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1. 发明授权

US4310705A Preparation of higher unsaturated ketones 失效
标题翻译：制备较高级的不饱和酮
公开(公告)号：US4310705A
公开(公告)日：1982-01-12
申请号：US163401
申请日：1980-06-26
申请人： Axel Nissen , Gerd Kaibel , Otto Woerz , Lothar Arnold , Manfred Braun , Walter Rebafka
发明人： Axel Nissen , Gerd Kaibel , Otto Woerz , Lothar Arnold , Manfred Braun , Walter Rebafka
IPC分类号： C07C49/20 , B01J31/14 , C07C45/00 , C07C45/67 , C07C45/68 , C07C67/00 , C07C45/48
CPC分类号： C07C45/676
摘要： An improved process for the preparation of higher unsaturated ketones, such as geranylacetone and farnesylacetone, by reacting a .beta.,.gamma.-unsaturated alcohol and an alkyl acetoacetate at an elevated temperature in the presence of an organic aluminum compound, with elimination, and removal, of the alcohol derived from the alkyl acetoacetate in a reactor system carrying a fractionating column. The improvement in the purity, yield, and especially space-time yield of the product is achieved by starting from an alcohol having a higher boiling point than that of the alkyl acetoacetate used, carrying out the reaction in the presence of a small amount of an inert liquid which has a boiling point between that of the alkyl acetoacetate and the alcohol to be eliminated therefrom, and ensuring that the temperature at the bottom of the fractionating column is only slightly higher than the boiling point of the added liquid, under the prevailing pressure.
摘要翻译：通过在有机铝化合物的存在下在升高的温度下使β，γ-不饱和醇和乙酰乙酸烷基酯反应来制备高级不饱和酮，如香叶基丙酮和法呢基丙酮的改进方法，消除和除去在含有分馏塔的反应器系统中衍生自乙酰乙酸烷基酯的醇。通过从具有比所用乙酰乙酸烷基酯的沸点高的醇开始的醇开始，在少量的存在下进行反应来实现产物的纯度，产率和特别的时空产率的改善沸点在乙酰乙酸烷基酯和被除去的醇之间的沸点的惰性液体，并且确保分馏塔底部的温度仅略高于添加液体的沸点，在主要压力下。

2. 发明授权

US4720327A Distillative separation of liquid mixtures of substances 失效
标题翻译：物质液体混合物的蒸馏分离
公开(公告)号：US4720327A
公开(公告)日：1988-01-19
申请号：US420485
申请日：1982-09-20
申请人： Werner Aquila , Axel Nissen , Gerd Kaibel , Michael Horner , Walter Rebafka
发明人： Werner Aquila , Axel Nissen , Gerd Kaibel , Michael Horner , Walter Rebafka
IPC分类号： A61K8/33 , A61Q13/00 , B01D3/34 , C07B31/00 , C07B63/00 , C07C27/00 , C07C29/141 , C07C29/80 , C07C31/04 , C07C33/025 , C07C45/00 , C07C45/82 , C07C47/21 , C07C67/00 , C11B9/00 , C11B9/02 , B01D3/38
CPC分类号： C07C45/82 , B01D3/34 , C11B9/027 , Y10S203/24 , Y10S203/90
摘要： Distillative separation of liquid mixtures of one or more water-insoluble substances which have boiling points higher than that of water and one or more substances which have boiling points lower than that of water or which form azeotropes having boiling points lower than that of water, wherein the mixture to be distilled is mixed with a quantity of water such that the boiling point of the water under the pressure applied limits the bottom temperature of the mixture of substances to be separated.
摘要翻译：沸点高于水的一种或多种水不溶性物质的液体混合物的蒸馏分离和一种或多种沸点低于水的沸点或者沸点低于水的沸点的物质，其中将要蒸馏的混合物与一定量的水混合，使得在施加压力下的水的沸点限制待分离物质的混合物的底部温度。

3. 发明授权

US4133836A Manufacture of acetals 失效
标题翻译：缩醛的制造
公开(公告)号：US4133836A
公开(公告)日：1979-01-09
申请号：US801561
申请日：1977-05-31
申请人： Axel Nissen , Gerd Kaibel
发明人： Axel Nissen , Gerd Kaibel
IPC分类号： C07C41/50 , B01J27/00 , C07C41/00 , C07C41/54 , C07C43/30 , C07C43/303 , C07C67/00 , C07C69/12 , C07C69/73
摘要： A process for the manufacture of acetals by reacting aliphatic aldehydes with aliphatic alcohols, especially olefinically unsaturated aldehydes and allyl alcohols, in the presence of a distillable acid, especially nitric acid, using a rectifying column as the reaction vessel. The products may be used as starting materials for plastics, active substances, scents and vitamins.
摘要翻译：通过使用精馏塔作为反应容器，在可馏出的酸，特别是硝酸的存在下，使脂族醛与脂族醇，特别是烯属不饱和醛和烯丙醇反应来制造缩醛的方法。该产品可用作塑料，活性物质，气味和维生素的起始原料。

4. 发明授权

US4288636A Preparation of citral 失效
标题翻译：柠檬醛的制备
公开(公告)号：US4288636A
公开(公告)日：1981-09-08
申请号：US158346
申请日：1980-06-10
申请人： Axel Nissen , Walter Rebafka , Werner Aquila
发明人： Axel Nissen , Walter Rebafka , Werner Aquila
IPC分类号： C07C45/00 , C07C45/51 , C07C47/21 , C07C67/00
CPC分类号： C07C45/515
摘要： Citral (I) ##STR1## is prepared by heating an acetal (IIa) or (IIb) ##STR2## in the presence of an acid catalyst while continuously distilling from the reaction mixture the 3-methylbut-2-en-1-ol (III, prenol) eliminated during the reaction.
摘要翻译：柠檬酸（I）通过在酸催化剂的存在下加热缩醛（IIa）或（IIb）IIa IIa IIB而制备，同时从反应混合物中连续蒸馏3-甲基丁-2-醇，烯丙醇（III，前醇）在反应期间消除。

5. 发明授权

US4146581A Manufacture of higher ketones 失效
标题翻译：制造高科隆
公开(公告)号：US4146581A
公开(公告)日：1979-03-27
申请号：US782637
申请日：1977-03-30
申请人： Axel Nissen , Otto Woerz , Gerd Heilen , Werner Fliege , Arnold Wittwer
发明人： Axel Nissen , Otto Woerz , Gerd Heilen , Werner Fliege , Arnold Wittwer
IPC分类号： B01J23/00 , B01J23/63 , B01J23/83 , B01J27/053 , C07B61/00 , C07C45/00 , C07C45/73 , C07C49/04 , C07C49/20 , C07C49/76 , C07C67/00 , C07B5/02 , C07C27/04 , C07C29/14
CPC分类号： B01J23/63 , B01J23/83 , C07C45/73
摘要： A process for the manufacture of higher ketones by reacting an aldehyde with a ketone in the presence of hydrogen over a catalyst system which contains, firstly, oxides or salts of the rare earth metals and, secondly, metals of group VIII of the periodic table of the elements. The process gives numerous higher ketones, required, for example, as solvents for surface coatings, or as scents, with high conversions and good selectivities, and therefore more simply and more economically than conventional methods.

6. 发明授权

US4270006A Preparation of aliphatic carbonyl compounds 失效
标题翻译：脂肪族羰基化合物的制备
公开(公告)号：US4270006A
公开(公告)日：1981-05-26
申请号：US106884
申请日：1979-12-27
申请人： Gerd Heilen , Axel Nissen , Otto Woerz
发明人： Gerd Heilen , Axel Nissen , Otto Woerz
IPC分类号： C07C45/73 , C07C45/45 , C07C47/02 , C07C49/04
CPC分类号： C07C45/73
摘要： Aliphatic carbonyl compounds are prepared by an aldol condensation of carbonyl compounds R.sup.1 --CH.sub.2 --CO--R.sup.2 (I; R.sup.1 and R.sup.2 =H or C.sub.1 -C.sub.8 -alkyl) in the presence of hydrogen and of a catalyst which has both condensing and hydrogenating properties, by using a catalyst system wherein the active components are from 1 to 90 percent by weight of a noble metal of group VIII of the periodic table and from 10 to 99 percent by weight of an oxide or salt of a rare earth metal, or of a mixture of different oxides and/or salts of rare earth metals.
摘要翻译：脂肪族羰基化合物通过羰基化合物R1-CH2-CO-R2（I; R1和R2 = H或C1-C8-烷基）在氢气和具有冷凝和氢化性质的催化剂存在下的醛醇缩合制备，通过使用催化剂体系，其中活性组分为1至90重量％的周期表第VIII族贵金属和10至99重量％的稀土金属的氧化物或盐，或稀土金属的不同氧化物和/或盐的混合物。

7. 发明授权

US4479016A Ethoxylates of diacetylene alcohols and the use of these compounds as surfactants 失效
标题翻译：乙炔醇的乙氧基化物和这些化合物作为表面活性剂的用途
公开(公告)号：US4479016A
公开(公告)日：1984-10-23
申请号：US391180
申请日：1982-06-23
申请人： Erhard Klahr , Walter Rebafka , Axel Nissen , Wolfgang Trieselt , Albert Hettche
发明人： Erhard Klahr , Walter Rebafka , Axel Nissen , Wolfgang Trieselt , Albert Hettche
IPC分类号： B01F17/38 , B01F17/42 , C07C43/178 , C07C43/196 , C11D1/72 , C11D3/20 , C07C43/14
CPC分类号： C11D1/721 , C07C43/178 , C07C43/196 , Y10S516/01
摘要： The invention relates to ethoxylates of diacetylene dialcohols as well as the use of these compounds as surfactants.
摘要翻译：本发明涉及二乙炔二醇的乙氧基化物以及这些化合物作为表面活性剂的用途。

8. 发明授权

US4173588A Manufacture of 2-methyl-2-hepten-6-one 失效
标题翻译：制备2-甲基-2-庚烯-6-酮
公开(公告)号：US4173588A
公开(公告)日：1979-11-06
申请号：US848211
申请日：1977-11-03
申请人： Heinrich Pasedach , Rudolf Mohr , Axel Nissen
发明人： Heinrich Pasedach , Rudolf Mohr , Axel Nissen
IPC分类号： C07C45/00 , B01J31/00 , C07B61/00 , C07C45/67 , C07C49/203 , C07C67/00 , C07C45/18
CPC分类号： C07C45/676
摘要： An improved process for the manufacture of 2-methyl-2-hepten-6-one by reacting an alkyl acetoacetate with 2-methyl-3-buten-2-ol in the presence of an organic aluminum compound such as aluminum trialcoholate, aluminum triacetoacetate, aluminum alkylacetoacetate or aluminum triaryloxylate. 2-Methyl-2-hepten-6-one is an intermediate for the manufacture of vitamins.
摘要翻译：通过使乙酰乙酸烷基酯与2-甲基-3-丁烯-2-醇在有机铝化合物如仲醇酸铝，三乙酰乙酸铝的存在下反应来制备2-甲基-2-庚烯-6-酮的改进方法，烷基乙酰乙酸铝或三芳氧基铝。 2-甲基-2-庚烯-6-酮是制造维生素的中间体。

9. 发明授权

US4049571A Manufacture of a catalyst composition containing zinc and nickel or cobalt 失效
标题翻译：制造含有锌和镍或钴的催化剂组合物
公开(公告)号：US4049571A
公开(公告)日：1977-09-20
申请号：US688763
申请日：1976-05-21
申请人： Axel Nissen , Werner Fliege , Dieter Voges
发明人： Axel Nissen , Werner Fliege , Dieter Voges
IPC分类号： B01J23/80 , C07B61/00 , C07C45/00 , C07C45/62 , C07C45/72 , C07C45/73 , C07C45/74 , C07C67/00 , B01J31/04
CPC分类号： C07C45/62 , B01J23/80 , C07C45/72 , C07C45/73 , C07C45/74
摘要： A process for the manufacture of a catalyst capable of causing condensation of aldehydes with ketones or ketones with each other while simultaneously hydrogenating the resulting olefinically unsaturated ketones to saturated ketones in the presence of hydrogen without attacking the ketone group, and containing zinc in addition to nickel or cobalt. The catalyst is subjected, prior to use, to a surface after-treatment with a zinc salt.
摘要翻译：制造能够使醛与酮或酮彼此缩合的催化剂的方法，同时在氢的存在下将所得的烯属不饱和酮氢化成饱和酮而不攻击酮基，并且除镍以外含有锌或钴。催化剂在使用前用锌盐进行表面后处理。

10. 发明授权

US4268446A Preparation of chromane derivatives 失效
标题翻译：色烯衍生物的制备
公开(公告)号：US4268446A
公开(公告)日：1981-05-19
申请号：US121170
申请日：1980-02-13
申请人： Michael Horner , Axel Nissen
发明人： Michael Horner , Axel Nissen
IPC分类号： C07D311/72 , C07D311/66 , C07D311/58
CPC分类号： C07D311/66
摘要： Chromane derivatives (I) ##STR1## where R.sup.1, R.sup.2 and R.sup.3 are H or C.sub.1 -C.sub.8 -alkyl, R.sup.4 is H, C.sub.1 -C.sub.8 -alkyl or C.sub.1 -C.sub.8 -acyl and R.sup.5 is C.sub.1 -C.sub.8 -alkyl are prepared by reacting a hydroquinone (II) ##STR2## with a Lewis acid or a Lewis acid derivative having the same action, and with a nitrile CH.sub.2 .dbd.CH--C(R.sup.5)(OR.sup.6)CN (III), where R.sup.6 is H, C.sub.1 -C.sub.4 -acyl or C.sub.1 -C.sub.4 -alkyl, or with a compound from which III is formed in situ, in the presence of an inert solvent.
摘要翻译：色原烷衍生物（I）其中R 1，R 2和R 3是H或C 1 -C 8 - 烷基，R 4是H，C 1 -C 8 - 烷基或C 1 -C 8酰基，R 5是C 1 -C 8 - 烷基是通过使氢醌（II）II与具有相同作用的路易斯酸或路易斯酸衍生物反应，并与腈CH2 = CH-C（R5）（OR6）CN（III）反应，其中R6为H，C1 -C 1-4酰基或C 1 -C 4 - 烷基，或与惰性溶剂存在下原位形成III的化合物反应。

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