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    • 2. 发明申请
    • MULTIMODAL POLYETHYLENE COMPOSITION, MIXED CATALYST AND PROCESS FOR PREPARING THE COMPOSITION
    • 多型聚乙烯组合物,混合催化剂和制备组合物的方法
    • WO2008077530A2
    • 2008-07-03
    • PCT/EP2007011113
    • 2007-12-18
    • BASELL POLYOLEFINE GMBHKIPKE JENNIFERMIHAN SHAHRAMKARER RAINERSCHMITZ HARALD
    • KIPKE JENNIFERMIHAN SHAHRAMKARER RAINERSCHMITZ HARALD
    • C08L23/04C08F297/08
    • B01J31/12C08F2/34C08F4/65912C08F10/00C08F10/02C08F210/16C08F2410/04C08J5/18C08J2323/04C08L23/04C08L23/06C08L23/0815C08L2205/03C08L2314/06Y02P20/52C08F4/65925C08F4/65916C08L23/00C08L2666/06C08F210/14C08F2500/07C08F2500/08C08F2500/04C08F2500/26C08F4/7042C08F4/61904
    • A multimodal polyethylene composition, in particular suitable for the preparation of films, but also textile articles, blow molded articles and injection molded articles is described. The polyethylene composition of the invention comprises at least three ethylene polymer fractions having distinct molecular weights or comonomer contents, said at least three ethylene polymer fractions comprising at least one first ethylene polymer fraction having a first molecular weight, a first comonomer content lower than a predetermined value and a first density; at least one second ethylene polymer fraction having a second molecular weight higher than said first molecular weight, a second comonomer content higher than said first comonomer content, and a second density; and at least one third ethylene polymer fraction having a third molecular weight higher than said first molecular weight, a third comonomer content lower than a predetermined value, and a third density; wherein said at least one first ethylene polymer fraction and said at least third ethylene polymer fraction are prepared by the use of a first and, respectively, third catalyst and said at least one second ethylene polymer fraction is prepared by the use of a second catalyst of the single site type. The films prepared from the composition of the invention have improved water vapor barrier properties. Furthermore, a mixed catalyst system comprising at least three catalyst components and a process particularly suitable to prepare the composition of the invention are described.
    • 描述了一种多峰聚乙烯组合物,特别适用于制备薄膜,但也包括纺织品,吹塑制品和注塑制品。 本发明的聚乙烯组合物包含至少三种具有不同分子量或共聚单体含量的乙烯聚合物部分,所述至少三种乙烯聚合物部分包含至少一种具有第一分子量的第一乙烯聚合物部分,第一共聚单体含量低于预定的 价值和第一密度; 至少一种具有高于所述第一分子量的第二分子量的第二乙烯聚合物部分,第二共聚单体含量高于所述第一共聚单体含量和第二密度; 和至少一种具有比所述第一分子量高的第三分子量,低​​于预定值的第三共聚单体含量和第三密度的第三乙烯聚合物部分; 其中所述至少一种第一乙烯聚合物部分和所述至少第三乙烯聚合物部分通过使用第一催化剂和第三催化剂制备,并且所述至少一种第二乙烯聚合物部分通过使用第二催化剂 单一网站类型。 由本发明组合物制备的膜具有改善的水蒸气阻隔性能。 此外,描述了包含至少三种催化剂组分的混合催化剂体系和特别适用于制备本发明组合物的方法。
    • 4. 发明申请
    • PROCESS AND APPARATUS FOR THE POLYMERIZATION OF ETHYLENE
    • 乙烯聚合的方法和装置
    • WO2006082007A8
    • 2007-08-30
    • PCT/EP2006000783
    • 2006-01-30
    • BASELL POLYOLEFINE GMBHPENZO GIUSEPPEAHMADZADE-YOUSSEFI CYRUSKARER RAINERNIEKEN ULRICH
    • PENZO GIUSEPPEAHMADZADE-YOUSSEFI CYRUSKARER RAINERNIEKEN ULRICH
    • C08F2/34C08F10/02
    • C08F10/02B01J8/0035B01J8/006B01J8/24B01J2208/00274B01J2208/00761B01J2219/00006C08F6/005C08F10/00C08F110/02C08F210/16Y02P20/582Y10S526/92C08L23/06C08L23/0815C08F4/69C08F2/34C08F2/01C08F210/08C08F210/14
    • Process for the polymerization of ethylene or of ethylene with further 1 -olefins, in which the ethylene is polymerized in the presence of a catalyst in a gas-phase reactor and reaction gas comprising propane and unpolymerized ethylene is circulated to remove the heat of polymerization, wherein the polymer particles are discharged continuously or discontinuously from the reactor, the polymer particles are separated from the major part of the concomitantly discharged gas and the polymer particles are degassed, the gas is freed of entrained fine particles and is separated from a low-boiling fraction comprising ethylene or from a high boiling fraction containing further 1-olefins or alkanes having from 4 to 12 carbon atoms in a first separation stage, a propane fraction is separated off in a second separation stage and this propane fraction is used for degassing the polymer particles discharged from the reactor, with the proportion of ethylene in the propane fraction being less than 1 mol% and the proportion of 1-olefins and alkanes having from 4 to 12 carbon atoms in the propane fraction being less than 4 mol%, in each case based on the total propane fraction. Furthermore, an apparatus for carrying out the process. In this way, a high heat discharge from the reactor, satisfactory degassing of the discharged polymer particles and recovery of the reaction gas discharged together with the polymer particles and also the gas used for degassing the polymer particles are made possible.
    • 乙烯或乙烯与进一步的1-烯烃聚合的方法,其中乙烯在催化剂存在下在气相反应器和包含丙烷和未聚合的乙烯的反应气体中聚合,循环除去聚合热, 其中聚合物颗粒从反应器中连续或不连续地排出,聚合物颗粒与伴随排出气体的主要部分分离,聚合物颗粒脱气,气体不含夹带的细颗粒,并从低沸点 在第一分离阶段,包含乙烯或含有另外的具有4至12个碳原子的1-烯烃或烷烃的高沸点馏分的馏分在第二分离阶段分离出丙烷馏分,该丙烷馏分用于使聚合物脱气 从反应器排出的颗粒,丙烷馏分中乙烯的比例小于1mol %,丙烷馏分中具有4至12个碳原子的1-烯烃和烷烃的比例小于4摩尔%,基于总丙烷馏分。 此外,一种用于执行该过程的装置。 以这种方式,可以从反应器的高热放电,排出的聚合物颗粒的令人满意的脱气和与聚合物颗粒一起排放的反应气体的回收以及用于使聚合物颗粒脱气的气体成为可能。
    • 7. 发明专利
    • processo para a polimerização de etileno ou de etileno com outras 1-olefinas, aparelho para realizar o processo, e, uso de propano
    • BRPI0607244B1
    • 2016-05-31
    • BRPI0607244
    • 2006-01-30
    • BASELL POLYOLEFINE GMBH
    • AHMADZADE-YOUSSEFI CYRUSPENZO GIUSEPPEKARER RAINERNIEKEN ULRICH
    • C08F2/34
    • processo para a polimerização de etileno ou de etileno com outras 1-olefinas, aparelho para realizar o processo, e, uso de propano. processo para a polimerização de etileno ou de etileno com outras 1 -olefinas, em que o etileno é polimerizado na presença de um catalisador em um reator em fase gasosa e o gás de reação compreendendo propano e etileno não polimerizado é circulado para remover o calor da polimerização, em que as partículas poliméricas são descarregadas continuamente ou descontinuamente do reator, as partículas poliméricas são separadas da parte principal do gás concomitantemente descarregado e as partículas poliméricas são desgaseificadas, o gás é livre de partículas finas arrastadas e é separado de uma fração de ebulição baixa que compreende etileno ou de uma fração de ebulição alta que contém as outras 1 -olefinas ou alcanos tendo de 4 a 12 átomos de carbono em um primeiro estágio de separação, uma fração de propano é separada em um segundo estágio de separação e esta fração de propano é usada para desgaseificar as partículas poliméricas descarregadas do reator, com a proporção de etileno na fração de propano sendo de menos do que 1 % em moi e a proporção de 1 -olefinas e alcanos tendo de 4 a 12 átomos de carbono na fração de propano sendo de menos do que 4% em moi, em cada caso com base na fração total de propano. além disso, um aparelho para realizar o processo. deste modo, uma descarga de alto calor do reator, a desgaseificação satisfatória das partículas poliméricas descarregadas e a recuperação do gás de reação descarregado junto com as partículas poliméricas e também o gás usado para desgaseificar as partículas poliméricas tomam-se possíveis.