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    • 1. 发明申请
    • PROCESS FOR PRODUCING THERMOPLASTICS
    • 用于生产热塑性
    • WO1998013412A1
    • 1998-04-02
    • PCT/EP1997005000
    • 1997-09-12
    • BASF AKTIENGESELLSCHAFTGÜNTHERBERG, NorbertHOFMANN, JürgenMAILAHN, ElmarOHLIG, HilmarCZAUDERNA, BernhardGRABOWSKI, SvenBUS, Klaus
    • BASF AKTIENGESELLSCHAFT
    • C08J03/205
    • B29B13/06B29C47/0011B29C47/0019B29C47/0023B29C47/40B29C47/64B29C47/76C08J3/205C08L51/04
    • A process is disclosed for producing thermoplastics modified to be impact-resistant or polymer blends containing such modified thermoplastics. The thermoplastics or polymer blends contain: (A) 5 to 95 wt % of at least one water-wet elastomer component A which contains up to 60 wt % residual water; (B) 5 to 95 wt % of at least one thermoplastic polymer B; (C) 0 to 95 wt % of at least another polymer C; and (D) 0 to 70 wt % additives D. The elastomer component A is mixed with the thermoplastic polymer B, if available with the other polymer C and if available with the additives D in a screw-machine while mechanically dewatering the elastomer component A. The process is characterised in that components A, B, C and D are supplied to an extruder with at least two screws that rotate in the same or opposite directions and have a diameter Dscrew. Seen in the feeding direction (downstream), the extruder substantially consists of at least one dosing section in which the elastomer component A is supplied to the extruder by a dosing device; at least one squeezing section for dewatering the elastomer component A having at least one pressure element and at least a corresponding dewatering opening located upstream of the (first) pressure element at a distance therefrom equal to at least one screw diameter Dscrew; at least one feeding section in which the thermoplastic polymer B is fed into the extruder as a molten mass; at least one plasticising section fitted with mixing and/or kneading elements; at least one degassing section with at least one degassing hole in which the residual water is removed as steam; and an extraction zone. The water expelled through the dewatering openings is partially or totally present in the liquid phase, and components C and/or are supplied together or separately, either together with components A and/or B or separately from A and B in one or more of the above-mentioned extruder sections.
    • 一种制备增韧热塑性塑料或抗冲改性的热塑性塑料含有热塑性塑料或A的聚合物共混物)的聚合物共混物为5〜95重量的至少一种水湿润,最多60重量含残留水基弹性体组分A的%%过程中,B)5〜 95重量%的至少一种热塑性聚合物B,C)0%至95重量%的至少一种其它聚合物C,和D)0%至70重量%的添加剂D,通过与热塑性聚合物B混合弹性体组分的 并且,如果存在的话,另外的聚合物C和,如果存在的话,在与弹性体成分的的机械脱水挤压机的添加剂D,其特征在于,组分A,B,C和D具有至少两个一个同向旋转或反向旋转的挤出机中 供给具有螺杆直径D螺杆丝杆,通过,其特征在于,在输送方向(下游)中Wesent挤出机 至少一个计量部分的结合,弹性体组分A由一计量装置加入到挤出机中,所述弹性体成分的脱水中的至少一项所述的服务挤压部,所述至少一个延迟元件和在每种情况下,至少一个相关联的脱水孔,其是在至少一个螺杆直径的距离 ð螺丝,(第一)延迟元件位于上游之前,包括,至少一个进料部分,其中该热塑性聚合物B被引入作为熔体到挤出机中,至少一个部分设置有混合和/或捏合元件塑化部,至少一个设置有至少一个排气口脱气 在其中剩余的水蒸汽除去,并构造一个排料区从脱水出来的光部分地或完全孔口水在液相中,并且所述 组分C和/或D彼此或者与组分A和/或B从A馈送一起或单独一起或单独和B的一个或多个所陈述的挤出机区段。