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1. 发明申请

WO1997043336A1 FLAME-RESISTANT THERMOPLASTIC MOULDING MATERIALS WITH IMPROVED PROCESSING BEHAVIOUR 审中-公开
标题翻译：具有改进的加工性能阻燃热塑性模塑材料
公开(公告)号：WO1997043336A1
公开(公告)日：1997-11-20
申请号：PCT/EP1997002290
申请日：1997-05-06
申请人： BASF AKTIENGESELLSCHAFT , WEBER, Martin , SEIBRING, Joachim
发明人： BASF AKTIENGESELLSCHAFT
IPC分类号： C08K05/5397
CPC分类号： C08K5/5397 , C08K5/523 , C08L25/06 , C08L53/025 , C08L63/00 , C08L71/123 , C08L2666/14 , C08L2666/04
摘要： The invention relates to flame-resistant thermoplastic moulding materials, containing (A) at least one polyphenylene ether and (B) at least one vinyl aromatic polymer, which are characterised in that they contain (C) as a flame-protection agent a mixture of (C1) at least one oligo phosphorus compound of general formula (I) and/or (II), in which R and R are independently of each other optionally substituted alkyl or aryl; R and R are independently of each other optionally substituted alkyl, aryl, alkoxy or aryloxy; R is alkylene, -SO2-, -CO-, -N=N- or -(R )P(O)-, R being optionally substituted alkyl, aryl or alkylaryl; and n and p including independently of each other have a value of from 1 to 30; and (C2) at least one phosphine oxide of general formula (III) in which R , R and R are independently of each other a hydrogen atom, optionally substituted alkyl, aryl, alkylaryl or cycloalkyl with up to 40 C-atoms. The invention also relates to the use of said flame-resistant thermoplastic moulding materials to produce flame-resistant moulded structures, fibres and sheets.
摘要翻译：本发明涉及阻燃包括阻燃的热塑性模塑组合物：（A）至少一种聚苯醚和（B）至少一种乙烯基芳族聚合物，其特征在于，它们：（C）作为阻燃剂（的（C1的混合物）通式中的至少一种低聚磷 I）和/或（II）其中R是<1>和R <4>独立地表示任选取代的烷基或芳基; [R <2>和R <3>独立地是任选取代的烷基，芳基，烷氧基或芳氧基，R <5>为亚烷基，-SO 2 - ， - CO - ， - N = N-或 - （R <6> ）p（O） - ，其中R <6>是任选取代的烷基，芳基或烷芳基并且n和p独立地取为1至30的值; 和（C2）通式中的至少一种膦氧化物（III）其中R <7> - [R <8>和R <9>各自独立为氢原子，任选取代的烷基，芳基，烷芳基或环烷基具有至多40个碳原子都包括在内，和它们用于制备阻燃的模制品，纤维和薄膜的用途。

2. 发明申请

WO1998013420A1 THERMOPLASTIC MOULDING COMPOUNDS 审中-公开
标题翻译：热塑性模塑化合物
公开(公告)号：WO1998013420A1
公开(公告)日：1998-04-02
申请号：PCT/EP1997005001
申请日：1997-09-12
申请人： BASF AKTIENGESELLSCHAFT , ITTEMANN, Peter , NEUMANN, Rainer , SEIBRING, Joachim , ROSENAU, Bernhard , KÖTTING, Manfred , GINSS, Christophe , GÜNTHERBERG, Norbert , MEYER, Christian
发明人： BASF AKTIENGESELLSCHAFT
IPC分类号： C08L25/04
CPC分类号： C08L51/04 , C08L2666/02
摘要： Thermoplastic moulding compounds contain, in relation to the total weight of the moulding compound: (A) 72 to 88.5 wt % of a thermoplastic polymer which, in relation to (A), consists of (a1) 50 to 100 wt % styrene or alpha -methylstyrene or their mixtures; (a2) 0 to 50 wt % acryl nitrile; (a3) 0 to 50 wt % one or several other monoethylenically unsaturated monomers; (B) 10 to 20 wt % of a first graft polymer with a mean particle diameter d50 of 400 to 600 nm and which, in relation to B, consists of (b1) 30 to 90 wt % of a rubber elastic graft core (with (b11) 80 to 99.99 wt % n-butylacrylate, (b12) 0.01 to 20 wt % of at least one cross-linking monomer, (b13) 0 to 40 wt % one or several other monoethylenically unsaturated monomers); (b2) 10 to 70 wt % of a graft shell (with in relation to (b2): (b21) 50 to 100 wt % styrene or alpha -methylstyrene or their mixtures, (b22) 0 to 50 wt % acryl nitrile, (b23) 0 to 50 wt % of one or several other monoethylenically unsaturated monomers); (C) 1.5 to 8 wt % of a second graft polymer with bimodal particle size distribution with mean particle diameters d50 of 25 to 200 nm on the one hand and 350 to 550 nm on the other hand, and which, in relation to (C), consists of (c1) 30 to 90 wt % of a rubber elastic graft core (with (c11) 50 to 100 wt % butadiene or isoprene or their mixtures, (c12) 0 to 50 wt % one or several other monoethylenically unsaturated monomers); (c2) 10 to 70 wt % of a graft shell (with (c21) 50 to 100 wt % styrene or alpha -methylstyrene or their mixtures, (c22) 0 to 50 wt % acryl nitrile, (c23) 0 to 50 wt % one or several other monoethylenically unsaturated monomers); (D) 0 to 50 wt % parting agents or mould release agents, pigments, dyes, fire-proofing agents, antioxidants, stabilisers against exposure to light, fibrous or powdery fillers or reinforcing agents or antistatic agents, or other additives or their mixtures. The sum of graft polymers (B) and (C) equals 11.5 to 25 wt % of the sum of the three components (A), (B) and (C), and the sum of the four components (A) to (D) equals 100 wt %.
摘要翻译：含有一种热塑性模塑材料，基于模塑组合物的总重量，（A）72至88.5重量的热塑性聚合物的重量％，基于（A），（A1）苯乙烯或α-甲基苯乙烯的50〜100重量％或它们的混合物，（A2）0〜50重量丙烯腈％，（a3）的0至50重量％的一种或多种其它单烯属不饱和单体的％，（B）10至20重量的第一接枝聚合物的％具有平均的400到600nm，其特征在于，基于（B），（B1）30〜90重量从由弹性体接枝，根据（b1）的％，粒径D50（B11）80〜99.99重量％的正从0丙烯酸丁酯，（B12）0.01至20重量％的至少一种交联单体的％，（B13），以40重量％的一种或多种其它单烯属不饱和单体的％，（B2）10〜70重量的接枝壳的％从基于（B2），（B21）50〜100重量的苯乙烯或α-甲基苯乙烯或它们的混合物的％，（B22）0至50重量的丙烯腈％，（B23）0至50重量％的 s以上进一步的单烯属不饱和单体，（C）1.5至8重量具有平均粒径双峰粒度分布的第二接枝聚合物的％是D50在25〜一方面200纳米和350至550nm，另一方面，其包括，基于从50从0（C），（C1）30重量％至90重量从由弹性体接枝的基础上，（C1），（C11）为100重量％的丁二烯或异戊二烯或它们的混合物，（C12）到第50个 - 一种或多种其它单烯属不饱和单体的％，（C2）10〜70重量的接枝壳的％，基于（C2），（C21）50至100重量苯乙烯或α-甲基苯乙烯或它们的混合物的％物，（ C22）0至50重量的丙烯腈从0至50％（重量），（C23）.-一种或多种其它单烯属不饱和单体的％。（D）0至50重量滑移或Endformungsmittel，颜料，染料，阻燃剂，抗氧化剂，光稳定剂，纤维状或粉状填料或增强材料或抗静电剂，或其它添加剂，或它们的混合物的％，其中，所述总和接枝聚合物（B）和（C）构成从11.5至三种组分（A），（B）和（C），并且其中的总和的25重量％的四种组分（A）到的总和（D）补足到100重量％。

3. 发明申请

WO1996015166A1 PROCESS FOR PRODUCING MODIFIED RUBBER MOULDING MASSES BY INCORPORATING GROUPS INTO THE RUBBER THAT FORM RADICALS BY THERMAL DECOMPOSITION 审中-公开
标题翻译：用于生产橡胶改性橡胶模塑料建成，自由基热分解LOWER组
公开(公告)号：WO1996015166A1
公开(公告)日：1996-05-23
申请号：PCT/EP1995004474
申请日：1995-11-14
申请人： BASF AKTIENGESELLSCHAFT , MC KEE, Graham, Edmund , MOORS, Rainer , GAUSEPOHL, Hermann , SEIBRING, Joachim
发明人： BASF AKTIENGESELLSCHAFT
IPC分类号： C08F265/04
CPC分类号： C08F265/04 , C08L51/04 , C08L2666/04
摘要： In a process for producing modified rubber moulding masses, a first mixture (A) that contains at least one alkyl acrylate or methacrylate (a) having the general formula (I), in which R stands for a hydrogen atom or a methyl group and R stands for an alkyl group with 1 to 32 carbon atoms, at least one first monomer (b) that forms radicals by thermal decomposition, and optionally a second or several other monomers (c), is in a first step polymerised into a rubber (B), preferably together with free radicals. In a second step, the thus obtained rubber (B) is mixed with a third or several other monomers (d), preferably dissolved or dipped therein, to form a second mixture (C), and in a third step the second mixture (C) is polymerised with free radicals into the modified rubber moulding mass (D).
摘要翻译：在用于制备橡胶改性的模制组合物的方法是在第一阶段中，包括至少一种丙烯酸烷基酯或甲基丙烯酸酯的第一混合物（A）的（a）通式（I）中R <1>是一个氢原子或一个甲基，R的 <2>表示碳原子数1〜32的烷基，其中至少一个在热分解形成自由基，和任选的第二单体（c）或更多，以得到橡胶（b）第一单体（b）聚合时，优选用自由基团，在第二阶段中，将得到的橡胶（B），以形成在第三单体（d）的第二混合物（C）以上的混合，优选溶解或溶胀，并且在第三级，第二混合物（C）与聚合的自由基，得到橡胶改性的模制材料（D）。

4. 发明申请

WO2000041470A3 METHOD FOR PRODUCING POLYESTER BLENDS 审中-公开
公开(公告)号：WO2000041470A3
公开(公告)日：2000-07-20
申请号：PCT/EP2000000014
申请日：2000-01-04
申请人： BASF AKTIENGESELLSCHAFT , WEBER, Martin , ULMERICH, Karlheinz , ZELTNER, Doris , KNOLL, Manfred
发明人： BASF AKTIENGESELLSCHAFT
IPC分类号： C08K5/49
摘要： The invention relates to a method for producing stabilized polyester/polycarbonate blends, whereby; A) 40 to 99.9 wt. % of a polyester and B) 0.1 to 60 wt. % of a stabilizer containing phosphorous are mixed in the melt, are removed, cooled, and granulated, and component A' which is obtained in this manner is subsequently mixed with a polycarbonate C), is optionally mixed with a polyester A) and a rubber elastic polymerizate D), and is optionally mixed with additional additives E).

5. 发明申请

WO1998024837A1 FLAME-RESISTANT THERMOPLASTIC MOULDING COMPOUNDS 审中-公开
标题翻译：阻燃热塑性模塑料
公开(公告)号：WO1998024837A1
公开(公告)日：1998-06-11
申请号：PCT/EP1997006421
申请日：1997-11-18
申请人： BASF AKTIENGESELLSCHAFT , GOTTSCHALK, Axel , WEBER, Martin , KOCH, Andreas , AUMÜLLER, Alexander
发明人： BASF AKTIENGESELLSCHAFT
IPC分类号： C08K05/5399
CPC分类号： C08L77/00 , C08K5/5399 , C08L25/02 , C08L33/06 , C08L51/04 , C08L67/02 , C08L69/00 , C08L2666/02 , C08L51/00
摘要： The invention concerns flame-resistant thermoplastic moulding compounds containing: A) between 1 and 97 wt % of at least one polycarbonate, polyamide, polyester, polyolefin or polymethacrylate or a mixture of the above-mentioned thermoplastic polymers; B) between 1 and 97 wt % of at least one graft polymer consisting of: b1) between 40 and 80 wt % of a graft basis comprising a rubber-elastic polymer with a glass transition temperature of less than 0 DEG C; and b2) between 20 and 60 wt % of a graft overlay comprising: b21) between 50 and 95 wt % vinylaromatic monomers of general formula PHI , in which R designates a C1-C8 alkyl group or a hydrogen atom and R designates a C1-C8 alkyl group, and n has the value 0, 1, 2 or 3 or methylmethacrylate or mixtures thereof; and b22) between 5 and 50 wt % acrylonitrile, methacrylonitrile, methylmethacrylate, maleic acid anhydride or mixtures thereof; C) between 1 and 97 wt % of at least one thermoplastic copolymer comprising: c1) between 50 and 95 wt % vinylaromatic monomers of general formula PHI or methylmethacrylate or mixtures thereof; and c2) between 5 and 50 wt % acrylonitrile, methacrylonitrile, methylmethacrylate, maleic acid anhydride or mixtures thereof; D) between 1 and 50 wt % flame retardants containing iminophosphoranes; and E) between 0 and 50 wt % further additives.
摘要翻译：含有A）1〜97重量％的至少一种聚碳酸酯，聚酰胺，聚酯，聚烯烃或聚甲基丙烯酸酯或上述热塑性聚合物的混合物，B）1至97重量％的至少一种接枝聚合物的％b1的组成）的％A阻燃的热塑性模塑材料 40至80重量接枝基础，其包含具有低于20 0℃和b2）的玻璃化转变温度的弹性体聚合物，以60重量从50包括B21接枝层）的％的％至95重量通式PHI的乙烯基芳族单体的％其中R是具有碳原子数1〜8或一个氢原子，R的烷基基团<1>表示碳原子数为1〜8，n为0，1，2或3，或甲基丙烯酸甲酯或它们的混合物的烷基和B22）5 到丙烯腈，甲基丙烯腈，甲基丙烯酸甲酯，马来酸酐或它们的混合物的50重量％，C）1〜97重量从50 c1的至少一种热塑性共聚物）％至95重量％的乙烯基芳族从0通式PHI或甲基丙烯酸甲酯或它们的混合物和丙烯腈，甲基丙烯腈，甲基丙烯酸甲酯，马来酸酐或它们的混合物的C2）5〜50重量％，D）1〜50重量的阻燃剂的％，包括亚氨基正膦，和E）至ř单体 50个重量其它添加剂％。

6. 发明申请

WO1998020074A1 PROCESS FOR PREPARING COMPOSITIONS BASED ON THERMOPLASTIC POLYMERS AND POLYAMIDES 审中-公开
标题翻译：用于基于热塑性聚合物及聚酰胺PRODUCING组合物
公开(公告)号：WO1998020074A1
公开(公告)日：1998-05-14
申请号：PCT/EP1997005795
申请日：1997-10-21
申请人： BASF AKTIENGESELLSCHAFT , WEBER, Martin , PIPPER, Gunter , FISCH, Herbert
发明人： BASF AKTIENGESELLSCHAFT
IPC分类号： C08L77/02
CPC分类号： C08L77/02 , C08G69/16 , C08G69/18 , C08J3/096 , C08L2666/02 , C08L23/00 , C08L81/00 , C08L2666/22 , C08L79/08
摘要： The invention concerns a process for preparing compositions containing at least one thermoplastic polymer A and at least one polyamide B by dissolving the thermoplastic polymer A in at least one lactam b and optionally further polyamide-forming monomers b, and subsequent polymerization of the monomers b. The monomers b are polymerized in the presence of between 0.001 and 5 wt % water, relative to the monomers b.
摘要翻译：由热塑性聚合物A溶解在至少一种内酰胺B和任选地进一步形成聚酰胺的单体B和单体B的后续聚合含有至少一种热塑性聚合物A和至少一种聚酰胺乙组合物的制备的方法，其中在存在的B单体 0.001至5重量％的水，基于所述单体b聚合。

7. 发明申请

WO1998012256A1 THERMOPLASTIC MOULDING COMPOUNDS 审中-公开
标题翻译：热塑性模塑化合物
公开(公告)号：WO1998012256A1
公开(公告)日：1998-03-26
申请号：PCT/EP1997004912
申请日：1997-09-09
申请人： BASF AKTIENGESELLSCHAFT , GÜNTHERBERG, Norbert , KNOLL, Konrad , WEBER, Martin , LINDENSCHMIDT, Gerhard
发明人： BASF AKTIENGESELLSCHAFT
IPC分类号： C08L51/00
CPC分类号： C08L25/12 , C08L51/003 , C08L53/025 , Y10S525/902 , C08L2666/24 , C08L2666/02
摘要： Thermoplastic moulding compounds contain: (A) 30 to 98 wt % of a graft polymer which consists of (ak) 30 to 90 wt % of a cross-linked acrylic rubber graft nucleus; (as) 10 to 70 wt % of a graft shell made of (as/1) 50 to 100 wt % of a styrene compound, of an acrylic or methacrylic acid (C1-C8-alkyl)ester, or of a mixture of the styrene compound and the acrylic or methacrylic acid (C1-C8-alkyl)ester; and (as/2) 0 to 50 wt % of one or several other monomers; (B) 1 to 50 wt % of a thermoplastic polymer; and (C) 1 to 70 wt % of a rubber elastic block copolymer.
摘要翻译：热塑性模塑组合物，其包括：（A）30至98重量（AK）30至90重量的交联丙烯酸橡胶的接枝的％的接枝聚合物的％; 如）10至70重量AS / 1）50的接枝壳为100重量苯乙烯化合物的％，或％一（C1-C8烷基）丙烯酸或甲基丙烯酸，或苯乙烯类化合物的混合物和酯的（C1 C8烷基）丙烯酸或甲基丙烯酸的酯，和如/ 2）0至50重量％的一种或多种其它单体的％; （B）弹性体嵌段共聚物的1〜50重量的热塑性聚合物的％和（C）1〜70重量％。

8. 发明申请

WO1997002299A1 ANTIDRIP AGENTS FOR THERMOPLASTIC MOLDING COMPOUNDS 审中-公开
标题翻译：抗滴落剂用于热塑性模塑料
公开(公告)号：WO1997002299A1
公开(公告)日：1997-01-23
申请号：PCT/EP1996002803
申请日：1996-06-27
申请人： BASF AKTIENGESELLSCHAFT , WEBER, Martin , HOFMANN, Jürgen , WEISS, Robert , HECKMANN, Walter , HINGMANN, Roland , WÜNSCH, Josef , MCKEE, Graham, Edmund
发明人： BASF AKTIENGESELLSCHAFT
IPC分类号： C08F12/00
CPC分类号： C08L25/06 , C08L53/025 , C08L71/123 , C08L2666/02 , C08L2666/04
摘要： Halogen-free antidrip agents for thermoplastic molding compounds contain polymers based on vinyl aromatic monomers with molecular weights (Mw) of at least 800 000 g/mol and a narrow molecular weight distribution.
摘要翻译：不含卤素的抗滴落剂，其包括基于具有至少800000克/摩尔和分子量分布窄的分子量（Mw）为乙烯基芳族单体的聚合物的热塑性模塑组合物。

9. 发明申请

WO1998008900A1 MOULDING COMPOUNDS CONSISTING OF A POLYCARBONATE MIXTURE AND A SILOXANE RETICULAR RUBBER 审中-公开
标题翻译：模塑料从混合物和聚碳酸酯SILOXANNETZWERKKAUTSCHUK
公开(公告)号：WO1998008900A1
公开(公告)日：1998-03-05
申请号：PCT/EP1997004543
申请日：1997-08-21
申请人： BASF AKTIENGESELLSCHAFT , WEBER, Martin , GÜNTHERBERG, Norbert
发明人： BASF AKTIENGESELLSCHAFT
IPC分类号： C08L69/00
CPC分类号： C08L69/00 , C08L2666/02
摘要： The invention concerns moulding compounds comprising as essential components an aromatic polycarbonate, a graft polymer based on alkylacrylates, styrenes and unsaturated nitriles, a copolymer based on styrenes and unsaturated nitriles, a siloxane reticular rubber, a copolymer comprising at least two different esters of acrylic acid, methacrylic acid or mixtures thereof, optionally halogen-free phosphorus compounds and additives. The invention further concerns moulded bodies, foils or fibres produced from these moulding compounds.
摘要翻译：包括作为主要组分，芳族聚碳酸酯，基于丙烯酸烷基酯，苯乙烯和不饱和腈接枝聚合物，基于苯乙烯和不饱和腈的共聚物的模塑组合物中，Siloxannetzwerkkautschuk，丙烯酸或甲基丙烯酸或它们的至少两种不同的酯的共聚物混合物，任选的游离卤素的磷化合物和添加剂，和模制品，薄膜或模塑从组合物获得的纤维。

10. 发明申请

WO1997045487A2 NON-FLAMMABLE, THERMOPLASTIC MOULDED MATERIALS BASED ON POLYPHENYLENE ETHERS 审中-公开
标题翻译：基于聚苯醚阻燃热塑性模塑料
公开(公告)号：WO1997045487A2
公开(公告)日：1997-12-04
申请号：PCT/EP1997002797
申请日：1997-05-28
申请人： BASF AKTIENGESELLSCHAFT , WEBER, Martin , WEISS, Robert , HECKMANN, Walter , HINGMANN, Roland , HÄHNLE, Hans-Joachim
发明人： BASF AKTIENGESELLSCHAFT
IPC分类号： C08L71/12
CPC分类号： C08L51/04 , C08K5/49 , C08L25/06 , C08L33/26 , C08L53/00 , C08L71/12 , C08L2666/02 , C08L2666/04
摘要： The invention relates to non-flammable, thermoplastic moulded materials containing (A) at least one polyphenylene ether, (B) at least one vinyl aromatic polymer, and (C) at least one flame-proofing agent. Said materials are characterised in that they also comprise (D) and as the non-drip agent a high-molecular polymer based on acrylamide with a viscosity approximately of above 1.5 mPas, measured in an aqueous solution of 0.1 % at 25 DEG C. The invention also relates to the use of said materials in the production of fibres, sheets and moulded structures.
摘要翻译：本发明涉及阻燃包括性热塑性模塑组合物）至少一种聚苯醚，B）至少一种乙烯基芳族聚合物和C）至少一种阻燃剂，其特征在于，它们还D）作为抗滴落剂，基于丙烯酰胺的高分子量聚合物和具有的粘度大于约1.5毫帕·秒，在25℃下在0.1％浓度的水溶液测定的更多，包括; 以及它们用于生产纤维，薄膜和模制品中的用途。

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