an adduct from polyisocyanate and alkoxysilane, whereby (A2) contains at least one reactive group of formula (II): -NR-C(O)-N-(X-SiR"x(OR')3-x)n(X'-SiR"y(OR')3-y)m (II), (B) a catalyst for cross-linking the -Si(OR')3-x units, and (C) an aprotic solvent or a mixture of aprotic solvents.
摘要翻译：热固性涂料组合物，包括（A）至少50重量％的基础上，在涂布剂的非易失性物质的量，（A1）0〜50重量％，基于总组分（A1）和（A2），含有超过50重量％（a1）中具有式（I）的至少一个反应性基团的聚甲基丙烯酸酯共聚物，基于该共聚物中的共聚单体（A1）的整体上，的可自由基聚合的烯属不饱和化合物-X-SIR “×（OR“）3-x（I）和（A2）50〜100重量％，基于总组分（A1）和（A2），聚异氰酸酯和烷氧基硅烷的加合物，其中，（A2）的至少的反应性基团的式II：-NR-C（O）-N-（X-SIR “×（OR“）3-X）N（X'-SIR” Y（OR'）3-Y）M（ II），（B）为-Si（OR“的交联催化剂）3-X单元，和（C）的非质子性溶剂或非质子溶剂的混合物。

3. 发明申请

WO2008110229A3 COATING AGENT CONTAINING ADDITION COMPOUNDS WITH SILANE FUNCTIONALITY AND HIGHLY SCRATCH-RESISTANT COATINGS WITH IMPROVED CRACK RESISTANCE 审中-公开
标题翻译：含有具有改进的抗风险性的高功能性添加剂和高循环涂层的涂料制造品
公开(公告)号：WO2008110229A3
公开(公告)日：2008-12-31
申请号：PCT/EP2008000441
申请日：2008-01-22
申请人： BASF COATINGS AG , POPPE ANDREAS , WEGNER EGON , KLEIN GUENTER
发明人： POPPE ANDREAS , WEGNER EGON , KLEIN GUENTER
IPC分类号： C09D183/04 , C08G18/61
CPC分类号： C09D5/29 , C08G18/289 , C08G18/61 , C08G18/6254 , C08G18/792 , C08G18/809 , C08L75/12 , C09D143/04 , C09D175/04 , C08L2666/20 , C08L2666/16
摘要： The invention relates to coating agents containing a film-forming material comprising at least one reactive functional group G´´´, a catalyst for cross-linking the silane groups, aprotic solvents, and at least one addition compound with silane functionality, that can be produced by an addition reaction of (a) at least one silane (S1) comprising at least one functional group G´ reactive with the complementary functional groups G´´ of the compound (O), and (b) at least one compound (O) comprising at least one complementary functional group G´´ and at least one surface-active radical. The invention also relates to multilayer lacquers having a transparent coating produced from said coating agents, and to methods for producing said multilayer lacquers and the use thereof. The invention further relates to the use of a mixture of the addition compound with silane functionality and the catalyst for cross-linking the silane groups in methods for improving the hardness and/or the scratch resistance of coatings.
摘要翻译：本发明涉及包含具有至少一个反应性官能团G“””，的催化剂用于硅烷基团，非质子溶剂和至少一种加成物与硅烷官能度，其可以通过（a）至少一种硅烷的加成反应来制备的交联膜形成用材料的涂料组合物（ S1），其具有至少一个能与化合物（O）的互补官能团G“反应的官能团G'，和（b）至少一种含有至少一个互补官能团G”的化合物（O）和具有至少一个表面活性基团。本发明还涉及多层涂料体系，其中透明涂料已由这些涂料组合物生产，并涉及生产这些多层涂料体系的方法及其用途。最后，本发明还涉及加合物与硅烷官能团的混合物和催化剂在改进涂层的硬度和/或耐刮擦性的方法中用于交联硅烷基团的用途。

4. 发明申请

WO2008148554A1 BINDING AGENTS HAVING HIGH OH NUMBER AND CLEAR PAINT COMPOSITION COMPRISING SAID AGENTS AND HAVING GOOD OPTICAL CHARACTERISTICS AND GOOD SCRATCH AND CHEMICAL RESISTANCE 审中-公开
标题翻译：粘接剂及高哦 - 具有良好的光学性能和良好的耐刮擦性和耐化学性数目并含有清漆组合物
公开(公告)号：WO2008148554A1
公开(公告)日：2008-12-11
申请号：PCT/EP2008004494
申请日：2008-06-05
申请人： BASF COATINGS JAPAN LTD , BASF COATINGS AG , NIMI RUI , POPPE ANDREAS , KLEIN GUENTER , FELDMANN BJOERN , CLAUSEN-MEIRING ULRIKE
发明人： NIMI RUI , POPPE ANDREAS , KLEIN GUENTER , FELDMANN BJOERN , CLAUSEN-MEIRING ULRIKE
IPC分类号： C08G18/42 , C08G63/91 , C08G83/00 , C09D201/00
CPC分类号： C08G18/42 , C08G63/912 , C08G83/006 , C09D167/00 , C09D201/005
摘要： The present invention relates to hydroxyfunctional binding agents having a hydroxyl number = 180 determined according to DIN 53240 and a solubility parameter SP = 10 and to clear paint compositions comprising the binding agent. The present invention further relates to a method for producing the hydroxyfunctional binding agent, the use thereof for producing clear paint coating compositions for automotive series painting, and substrates coated with the clear paint composition according to the invention.
摘要翻译：本发明涉及羟基官能的粘合剂具有的羟基数= 180根据DIN 53240和溶解度参数SP = 10确定，并且粘合剂占组合物清漆。此外，本发明提供了用于制备羟基官能的粘合剂，其用于制备透明涂料组合物用于汽车OEM精加工使用和涂覆有本发明的透明涂料组合物涉及衬底的方法。

5. 发明专利

DE102008050916A1 未知
公开(公告)号：DE102008050916A1
公开(公告)日：2010-04-15
申请号：DE102008050916
申请日：2008-10-10
申请人： BASF COATINGS AG
发明人： POPPE ANDREAS , HOLTSCHULTE SABINE , FELDMANN BJOERN , KLEIN GUENTER , HILGE OLIVER
IPC分类号： C09D175/00 , C07C275/06 , C07F7/10 , C07F7/18 , C09D7/12 , C09D183/04

6. 发明专利

DE102007061855A1 未知
公开(公告)号：DE102007061855A1
公开(公告)日：2009-06-25
申请号：DE102007061855
申请日：2007-12-19
申请人： BASF COATINGS AG
发明人： POPPE ANDREAS , HOLTSCHULTE SABINE , FELDMANN BJOERN , HILGE OLIVER , KLEIN GUENTER
IPC分类号： C09D175/04 , B05D1/38 , C09D5/00 , C09D7/12 , C09D7/45 , C09D133/04 , C09D183/04

7. 发明专利

DE102004050748A1 未知
公开(公告)号：DE102004050748A1
公开(公告)日：2006-04-20
申请号：DE102004050748
申请日：2004-10-19
申请人： BASF COATINGS AG
发明人： POPPE ANDREAS , KUTSCHERA MICHAEL , KLEIN GUENTER
IPC分类号： C09D133/08 , C09D5/46 , C09D183/10
摘要： The invention relates to coating agents, containing (A) at least 50 wt. %, (in relation to the content of non-volatile substances in said coating agent), of at least one compound (A1) and/or (A1′) comprising at least two reactive groups of formula (I): —X—SiR″x(OR′)3-x, in which R′=hydrogen, alkyl or cycloalkyl, whereby the carbon chain can be interrupted by non-adjacent oxygen, sulphur or NRa groups, Ra=alkyl, cycloalkyl, aryl or aralkyl, X=a linear and/or branched alkene or cycloalkene group comprising between 2 and 20 carbon atoms, R″=alkyl, cycloalkyl, aryl or aralkyl, whereby the carbon chain can be interrupted by non-adjacent oxygen, sulphur or NRa groups, and x=0 to 2, (B) a catalyst for cross-linking the —Si(OR′)3-x units, and (C) an organic solvent or a mixture of organic solvents. According to the invention, during the curing of the coating agents, the reactive groups (I) are cross-linked in such a way, that the following characteristics are noted during the nanoindentation test on the cured coating: elastic recovery of volume >86.5%; plastic deformation

8. 发明专利

DE10335491A1 Thermosetting clear coating composition, used in coil coating, e.g. for automotive use, contains acrylate polymer, polyester with cycloaliphatic units and 2 blocked polyisocyanates with units imparting flexibility and rigidity respectively 未知
公开(公告)号：DE10335491A1
公开(公告)日：2005-02-24
申请号：DE10335491
申请日：2003-08-02
申请人： BASF COATINGS AG
发明人： KLEIN GUENTER , ROECKRATH ULRIKE , NIEMANN JUERGEN , POTH ULRICH , BROSSEIT ANDRE , WERMELT KARIN , SCHMELING ALEXANDRA
IPC分类号： C08G18/40 , C08G18/72 , C08G18/80 , C09D175/04 , C09D133/14 , C09D167/02 , C09D5/46
摘要： Thermosetting clear coating composition contains (A) (meth)acrylate (co)polymer(s), (B) polyester(s) with cycloaliphatic structural units and (C, D) blocked polyisocyanate(s). Values are given for (A, B) molecular weight, hydroxyl number and (B) acid number; and structural unit(s) bound to the blocking groups impart (C) flexibility, (D) rigidity and (C) lower. Thermosetting clear coating composition contains (wt.%) (A) 10-40% (meth)acrylate (co)polymer(s) of number average molecular weight Mn 1000-6000 dalton, glass transition temperature (Tg) -15 to +70[deg]C and hydroxyl (OH) number 80-200 mg KOH/g; (B) 10-40% polyester(s) with 30-70% cycloaliphatic structural units, having Mn 800-5000 dalton, OH number 80-200 and acid number 1-50 mg KOH/g, (C) 10-40% blocked polyisocyanate(s) with blocking groups bound to flexibilizing structural unit(s) that lower the Tg of a 3-dimensional (3D) network and (D) 10-40% blocked polyisocyanate(s) with blocking groups bound to structural unit(s) that impart rigidity and raise the Tg of a 3D network. An independent claim is also included for production of the coating composition by mixing components (A-D) and optionally additive(s) and homogenizing the mixture.

9. 发明专利

CA2671662C COATING COMPOSITIONS WITH HIGH SCRATCH RESISTANCE AND WEATHERING STABILITY 未知
公开(公告)号：CA2671662C
公开(公告)日：2016-03-08
申请号：CA2671662
申请日：2007-12-19
申请人： BASF COATINGS AG
发明人： GROENEWOLT MATTHIJS , POPPE ANDREAS , KLEIN GUENTER , NIEMEIER MANUELA , WESTHOFF ELKE , STUEBBE WILFRIED , HESENER SIMONE
IPC分类号： C08G18/28 , C08G18/62 , C08G18/77 , C08G18/80 , C09D175/04
摘要： The invention relates to coating agents which contain: a) at least one hydroxyl group containing compound (A), b) at least one isocyanate group containing compound (B), c) at least one catalyst (D) for cross-linking silane groups, wherein: i) one or more components of the coating agent contain hydrolysable silane groups and ii) the coating agent can be finally hardened to give a coating having randomly distributed regions of an Si-O-Si network. The coating agents according to the invention are characterized in that the catalyst (D) or the catalysts (D) contain phosphorus.

10. 发明专利

MX2009005613A AGENTES DE REVESTIMIENTO QUE TIENEN ALTA RESISTENCIA AL RAYADO Y ESTABILIDAD AL DESGASTE POR LA INTEMPERIE. 未知
公开(公告)号：MX2009005613A
公开(公告)日：2009-06-08
申请号：MX2009005613
申请日：2007-12-19
申请人： BASF COATINGS AG
发明人： POPPE ANDREAS , WESTHOFF ELKE , STUEBBE WILFRIED , KLEIN GUENTER , NIEMEIER MANUELA , HESENER SIMONE , GROENEWOLT MATTHIJS
IPC分类号： C08G18/28 , C08G18/62 , C08G18/77 , C08G18/80 , C09D175/04
摘要： La invención se refiere a agentes de revestimiento que contienen: (a) por lo menos un compuesto que contiene hidroxilo (A), (b) por lo menos un compuesto (B) que tiene grupos isocianato libres y/o bloqueados, (c) por lo menos un catalizador (D) para el entrelazamiento de los grupos silano, en donde (i) por lo menos un catalizador (D) para el entrelazamiento de los grupos silano, en donde (i) uno o más constituyentes de la composición de revestimiento contienen grupos de silano hidrolizables y (ii) la composición de revestimiento finalmente pueden curarse a un revestimiento que estadísticamente tiene regiones distribuidas de una red de Si-O-Si, en donde el revestimiento finalmente curado obtenido de la composición de revestimiento tiene un índice de entrelazamiento posterior (PCI) menor a 2, en donde el índice de entrelazamiento posterior (PCI) se define como la relación del módulo de almacenamiento E'(200) del revestimiento curado finalmente, medido a 200ºC, al mínimo del módulo de almacenamiento E' (min) del revestimiento finalmente curado, medido a una temperatura por arriba de la temperatura de transición de vidrio medida Tg, los módulos de almacenamiento E'(200) y E'(min) y también la temperatura de transición de vidrio Tg habiendo sida medida en tres películas con un grosor de 40 µm + 10 µm por termo-análisis dinámico-mecánico (DMTA, por sus siglas en inglés) a un régimen de calentamiento 2K por minuto y a una frecuencia de 1 Hz, y las mediciones de DMTA en tres películas con un grosor de 40 µm +/- 10 µm que se han curado durante 20 minutos a una temperatura del artículo de 140ºC y almacenado a 25ºC durante 8 días después de la curación se llevaron a cabo antes de las mediciones de DMTA.

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