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1. 发明申请

WO1998012257A1 THERMOPLASTIC MOULDING COMPOUNDS 审中-公开
标题翻译：热塑性模塑化合物
公开(公告)号：WO1998012257A1
公开(公告)日：1998-03-26
申请号：PCT/EP1997004913
申请日：1997-09-09
申请人： BASF AKTIENGESELLSCHAFT , GÜNTHERBERG, Norbert , WEBER, Martin , KNOLL, Konrad , LINDENSCHMIDT, Gerhard
发明人： BASF AKTIENGESELLSCHAFT
IPC分类号： C08L51/00
CPC分类号： C08L51/003 , C08F265/04 , C08L25/12 , C08L53/02 , C08L2666/24
摘要： Thermoplastic moulding compounds contain: (A) 30 to 98 wt % of a graft polymer which consists of (ak) 30 to 90 wt % of a cross-linked acrylic rubber graft nucleus; (as) 10 to 70 wt % of a graft shell made of (as/1) 50 to 100 wt % of a styrene compound, of an acrylic or methacrylic acid (C1-C8-alkyl)ester, or of a mixture of the styrene compound and the acrylic or methacrylic acid (C1-C8-alkyl)ester; and (as/2) 0 to 50 wt % of one or several other monomers; (B) 1 to 50 wt % of a thermoplastic polymer; and (C) 1 to 70 wt % of a rubber elastic block copolymer.
摘要翻译：热塑性模塑组合物，其包括：（A）30至98重量的接枝聚合物的％：AK）30至90重量的交联丙烯酸橡胶的接枝的％; 如）10至70重量AS / 1）50的接枝壳为100重量苯乙烯化合物的％，或％一（C1-C8烷基）丙烯酸或甲基丙烯酸，或苯乙烯类化合物的混合物和酯的（C1 C8-烷基）丙烯酸或甲基丙烯酸和作为/ 2酯）0〜50重量％的一种或多种其它单体的％; （B）1〜50重量的热塑性聚合物的％; （C）弹性体嵌段共聚物的1〜70重量％。

2. 发明申请

WO1998012256A1 THERMOPLASTIC MOULDING COMPOUNDS 审中-公开
标题翻译：热塑性模塑化合物
公开(公告)号：WO1998012256A1
公开(公告)日：1998-03-26
申请号：PCT/EP1997004912
申请日：1997-09-09
申请人： BASF AKTIENGESELLSCHAFT , GÜNTHERBERG, Norbert , KNOLL, Konrad , WEBER, Martin , LINDENSCHMIDT, Gerhard
发明人： BASF AKTIENGESELLSCHAFT
IPC分类号： C08L51/00
CPC分类号： C08L25/12 , C08L51/003 , C08L53/025 , Y10S525/902 , C08L2666/24 , C08L2666/02
摘要： Thermoplastic moulding compounds contain: (A) 30 to 98 wt % of a graft polymer which consists of (ak) 30 to 90 wt % of a cross-linked acrylic rubber graft nucleus; (as) 10 to 70 wt % of a graft shell made of (as/1) 50 to 100 wt % of a styrene compound, of an acrylic or methacrylic acid (C1-C8-alkyl)ester, or of a mixture of the styrene compound and the acrylic or methacrylic acid (C1-C8-alkyl)ester; and (as/2) 0 to 50 wt % of one or several other monomers; (B) 1 to 50 wt % of a thermoplastic polymer; and (C) 1 to 70 wt % of a rubber elastic block copolymer.
摘要翻译：热塑性模塑组合物，其包括：（A）30至98重量（AK）30至90重量的交联丙烯酸橡胶的接枝的％的接枝聚合物的％; 如）10至70重量AS / 1）50的接枝壳为100重量苯乙烯化合物的％，或％一（C1-C8烷基）丙烯酸或甲基丙烯酸，或苯乙烯类化合物的混合物和酯的（C1 C8烷基）丙烯酸或甲基丙烯酸的酯，和如/ 2）0至50重量％的一种或多种其它单体的％; （B）弹性体嵌段共聚物的1〜50重量的热塑性聚合物的％和（C）1〜70重量％。

3. 发明申请

WO1996020249A1 THERMOPLASTIC MOULDING MASSES BASED ON GRAFT COPOLYMERS AND BLOCK POLYMERS 审中-公开
标题翻译：热塑性模塑化合物基于接枝共聚物和嵌段聚合物
公开(公告)号：WO1996020249A1
公开(公告)日：1996-07-04
申请号：PCT/EP1995005094
申请日：1995-12-22
申请人： BASF AKTIENGESELLSCHAFT , GÜNTHERBERG, Norbert , WEBER, Martin , KNOLL, Konrad
发明人： BASF AKTIENGESELLSCHAFT
IPC分类号： C08L53/02
CPC分类号： B32B27/08 , B32B27/302 , B32B27/32 , B32B27/34 , B32B27/36 , C08L53/02 , C08L2666/02
摘要： Thermoplastic moulding masses made of thermoplastic polymers obtained by mixed graft polymerisation and having a glass transition temperature above 20 DEG C, and of special rubber-elastic block copolymers, are characterised by a balanced spectrum of properties.
摘要翻译：由接枝共聚的具有玻璃化转变温度大于20℃，具体弹性嵌段共聚物的热塑性模塑组合物，热塑性聚合物由平衡的性能分布表征。

4. 发明申请

WO1997000285A1 STABILISATION OF POLYMERS OF STYRENE OR A (METH)ACRYLIC COMPOUND 审中-公开
标题翻译：镇定苯乙烯或（甲基）丙烯酸连接聚合物的
公开(公告)号：WO1997000285A1
公开(公告)日：1997-01-03
申请号：PCT/EP1996002527
申请日：1996-06-11
申请人： BASF AKTIENGESELLSCHAFT , NIESSNER, Norbert , GÜNTHERBERG, Norbert , KNOLL, Konrad , LOTH, Wolfgang , TRAUTH, Hubert
发明人： BASF AKTIENGESELLSCHAFT
IPC分类号： C08K05/15
CPC分类号： C08K5/524 , C08K5/13 , C08K5/1545 , C08L25/04 , C08L33/06
摘要： A faint-smelling, light-, heat- and/or air-oxygen-stabilised moulding material made of at least one styrene homopolymer or copolymer or acrylate or methacrylate polymers contain stabilising amounts of for example 0.01 to 1 % by weight alpha-tocopherol and 0.1 to 2 % by weight of an organic phosphite, in a quantitative ratio between alpha-tocopherol and phosphite from 1:1 to 1:4, and preferably 0.01 to 2 % by weight of a sterically hindered phenol. The percentages by weight refer to the polymer fraction. The organic phosphite is in turn stabilised with up to 5 % by weight (in relation to the phosphite weight) of an amine or alkanolamine.
摘要翻译：针对由光和/或热和/或大气氧降解是稳定的至少一种苯乙烯均聚物或共聚物，或丙烯酸酯或含有如稳定量的甲基丙烯酸酯聚合物的气味成型用组合物为0.01〜1重量％的α-生育酚和0.1至2重量％，在α-生育酚和亚磷酸酯的摩尔比的有机亚磷酸酯的％是从1：1至1：4，优选为0.01〜2重量 .-空间位阻酚的％，各自基于聚合物级分每一种情况下，并且其中所述有机亚磷酸酯是反过来稳定至多5重量％（相对于亚磷酸酯），胺或烷醇胺。

5. 发明申请

WO1995034600A1 STYRENE/BUTADIENE BLOCK COPOLYMERS STABILIZED WITH 'alpha'-TOCOPHEROL 审中-公开
标题翻译：与α-生育酚稳定化的苯乙烯/丁二烯嵌段共聚物
公开(公告)号：WO1995034600A1
公开(公告)日：1995-12-21
申请号：PCT/EP1995002212
申请日：1995-06-08
申请人： BASF AKTIENGESELLSCHAFT , NIESSNER, Norbert , LOTH, Wolfgang , KNOLL, Konrad , GÜNTHERBERG, Norbert , NAEGELE, Paul , TRAUTH, Hubert , POHRT, Jürgen
发明人： BASF AKTIENGESELLSCHAFT
IPC分类号： C08K05/15
CPC分类号： C08L53/02 , C08K5/1545 , C08K5/524
摘要： The invention concerns moulding compounds consisting of styrene/butadiene block copolymers produced by anionic polymerization and general structure (I), in which A is a block-copolymer segment made up of at least one polystyrene block with a molecular weight of 3,000 to 230,000 and one polybutadiene block with a molecular weight of 2,000 to 30,000 and B is a block-copolymer segment made up of at least one polystyrene block with a molecular weight of 2,000 to 60,000 and one polybutadiene block with a molecular weight of 2,000 to 30,000, the total molecular weight of A being 50,000 to 250,000 and that of B 5,000 to 75,000, the block transitions being sharp or indistinct and the overall star-branch number m+n being 3 to 15, with the provision that m
摘要翻译：由通用结构（I）其中A是嵌段共聚物链段包括至少一种聚苯乙烯嵌段分子量的苯乙烯 - 丁二烯嵌段共聚物的阴离子聚合模制的可获得的材料为3000〜230000 [克/摩尔]和分子量为2000的一个聚丁二烯〜30000 [克 /摩尔]和B是嵌段共聚物链段包括至少一种聚苯乙烯嵌段分子量为2000〜60000 [克/摩尔]和分子量为2000的一个聚丁二烯〜30000 [克/摩尔]，一个50000-250000的总分子量[ 克/摩尔]和B的从5000到75000 [克/摩尔]，块转换是尖锐的或模糊和星形分支M + N为3至15的数，n为与条件是m

6. 发明申请

WO1998008900A1 MOULDING COMPOUNDS CONSISTING OF A POLYCARBONATE MIXTURE AND A SILOXANE RETICULAR RUBBER 审中-公开
标题翻译：模塑料从混合物和聚碳酸酯SILOXANNETZWERKKAUTSCHUK
公开(公告)号：WO1998008900A1
公开(公告)日：1998-03-05
申请号：PCT/EP1997004543
申请日：1997-08-21
申请人： BASF AKTIENGESELLSCHAFT , WEBER, Martin , GÜNTHERBERG, Norbert
发明人： BASF AKTIENGESELLSCHAFT
IPC分类号： C08L69/00
CPC分类号： C08L69/00 , C08L2666/02
摘要： The invention concerns moulding compounds comprising as essential components an aromatic polycarbonate, a graft polymer based on alkylacrylates, styrenes and unsaturated nitriles, a copolymer based on styrenes and unsaturated nitriles, a siloxane reticular rubber, a copolymer comprising at least two different esters of acrylic acid, methacrylic acid or mixtures thereof, optionally halogen-free phosphorus compounds and additives. The invention further concerns moulded bodies, foils or fibres produced from these moulding compounds.
摘要翻译：包括作为主要组分，芳族聚碳酸酯，基于丙烯酸烷基酯，苯乙烯和不饱和腈接枝聚合物，基于苯乙烯和不饱和腈的共聚物的模塑组合物中，Siloxannetzwerkkautschuk，丙烯酸或甲基丙烯酸或它们的至少两种不同的酯的共聚物混合物，任选的游离卤素的磷化合物和添加剂，和模制品，薄膜或模塑从组合物获得的纤维。

7. 发明申请

WO1997045484A1 THERMOPLASTIC MOULDED MATERIALS BASED ON POLYCARBONATES AND STYRENE/ACRYLONITRILE POLYMERS WHICH CONTAIN COPOLYMERS BASED ON ALKYL(METH)ACRYLATE TO IMPROVE THEIR PROPERTIES 审中-公开
标题翻译：热塑性模塑化合物基于苯乙烯和聚碳酸酯/丙烯腈聚合物用于改善你的属性共聚物烷基上的（甲基）丙烯酸基本包括
公开(公告)号：WO1997045484A1
公开(公告)日：1997-12-04
申请号：PCT/EP1997002791
申请日：1997-05-28
申请人： BASF AKTIENGESELLSCHAFT , GÜNTHERBERG, Norbert , WEBER, Martin
发明人： BASF AKTIENGESELLSCHAFT
IPC分类号： C08L69/00
CPC分类号： C08L25/02 , C08L25/08 , C08L33/06 , C08L51/04 , C08L69/00 , C08L2666/02
摘要： The present invention relates to thermoplastic moulded materials which contain (a) polycarbonates, (B) rubber-like graft copolymers, (C+D) two different, thermoplastic copolymers based on styrene or alpha -methyl styrene, (E) copolymers based on alkyl(meth)acrylate, and (F) polymer compounds containing OH groups.
摘要翻译：本发明涉及一种基于苯乙烯或α--Methylstyrolbasis，E）烷基的共聚物，（甲基）丙烯酸酯和F）聚合物，其包括一种热塑性模塑组合物）Polycarbonatem B）橡胶状接枝共聚物，C + D）的两个不同的热塑性共聚物OH 含氮化合物含基团的。

8. 发明申请

WO1996020248A1 IMPACT-RESISTANT, THERMOPLASTIC MIXTURE OF ELASTOMERS AND THERMOPLASTIC MATERIALS 审中-公开
标题翻译： SHOCK TOUGH，热塑性加工混合弹性体和热塑性塑料
公开(公告)号：WO1996020248A1
公开(公告)日：1996-07-04
申请号：PCT/EP1995005024
申请日：1995-12-19
申请人： BASF AKTIENGESELLSCHAFT , NIESSNER, Norbert , KNOLL, Konrad , BENDER, Dietmar , GOTTSCHALK, Axel , WEBER, Martin
发明人： BASF AKTIENGESELLSCHAFT
IPC分类号： C08L53/02
CPC分类号： B32B27/08 , B32B27/302 , B32B27/32 , B32B27/34 , B32B27/36 , C08L53/02 , C08L2666/02
摘要： A polymer mixture contains (P1) 0.1 to 99.9 % by weight of a rubber-elastic block copolymer made of at least one block S having polymerised units of a vinyl aromatic monomer and forming a hard phase and of at least one elastomer block B/S that contains both polymerised units of a vinyl aromatic monomer (S) and a diene (B) and forms a soft phase. The glass transition temperature Tg of block S is higher than 25 DEG C and that of block B/S is lower than 25 DEG C. The phase volume ratio between block S and block B/S is selected so that the hard phase forms 1 to 40 % by volume of the whole block copolymer and the diene forms less than 50 % by weight of the whole block copolymer. The polymer mixture also contains (P2) 0.1 to 99.9 % by weight of at least one thermoplastic or duroplastic polymer or mixtures of said polymers; and (P3) 0 to 70 % by weight of other additives and auxiliary substances. The percentages by weight of components (P1) to (P3) add up to 100 % by weight.
摘要翻译：弹性体，其包括99.9重量具有乙烯基芳族单体，硬质相形成块S的至少一种聚合单元和至少一种乙烯基芳族单体（S）的两个聚合单元的弹性体嵌段共聚物的％如二烯（B） - 0.1聚合物混合物，其包含P1）低于25℃和块S的相体积比软质相形成嵌段B / S，其中所述玻璃化转变温度为所述子块S 25℃的Tg和该块的B / S被选择为块B / S，使在整个嵌段共聚物中的硬质相的比例为1-40％（体积）和比例（重量）的二烯的重量.-％小于50; 0.1 P2） - 99.9重量％的至少一种热塑性加工的或热固性聚合物或它们的混合物的％; P3）0 - 70重量其它添加剂和加工助剂的重量％组分P1）至P3百分比）一起给予100％。

9. 发明申请

WO1998013412A1 PROCESS FOR PRODUCING THERMOPLASTICS 审中-公开
标题翻译：用于生产热塑性
公开(公告)号：WO1998013412A1
公开(公告)日：1998-04-02
申请号：PCT/EP1997005000
申请日：1997-09-12
申请人： BASF AKTIENGESELLSCHAFT , GÜNTHERBERG, Norbert , HOFMANN, Jürgen , MAILAHN, Elmar , OHLIG, Hilmar , CZAUDERNA, Bernhard , GRABOWSKI, Sven , BUS, Klaus
发明人： BASF AKTIENGESELLSCHAFT
IPC分类号： C08J03/205
CPC分类号： B29B13/06 , B29C47/0011 , B29C47/0019 , B29C47/0023 , B29C47/40 , B29C47/64 , B29C47/76 , C08J3/205 , C08L51/04
摘要： A process is disclosed for producing thermoplastics modified to be impact-resistant or polymer blends containing such modified thermoplastics. The thermoplastics or polymer blends contain: (A) 5 to 95 wt % of at least one water-wet elastomer component A which contains up to 60 wt % residual water; (B) 5 to 95 wt % of at least one thermoplastic polymer B; (C) 0 to 95 wt % of at least another polymer C; and (D) 0 to 70 wt % additives D. The elastomer component A is mixed with the thermoplastic polymer B, if available with the other polymer C and if available with the additives D in a screw-machine while mechanically dewatering the elastomer component A. The process is characterised in that components A, B, C and D are supplied to an extruder with at least two screws that rotate in the same or opposite directions and have a diameter Dscrew. Seen in the feeding direction (downstream), the extruder substantially consists of at least one dosing section in which the elastomer component A is supplied to the extruder by a dosing device; at least one squeezing section for dewatering the elastomer component A having at least one pressure element and at least a corresponding dewatering opening located upstream of the (first) pressure element at a distance therefrom equal to at least one screw diameter Dscrew; at least one feeding section in which the thermoplastic polymer B is fed into the extruder as a molten mass; at least one plasticising section fitted with mixing and/or kneading elements; at least one degassing section with at least one degassing hole in which the residual water is removed as steam; and an extraction zone. The water expelled through the dewatering openings is partially or totally present in the liquid phase, and components C and/or are supplied together or separately, either together with components A and/or B or separately from A and B in one or more of the above-mentioned extruder sections.
摘要翻译：一种制备增韧热塑性塑料或抗冲改性的热塑性塑料含有热塑性塑料或A的聚合物共混物）的聚合物共混物为5〜95重量的至少一种水湿润，最多60重量含残留水基弹性体组分A的％％过程中，B）5〜 95重量％的至少一种热塑性聚合物B，C）0％至95重量％的至少一种其它聚合物C，和D）0％至70重量％的添加剂D，通过与热塑性聚合物B混合弹性体组分的并且，如果存在的话，另外的聚合物C和，如果存在的话，在与弹性体成分的的机械脱水挤压机的添加剂D，其特征在于，组分A，B，C和D具有至少两个一个同向旋转或反向旋转的挤出机中供给具有螺杆直径D螺杆丝杆，通过，其特征在于，在输送方向（下游）中Wesent挤出机至少一个计量部分的结合，弹性体组分A由一计量装置加入到挤出机中，所述弹性体成分的脱水中的至少一项所述的服务挤压部，所述至少一个延迟元件和在每种情况下，至少一个相关联的脱水孔，其是在至少一个螺杆直径的距离 ð螺丝，（第一）延迟元件位于上游之前，包括，至少一个进料部分，其中该热塑性聚合物B被引入作为熔体到挤出机中，至少一个部分设置有混合和/或捏合元件塑化部，至少一个设置有至少一个排气口脱气在其中剩余的水蒸汽除去，并构造一个排料区从脱水出来的光部分地或完全孔口水在液相中，并且所述组分C和/或D彼此或者与组分A和/或B从A馈送一起或单独一起或单独和B的一个或多个所陈述的挤出机区段。

10. 发明申请

WO1997041174A2 MOULDINGS MADE OF THERMOPLASTIC MOULDING MASSES 审中-公开
标题翻译： TRIMS，热塑性模塑料制成
公开(公告)号：WO1997041174A2
公开(公告)日：1997-11-06
申请号：PCT/EP1997002099
申请日：1997-04-24
申请人： BASF AKTIENGESELLSCHAFT , LINDENSCHMIDT, Gerhard , ROSENAU, Bernhard , MC KEE, Graham, Edmund , FISCHER, Wolfgang
发明人： BASF AKTIENGESELLSCHAFT
IPC分类号： C08L00/00
CPC分类号： C08L25/12 , C08L51/003 , C08L51/04 , C08L2666/24 , C08L2666/04
摘要： Mouldings made of thermoplastic moulding masses contain (A) 30 to 99 wt %, relative to the total weight of the moulding mass, of a thermoplastic polymer, comprising, relative to (A): (a1) 50 to 100 wt % of a styrene compound of general formula (I), in which R1 and R2 stand for hydrogen or C1-C8 alkyl, or a (C1-C8-alkyl)ester of acrylic or methacrylic acid, or mixtures of the styrene compound and of the (C1-C8-alkyl)ester of acrylic or methacrylic acid; (a2) 0 to 40 wt % acryl nitrile or methacryl nitrile or their mixtures; and (a3) 0 to 40 wt % of one or several other monoethylenically unsaturated monomers different from (a2); (b) 1 to 70 wt %, with respect to the total weight of the moulding mass, of a graft polymer comprising, relative to (B): (b1) 30 to 90 wt % of a rubber-elastic grafted core made of a polymer with a glass transition temperature below 0 DEG C and obtained by copolymerising (b11) 50 to 99.99 wt %, with respect to (b1), of a (C1-C10-alkyl)ester of acrylic acid; (b12) 0.01 to 10 wt % of a polyfunctional, cross-linking monomer; and (b13) 0 to 40 wt % of one or several others monoethylenically unsaturated monomers different from (b11); and (b2) 10 to 70 wt % of a grafted sheath which contains, relative to (b2): (b21) 50 to 100 wt % of a styrene compound of general formula (I), in which R and R stand for hydrogen or C1-C8-alkyl; or a (C1-C8-alkyl)ester of acrylic acid or methacrylic acid; or mixtures of the styrene compound and of the (C1-C8-alkyl)ester of acrylic or methacrylic acid; (b22) 0 to 40 wt % acryl nitrile or methacryl nitrile or their mixtures; and (b23) 0 to 40 wt % of one or several other monoethylenically unsaturated monomers.
摘要翻译： A））30至99重量％，基于模塑组合物的总重量计，的热塑性聚合物，基于A A1）50〜100重量通式的苯乙烯化合物的％：从含有热塑性模塑化合物制备的模制品（I），<1>和R <2>是R代表氢或C1-C8烷基，或（C1-C8烷基）丙烯酸或甲基丙烯酸，或苯乙烯类化合物的混合物和（C1-C8的酯烷基）丙烯酸或甲基丙烯酸的酯，A2）0〜40重量丙烯腈或甲基丙烯腈或它们的混合物的％和a3）0〜40重量％的一种或多种选自A2其它单烯键式不饱和不同）单体，B的％）1〜70重量％，基于模塑组合物的总重量计，其包括，基于B的接枝聚合物的，），B1）为30〜90重量具有低于0℃的玻璃化转变温度的聚合物的橡胶弹性接枝芯％，可获得由共聚，基于b 1），B11）50〜99.99重量一（C1-C10烷基的％）丙烯酸的酯，B12）0.01至10重量重量的多官能团的％，交联单体，和B13）0至40 .-的一种或多种其它单烯属不饱和的，从B11）不同的单体，和b2）为10〜70重量的接枝壳的基础上，b2的％），B21）50〜100重量通式的苯乙烯化合物的％％（I），<1>和R <2>是R代表氢或C1-C8烷基，或（C1-C8烷基）丙烯酸或甲基丙烯酸，或苯乙烯类化合物的混合物和（C1-C8的酯烷基）丙烯酸或甲基丙烯酸的酯，B22）0至40重量丙烯腈或甲基丙烯腈或它们的混合物的％和B23）从0至40重量的一种或多种其它单烯属不饱和单体的％。

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