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1. 发明申请

WO2012139897A1 CATALYST COMPONENTS FOR THE POLYMERIZATION OF OLEFINS 审中-公开
标题翻译：用于烯烃聚合的催化组分
公开(公告)号：WO2012139897A1
公开(公告)日：2012-10-18
申请号：PCT/EP2012/055593
申请日：2012-03-29
申请人： BASELL POLIOLEFINE ITALIA S.R.L. , GUIDOTTI, Simona , MORINI, Giampiero , ESPOSITO, Simona , MIGNOGNA, Alessandro , PATER, Joachim T. M. , PIEMONTESI, Fabrizio , BRITA, Diego
发明人： GUIDOTTI, Simona , MORINI, Giampiero , ESPOSITO, Simona , MIGNOGNA, Alessandro , PATER, Joachim T. M. , PIEMONTESI, Fabrizio , BRITA, Diego
IPC分类号： C08F10/06 , C08F4/651
CPC分类号： C08F4/16 , C08F10/06 , C08F4/651 , C08F110/06 , C08F2500/12 , C08F2500/15 , C08F2500/02 , C08F210/06 , C08F2/001
摘要： A porous solidcatalyst component comprising a magnesium halide, a titanium compound having at least a Ti-halogen bond and at least two electron donor compounds one of which being selected from 1,3-diethers and the other being selected from succinates, characterized by the fact that the molar ratio ID/Ti is from 0.30 to 0.90, where ID is the total molar amount of succinate and 1,3-diether, the molar ratio of the 1,3-diether donor tothe succinate donor is higher than, or equal to, 0.60.
摘要翻译：一种多孔固体催化剂组分，其包含卤化镁，至少具有Ti-卤素键的钛化合物和至少两种电子给体化合物，其中一种选自1,3-二醚，另一种选自琥珀酸盐，其特征在于： ID / Ti的摩尔比为0.30〜0.90，其中ID是琥珀酸盐和1,3-二醚的总摩尔量，1,3-二醚供体与琥珀酸盐供体的摩尔比高于或等于，0.60。

2. 发明申请

WO2010012587A1 ETHYLENE POLYMERS 审中-公开
标题翻译：乙烯聚合物
公开(公告)号：WO2010012587A1
公开(公告)日：2010-02-04
申请号：PCT/EP2009/058993
申请日：2009-07-14
申请人： BASELL POLYOLEFINE ITALIA S.R.L. , BALBONI, Davide , ESPOSITO, Simona , MORINI, Giampiero , PIEMONTESI, Fabrizio
发明人： BALBONI, Davide , ESPOSITO, Simona , MORINI, Giampiero , PIEMONTESI, Fabrizio
IPC分类号： C08F210/18 , C08F4/6592
CPC分类号： C08F210/02 , C08F4/65912 , C08F210/18 , C08F4/65927 , C08F210/06 , C08F236/20 , C08F2500/25 , C08F2500/17
摘要： A process for copolymerizing ethylene, one or more non-conjugated cyclic diene and optionally one or more alpha olefins of formula CH 2 =CHT wherein T is a C 1 -C 20 alkyl radical comprising the step of contacting the monomers under polymerization conditions in the presence of a catalyst system comprising a metallocene compound of formula (I) wherein: M is titanium zirconium or hafnium; X, is a hydrogen atom, a halogen atom, a R, OR, OR'O, OSO 2 CF 3 , OCOR, SR, NR 2 or PR 2 group wherein R is an hydrocarbon radical and R' is a C 1 -C 20 -alkylidene, C 6 -C 20 -arylidene, C 7 -C 20 -alkylarylidene, or C 7 -C 20 -arylalkylidene radical; R 1 , is a C 1 -C 20 -alkyl radical; R 2 , R 3 , R 4 , R 5 , R 6 and R 7 are hydrogen atoms, or C 1 -C 20 hydrocarbon radicals or two or more R 2 , R 3 , R 4 , and R 5 can also be joined to form a C 3 -C 10 ring; L is a divalent C 1 -C 40 hydrocarbon radical.
摘要翻译：共聚乙烯，一种或多种非共轭环状二烯和任选一种或多种式CH 2 = CHT的α-烯烃的方法，其中T是C 1 -C 20烷基，其包括在聚合条件下，在催化剂体系包含式（I）的茂金属化合物，其中：M是钛锆或铪; X，是氢原子，卤素原子，R，OR，OR'O，OSO 2 CF 3，OCOR，SR，NR 2或PR 2基团，其中R是烃基，R'是C 1 -C 20亚烷基，C 6 -C 20 亚芳基，C 7 -C 20 - 亚烷基亚芳基或C 7 -C 20 - 芳基亚烷基; R1是C1-C20烷基; R2，R3，R4，R5，R6和R7是氢原子，或C1-C20烃基或两个或更多个R2，R3，R4和R5也可以连接形成C 3 -C 10环; L是二价C1-C40烃基。

3. 发明申请

WO2009115402A1 1-BUTENE TERPOLYMERS 审中-公开
标题翻译： 1-BOTENE TERPOLYMERS
公开(公告)号：WO2009115402A1
公开(公告)日：2009-09-24
申请号：PCT/EP2009/052364
申请日：2009-02-27
申请人： BASELL POLIOLEFINE ITALIA S.R.L. , RESCONI, Luigi , BALBONI, Davide , ESPOSITO, Simona
发明人： RESCONI, Luigi , BALBONI, Davide , ESPOSITO, Simona
IPC分类号： C08F210/08 , C08F210/14 , C08F210/16
CPC分类号： C08F210/16 , C08F4/65912 , C08F210/08 , C08F210/14 , C08F2420/05 , C08F4/65927 , C08F2500/15 , C08F2500/17 , C08F2500/20
摘要： A terpolymer of 1-butene, ethylene and a at least a C 8 -C 12 alpha-olefin derived units, containing from 0.1 % to 5 % by mole of ethylene derived units and from 1 from 20% by mol of C 8 -C 12 alpha-olefin derived units, endowed with the following properties : i) isotactic pentad mmmm higher than or equal to 90%; pentads (mmrr+mrrm) lower than 4 and pentad rmmr not detectable by 13 C NMR. ii) intrinsic viscosity (IV) measured in tetrahydronaphthalene at 135°C comprised between 0.8 and 5.0 dL/g; iii) the melting point measured by DSC (TmI) and the C 8 -C 12 alpha-olefin content fulfil the following relationship: TmI -0.3 wherein C is the molar content of C 8 -C 12 alpha-olefin derived units and TmI is the highest melting peak in the first melting transition measured by DSC otherwise the melting point TmI is not detectable.
摘要翻译： 1-丁烯，乙烯和至少一种C 8 -C 12α-烯烃衍生单元的三元共聚物，其含有0.1％至5％（摩尔）的乙烯衍生单元，和1％为20％（摩尔）的C 8 -C 12α-烯烃具有以下性质：i）等于或等于90％的全同立构五单元mmmm; 低于4的五元组（mmrr + mrrm）和13C NMR不能检测到的五元组。 ii）在135℃的四氢化萘中测得的特性粘度（Ⅳ）为0.8至5.0dL / g; iii）通过DSC（TmI）和C8-C12α-烯烃含量测量的熔点满足以下关系：TmI -0.3其中C是C8-C12α-烯烃衍生单元的摩尔含量，TmI是最高的熔融峰在通过DSC测量的第一熔融转变中，不能检测到熔点Tm1。

4. 发明申请

WO2010009955A1 1-BUTENE COPOLYMERS 审中-公开
标题翻译： 1-BOTENE共聚物
公开(公告)号：WO2010009955A1
公开(公告)日：2010-01-28
申请号：PCT/EP2009/058108
申请日：2009-06-29
申请人： BASELL POLIOLEFINE ITALIA S.R.L. , RESCONI, Luigi , BALBONI, Davide , MOSCARDI, Gilberto , ESPOSITO, Simona
发明人： RESCONI, Luigi , BALBONI, Davide , MOSCARDI, Gilberto , ESPOSITO, Simona
IPC分类号： C08F210/08 , C08F4/6592
CPC分类号： C08F210/08 , C08F4/65912 , C08F4/65927 , C08F2420/05 , C08F210/14 , C08F2500/15 , C08F2500/17 , C08F2500/20
摘要： A crosslinked copolymer of 1-butene and 1-octene or 1-decene; containing from 3.0% to 20.0% by mole of 1-octene or 1-decene derived units;
摘要翻译： 1-丁烯和1-辛烯或1-癸烯的交联共聚物; 含有3.0％至20.0％摩尔的1-辛烯或1-癸烯衍生的单元;

5. 发明申请

WO2011061151A1 ETHYLENE COPOLYMERS 审中-公开
标题翻译：乙烯共聚物
公开(公告)号：WO2011061151A1
公开(公告)日：2011-05-26
申请号：PCT/EP2010/067490
申请日：2010-11-15
申请人： BASELL POLYOLEFINE GMBH , PIEMONTESI, Fabrizio , ESPOSITO, Simona
发明人： PIEMONTESI, Fabrizio , ESPOSITO, Simona
IPC分类号： C08F210/02
CPC分类号： C08F210/02 , C08F4/65912 , C08F10/00 , C08F210/18 , C08F210/06 , C08F236/20 , C08F2500/17 , C08F2500/25 , C08F4/65927
摘要： A process for copolymerizing ethylene, comprising the step of contacting ethylene, one or more non-conjugated cyclic diene and optionally one or more alpha olefins of formula CH 2 =CHT wherein T is a C 1 -C 20 alkyl radical under polymerization conditions in the presence of a catalyst system obtainable by contacting: A) a metallocene compound of formula (I) wherein: M is titanium zirconium or hafnium; X, equal to or different from each other, is a hydrogen atom, a halogen atom, a hidrocabon group optionally containing heteroatoms belonging to groups 13-17 of the Periodic Table of the Elements; R 1 are C 1 -C 40 hydrocarbon radical; R 2 , and R 5 are hydrogen atoms, or C 1 -C 20 hydrocarbon radicals; R6, equal to or different from each other, are C1-C20 hydrocarbon radicals; R 3 and R 4 , form together a condensed saturated or unsaturaded C 3 -C 7 -membered ring; B) an alumoxane or a compound capable of forming an alkyl metallocene cation; and optionally (C) an organo aluminum compound.
摘要翻译：一种使乙烯共聚的方法，其包括使乙烯，一种或多种非共轭环状二烯和任选的一种或多种式CH 2 = CHT的α-烯烃接触的步骤，其中T是C1-C20烷基，在聚合条件下，在催化剂体系可通过以下方式获得：A）式（I）的茂金属化合物，其中：M是钛锆或铪; X为相同或不同的氢原子，卤素原子，任选含有元素周期表第13-17族杂原子的吡啶酮基; R1是C1-C40烃基; R2和R5是氢原子或C1-C20烃基; R6相同或不同，为C1-C20烃基; R3和R4一起形成饱和或不饱和的C3-C7-元环; B）铝氧烷或能够形成烷基茂金属阳离子的化合物; 和（C）有机铝化合物。

6. 发明申请

WO2009000637A1 1-BUTENE ETHYLENE COPOLYMERS 审中-公开
标题翻译： 1-BOTENE乙烯共聚物
公开(公告)号：WO2009000637A1
公开(公告)日：2008-12-31
申请号：PCT/EP2008/057180
申请日：2008-06-09
申请人： BASELL POLYOLEFINE GMBH , PELLEGATTI, Giampaolo , SPATARO, Stefano , MARCHINI, Roberta , GUIDOTTI, Simona , ESPOSITO, Simona
发明人： PELLEGATTI, Giampaolo , SPATARO, Stefano , MARCHINI, Roberta , GUIDOTTI, Simona , ESPOSITO, Simona
IPC分类号： C08F210/08
CPC分类号： C08F210/08 , C08F4/65912 , C08F210/16 , C08F4/65927 , C08F2500/03 , C08F2500/11 , C08F2500/20
摘要： A 1-butene ethylene copolymer having an ethylene derived units content ranging from 15.10 % by molto 18.00 % by mol having the following properties: a) distribution of molecular weight lower than 3; preferably b) hardness shore A (measured according to ISO 868) lower than 65; c) tension set lower than 30% at 100% of deformation (ISO 2285) d) no melting pointdetectable at the DSC; e) Melting enthalpy measured after 10 days of aging at room temperature comprised between 4 and 15 J/g.
摘要翻译：乙烯衍生单元含量范围为15.10摩尔％至18.00摩尔％的1-丁烯乙烯共聚物具有以下特性：a）低于3的分子量分布; 优选b）硬度岸A（根据ISO 868测量）低于65; c）100％变形时张力设定低于30％（ISO 2285）d）在DSC下无法检测到熔点; e）在室温下老化10天后测量的熔融焓在4至15J / g之间。

7. 发明申请

WO2013182474A1 CATALYST COMPONENTS FOR THE POLYMERIZATION OF BUTENE-1 审中-公开
标题翻译：催化剂组分对于BUTENE-1的聚合
公开(公告)号：WO2013182474A1
公开(公告)日：2013-12-12
申请号：PCT/EP2013/061158
申请日：2013-05-30
申请人： BASELL POLIOLEFINE ITALIA S.R.L.
发明人： MIGNOGNA, Alessandro , ESPOSITO, Simona , GUIDOTTI, Simona , MORINI, Giampiero , PATER, Joachim T. M. , PIEMONTESI, Fabrizio , VITALE, Gianni
IPC分类号： C08F110/08 , C08F4/651
CPC分类号： C08F4/52 , C08F4/10 , C08F4/16 , C08F110/08 , C08F4/651 , C08F2500/15 , C08F2500/17 , C08F110/06 , C08F2500/12
摘要： Process for the polymerization of butene-1 carried out in the presence of a catalyst comprising (a) a solid catalyst component comprising Mg, Ti and an electron donor compound of the following formula (I), In which the R groups equal to or different from each other, are C 1 -C 15 hydrocarbon groups, the R 1 -R 2 groups, equal to or different from each other, are hydrogen, halogen or C 1 -C 15 hydrocarbon groups, optionally containing an heteroatom selected from halogen, P, S, N and Si, n and m are integer from 0 to 3 with the proviso that at least one of them is different from 0; (b) An aluminium alkyl cocatalyst and (c) an external electron donor
摘要翻译：在催化剂存在下进行的丁烯-1的聚合方法，包括（a）包含Mg，Ti和下式（I）的电子给体化合物的固体催化剂组分，其中R基团等于或不同彼此相同的是C 1 -C 15烃基，R 1 -R 2基彼此相同或不同，是氢，卤素或C 1 -C 15烃基，任选地含有选自卤素，P，S，N的杂原子和 Si，n和m为0-3的整数，条件是它们中的至少一个不同于0; （b）烷基铝助催化剂和（c）外电子给体

8. 发明申请

WO2013057036A1 CATALYST COMPONENTS FOR THE POLYMERIZATION OF OLEFINS 审中-公开
标题翻译：用于烯烃聚合的催化组分
公开(公告)号：WO2013057036A1
公开(公告)日：2013-04-25
申请号：PCT/EP2012/070136
申请日：2012-10-11
申请人： BASELL POLIOLEFINE ITALIA S.R.L.
发明人： NIFANT'EV, Ilya , MIGNOGNA, Alessandro , BAGROV, Vladimir , ESPOSITO, Simona , GUIDOTTI, Simona , MORINI, Giampiero , PATER, Joachim T. M. , PIEMONTESI, Fabrizio , TOLORAYA, Sophia A.
IPC分类号： C08F4/651 , C08F10/00 , C08F4/654
CPC分类号： C08F4/6498 , C08F10/00 , C08F4/6543 , C08F4/651
摘要： Catalyst component for the polymerization of olefins comprising Mg, Ti and an electron donor compound of the following formula (I) In which R to R 12 groups, equal to or different from each other, are hydrogen, halogen or C 1 -C 15 hydrocarbon groups, optionally containing an heteroatom selected from halogen, P, S, N and Si, with the proviso that R groups cannot be hydrogen and that the carboxylate groups are in trans configuration with respect to each other.
摘要翻译：用于包含Mg，Ti和下式（I）的电子给体化合物的烯烃聚合的催化剂组分其中R至R12基团彼此相同或不同的是氢，卤素或C 1 -C 15烃基，任选地含有选自卤素，P，S，N和Si的杂原子，条件是R基团不能是氢，并且羧酸酯基团相对于反式构型。

9. 发明申请

WO2014111381A1 CATALYST COMPONENTS FOR THE POLYMERIZATION OF OLEFINS 审中-公开
标题翻译：用于烯烃聚合的催化组分
公开(公告)号：WO2014111381A1
公开(公告)日：2014-07-24
申请号：PCT/EP2014/050606
申请日：2014-01-14
申请人： BASELL POLIOLEFINE ITALIA S.R.L.
发明人： VITALE, Gianni , ESPOSITO, Simona , GUIDOTTI, Simona , MIGNOGNA, Alessandro , MORINI, Giampiero , PIEMONTESI, Fabrizio
IPC分类号： C08F110/08 , C08F4/651 , C08F10/08
CPC分类号： C08F10/08 , C08F110/08 , C08F4/651 , C08F4/6555 , C08F4/6565 , C08F4/6567 , C08F110/06 , C08F2500/12 , C08F2500/15 , C08F2500/17
摘要： A liquid phase process for the polymerization of butene-1 carried out in the presence of a catalyst comprising (a) a solid catalyst component comprising Mg, Ti and an electron donor compound of the following formula (I) in which the R groups, equal to or different from each other, are C 1 -C 10 hydrocarbon groups; (b) an aluminium alkyl cocatalyst and (c) an external electron donor.
摘要翻译：在催化剂存在下进行丁烯-1聚合的液相方法，包括（a）包含Mg，Ti的固体催化剂组分和下式（I）的电子给体化合物，其中R基团相等彼此是或不同的是C 1 -C 10烃基; （b）烷基铝助催化剂和（c）外电子给体。

10. 发明申请

WO2014048964A1 CATALYST COMPONENTS FOR THE POLYMERIZATION OF OLEFINS AND CATALYSTS THEREFROM OBTAINED 审中-公开
标题翻译：用于获得烯烃和催化剂聚合的催化剂组分
公开(公告)号：WO2014048964A1
公开(公告)日：2014-04-03
申请号：PCT/EP2013/069927
申请日：2013-09-25
申请人： BASELL POLIOLEFINE ITALIA S.R.L.
发明人： GUIDOTTI, Simona , ESPOSITO, Simona , LIGUORI, Dario , MORINI, Giampiero , PIEMONTESI, Fabrizio , VITALE, Gianni
IPC分类号： C08F10/06 , C08F4/657 , C08F4/651
CPC分类号： C08F10/06 , C08F4/6574 , C08F4/651 , C08F110/02 , C08F2500/18 , C08F2500/21 , C08F110/06 , C08F210/06 , C08F210/16
摘要： Catalyst components component for the (co)polymerization of olefins CH 2 =CHR, in which R is a hydrocarbyl radical with 1-12 carbon atoms, optionally in mixture with ethylene, comprising Ti, Mg, Zn, CI, and an electron donor compound characterized by the fact that more than 50% of the titanium atoms are in the +4 valence state, and that the amount of Zn ranges from 0.1 to 4% by weight based on then total weight of said solid catalyst component.
摘要翻译：用于（共）聚合烯烃CH 2 = CHR的催化剂组分组分，其中R是具有1-12个碳原子的烃基，任选与乙烯混合，包括Ti，Mg，Zn，Cl和电子给体化合物，其特征在于由于超过50％的钛原子处于+4价态，并且Zn的量基于所述固体催化剂组分的总重量为0.1至4重量％。

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