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1. 发明专利

CA2160952A1 THERMOPLASTIC MOLDING MATERIALS 未知
公开(公告)号：CA2160952A1
公开(公告)日：1996-04-21
申请号：CA2160952
申请日：1995-10-19
申请人： GUENTHERBERG NORBERT , WEBER MARTIN , GRUBER FREDDY , LINDENSCHMIDT GERHARD
发明人： GUENTHERBERG NORBERT , WEBER MARTIN , GRUBER FREDDY , LINDENSCHMIDT GERHARD
IPC分类号： B29C45/00 , B29C48/03 , B29C48/305 , C08F265/06 , C08L9/06 , C08L21/00 , C08L25/02 , C08L25/04 , C08L51/00 , C08L51/04 , C08L51/06 , C08L53/02 , C08L71/02 , C08L47/00 , C08J9/12
摘要： Thermoplastic molding materials comprise A) from 30 to 98 % by weight of a graft polymer of aK) from 30 to 90 % by weight of an elastomeric graft core, obtainable by copolymerization of aK/1) from 80 to 99.99 % by weight of a C1-C10-alkyl ester of acrylic acid, aK/2) from 0.01 to 20 % by weight of a crosslinking mono mer and aK/3) from 0 to 40 % by weight of one or more further monomers, and as) from 10 to 70 % by weight of a graft shell of a5/2) from 50 to 100 % by weight of a styrene compound of the general formula where R1 and R2 are each hydrogen or C1-C8-alkyl, and/or of a C1-C8-alkyl ester of acrylic acid or methacrylic acid, and as/2)from 0 to 50 % by weight of one or more further monomers, B) from 1 to 50 % by weight of a thermoplastic polymer of b1) from 50 to 100 % by weight of styrene and/or .alpha.-methylsty- rene, b2) from 0 to 50 % by weight of acrylonitrile and b3) from 0 to 50 % by weight of one or more further monomers, and C) from 1 to 70 % by weight of a copolymer of c1) from 30 to 90 % by weight of styrene and/or .alpha.-methylsty- rene, c2) from 10 to 70 % by weight of butadiene and c3) from 0 to 30 % by weight of one or more further monomers, in which all or virtually all of the olefinic double bonds have been hydrogenated.

2. 发明申请

WO1998012257A1 THERMOPLASTIC MOULDING COMPOUNDS 审中-公开
标题翻译：热塑性模塑化合物
公开(公告)号：WO1998012257A1
公开(公告)日：1998-03-26
申请号：PCT/EP1997004913
申请日：1997-09-09
申请人： BASF AKTIENGESELLSCHAFT , GÜNTHERBERG, Norbert , WEBER, Martin , KNOLL, Konrad , LINDENSCHMIDT, Gerhard
发明人： BASF AKTIENGESELLSCHAFT
IPC分类号： C08L51/00
CPC分类号： C08L51/003 , C08F265/04 , C08L25/12 , C08L53/02 , C08L2666/24
摘要： Thermoplastic moulding compounds contain: (A) 30 to 98 wt % of a graft polymer which consists of (ak) 30 to 90 wt % of a cross-linked acrylic rubber graft nucleus; (as) 10 to 70 wt % of a graft shell made of (as/1) 50 to 100 wt % of a styrene compound, of an acrylic or methacrylic acid (C1-C8-alkyl)ester, or of a mixture of the styrene compound and the acrylic or methacrylic acid (C1-C8-alkyl)ester; and (as/2) 0 to 50 wt % of one or several other monomers; (B) 1 to 50 wt % of a thermoplastic polymer; and (C) 1 to 70 wt % of a rubber elastic block copolymer.
摘要翻译：热塑性模塑组合物，其包括：（A）30至98重量的接枝聚合物的％：AK）30至90重量的交联丙烯酸橡胶的接枝的％; 如）10至70重量AS / 1）50的接枝壳为100重量苯乙烯化合物的％，或％一（C1-C8烷基）丙烯酸或甲基丙烯酸，或苯乙烯类化合物的混合物和酯的（C1 C8-烷基）丙烯酸或甲基丙烯酸和作为/ 2酯）0〜50重量％的一种或多种其它单体的％; （B）1〜50重量的热塑性聚合物的％; （C）弹性体嵌段共聚物的1〜70重量％。

3. 发明申请

WO1998005695A1 CROSS-LINKING AGENTS FOR EMULSION POLYMERS 审中-公开
标题翻译：链接器为乳液聚合物
公开(公告)号：WO1998005695A1
公开(公告)日：1998-02-12
申请号：PCT/EP1997004127
申请日：1997-07-29
申请人： BASF AKTIENGESELLSCHAFT , FISCHER, Michael , LINDENSCHMIDT, Gerhard , MC KEE, Graham, Edmund , ROSENAU, Bernhard , NAARMANN, Herbert
发明人： BASF AKTIENGESELLSCHAFT
IPC分类号： C08F290/12
CPC分类号： C08F265/04
摘要： Compounds are disclosed having the general formula (I) H(-CH2-CR R )m(-CH2-CR R )n-H, in which R is H or methyl; R is -C(O)-Y-R , R being H, methyl, ethyl or allyl; R is -C(O)-Y-allyl; and Y is O or NH; or in which R is H or C1-20-alkyl; R is H; and R is (-CH2-CR =CR -CH2)p-H, R and R independently representing H, methyl, ethyl, chlorine, and p = 1-100; or in which R is H; R is OH or O-allyl; and R is O-allyl; or in which R is H; R is OH or R , R being (meth)acrylate, -O-C(O)-CH=CH-COOH or -O-C(O)-CH2-C(=CH2)-COOH, m is an integer from 5 to 500,000 and n is an integer from 2 to 100,000. These compounds are used as crosslinkers in particulate emulsion polymers with a glass transition temperature below 0 DEG C and a mean particle size from 50 to 1000 nm.
摘要翻译：通式的化合物的用途，（I）H（-CH 2-CR <1> [R <2>）米（-CH2-CR <1> [R <3>）N中的H其中R <1>为H或甲基 [R <2> -C（O）-Y-R <4>其中R <4>为H，甲基，乙基或烯丙基 - [R <3> -C（O）-Y-烯丙基Y是O或NH，或R <1>为H或C1 -20 - 烷基 - [R <2> HR <3>（-CH 2 CR <5> = CR <6> -CH 2）的pH，其中R <5> - [R <6>独立地是H，甲基，乙基，氯，p值= 1-100或R <1> HR <2>是OH或O-烯丙基 - [R <3> O-烯丙基，或R <1> HR - [R <3>（甲基）丙烯酸酯<2> OH或R <3>，-OC （O）-CH = CH-COOH或-O-C（O）-CH 2 C（= CH 2）-COOH，m是一个整数为5〜50万，并且n为2至100,000的整数，如在粒状交联剂具有低于0℃的玻璃化转变温度和50的平均粒径为1000纳米的乳液聚合物。

4. 发明申请

WO1998005694A1 IMPACT RESISTANT THERMOPLASTIC MOULDING MATERIALS 审中-公开
标题翻译： SHOCK TOUGH热塑性模塑化合物
公开(公告)号：WO1998005694A1
公开(公告)日：1998-02-12
申请号：PCT/EP1997004126
申请日：1997-07-29
申请人： BASF AKTIENGESELLSCHAFT , LINDENSCHMIDT, Gerhard , MC KEE, Graham, Edmund , ROSENAU, Bernhard , NAARMANN, Herbert , FISHER, Michael
发明人： BASF AKTIENGESELLSCHAFT
IPC分类号： C08F290/04
CPC分类号： C08F290/042 , C08F20/18 , C08F20/54 , C08F290/04
摘要： Compounds having the general formula (I) H2C=CR -C(O)-Y-R , in which R stands for H, CH3, C2H5, C3H7; Y stands for O, NH, O-phenylene; R stands for a radical composed of 2 to 10,000 polymerised isobutene units or 2-1000 polymerised butadiene or isoprene units, are used for producing particulate emulsion polymers with a glass transition temperature below 0 DEG C and a mean particle size from 50 to 1000 nm.
摘要翻译：通式（I）H 2 C =的化合物的用途，CR <1> -C（O）-Y-R <2>中，R <1>是H，CH3，C2H5，C3H7，Y是O，NH，O - 亚苯基，R < 2>从2至10,000的聚合异丁烯单元或从2至1000的聚合的丁二烯单元或异戊二烯单元的基团是具有低于0℃的Glasübergagstemperatur和50-1000nm的平均粒度的颗粒的乳液聚合物的制备。

5. 发明申请

WO9741174A3 MOULDINGS MADE OF THERMOPLASTIC MOULDING MASSES 审中-公开
标题翻译：热塑性塑料模具的制造
公开(公告)号：WO9741174A3
公开(公告)日：1997-12-11
申请号：PCT/EP9702099
申请日：1997-04-24
申请人： BASF AG , LINDENSCHMIDT GERHARD , ROSENAU BERNHARD , MC KEE GRAHAM EDMUND , FISCHER WOLFGANG
发明人： LINDENSCHMIDT GERHARD , ROSENAU BERNHARD , MC KEE GRAHAM EDMUND , FISCHER WOLFGANG
IPC分类号： C08L25/12 , C08L51/00 , C08L51/04 , C08L , C08J , E04B
CPC分类号： C08L25/12 , C08L51/003 , C08L51/04 , C08L2666/24 , C08L2666/04
摘要： Mouldings made of thermoplastic moulding masses contain (A) 30 to 99 wt %, relative to the total weight of the moulding mass, of a thermoplastic polymer, comprising, relative to (A): (a1) 50 to 100 wt % of a styrene compound of general formula (I), in which R?1 and R2¿ stand for hydrogen or C¿1?-C8 alkyl, or a (C1-C8-alkyl)ester of acrylic or methacrylic acid, or mixtures of the styrene compound and of the (C1-C8-alkyl)ester of acrylic or methacrylic acid; (a2) 0 to 40 wt % acryl nitrile or methacryl nitrile or their mixtures; and (a3) 0 to 40 wt % of one or several other monoethylenically unsaturated monomers different from (a2); (b) 1 to 70 wt %, with respect to the total weight of the moulding mass, of a graft polymer comprising, relative to (B): (b1) 30 to 90 wt % of a rubber-elastic grafted core made of a polymer with a glass transition temperature below 0 °C and obtained by copolymerising (b11) 50 to 99.99 wt %, with respect to (b1), of a (C1-C10-alkyl)ester of acrylic acid; (b12) 0.01 to 10 wt % of a polyfunctional, cross-linking monomer; and (b13) 0 to 40 wt % of one or several others monoethylenically unsaturated monomers different from (b11); and (b2) 10 to 70 wt % of a grafted sheath which contains, relative to (b2): (b21) 50 to 100 wt % of a styrene compound of general formula (I), in which R?1 and R2¿ stand for hydrogen or C¿1?-C8-alkyl; or a (C1-C8-alkyl)ester of acrylic acid or methacrylic acid; or mixtures of the styrene compound and of the (C1-C8-alkyl)ester of acrylic or methacrylic acid; (b22) 0 to 40 wt % acryl nitrile or methacryl nitrile or their mixtures; and (b23) 0 to 40 wt % of one or several other monoethylenically unsaturated monomers.

6. 发明申请

WO1997041174A2 MOULDINGS MADE OF THERMOPLASTIC MOULDING MASSES 审中-公开
标题翻译： TRIMS，热塑性模塑料制成
公开(公告)号：WO1997041174A2
公开(公告)日：1997-11-06
申请号：PCT/EP1997002099
申请日：1997-04-24
申请人： BASF AKTIENGESELLSCHAFT , LINDENSCHMIDT, Gerhard , ROSENAU, Bernhard , MC KEE, Graham, Edmund , FISCHER, Wolfgang
发明人： BASF AKTIENGESELLSCHAFT
IPC分类号： C08L00/00
CPC分类号： C08L25/12 , C08L51/003 , C08L51/04 , C08L2666/24 , C08L2666/04
摘要： Mouldings made of thermoplastic moulding masses contain (A) 30 to 99 wt %, relative to the total weight of the moulding mass, of a thermoplastic polymer, comprising, relative to (A): (a1) 50 to 100 wt % of a styrene compound of general formula (I), in which R1 and R2 stand for hydrogen or C1-C8 alkyl, or a (C1-C8-alkyl)ester of acrylic or methacrylic acid, or mixtures of the styrene compound and of the (C1-C8-alkyl)ester of acrylic or methacrylic acid; (a2) 0 to 40 wt % acryl nitrile or methacryl nitrile or their mixtures; and (a3) 0 to 40 wt % of one or several other monoethylenically unsaturated monomers different from (a2); (b) 1 to 70 wt %, with respect to the total weight of the moulding mass, of a graft polymer comprising, relative to (B): (b1) 30 to 90 wt % of a rubber-elastic grafted core made of a polymer with a glass transition temperature below 0 DEG C and obtained by copolymerising (b11) 50 to 99.99 wt %, with respect to (b1), of a (C1-C10-alkyl)ester of acrylic acid; (b12) 0.01 to 10 wt % of a polyfunctional, cross-linking monomer; and (b13) 0 to 40 wt % of one or several others monoethylenically unsaturated monomers different from (b11); and (b2) 10 to 70 wt % of a grafted sheath which contains, relative to (b2): (b21) 50 to 100 wt % of a styrene compound of general formula (I), in which R and R stand for hydrogen or C1-C8-alkyl; or a (C1-C8-alkyl)ester of acrylic acid or methacrylic acid; or mixtures of the styrene compound and of the (C1-C8-alkyl)ester of acrylic or methacrylic acid; (b22) 0 to 40 wt % acryl nitrile or methacryl nitrile or their mixtures; and (b23) 0 to 40 wt % of one or several other monoethylenically unsaturated monomers.
摘要翻译： A））30至99重量％，基于模塑组合物的总重量计，的热塑性聚合物，基于A A1）50〜100重量通式的苯乙烯化合物的％：从含有热塑性模塑化合物制备的模制品（I），<1>和R <2>是R代表氢或C1-C8烷基，或（C1-C8烷基）丙烯酸或甲基丙烯酸，或苯乙烯类化合物的混合物和（C1-C8的酯烷基）丙烯酸或甲基丙烯酸的酯，A2）0〜40重量丙烯腈或甲基丙烯腈或它们的混合物的％和a3）0〜40重量％的一种或多种选自A2其它单烯键式不饱和不同）单体，B的％）1〜70重量％，基于模塑组合物的总重量计，其包括，基于B的接枝聚合物的，），B1）为30〜90重量具有低于0℃的玻璃化转变温度的聚合物的橡胶弹性接枝芯％，可获得由共聚，基于b 1），B11）50〜99.99重量一（C1-C10烷基的％）丙烯酸的酯，B12）0.01至10重量重量的多官能团的％，交联单体，和B13）0至40 .-的一种或多种其它单烯属不饱和的，从B11）不同的单体，和b2）为10〜70重量的接枝壳的基础上，b2的％），B21）50〜100重量通式的苯乙烯化合物的％％（I），<1>和R <2>是R代表氢或C1-C8烷基，或（C1-C8烷基）丙烯酸或甲基丙烯酸，或苯乙烯类化合物的混合物和（C1-C8的酯烷基）丙烯酸或甲基丙烯酸的酯，B22）0至40重量丙烯腈或甲基丙烯腈或它们的混合物的％和B23）从0至40重量的一种或多种其它单烯属不饱和单体的％。

7. 发明申请

WO1998012256A1 THERMOPLASTIC MOULDING COMPOUNDS 审中-公开
标题翻译：热塑性模塑化合物
公开(公告)号：WO1998012256A1
公开(公告)日：1998-03-26
申请号：PCT/EP1997004912
申请日：1997-09-09
申请人： BASF AKTIENGESELLSCHAFT , GÜNTHERBERG, Norbert , KNOLL, Konrad , WEBER, Martin , LINDENSCHMIDT, Gerhard
发明人： BASF AKTIENGESELLSCHAFT
IPC分类号： C08L51/00
CPC分类号： C08L25/12 , C08L51/003 , C08L53/025 , Y10S525/902 , C08L2666/24 , C08L2666/02
摘要： Thermoplastic moulding compounds contain: (A) 30 to 98 wt % of a graft polymer which consists of (ak) 30 to 90 wt % of a cross-linked acrylic rubber graft nucleus; (as) 10 to 70 wt % of a graft shell made of (as/1) 50 to 100 wt % of a styrene compound, of an acrylic or methacrylic acid (C1-C8-alkyl)ester, or of a mixture of the styrene compound and the acrylic or methacrylic acid (C1-C8-alkyl)ester; and (as/2) 0 to 50 wt % of one or several other monomers; (B) 1 to 50 wt % of a thermoplastic polymer; and (C) 1 to 70 wt % of a rubber elastic block copolymer.
摘要翻译：热塑性模塑组合物，其包括：（A）30至98重量（AK）30至90重量的交联丙烯酸橡胶的接枝的％的接枝聚合物的％; 如）10至70重量AS / 1）50的接枝壳为100重量苯乙烯化合物的％，或％一（C1-C8烷基）丙烯酸或甲基丙烯酸，或苯乙烯类化合物的混合物和酯的（C1 C8烷基）丙烯酸或甲基丙烯酸的酯，和如/ 2）0至50重量％的一种或多种其它单体的％; （B）弹性体嵌段共聚物的1〜50重量的热塑性聚合物的％和（C）1〜70重量％。

8. 发明申请

WO1995029204A1 USE OF MOULDING MATERIALS TO PRODUCE MOULDED ARTICLES WITH GOOD RESISTANCE TO PARTIALLY HALOGENATED CHLOROFLUOROCARBONS 审中-公开
标题翻译：模塑料利于生产具有良好性的成型零件部分卤代的氟氯烃使用
公开(公告)号：WO1995029204A1
公开(公告)日：1995-11-02
申请号：PCT/EP1995001535
申请日：1995-04-24
申请人： BASF AKTIENGESELLSCHAFT , LINDENSCHMIDT, Gerhard , ZELTNER, Doris , MORGENSTERN, Herbert , BRANDSTETTER, Franz
发明人： BASF AKTIENGESELLSCHAFT
IPC分类号： C08L51/04
CPC分类号： C08L25/02 , C08L51/04 , C08L2666/24 , C08L2666/04
摘要： The use is disclosed of moulding materials to produce moulded articles which come into contact with partially halogenated chlorofluorocarbons.
摘要翻译：用于生产该成与部分卤代的氟氯接触模制品的使用模塑组合物。

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