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1. 发明申请

WO2007057361A1 PROPYLENE-ETHYLENE COPOLYMERS AND PROCESS FOR THEIR PREPARATION 审中-公开
标题翻译：丙烯 - 乙烯共聚物及其制备方法
公开(公告)号：WO2007057361A1
公开(公告)日：2007-05-24
申请号：PCT/EP2006/068354
申请日：2006-11-10
申请人： BASELL POLIOLEFINE ITALIA S.R.L. , BACCI, Dino , FAIT, Anna , MORINI, Giampiero , PELLEGATTI, Giampaolo , PIEMONTESI, Fabrizio
发明人： BACCI, Dino , FAIT, Anna , MORINI, Giampiero , PELLEGATTI, Giampaolo , PIEMONTESI, Fabrizio
IPC分类号： C08F210/02
CPC分类号： C08F210/06 , C08F210/16 , C08F2500/04 , C08F2500/12 , C08F2500/17 , C08F2500/15 , C08F2500/11 , C08F2500/20
摘要： Propylene-ethylene copolymers are flexible and show a very good balance between softness and mechanical properties in their crude state are obtained by solution polymerization in the presence of Ziegler-Natta catalysts. The said copolymers comprise from 10 to 50%wt of ethylene and are characterized by: product of the comonomer reactivity ratio r1•r2 ≤1.5; absence of 2,1 propylene insertions and tensile strength at break higher than 4 Mpa.
摘要翻译：丙烯 - 乙烯共聚物是柔性的，并且在齐格勒 - 纳塔催化剂存在下通过溶液聚合获得在其粗态下的柔软性和机械性能之间的非常好的平衡。所述共聚物包含10至50重量％的乙烯，其特征在于：共聚单体反应性比r1 r2 = 1.5的产物; 没有2,1丙烯插入和断裂拉伸强度高于4 Mpa。

2. 发明申请

WO2006042815A1 BUTENE-1 (CO)POLYMERS HAVING LOW ISOTACTICITY 审中-公开
标题翻译：具有低等密度的BUTENE-1（CO）聚合物
公开(公告)号：WO2006042815A1
公开(公告)日：2006-04-27
申请号：PCT/EP2005/055180
申请日：2005-10-12
申请人： BASELL POLIOLEFINE ITALIA S.R.L. , BACCI, Dino , MORHARD, Friederike , PIEMONTESI, Fabrizio , TONTI, Maria Silvia , VITALE, Gianni , MORINI, Giampiero , PELLICONI, Anteo
发明人： BACCI, Dino , MORHARD, Friederike , PIEMONTESI, Fabrizio , TONTI, Maria Silvia , VITALE, Gianni , MORINI, Giampiero , PELLICONI, Anteo
IPC分类号： C08F10/08 , C08L23/18
CPC分类号： C08F10/08 , C08F110/08 , C08F210/08 , C08F2500/17 , C08F2500/20 , C08F2500/15 , C08F210/14 , C08F210/16 , C08F210/06
摘要： Butene-1 (co)polymers characterized by the following properties: content of butene-1 units in the form of isotactic pentads (mmmm) from 25 to 55%; intrinsic viscosity [η] measured in tetraline at 135°C from 1 to 3dL/g; content of xylene insoluble fraction at 0°C from 3 to 60%; and a ratio ES 2 /ES 1 ≥1, where ES 1 is the boiling diethyl ether soluble fraction determined on the polymer as such and ES 2 is the boiling diethyl ether soluble fraction determined after milling the polymer. The butene-1 (co)polymers show a good balance between processability and elastomeric behavior.
摘要翻译：丁烯-1（共）聚合物，其特征在于以下性质：全同立构五单元形式的丁烯-1单元的含量（mmmm）为25至55％; 在135℃的四氢萘中测定的特性粘度[η]为1〜3dL / g; 0℃下二甲苯不溶部分含量为3〜60％; 和ES 2的比例ES 2其中ES 1是在聚合物上测定的沸腾二乙醚可溶级分，ES是ES 沸点二乙醚可溶级分是在研磨聚合物之后测定的。丁烯-1（共）聚合物在加工性和弹性体性能之间显示出良好的平衡。

3. 发明申请

WO2010118962A1 PROCESS FOR THE PREPARATION OF POLYMER OF 1-BUTENE 审中-公开
标题翻译：制备1-BOTENE聚合物的方法
公开(公告)号：WO2010118962A1
公开(公告)日：2010-10-21
申请号：PCT/EP2010/054356
申请日：2010-03-31
申请人： BASELL POLIOLEFINE ITALIA S.R.L. , VITALE, Gianni , PIEMONTESI, Fabrizio , MINGOZZI, Ines , CAMURATI, Isabella, Maria, Vittoria , PELLEGATTI, Giampaolo
发明人： VITALE, Gianni , PIEMONTESI, Fabrizio , MINGOZZI, Ines , CAMURATI, Isabella, Maria, Vittoria , PELLEGATTI, Giampaolo
IPC分类号： C08F10/08 , C08F4/649 , C08F4/654
CPC分类号： C08F10/08 , C08F110/08 , C08F210/08 , C08F4/6494 , C08F2500/03 , C08F2500/15 , C08F2500/17 , C08F210/06 , C08F210/16
摘要： A process for the preparation of 1-butene homopolymers or 1-butene/alpha olefin copolymers wherein the alpha olefins are selected from ethylene, propylene or alpha olefins of formula CH 2 =CHZ wherein Z is a C 3 -C 20 alkyl radical, comprising contacting 1-butene or 1-butene and one or more alpha olefins under polymerization conditions in the presence of a catalyst system comprising: (a) a solid component comprising a Ti compound and an internal electron-donor compound supported on MgCl 2 (b) an alkylaluminum co catalyst; and (c) a compound of formula (I) as external donor Wherein: R 1 , R 2 , R 3 and R 4 , equal to or different from each other, are hydrogen atoms or C 1 -C 20 hydrocarbon radicals optionally containing heteroatoms belonging to groups 13-17 of the Periodic Table of the Elements; or two R 1 , R 2 , R 3 and R 4 can be joined to form a C 5 -C 20 , saturated or unsaturated ring.
摘要翻译：一种制备1-丁烯均聚物或1-丁烯/α-烯烃共聚物的方法，其中α-烯烃选自式CH 2 = CHZ的乙烯，丙烯或α-烯烃，其中Z为C 3 -C 20烷基，其包括使1- 丁烯或1-丁烯和一种或多种α-烯烃在催化剂体系存在下在聚合条件下，包括：（a）固体组分，其包含Ti化合物和负载在MgCl 2上的内部电子给体化合物（b）烷基铝助催化剂 ; 和（c）作为外部给体的式（I）化合物，其中R1，R2，R3和R4彼此相同或不同，是氢原子或任选含有属于第13-17族的杂原子的C 1 -C 20烃基的元素周期表; 或两个R 1，R 2，R 3和R 4可以连接形成C 5 -C 20饱和或不饱和环。

4. 发明申请

WO2008017525A1 BUTENE-1 COPOLYMERS 审中-公开
标题翻译： BUTENE-1共聚物
公开(公告)号：WO2008017525A1
公开(公告)日：2008-02-14
申请号：PCT/EP2007/054798
申请日：2007-05-17
申请人： Basell Poliolefine Italia s.r.l. , PELLEGATTI, Giampaolo , SPATARO, Stefano , PIEMONTESI, Fabrizio , VITALE, Gianni
发明人： PELLEGATTI, Giampaolo , SPATARO, Stefano , PIEMONTESI, Fabrizio , VITALE, Gianni
IPC分类号： C08F210/08 , C08F210/12
CPC分类号： C08F210/08 , C08F210/16 , C08F210/06 , C08F2500/03 , C08F2500/21 , C08F2500/12 , C08F210/14
摘要： Butene-1 copolymers containing: a) from 1 to 7 % by mole of ethylene derived units, and b) from 3 to 20 % by mole of units derived from one or more alpha-olefin(s) having general formula H 2 C=CHR, wherein R is methyl or a linear or branched alkyl radical C3-C8; said copolymers having a molecular weight distribution with a ratio (I) of less than or equal to 4 and a (b)/(a) molar ratio of more than or equal to 2.3.
摘要翻译：丁烯-1共聚物，其含有：a）1至7摩尔％的乙烯衍生单元，和b）3至20摩尔％的衍生自一种或多种具有通式H的α-烯烃的单元， 2 C = CHR，其中R是甲基或直链或支链烷基C3-C8; 所述共聚物具有小于或等于4的比率（I）和（b）/（a）摩尔比大于或等于2.3的分子量分布。

5. 发明申请

WO2011061134A1 PROCESS FOR THE PREPARATION OF IMPACT RESISTANT PROPYLENE POLYMER COMPOSITIONS 审中-公开
标题翻译：制备抗冲击丙烯聚合物组合物的方法
公开(公告)号：WO2011061134A1
公开(公告)日：2011-05-26
申请号：PCT/EP2010/067434
申请日：2010-11-15
申请人： Basell Poliolefine Italia S.r.l. , COLLINA, Gianni , CIARAFONI, Marco , FUSCO, Ofelia , GADDI, Benedetta , GALVAN, Monica , MORINI, Giampiero , PANTALEONI, Roberto , PATER, Joachim T.M. , PIEMONTESI, Fabrizio , VERROCCHIO, Francesca
发明人： COLLINA, Gianni , CIARAFONI, Marco , FUSCO, Ofelia , GADDI, Benedetta , GALVAN, Monica , MORINI, Giampiero , PANTALEONI, Roberto , PATER, Joachim T.M. , PIEMONTESI, Fabrizio , VERROCCHIO, Francesca
IPC分类号： C08F10/06
CPC分类号： C08F10/06 , C08F110/06 , C08F210/06 , C08F210/16 , C08F2/001 , C08F4/6494 , C08F4/651 , C08F2500/12 , C08F2500/15 , C08F2500/05
摘要： A process for the preparation of propylene polymer compositions comprising from 50 to 90% by weight of a propylene polymer fraction insoluble in xylene at 25°C, and from 10 to 50% by weight of an ethylene copolymer fraction soluble in xylene at 25°C, said process being carried out in the presence of a specific catalyst system, is also characterized by the following step: (i) contacting the catalyst components (a), (b) and optionally (c) for a period of time ranging from 0.1 to 120 minutes, at a temperature ranging from 0 to 90°C; (ii) polymerizing propylene in the optional presence of ethylene and/or C 4 -C 10 alpha olefins producing a propylene (co)polymer being for at least 85% by weight of insoluble in xylene at 25°C and (iii) in a successive step, carried out in gas-phase, in the presence of the product coming from (ii), polymerizing mixtures of ethylene with α-olefins CH 2 =CHR in which R is a hydrocarbon radical having 1-10 carbon atoms, to produce an ethylene copolymer. An increased reactivity in the last step is observed.
摘要翻译：一种制备丙烯聚合物组合物的方法，其包含50至90重量％的在25℃下不溶于二甲苯的丙烯聚合物级分和10至50重量％在25℃下可溶于二甲苯的乙烯共聚物部分所述方法在特定催化剂体系的存在下进行，其特征还在于以下步骤：（i）使催化剂组分（a），（b）和任选地（c）接触一段时间为0.1 至120分钟，温度范围为0至90℃; （ii）在乙烯和/或C 4 -C 10α-烯烃的任选存在下聚合丙烯，产生丙烯（共）聚合物，其在25℃下为不溶于二甲苯的至少85重量％，和（iii）在连续步骤在（ii）产物存在下进行，在乙烯与α-烯烃CH2 = CHR的混合物中聚合，其中R是具有1-10个碳原子的烃基，以产生乙烯共聚物。观察到在最后步骤中增加的反应性。

6. 发明申请

WO2012139897A1 CATALYST COMPONENTS FOR THE POLYMERIZATION OF OLEFINS 审中-公开
标题翻译：用于烯烃聚合的催化组分
公开(公告)号：WO2012139897A1
公开(公告)日：2012-10-18
申请号：PCT/EP2012/055593
申请日：2012-03-29
申请人： BASELL POLIOLEFINE ITALIA S.R.L. , GUIDOTTI, Simona , MORINI, Giampiero , ESPOSITO, Simona , MIGNOGNA, Alessandro , PATER, Joachim T. M. , PIEMONTESI, Fabrizio , BRITA, Diego
发明人： GUIDOTTI, Simona , MORINI, Giampiero , ESPOSITO, Simona , MIGNOGNA, Alessandro , PATER, Joachim T. M. , PIEMONTESI, Fabrizio , BRITA, Diego
IPC分类号： C08F10/06 , C08F4/651
CPC分类号： C08F4/16 , C08F10/06 , C08F4/651 , C08F110/06 , C08F2500/12 , C08F2500/15 , C08F2500/02 , C08F210/06 , C08F2/001
摘要： A porous solidcatalyst component comprising a magnesium halide, a titanium compound having at least a Ti-halogen bond and at least two electron donor compounds one of which being selected from 1,3-diethers and the other being selected from succinates, characterized by the fact that the molar ratio ID/Ti is from 0.30 to 0.90, where ID is the total molar amount of succinate and 1,3-diether, the molar ratio of the 1,3-diether donor tothe succinate donor is higher than, or equal to, 0.60.
摘要翻译：一种多孔固体催化剂组分，其包含卤化镁，至少具有Ti-卤素键的钛化合物和至少两种电子给体化合物，其中一种选自1,3-二醚，另一种选自琥珀酸盐，其特征在于： ID / Ti的摩尔比为0.30〜0.90，其中ID是琥珀酸盐和1,3-二醚的总摩尔量，1,3-二醚供体与琥珀酸盐供体的摩尔比高于或等于，0.60。

7. 发明申请

WO2011006776A1 PROCESS FOR THE PREPARATION OF POLYMER OF 1-BUTENE 审中-公开
标题翻译：制备1-BOTENE聚合物的方法
公开(公告)号：WO2011006776A1
公开(公告)日：2011-01-20
申请号：PCT/EP2010/059440
申请日：2010-07-02
申请人： Basell Poliolefine Italia s.r.l. , VITALE, Gianni , PIEMONTESI, Fabrizio , MINGOZZI, Ines , CAMURATI, Isabella Maria Vittoria
发明人： VITALE, Gianni , PIEMONTESI, Fabrizio , MINGOZZI, Ines , CAMURATI, Isabella Maria Vittoria
IPC分类号： C08F210/08 , C08F4/649 , C08F4/651
CPC分类号： C08F210/08 , C08F10/08 , C08F110/08 , C08F4/651 , C08F4/6494 , C08F2500/15 , C08F2500/17 , C08F210/06
摘要： A process for the preparation of 1-butene homopolymers or 1-butene/alpha olefin copolymers wherein the alpha olefins are selected from ethylene, propylene or alpha olefins of formula CH 2 =CHZ wherein Z is a C 3 -C 20 alkyl radical, comprising contacting 1-butene or 1-butene and one or more alpha olefins under polymerization conditions in the presence of a catalyst system comprising: (a) a solid component comprising a Ti compound and an internal electron-donor compound supported on MgCl 2 (b) an alkylaluminum cocatalyst; and (c) a compound of formula (I) as external donor wherein R 1 , R 2 , R 3 , R 4 and R 5 hydrogen atoms or C 1 -C 20 hydrocarbon radicals, or two R 1 , R 2 , R 3 and R 4 can be joined to form a C 5 -C 20 , saturated or unsaturated, ring.
摘要翻译：一种制备1-丁烯均聚物或1-丁烯/α-烯烃共聚物的方法，其中α-烯烃选自式CH 2 = CHZ的乙烯，丙烯或α-烯烃，其中Z为C 3 -C 20烷基，其包括使1- 丁烯或1-丁烯和一种或多种α-烯烃在催化剂体系存在下在聚合条件下，包括：（a）固体组分，其包含Ti化合物和负载在MgCl 2（b）烷基铝助催化剂上的内电子给体化合物; 和（c）作为外给体的式（I）化合物，其中R1，R2，R3，R4和R5的氢原子或C1-C20烃基，或者两个R1，R2，R3和R4可以连接形成C5- C20，饱和或不饱和的环。

8. 发明申请

WO2010026184A1 CATALYSTS FOR POLYMERIZING OLEFINS AND METHOD THEREOF 审中-公开
标题翻译：用于聚合烯烃的催化剂及其方法
公开(公告)号：WO2010026184A1
公开(公告)日：2010-03-11
申请号：PCT/EP2009/061394
申请日：2009-09-03
申请人： BASELL POLIOLEFINE ITALIA S.R.L. , GULEVICH, Yuri , PIEMONTESI, Fabrizio , GADDI, Benedetta , GUIDOTTI, Simona , NIFANT'EV, Ilya E. , LYUBIMTSEV, Andrey
发明人： GULEVICH, Yuri , PIEMONTESI, Fabrizio , GADDI, Benedetta , GUIDOTTI, Simona , NIFANT'EV, Ilya E. , LYUBIMTSEV, Andrey
IPC分类号： C08F10/00 , C08F4/651 , C08F4/649
CPC分类号： C08F10/00 , C08F110/06 , C08F4/651 , C08F4/6496 , C08F2500/12 , C08F2500/18
摘要： A solid catalyst component for polymerizing at least one olefin comprising Mg, Ti, at least one halogen, and at least one electron donor selected from arylsulfonates and arylsulfonyl derivatives of a specified formula. The solid catalyst component is able to give in high yields polyolefins with high stereoregularity.
摘要翻译：用于聚合包含Mg，Ti，至少一种卤素和至少一种选自具有规定式的芳基磺酸盐和芳基磺酰基衍生物的至少一种电子给体的至少一种烯烃的固体催化剂组分。固体催化剂组分能够以高收率产生具有高立构规整性的聚烯烃。

9. 发明申请

WO2005095472A1 MAGNESIUM CHLORIDE-BASED ADDUCTS AND CATALYST COMPONENTS OBTAINED THEREFROM 审中-公开
标题翻译：基于氯化镁的添加剂和由其获得的催化剂组分
公开(公告)号：WO2005095472A1
公开(公告)日：2005-10-13
申请号：PCT/EP2005/002371
申请日：2005-03-03
申请人： BASELL POLIOLEFINE ITALIA S.P.A. , GULEVICH, Yuri , CAMURATI, Isabella , CRISTOFORI, Antonio , DALL'OCCO, Tiziano , MORINI, Giampiero , PIEMONTESI, Fabrizio , VITALE, Gianni
发明人： GULEVICH, Yuri , CAMURATI, Isabella , CRISTOFORI, Antonio , DALL'OCCO, Tiziano , MORINI, Giampiero , PIEMONTESI, Fabrizio , VITALE, Gianni
IPC分类号： C08F110/06
CPC分类号： C07F3/003 , C07F7/006 , C08F110/06 , C08F4/651 , C08F4/6543 , C08F2500/15 , C08F2500/12 , C08F2500/17
摘要： Lewis base adducts comprising MgCl n (OR) 2-n , and an aprotic Lewis base that are in molar ratios to each other defined by the formula: MgCl n (OR) 2-n LB p in which n is from 0.1 to 1.9, p is higher than 0.4, and R is a C1-C15 hydrocarbon group. The adducts of the present invention are particularly useful as precursors of Ziegler-Natta catalyst components for the polymerization of olefins.
摘要翻译：包含MgCln（OR）2-n和非质子路易斯碱的路易斯碱加成物，其彼此的摩尔比以下式定义：MgCln（OR）2-nLBp，其中n为0.1至1.9，p高于 0.4，R为C1-C15烃基。本发明的加合物特别可用作烯烃聚合的齐格勒 - 纳塔催化剂组分的前体。

10. 发明申请

WO2003055831A1 SEPARATION OF DIASTEREOISOMERS 审中-公开
标题翻译：分离器
公开(公告)号：WO2003055831A1
公开(公告)日：2003-07-10
申请号：PCT/EP2002/014875
申请日：2002-12-20
申请人： BASELL POLIOLEFINE ITALIA S.P.A. , MORINI, Giampiero , PIEMONTESI, Fabrizio , CRISTOFORI, Antonio , MILANI, Stefania
发明人： MORINI, Giampiero , PIEMONTESI, Fabrizio , CRISTOFORI, Antonio , MILANI, Stefania
IPC分类号： C07B57/00
CPC分类号： C07B57/00
摘要： Process for modifying the relative ratios of the components of a liquid starting mixture of specific diastereoisomers, containing at least two asymmetric carbon atoms comprising contacting said liquid mixture with a Lewis acid compound capable of co-ordinating said specific diastereoisomers and subjecting the resulting mixture to conditions such that a reaction product, having a molar ratio between its diastereoisomeric components different from the corresponding molar ratio in the said liquid starting mixture, becomes separated from the said liquid mixture, said process being carried out using an amount of said Lewis acid not enough to co-ordinate the total amount of the diastereoisomeric components of the liquid starting mixture. This method shows an excellent balance of efficiency and easiness of procedure that cannot be reached with the physical methods of diastereoisomers separation known in the art.
摘要翻译：用于改变含有至少两个不对称碳原子的特定非对映异构体的液体起始混合物的组分的相对比例的方法，包括使所述液体混合物与能够协调所述特定非对映异构体的路易斯酸化合物接触，并将所得混合物进行条件使得具有与所述液体起始混合物中的相应摩尔比不同的非对映异构体的摩尔比的反应产物与所述液体混合物分离，所述方法使用一定量的所述路易斯酸进行，所述量不足以统计液体起始混合物的非对映异构体组分的总量。该方法显示出与本领域已知的非对映异构体分离的物理方法无法达到的效率和操作简单性的极好平衡。

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