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1. 发明授权

US4310705A Preparation of higher unsaturated ketones 失效
标题翻译：制备较高级的不饱和酮
公开(公告)号：US4310705A
公开(公告)日：1982-01-12
申请号：US163401
申请日：1980-06-26
申请人： Axel Nissen , Gerd Kaibel , Otto Woerz , Lothar Arnold , Manfred Braun , Walter Rebafka
发明人： Axel Nissen , Gerd Kaibel , Otto Woerz , Lothar Arnold , Manfred Braun , Walter Rebafka
IPC分类号： C07C49/20 , B01J31/14 , C07C45/00 , C07C45/67 , C07C45/68 , C07C67/00 , C07C45/48
CPC分类号： C07C45/676
摘要： An improved process for the preparation of higher unsaturated ketones, such as geranylacetone and farnesylacetone, by reacting a .beta.,.gamma.-unsaturated alcohol and an alkyl acetoacetate at an elevated temperature in the presence of an organic aluminum compound, with elimination, and removal, of the alcohol derived from the alkyl acetoacetate in a reactor system carrying a fractionating column. The improvement in the purity, yield, and especially space-time yield of the product is achieved by starting from an alcohol having a higher boiling point than that of the alkyl acetoacetate used, carrying out the reaction in the presence of a small amount of an inert liquid which has a boiling point between that of the alkyl acetoacetate and the alcohol to be eliminated therefrom, and ensuring that the temperature at the bottom of the fractionating column is only slightly higher than the boiling point of the added liquid, under the prevailing pressure.
摘要翻译：通过在有机铝化合物的存在下在升高的温度下使β，γ-不饱和醇和乙酰乙酸烷基酯反应来制备高级不饱和酮，如香叶基丙酮和法呢基丙酮的改进方法，消除和除去在含有分馏塔的反应器系统中衍生自乙酰乙酸烷基酯的醇。通过从具有比所用乙酰乙酸烷基酯的沸点高的醇开始的醇开始，在少量的存在下进行反应来实现产物的纯度，产率和特别的时空产率的改善沸点在乙酰乙酸烷基酯和被除去的醇之间的沸点的惰性液体，并且确保分馏塔底部的温度仅略高于添加液体的沸点，在主要压力下。

2. 发明授权

US4720327A Distillative separation of liquid mixtures of substances 失效
标题翻译：物质液体混合物的蒸馏分离
公开(公告)号：US4720327A
公开(公告)日：1988-01-19
申请号：US420485
申请日：1982-09-20
申请人： Werner Aquila , Axel Nissen , Gerd Kaibel , Michael Horner , Walter Rebafka
发明人： Werner Aquila , Axel Nissen , Gerd Kaibel , Michael Horner , Walter Rebafka
IPC分类号： A61K8/33 , A61Q13/00 , B01D3/34 , C07B31/00 , C07B63/00 , C07C27/00 , C07C29/141 , C07C29/80 , C07C31/04 , C07C33/025 , C07C45/00 , C07C45/82 , C07C47/21 , C07C67/00 , C11B9/00 , C11B9/02 , B01D3/38
CPC分类号： C07C45/82 , B01D3/34 , C11B9/027 , Y10S203/24 , Y10S203/90
摘要： Distillative separation of liquid mixtures of one or more water-insoluble substances which have boiling points higher than that of water and one or more substances which have boiling points lower than that of water or which form azeotropes having boiling points lower than that of water, wherein the mixture to be distilled is mixed with a quantity of water such that the boiling point of the water under the pressure applied limits the bottom temperature of the mixture of substances to be separated.
摘要翻译：沸点高于水的一种或多种水不溶性物质的液体混合物的蒸馏分离和一种或多种沸点低于水的沸点或者沸点低于水的沸点的物质，其中将要蒸馏的混合物与一定量的水混合，使得在施加压力下的水的沸点限制待分离物质的混合物的底部温度。

3. 发明授权

US4133836A Manufacture of acetals 失效
标题翻译：缩醛的制造
公开(公告)号：US4133836A
公开(公告)日：1979-01-09
申请号：US801561
申请日：1977-05-31
申请人： Axel Nissen , Gerd Kaibel
发明人： Axel Nissen , Gerd Kaibel
IPC分类号： C07C41/50 , B01J27/00 , C07C41/00 , C07C41/54 , C07C43/30 , C07C43/303 , C07C67/00 , C07C69/12 , C07C69/73
摘要： A process for the manufacture of acetals by reacting aliphatic aldehydes with aliphatic alcohols, especially olefinically unsaturated aldehydes and allyl alcohols, in the presence of a distillable acid, especially nitric acid, using a rectifying column as the reaction vessel. The products may be used as starting materials for plastics, active substances, scents and vitamins.
摘要翻译：通过使用精馏塔作为反应容器，在可馏出的酸，特别是硝酸的存在下，使脂族醛与脂族醇，特别是烯属不饱和醛和烯丙醇反应来制造缩醛的方法。该产品可用作塑料，活性物质，气味和维生素的起始原料。

4. 发明申请

US20140061020A1 DEVICES AND METHOD FOR CONTINUOUS DISTILLATIVE SEPARATION OF A MIXTURE CONTAINING ONE OR MORE ALKANOLAMINE(S) 有权
标题翻译：含有一种或多种烷基胺的混合物的连续分离的装置和方法（S）
公开(公告)号：US20140061020A1
公开(公告)日：2014-03-06
申请号：US14057017
申请日：2013-10-18
申请人： Willi Schmidt , Gerd Kaibel , Elke Geißler , Wolfgang Reif , Manfred Julius , Frank-Friedrich Pape
发明人： Willi Schmidt , Gerd Kaibel , Elke Geißler , Wolfgang Reif , Manfred Julius , Frank-Friedrich Pape
IPC分类号： B01D3/32
CPC分类号： B01D3/32 , B01D3/14 , B01D3/42 , C07C213/04 , C07C213/10 , Y02P20/582 , C07C215/08 , C07C215/10
摘要： Apparatus and processes for continuous distillative separation of a mixture comprising one or more alkanolamine(s) are described. The separation is performed in one or more dividing wall column(s) and the alkanolamine or the alkanolamines is/are withdrawn as a side draw stream or side draw streams (side fraction(s)).
摘要翻译：描述了包含一种或多种链烷醇胺的混合物的连续蒸馏分离的装置和方法。分离在一个或多个分隔壁柱中进行，并且链烷醇胺或链烷醇胺作为侧馏分流或侧馏分流（侧馏分）排出。

5. 发明申请

US20100113805A1 PROCESS FOR OBTAINING MALEIC ANHYDRIDE BY DISTILLATION 有权
标题翻译：通过蒸馏获得马来酸酐的方法
公开(公告)号：US20100113805A1
公开(公告)日：2010-05-06
申请号：US12532660
申请日：2008-03-19
申请人： Gunther Windecker , Gerd Kaibel , Michael Steiniger , Thilo Buntrock , Jens Weiguny , Dany Vanden Hautte , Thierry Lurquin
发明人： Gunther Windecker , Gerd Kaibel , Michael Steiniger , Thilo Buntrock , Jens Weiguny , Dany Vanden Hautte , Thierry Lurquin
IPC分类号： C07D307/60
CPC分类号： B01D3/14 , B01D3/141 , C07C51/573 , C07C57/145
摘要： What is described is a process for obtaining maleic anhydride by distillation from a solution of maleic anhydride in a high-boiling absorbent which has been obtained by gas phase oxidation of a hydrocarbon and at least partial absorption of the oxidation products into the absorbent, by i) introducing the solution into the side of a feed column with a rectifying section disposed above the feed point and a stripping section disposed below the feed point, ii) providing an upper combining column which communicates with the upper end of the rectifying section and a lower combining column which communicates with the lower end of the stripping section, iii) providing a draw column which communicates with the upper combining column and the lower combining column, iv) drawing maleic anhydride off as a side draw from the draw column, and drawing off compounds having a lower boiling point than maleic anhydride at the top of the upper combining column and the high-boiling absorbent at the bottom of the lower combining column. The maleic anhydride obtained as a side draw has a low content of acrylic acid and acetic acid.
摘要翻译：所描述的是通过蒸馏从马来酸酐在高沸点吸收剂中的溶液获得马来酸酐的方法，其通过烃的气相氧化和至少部分吸收氧化产物进入吸收剂中获得，将溶液引入进料塔的侧面，其中设置在进料点上方的精馏部分和设置在进料点下方的汽提部分，ii）提供与精馏部分的上端连通的上部混合塔和下部组合柱与汽提部分的下端连通，iii）提供与上部混合塔和下部混合塔连通的牵引柱，iv）将拉伸马来酸酐作为拉伸塔的牵引拉出，拉出在上部混合塔的顶部具有比马来酸酐低的沸点的化合物和在底部o的高沸点吸收剂 f下组合列。作为侧馏分获得的马来酸酐具有低含量的丙烯酸和乙酸。

6. 发明申请

US20100081804A1 PROCESS FOR CONTINUOUS HYDROGENATION OR HYDROGENATING AMINATION 有权
标题翻译：连续加氢或加氢胺化的方法
公开(公告)号：US20100081804A1
公开(公告)日：2010-04-01
申请号：US12090377
申请日：2006-10-16
申请人： Bram Willem Hoffer , Hartwig Voss , Ekkehard Schwab , Udo Rheude , Gerd Kaibel , Mathias Haake , Jan Eberhardt , Michael Karcher
发明人： Bram Willem Hoffer , Hartwig Voss , Ekkehard Schwab , Udo Rheude , Gerd Kaibel , Mathias Haake , Jan Eberhardt , Michael Karcher
IPC分类号： C07D265/30 , C07C45/00
CPC分类号： C07C45/62 , C07C47/228 , C07C49/04 , C07C47/02
摘要： A process is described for continuously hydrogenating unsaturated compounds, in which particles of a first hydrogenation catalyst are suspended in a liquid phase in which an unsaturated compound is dissolved, the liquid phase, in the presence of a hydrogenous gas at a first partial hydrogen pressure and at a first temperature, is conducted through a packed bubble column reactor in cocurrent counter to the direction of gravity, the effluent from the bubble column reactor is sent to a gas-liquid separation, the liquid phase is sent to a crossfiltration to obtain a retentate and a filtrate, the retentate is recycled into the bubble column reactor and the filtrate, in the presence of a hydrogenous gas at a second partial hydrogen pressure and at a second temperature, is passed over a bed of a second hydrogenation catalyst, wherein the second partial hydrogen pressure is at least 10 bar higher than the first partial hydrogen pressure.
摘要翻译：描述了在第一部分氢气压力下在氢气存在下将不饱和化合物连续氢化的方法，其中第一氢化催化剂的颗粒悬浮在其中溶解不饱和化合物的液相中，液相，以及在第一个温度下，通过气泡塔反应器与重力方向并流，将来自泡罩塔反应器的流出物送入气液分离，将液相送至交叉过滤，得到滞留物和滤液，将滞留物再循环到泡罩塔反应器中，并且在第二部分氢气压力和第二温度下在氢气存在下将滤液通过第二氢化催化剂床，其中第二部分氢气压力比第一部分氢气压力高至少10巴。

7. 发明申请

US20090143601A1 METHOD FOR PREVENTING FUMARIC ACID DEPOSITS IN THE PRODUCTION OF MALEIC ACID ANHYDRIDE 审中-公开
标题翻译：在制备马来酸酐时防止含氟酸沉积物的方法
公开(公告)号：US20090143601A1
公开(公告)日：2009-06-04
申请号：US12300571
申请日：2007-05-16
申请人： Rolf Pinkos , Gerd Kaibel , Ellen Dahlhoff , Gunther Windecker , Jens Heimann
发明人： Rolf Pinkos , Gerd Kaibel , Ellen Dahlhoff , Gunther Windecker , Jens Heimann
IPC分类号： C07D307/60
CPC分类号： C07C51/573 , C07C57/145
摘要： The present invention provides a process for preventing fumaric acid deposits in the preparation of maleic anhydride, comprising the following steps:a) absorption of a C4-dicarboxylic acid or of a derivative from a crude product mixture into an organic solvent or water as an absorbent,b) removal of the C4-dicarboxylic acid or of a derivative from the absorbent,the absorbent thus recovered being catalytically hydrogenated fully or partly and recycled fully or partly into the absorption stage (a).
摘要翻译：本发明提供了一种在制备马来酸酐中防止富马酸沉积的方法，包括以下步骤：a）将C4-二羧酸或衍生物从粗产物混合物中吸收到作为吸收剂的有机溶剂或水中 b）从吸收剂中除去C4-二羧酸或衍生物，这样回收的吸收剂被完全或部分催化氢化，或者完全或部分地再循环到吸收阶段（a）中。

8. 发明授权

US07345205B2 Method for the production of tetrahydrogeranylacetone 有权
标题翻译：四氢笨花丙酮生产方法
公开(公告)号：US07345205B2
公开(公告)日：2008-03-18
申请号：US10519684
申请日：2003-07-14
申请人： Hans-Georg Goebbel , Gerd Kaibel , Christian Miller , Walter Dobler , Thomas Dirnsteiner , Thilo Hahn , Klaus Breuer , Werner Aquila
发明人： Hans-Georg Goebbel , Gerd Kaibel , Christian Miller , Walter Dobler , Thomas Dirnsteiner , Thilo Hahn , Klaus Breuer , Werner Aquila
IPC分类号： C07C45/62
CPC分类号： C07C45/62 , C07C49/04
摘要： A process is described for preparing tetrahydrogeranylacetone in which pseudoionone, geranylacetone and/or dihydrogeranylacetone in a liquid phase, in which particles of a catalyst which is capable of preferentially hydrogenating carbon-carbon double bonds over carbon-oxygen double bonds are suspended, is conducted through a device which inhibits the transport of the catalyst particles in the presence of a hydrogen-containing gas.
摘要翻译：描述了一种制备四氢ger anyl anyl A A is ger ger ger through through through through through through through through through through through through through through through through through through through through through through through through through through through through through through through through through through through through through through through through through through through through through through through through through through 在含氢气体的存在下抑制催化剂颗粒的输送的装置。

9. 发明申请

US20050197504A1 Method for the separation of ascorbic acid from a polar solvent containing ascorbic acid and 2-keto-l-gulonic acid 失效
标题翻译：将抗坏血酸与含有抗坏血酸和2-酮-L-古洛糖酸的极性溶剂分离的方法
公开(公告)号：US20050197504A1
公开(公告)日：2005-09-08
申请号：US10515625
申请日：2003-07-07
申请人： Gerd Kaibel , Martin Merger , Thomas Domschke , Petra Deckert , Friedrich Sauer
发明人： Gerd Kaibel , Martin Merger , Thomas Domschke , Petra Deckert , Friedrich Sauer
IPC分类号： C07D307/62 , C07D305/12
CPC分类号： C07D307/62 , Y02P20/582
摘要： The invention relates to a method for the separation of ascorbic acid from a mixture containing ascorbic acid and 2-keto-L-gulonic acid in a polar, preferably aqueous solvent, by means of liquid/liquid extraction using an amide. The method preferably also comprises steps for the back-extraction of the ascorbic acid, recycling of the extraction solvent and/or the back extraction solvent and for isolation of the ascorbic acid from the back extraction solvent. The invention further relates to a method for the production of ascorbic acid from KGA and isolation of the ascorbic acid so produced.
摘要翻译：本发明涉及通过使用酰胺的液/液萃取从抗坏血酸和2-酮-L-古洛糖酸的混合物中分离抗坏血酸在极性，优选水性溶剂中的方法。该方法优选还包括用于反萃取抗坏血酸的步骤，提取溶剂和/或反萃取溶剂的再循环以及用于从反萃取溶剂中分离抗坏血酸的步骤。本发明还涉及从KGA生产抗坏血酸并分离如此生产的抗坏血酸的方法。

10. 发明授权

US06831182B2 Method for the hydrogenation of maleic anhydride and related compounds in two serial reaction zones 有权
公开(公告)号：US06831182B2
公开(公告)日：2004-12-14
申请号：US10433424
申请日：2003-06-04
申请人： Holger Borchert , Stephan Schlitter , Rolf-Hartmuth Fischer , Markus Rösch , Frank Stein , Ralf-Thomas Rahn , Alexander Weck , Gerd Kaibel
发明人： Holger Borchert , Stephan Schlitter , Rolf-Hartmuth Fischer , Markus Rösch , Frank Stein , Ralf-Thomas Rahn , Alexander Weck , Gerd Kaibel
IPC分类号： C07D30708
CPC分类号： C07D307/08
摘要： The present invention relates to a process for the gas-phase hydrogenation of C4-dicarboxylic acids and/or their derivatives over a catalyst based on copper oxide to give substituted or unsubstituted &ggr;-butyrolactone and/or tetrahydrofuran, which comprises, which a first reaction zone in which the C4-dicarboxylic acid and/or its derivatives is/are reacted to give a mixture comprising a substituted or unsubstituted &ggr;-butyrolactone as main product and a subsequent second reaction zone in which the substituted or unsubstituted &ggr;-butyrolactone present in the mixture from the first hydrogenation step is reacted at a temperature lower than the temperature in the first hydrogenation step to give substituted or unsubstituted tetrahydrofuran.

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