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1. 发明申请

WO2007082928A3 METHOD FOR PRODUCTION OF A RUTHENIUM CATALYST 审中-公开
标题翻译：用于生产钌催化剂
公开(公告)号：WO2007082928A3
公开(公告)日：2008-04-10
申请号：PCT/EP2007050530
申请日：2007-01-19
申请人： BASF AG , JAEKEL CHRISTOPH , HETTCHE FRANK , RUDOLPH JENS , PACIELLO ROCCO
发明人： JAEKEL CHRISTOPH , HETTCHE FRANK , RUDOLPH JENS , PACIELLO ROCCO
IPC分类号： B01J37/04 , B01J31/18 , B01J31/22 , B01J31/24 , C07F15/00
CPC分类号： C07F15/0046 , B01J31/1805 , B01J31/1815 , B01J31/182 , B01J31/183 , B01J31/1845 , B01J31/185 , B01J31/186 , B01J31/1865 , B01J31/1875 , B01J31/2291 , B01J31/2295 , B01J31/24 , B01J31/2409 , B01J31/2414 , B01J31/2419 , B01J31/2438 , B01J31/2452 , B01J31/2457 , B01J31/2471 , B01J31/248 , B01J31/2495 , B01J37/04 , B01J2231/643 , B01J2531/0263 , B01J2531/0266 , B01J2531/821 , C07F15/0053
摘要： The invention relates to a method for production of a ruthenium catalyst comprising i) a bidentate phosphorous ligand or two monodentate phosphorus ligands and ii) a bidentate nitrogen ligand or two monodentate nitrogen ligands.
摘要翻译：本发明涉及一种方法，用于制备的钌催化剂，其中ⅰ）的磷二齿配位体或两个单齿磷配体，和ii）一个氮二齿配位体或两个单齿氮配位体。

2. 发明申请

WO2006002999A3 METHOD FOR THE PRODUCTION OF OPTICALLY ACTIVE ALKYL SUCCINIC ACID MONOALKYL ESTERS 审中-公开
标题翻译：工艺制备光学活性ALKYLBERNSTEINSÄUREMONOALKYLESTERN
公开(公告)号：WO2006002999A3
公开(公告)日：2006-09-08
申请号：PCT/EP2005007289
申请日：2005-07-06
申请人： BASF AG , HETTCHE FRANK , JAEKEL CHRISTOPH , FRIEDRICH MARKO , PACIELLO ROCCO
发明人： HETTCHE FRANK , JAEKEL CHRISTOPH , FRIEDRICH MARKO , PACIELLO ROCCO
IPC分类号： C07C67/303 , C07C69/34
CPC分类号： C07C67/303 , C07B2200/07 , C07C69/34
摘要： The invention relates to a method for producing optically active alkyl succinic acid monoalkyl esters of formula (I), wherein D and E independently represent H, C 1 -C 10 alkyl, RC 1 -C 10 alkyl, aryl, or alkylaryl.
摘要翻译：本发明涉及一种制备式的旋光活性Alkylbernsteinsäuremonoalkylestern（I），其中D和E彼此独立地H，C _{1 -C _{10 烷基，RC _{的制备 1 -C _{10 - 烷基，芳基，或烷芳基。}}}}

3. 发明申请

WO2006034812A3 METHOD FOR PRODUCING AN OPTICALLY ACTIVE 2-METHYL-ALKANE-1-OL FROM THE CORRESPONDING 2-METHYLALK-2-EN-1-AL, COMPRISING CARBONYL-SELECTIVE REDUCTION, ENANTIOSELECTIVE HYDRATION AND LIPASE-CATALYZED, STEREOSELECTIVE ACYLATION IN ORDER TO ENRICH THE DES 审中-公开
标题翻译：用于生产光学活性的2-甲基-1- OLS的烷从相关2- methylalk-2-CN-1-AL，包括CARBONYLSELEKTIVE REDUCTION，A对映选择性氢化以及脂肪酶催化，STEREO选择性酰化ZWEC
公开(公告)号：WO2006034812A3
公开(公告)日：2006-07-20
申请号：PCT/EP2005010240
申请日：2005-09-22
申请人： BASF AG , JAEKEL CHRISTOPH , HEYDRICH GUNNAR , STUERMER RAINER , PACIELLO ROCCO
发明人： JAEKEL CHRISTOPH , HEYDRICH GUNNAR , STUERMER RAINER , PACIELLO ROCCO
IPC分类号： C07C29/141 , C07C29/17 , C12P7/04 , C12P41/00
CPC分类号： C12P7/04 , C07B2200/07 , C07C29/14 , C07C29/141 , C07C29/172 , C12C11/02 , C07C33/025 , C07C31/125
摘要： The invention relates to a method for producing optically active 2-methylalkane-1-ol of general formula (III), comprising the following steps: (i) carbonyl-selective reduction of 2-methylalk-2-en-1-al of general formula (I) to 2-methylalk-2-en-1-ol of general formula (II), (ii) enantioselective hydration of 2-methylalk-2-en-1-ol to give the compound of general formula (III), (iii) increasing the optical yield of the optically active 2-methylalkane-1-ol (III) obtained in step (ii) by way of a lipase-catalyzed acylation reaction, whereby R represents C 1 -C 10 alkyl.
摘要翻译：一种制备光学活性的2-甲基的通式（III）的烷-1-醇，其包括以下步骤：（ⅰ）carbonylselektive还原的2- methylalk -2-烯-1-醛的通式（I）的2- methylalk -2-烯-1-醇，通式（II），（II）通式（III）的2- methylalk -2-烯-1-醇的对映选择性氢化的，（iii）增加的步骤的光学收率（ii）所述得到的光学活性2-甲基烷烃-1-醇（III）由脂肪酶催化酰化反应（式I - IV），其中R表示C _{1 -C _{10 具有烷基。}}

4. 发明专利

DE102006041064A1 New phosphorous compound useful as ligand in catalyst for e.g. hydroformylation-, hydrocyanation-, carbonylation-, hydroacylation-, hydroamination- and hydro esterification reactions 未知
公开(公告)号：DE102006041064A1
公开(公告)日：2007-03-08
申请号：DE102006041064
申请日：2006-09-01
申请人： BASF AG
发明人： JAEKEL CHRISTOPH , HETTCHE FRANK , VOLLAND MARTIN , BREIT BERNHARD , LAUNGANI ANDY
IPC分类号： C07K5/062 , B01J31/24 , C07B53/00 , C07C45/50 , C07F9/6564
摘要： Phosphorous compound (I) is new. Phosphorous compound of formula (I) is new. Y1>bivalent bridge group with bridge atoms between the flanking bonds; Ra, Rb : (cyclo)alkyl, heterocycloalkyl or (het)aryl (where alkyl is substituted by 1-5 (hetero)cycloalkyl, (het)aryl,(cyclo)alkoxy, heterocycloalkoxy, (het)aryloxy, OH, SH, polyalkyleneoxide, polyalkylene imine, COOH, carboxylate, SO3H, sulfonate, NE1>E2>, NE1>E2>E3>X->, halo, NO2, acyl or CN), where (hetero)cycloalkyl- and (het)aryl are substituted with 1-5 alkyl; or RaRb+P+X1>X2>5-8 membered heterocycle, optionally substituted with 1-3 (hetero)cycloalkyl or (het)aryl, where heterocycle and the substituted group consists of 1-4 of (cyclo)alkyl, heterocycloalkyl, (het)aryl, OH, SH, polyalkylene oxide, polyalkylene imine, alkoxy, halo, COOH, carboxylate, SO3H, sulfonate, NE4>E5>, NE4>E5>E6>X-, NO2, alkoxycarbonyl, acyl or CN; E1>-E8>H, (cyclo)alkyl or aryl; X->anion; Ry : peptide group comprising at least two amino acid units; X1>, X2>O, S, SiRcRd or NRe; Z : NR9> or CR9>R10>; Rc, Rd, Re : H, (cyclo)alkyl, heterocycloalkyl or (het)aryl; R1>-R10>H, (cyclo)alkyl, heterocycloalkyl, (het)aryl, OH, SH, polyalkylene oxide, polyalkylene imine, alkoxy, halo, SO3H, sulfonate, NE7>E8>, alkylene-NE7>E8>, CF3, NO2, alkoxycarbonyl, carboxyl, acyl or CN; or two adjacent groups of R1>, R2>, R4>, R6>, R8>, R9> (for a bonding portion of double bond between the ring atoms) : six membered ring exhibiting a maximum of three non-cumulative double bonds; and a, b, c : 0 or 1. Independent claims are also included for: (1) a catalyst comprising at least a complex having a transition metal and (I) as ligand; (2) a method for hydroformylating a compound containing at least an ethylenic unsaturated double bond comprising reacting the ethylenic unsaturated double bond with carbon monoxide and hydrogen in the presence of the catalyst; and (3) a method for the preparation of chiral compounds comprising reacting the prochiral compound containing at least an ethylenic unsaturated double bond with a substrate in the presence of a chiral catalyst. [Image].

5. 发明专利

DE102005040655A1 未知
公开(公告)号：DE102005040655A1
公开(公告)日：2007-03-01
申请号：DE102005040655
申请日：2005-08-26
申请人： BASF AG
发明人： RAULS MATTHIAS , JAEKEL CHRISTOPH , KASHANI-SHIRAZI NAWID , EBEL KLAUS
IPC分类号： C07C29/76 , C07C29/17 , C07C35/08 , C07C35/12

6. 发明专利

DE102004052040A1 未知
公开(公告)号：DE102004052040A1
公开(公告)日：2006-04-27
申请号：DE102004052040
申请日：2004-10-26
申请人： BASF AG
发明人： AHLERS WOLFGANG , EGEN MARTINA , VOLLAND MARTIN , JAEKEL CHRISTOPH , HETTCHE FRANK , PACIELLO ROCCO
IPC分类号： C07F9/645 , B01J31/24 , C07B31/00 , C07B37/00 , C07B37/02 , C07B41/00 , C07B41/06 , C07B43/00 , C07B47/00 , C07B53/00 , C07F17/00
摘要： The invention relates to chiral phosphorus chelate compounds, to catalysts comprising such a compound such a compound as the ligand, and to asymmetric synthesis methods in the presence of such a catalyst.

7. 发明专利

DE10355066A1 未知
公开(公告)号：DE10355066A1
公开(公告)日：2005-06-23
申请号：DE10355066
申请日：2003-11-25
申请人： BASF AG , ALBERT LUDWIGS UNI
发明人： JAEKEL CHRISTOPH , VOLLAND MARTIN , MACKEWITZ THOMAS , PACIELLO ROCCO , BREIT BERNHARD , SEICHE WOLFGANG , WEIS MARTINE , WALOCH CHRISTOPH
IPC分类号： C07B53/00 , C07F9/58 , C07F9/6571 , C07B41/00
摘要： The present invention relates to a process for asymmetric synthesis in the presence of a chiral catalyst comprising at least one complex of a metal of transition group VIII with ligands capable of dimerization via noncovalent bonds, such catalysts and their use.

8. 发明专利

DE102005036340A1 未知
公开(公告)号：DE102005036340A1
公开(公告)日：2007-02-01
申请号：DE102005036340
申请日：2005-07-29
申请人： BASF AG
发明人： JAEKEL CHRISTOPH , PACIELLO ROCCO
IPC分类号： C07F9/50 , C07B53/00 , C07B57/00 , C07C45/62 , C07C47/21

9. 发明专利

DE102005029228A1 Preparation of optically active 3-phenylpropionic acid derivatives, used for preparing halo-phenyl compounds, comprises hydrogenating cis-isomer mixture of phenyl compound, crystallizing enantiomer mixture and isolating solid material 未知
公开(公告)号：DE102005029228A1
公开(公告)日：2006-12-28
申请号：DE102005029228
申请日：2005-06-23
申请人： BASF AG
发明人： HETTCHE FRANK , VOELKERT MARTIN , JAEKEL CHRISTOPH , BEY OLIVER
IPC分类号： C07C59/64 , C07C43/225
摘要： Preparation of an optically active 3-phenylpropionic acid derivative (I) comprises: (a) an enantioselective hydrogenation of a cis-isomer or cis/trans-isomer mixture of a phenyl compound (II) in the presence of a chiral hydrogenation catalyst to give an enantiomer enriched enantiomer mixture; (b) crystallization of the enantiomer enriched enantiomer mixture by supplementation of a basic salt former in a solvent and isolating the stereoisomer enriched solid material; and (c) optionally isolation of the protonated isomer or a substitutional cation. Preparation of an optically active 3-phenylpropionic acid derivative of formula (I) comprises: (a) an enantioselective hydrogenation of a cis-isomer or cis/trans-isomer mixture of a phenyl compound of formula (II) in the presence of a chiral hydrogenation catalyst to give an enantiomer enriched enantiomer mixture; (b) crystallization of the enantiomer enriched enantiomer mixture by supplementation of a basic salt former in a solvent and isolating the stereoisomer enriched solid material; and (c) optionally isolation of the protonated isomer or a substitutional cation. R 1>-R 4>H, 1-6C alkyl, halo-1-6C alkyl, OH-1-6C alkyl, 1-6C alkoxy, OH-1-6C alkoxy, 1-6C alkoxy-1-6C alkyl, OH-1-6C alkoxy-1-6C alkyl, 1-6C alkoxy-1-6C alkoxy or OH-1-6C alkoxy-1-6C alkoxy; R 5>1-6C alkyl, 5-8C cycloalkyl, phenyl or benzyl; and A : H or cationic equivalent. Independent claims are also included for: (1) the preparation of optically active halo-phenyl compound of formula (III), which comprises protonating (I) in to an acid; reducing the acids or the metal salts to give an alcohol compound of formula (IV); and halodehydroxylating (IV); and (2) an optically active compound 3-phenylpropionic acid derivative (I). Hal : Cl, Br or I. [Image] [Image].

10. 发明专利

DE112004002335D2 未知
公开(公告)号：DE112004002335D2
公开(公告)日：2006-11-02
申请号：DE112004002335
申请日：2004-12-22
申请人： BASF AG
发明人： VOLLAND MARTIN , SIEGEL WOLFGANG , EBEL KLAUS , DITRICH KLAUS , PACIELLO ROCCO , CHABANAS MATHIEU , TELES JOAQUIM HENRIQUE , JAEKEL CHRISTOPH , PAPP REINER , MERGER ROLAND
IPC分类号： C07D311/00 , C07D311/82

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