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    • 1. 发明申请
    • DISPERSIONS CONTAINING POLYURETHANES WITH CARBONYL GROUPS IN THE KETO FUNCTION
    • 分散体含聚氨酯在ketofunction羰基
    • WO1997011103A1
    • 1997-03-27
    • PCT/EP1996004031
    • 1996-09-13
    • BASF AKTIENGESELLSCHAFTKOKEL, NicolasRAU, Maria, GyoparETTL, RolandLARBIG, HaraldMELDER, Johann-PeterGULBINS, ErichWIRTH, Thomas
    • BASF AKTIENGESELLSCHAFT
    • C08G18/08
    • C14C11/006C08G18/0823C08G18/12C08G18/3825C08G18/5039C08G18/833C08G18/3228
    • The invention concerns aqueous dispersions containing a polyurethane (A), containing structural units derived from compounds of formula (I), in which the substituents have the following meanings: R , R , R each designate hydrogen, C1-C24 alkyl or C6 - C24 alkenyl; R designates hydrogen; R , R a) together designate C4-C10 alkane-diyl, b) each designate C2-C10 alkyl, C5-C8 cycloalkyl or C7-C20 aralkyl, c) each designate a hydroxyl-terminated poly(C2-C4 alkylene oxide), or d) designate an R or R group with the meaning given in (a) to (c) and the other group designating hydrogen or a group of formula (II), in which X designates C2-C6 alkane-diyl; and R has the same meaning as R or R with the exception that R is not a group of formula II, R and R carrying a total of between 2 and 5 hydroxyl groups bonded to aliphatic carbon atoms; and R and/or R optionally carrying 1 or 2 aromatically bonded hydroxyl groups or 1 nitrile, tertiary amino, carboxylic acid or sulphonic acid group which are optionally present in the form of their salts.
    • 包含含有从式(I)的化合物的结构单元的聚氨酯(A),其中取代基具有以下含义的水性分散体:R t <1>,R <2>,R <3>各自是氢, C1至C24的烷基或C6至C24链烯基; [R <4>氢; [R <5> - [R <6>一个)一起C4-C10链烷,b)分别是C2至C10烷基,C5-C8的环烷基或C 7至C 20 - 芳烷基,c)是各自为羟基封端的聚 (C2至C4环氧烷)中,d)基团R <5>或R <6>中所定义的(a)至c(同上),并且另一个基团为氢或式的基团(II),其中X C2至C6烷二基且R <7>是等效于R <5>或R <6>,不同之处在于R <7>并不意味着一个式的基团(II),其中R <5> 且R <6>穿总共2至5连接到脂族碳原子,羟基基团和,如果合适的话,基团R <5>和/或R <6> 1或2个芳族键合羟基基团或1腈,叔氨基,羧酸或 磺酸基团,其存在任选地为其盐的形式,有助于。
    • 3. 发明申请
    • PROCESS FOR PREPARING ALIPHATIC ALPHA,OMEGA-AMINONITRILES
    • 用于生产脂肪族α,ω-氨基腈
    • WO1996020166A1
    • 1996-07-04
    • PCT/EP1995004985
    • 1995-12-16
    • BASF AKTIENGESELLSCHAFTMELDER, Johann-PeterSCHNURR, WernerFLICK, KlemensEBEL, KlausWITZEL, TomFISCHER, RolfHARDER, WolfgangREHFINGER, Alwin
    • BASF AKTIENGESELLSCHAFT
    • C07C253/30
    • B01J23/8898B01J23/76B01J23/8892B01J37/0201C07C253/30C07C255/24
    • Aliphatic alpha,omega-aminonitriles are prepared by partially hydrogenating aliphatic alpha,omega-dinitriles at an increased temperature and pressure in the presence of a solvent and a catalyst. The catalyst contains (a) a compound based on a metal selected from the group made up of nickel, cobalt, iron, ruthenium and rhodium; (b) 0.01 to 25 % by weight in relation to (a) of a promoter based on a metal selected from the group comprising of palladium, platinum, iridium, osmium, copper, silver, gold, chromium, molybdenum, tungsten, manganese, rhenium, zinc, cadmium, lead, aluminium, tin, phosphorus, arsenic, antimony, bismuth, silicium, titanium, zirconium and rare earth metals; and (c) 0 to 5 % by weight in relation to (a) of a compound based on an alkaline or alkaline-earth metal, provided that component (a) not be based on iron or iron and a metal selected from the group comprising cobalt, ruthenium and rhodium when (b) is a promoter based on a metal selected from the group comprising titanium, manganese, chromium and molybdenum. Moreover, when component (a) is a compound based only on ruthenium or on rhodium, ruthenium and rhodium, or nickel and rhodium, promoter (b) may be dispensed with.
    • 通过在升高的温度和升高的压力下,在溶剂和催化剂的存在下的脂族α,ω-二腈的部分氢化的脂族α,ω-氨基腈的制备,通过使用包括(a)基于金属的化合物的催化剂, 选自由镍,钴,铁,钌,铑,和(b)是组成的组中为0.01〜25重量%,基于(a),选自基于金属的启动子的 选自由钯,铂,铱,锇,铜,银,金,铬,钼,钨,锰,铼,锌,镉,铅,铝,锡,磷,砷,锑,铋,硅,钛组成的组中 含从0锆和稀土金属,和(c)至5重量%,基于(a)中,基于碱金属或碱土金属的化合物,条件是组分(a)是不上的 基于铁或铁和德 [R选自由钴,钌和铑的组中选择的金属,是当(b)是基于从由钛,锰,铬和钼组成的组中选择的金属的启动子,是以及与所述另一 当作为组分(a)被选择条件仅基于钌或铑或钌,铑或镍和铑的化合物,该启动子可被省略(b)中。
    • 8. 发明申请
    • IMPROVED METHOD FOR PRODUCING HEXAMETHYLENE DIAMINE
    • 改进工艺用于生产己二胺
    • WO2000003972A1
    • 2000-01-27
    • PCT/EP1999004582
    • 1999-07-02
    • BASF AKTIENGESELLSCHAFTFISCHER, RolfBASSLER, PeterLUYKEN, HermannOHLBACH, FrankMELDER, Johann-PeterMERGER, MartinANSMANN, AndreasREHFINGER, AlwinVOIT, Guido
    • BASF AKTIENGESELLSCHAFT
    • C07C209/48
    • C07C209/48C07C211/12
    • A method for catalytic hydrogenation of adipodinitrile into hexamethylene diamine at a high temperature and high pressure in the presence of catalysts based on elementary iron as a catalytically active constituent and ammonia as a solvent. The invention is characterized in that a) adipodinitrile is hydrogenated at temperatures ranging from 70 to 220 °C and at pressures of 100-400 bars in the presence of catalysts based on elementary iron and ammonia as a solvent to obtain a mixture containing adipodinitrile, 6-aminocapronitrile, hexamethylene diamine and high boilers until the sum of the 6-aminocapronitrile and adipodinitrile concentrations amount to 1-50 wt. % in relation to the ammonia-free hydrogenation mixture; b) ammonia is separated from the hydrogenation product; c) hexamethylene diamine is separated from the remaining mixture; d) 6-aminocapronitrile and adipodinitrile are separated individually or jointly from high boilers and e) 6-aminocapronitrile, adipodinitrile or the mixtures thereof are returned to step a).
    • 一种用于己二腈的催化加氢过程中在升高的温度和升高的压力下在催化剂的存在下根据元素铁作为催化活性组分和氨作为溶剂,其特征在于:a)己二腈在70℃至220℃六亚甲基二胺 氢化和基于元素铁作为催化活性组分和氨作为溶剂的混合物,其包含己二腈,6-氨基己腈,六亚甲基二胺和高沸点直到6-氨基己腈的总和至400巴在催化剂的存在下的100的压力 和的1的己二腈的浓度至50重量%,基于该无氨氢化混合物; b)从该氢化产物氨分离; c)从剩余的混合物中分离六亚甲基二胺; D)6-氨基己腈和己二腈从高沸点单独或一起被分离; 和e)6-氨基己腈,己二腈或它们的混合物到步骤a)引回。
    • 9. 发明申请
    • PROCESS FOR PRODUCING MODIFIED RUBBER MOULDING MASSES BY USING PEROXY GROUP-CONTAINING COMPOUNDS
    • 用于生产橡胶改性模塑料使用过氧HAVING CONNECTIONS
    • WO1996015164A1
    • 1996-05-23
    • PCT/EP1995004476
    • 1995-11-14
    • BASF AKTIENGESELLSCHAFTMC KEE, Graham, EdmundMOORS, RainerHECKMANN, WalterLARBIG, HaraldROSENAU, Bernhard
    • BASF AKTIENGESELLSCHAFT
    • C08F65/04
    • C08F285/00
    • In a process for producing modified rubber moulding masses, a first mixture (A) that contains at least one alkyl acrylate or methacrylate (a) having the general formula (I), in which R stands for a hydrogen atom or a methyl group and R stands for an alkyl group with 1 to 32 carbon atoms, optionally a first monomer (b) with two or more double bonds and optionally a second or several other monomers (c), is in a first step polymerised into a rubber (B), preferably together with free radicals. In a second step, a third or several other monomers (d) are added to the thus obtained rubber (B) to form a second mixture (C). In a third step, the second mixture (C) is polymerised together with free radicals into the modified rubber moulding mass (D). During or after polymerisation, the mixture is reacted at a temperature above 120 DEG C with a compound (e) that contains at least two peroxy groups.
    • 在用于制备橡胶改性的模制组合物的方法:在第一阶段中,第一混合物(A)包含至少一种丙烯酸烷基酯或甲基丙烯酸酯,通式(I),其中R <1>是氢原子或甲基的(a)和 [R <2>表示具有1至32个碳原子,任选的烷基的第一,两个或多个表现出单体(b)和可选地还包括第二单体(c)或更多,以得到橡胶(b)的双键进行聚合,最好用 自由基; 在第二阶段中的橡胶得到的(B),以形成第二混合物(C)的第三单体(d)或更多被添加为好:在第三阶段,形成了(C)与自由基所述第二混合物,得到橡胶改性的模制材料(D) 聚合和期间或此聚合后,将混合物进行反应,同时具有至少两个过氧基团的化合物(e)中,在温度> 120℃。