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1. 发明授权

US6056967A Method of producing water-soluble condensates and addition products containing amino groups, and use of said condensates and addition products 失效
标题翻译：制备水溶性缩合物和含有氨基的加成产物的方法，以及使用所述缩合物和加成产物
公开(公告)号：US6056967A
公开(公告)日：2000-05-02
申请号：US101184
申请日：1998-07-06
申请人： Ulrich Steuerle , Hubert Meixner , Rainer Dyllick-Brenzinger , Wolfgang Reuther , Hartmut Kanter , Albert Hettche , Jurgen Weiser , Gunter Scherr
发明人： Ulrich Steuerle , Hubert Meixner , Rainer Dyllick-Brenzinger , Wolfgang Reuther , Hartmut Kanter , Albert Hettche , Jurgen Weiser , Gunter Scherr
IPC分类号： A61K8/72 , A61K8/84 , A61K8/91 , A61Q5/12 , A61Q19/00 , B01D21/01 , B01D61/14 , B01D61/58 , B01D63/02 , B01D63/06 , B01D63/08 , B01D63/10 , C08G73/00 , C08G73/02 , D21H17/54 , D21H17/56 , D21H21/10 , D21H21/16 , A61K7/00 , A61K7/06 , C08F6/00
CPC分类号： A61K8/91 , A61K8/84 , A61Q19/00 , A61Q5/00 , A61Q5/12 , B01D21/01 , B01D61/145 , C08G73/00 , C08G73/0213 , C08G73/0226 , C08G73/028 , D21H17/56 , D21H21/10 , D21H17/54 , D21H21/16
摘要： A process for the preparation of water-soluble, amino-containing condensates and adducts having a greater drainage and retention effect in papermaking, in which from 5 to 95% by weight of the condensates or adducts are separated off as permeate from solutions of water-soluble, amino-containing condensates or adducts by ultrafiltration through membranes and the amino-containing condensates or adducts having improved efficiency are, if required, isolated from the retentate, and the high molecular weight polymer fractions contained in the retentate are used as retention aids, drainage aids and fixing compositions in papermaking, as promoters in the sizing of paper with alkyldiketenes, as flocculants for sewage sludges, as adhesion promoters in the production of laminated films, as additives for hair and skincare compositions and as compositions for immobilizing anionic active ingredients.
摘要翻译： PCT No.PCT / EP97 / 00009 Sec。 371日期：1998年7月6日 102（e）日期1998年7月6日PCT 1997年1月3日PCT PCT。公开号WO97 / 25367 日期1997年7月17日制备在造纸中具有较大排水和保留效果的水溶性含氨基缩合物和加合物的方法，其中将5至95重量％的缩合物或加合物作为渗透物分离通过膜通过超滤从水溶性，含氨基的缩合物或加合物的溶液中，并且如果需要，具有改进效率的含氨基的缩合物或加合物是从滞留物中分离出来的，并且包含在渗余物中的高分子量聚合物级分是用作造纸中的助留剂，引流助剂和定影组合物，作为在使用烷基恶臭酮的纸浆上浆中的促进剂，作为污水污泥的絮凝剂，作为层合膜生产中的粘合促进剂，作为头发和护肤组合物的添加剂以及组合物固定阴离子活性成分。

2. 发明授权

US4702858A Washing agents containing, as additives, carboxyl-containing copolymers which are neutralized or amidated with amines 失效
标题翻译：作为添加剂含有用胺中和或酰胺化的含羧基共聚物的洗涤剂
公开(公告)号：US4702858A
公开(公告)日：1987-10-27
申请号：US888957
申请日：1986-07-24
申请人： Walter Denzinger , Heinrich Hartmann , Wolfgang Trieselt , Erhard Klahr , Albert Hettche
发明人： Walter Denzinger , Heinrich Hartmann , Wolfgang Trieselt , Erhard Klahr , Albert Hettche
IPC分类号： C08F8/32 , C08F8/44 , C11D3/37
CPC分类号： C11D3/3761 , C11D3/3769
摘要： Washing agents contain, as additives for inhibiting redeposition and promoting the primary washing action, homopolymers of acrylic acid and of methacrylic acid, copolymers of acrylic acid and methacrylic acid and copolymers which contain, as essential components,(a) an ethylenically unsaturated dicarboxylic acid of 4 to 6 carbon atoms and(b) acrylic acid, methacrylic acid and/or hydroxy-C.sub.2 -C.sub.6 -alkyl esters of ethylenically unsaturated C.sub.3 -C.sub.6 -carboxylic acids as copolymerized units,where the homo- and copolymers in the form of the free acids have a weight average molecular weight of from 5000 to 500,000 in the neutralized or amidated form, the carboxyl groups of the homo- and copolymers in each case being partially or completely neutralized with amines of the formula ##STR1## where R is C.sub.8 -C.sub.18 -alkyl or R.sup.1 --O--CH.sub.2 --(CH.sub.2).sub.n --, n is from 1 to 3, R.sup.1 is C.sub.1 -C.sub.18 -alkyl, R.sup.2 and R.sup.3 are each H or C.sub.1 -C.sub.18 -alkyl and/or from 5 to 50% of the said carboxyl groups being in the form of amides derived from primary and secondary amines of the formula I.
摘要翻译：洗涤剂含有作为抑制再沉积和促进初次洗涤作用的添加剂，丙烯酸和甲基丙烯酸的均聚物，丙烯酸和甲基丙烯酸的共聚物以及含有作为必要成分的（a）烯属不饱和二羧酸 4至6个碳原子，和（b）丙烯酸，甲基丙烯酸和/或烯属不饱和C 3 -C 6 - 羧酸的羟基-C 2 -C 6烷基酯作为共聚单元，其中以自由基形式存在的均聚物和共聚物酸的中和或酰胺化形式的重均分子量为5000至500,000，每种情况下的均聚物和共聚物的羧基用式“IMAGE”的胺部分或完全中和，其中R为C8-C18 - 烷基或R 1 -O-CH 2 - （CH 2）n - ，n为1至3，R 1为C 1 -C 18烷基，R 2和R 3各自为H或C 1 -C 18 - 烷基和/或5至50％的所述羧基为衍生自原料的酰胺形式芳胺和仲胺。

3. 发明授权

US4698174A Additives for detergents and cleaning agents 失效
标题翻译：洗涤剂和清洁剂的添加剂
公开(公告)号：US4698174A
公开(公告)日：1987-10-06
申请号：US822610
申请日：1986-01-27
申请人： Walter Denzinger , Heinrich Hartmann , Wolfgang Trieselt , Albert Hettche , Rolf Schneider , Hans-Juergen Raubenheimer
发明人： Walter Denzinger , Heinrich Hartmann , Wolfgang Trieselt , Albert Hettche , Rolf Schneider , Hans-Juergen Raubenheimer
IPC分类号： C11D3/33 , C11D3/37
CPC分类号： C11D3/33 , C11D3/3761
摘要： Pulverulent and/or granular additives for pulverulent detergents and cleaning agents, consisting of(a) from 80 to 20% by weight of one or more copolymers comprising from 40 to 90% by weight of (meth)acrylic acid and from 60 to 10% by weight of maleic acid and/or one or more copolymers comprising from 10 to 45% by weight of (meth)acrylic acid, from 10 to 45% by weight of maleic acid and from 10 to 60% by weight of one or more hydroxyalkyl (meth)acrylates where hydroxyalkyl is of 2 to 6 carbon atoms, if appropriate in the form of a partially or completely neutralized water-soluble salt,(b) from 20 to 80% by weight of nitrilotriacetic acid or its mono-, di- or trisodium or mono-, di- or tripotassium salt and(c) from 0 to 20% by weight of one or more additives conventionally used for detergent and cleaning agent formulations, the use of these pulverulent and/or granular mixtures as additives for pulverulent and/or granular detergents and cleaning agents, and processes for the preparation of the said additives.
摘要翻译：用于粉状洗涤剂和清洁剂的粉末和/或颗粒添加剂由（a）80至20重量％的一种或多种共聚物组成，所述共聚物包含40至90重量％的（甲基）丙烯酸和60至10重量％的马来酸和/或一种或多种共聚物，其包含10至45重量％的（甲基）丙烯酸，10至45重量％的马来酸和10至60重量％的一种或多种羟烷基（甲基）丙烯酸酯，其中羟基烷基为2至6个碳原子，如果合适的话以部分或完全中和的水溶性盐的形式，（b）20至80重量％的次氮基三乙酸或其单 - 或三钠或单，二或三钾盐和（c）0至20重量％的常规用于洗涤剂和清洁剂配方的一种或多种添加剂，使用这些粉状和/或颗粒状混合物作为粉末状添加剂和/或颗粒状洗涤剂和清洁剂，以及制备方法 n的所述添加剂。

4. 发明授权

US4680327A Stabilizers 失效
标题翻译：稳定剂
公开(公告)号：US4680327A
公开(公告)日：1987-07-14
申请号：US823744
申请日：1986-01-29
申请人： Albert Hettche , Stefan Weiss , Hubert Trauth , Peter Lechtken , Michael Horner
发明人： Albert Hettche , Stefan Weiss , Hubert Trauth , Peter Lechtken , Michael Horner
IPC分类号： C08K5/11 , C08K5/00 , C08K5/10 , C08K5/103 , C08K5/1545 , C08L101/00 , C08K5/15
CPC分类号： C08K5/1545 , C08K5/103
摘要： Stabilizers consisting of (a) 2,5,7,8-tetramethyl-2-(2'-stearyloxyethyl)-chroman and (b) glyceryl stearate, glyceryl hydroxystearate, partial esters of stearic acid with condensates of glycerol and trimethylolpropane, triglyceryl stearate and/or tetraglyceryl stearate, with or without further conventional additives, the weight ratio of (a) to (b) being from 10:1 to 1:10, give improved stabilization to discoloration and superior stability during processing when used in plastics such as polyethylene or polypropylene.
摘要翻译：稳定剂由（a）2,5,7,8-四甲基-2-（2'-硬脂酰氧基乙基） - 苯并二氢吡喃和（b）硬脂酸甘油酯，羟基硬脂酸甘油酯，硬脂酸与甘油和三羟甲基丙烷缩合物的偏酯，硬脂酸甘油三酯和/或四甘油硬脂酸酯，使用或不含其它常规添加剂时，（a）至（b）的重量比为10:1至1:10，当在塑料中使用时，提供改进的变色稳定性和加工过程中优异的稳定性聚乙烯或聚丙烯。

5. 发明授权

US4207255A Manufacture of very pure halonaphthalic acid anhydrides 失效
标题翻译：制造非常纯的卤代二氢酸酐
公开(公告)号：US4207255A
公开(公告)日：1980-06-10
申请号：US850239
申请日：1977-11-10
申请人： Wolfgang Eisfeld , Walter Disteldorf , Albert Hettche
发明人： Wolfgang Eisfeld , Walter Disteldorf , Albert Hettche
IPC分类号： C07D311/92 , C07C51/31 , C07C63/34
CPC分类号： C07C51/316
摘要： Pure halonaphthalic acid anhydrides are prepared from haloacenaphthenes by oxidation with nitric acid in a mixture of aliphatic carboxylic acid, water and nitric acid in the presence of vanadate, with or without further metal salts, at an elevated temperature and the reaction product is isolated and subjected to an oxidative after-treatment with hypochlorite in aqueous solution at a pH of from 9 to 12 at an elevated temperature. The products are intermediates for the manufacture of optical brighteners.
摘要翻译：纯的卤代邻苯二甲酸酐通过在酸酐存在下，在有或者没有其它金属盐的情况下，用硝酸在脂族羧酸，水和硝酸的混合物中进行氧化由卤代苊制备，并将反应产物分离并进行在升高的温度下在pH为9至12的水溶液中用次氯酸盐进行氧化后处理。该产品是制造荧光增白剂的中间体。

6. 发明授权

US4075211A Naphthalimide compounds and optical brighteners 失效
标题翻译：萘二甲酰亚胺化合物和荧光增白剂
公开(公告)号：US4075211A
公开(公告)日：1978-02-21
申请号：US646181
申请日：1976-01-02
申请人： Horst Scheuermann , Albert Hettche
发明人： Horst Scheuermann , Albert Hettche
IPC分类号： C07D221/14 , C07D401/06 , C07D413/06 , C09K11/06
CPC分类号： C07D401/06 , C07D221/14
摘要： Compounds of the naphthalimide series which in the dissolved condition exhibit a characteristic blue, violet or bluish violet fluorescence, and a process for their production. The compounds are outstandingly suitable for the optical brightening of synthetic fibers.
摘要翻译：处于溶解状态的萘二甲酰亚胺系列化合物呈现特征性蓝色，紫色或蓝紫色荧光，以及其生产方法。该化合物非常适用于合成纤维的光学增白。

7. 发明授权

US4750933A Floor polish emulsions based on ethylene copolymer 失效
标题翻译：基于乙烯共聚物的地板抛光乳液
公开(公告)号：US4750933A
公开(公告)日：1988-06-14
申请号：US914509
申请日：1986-10-02
申请人： Franz Brandstetter , Walter Ziegler , Wolfram Dietsche , Stefan Weiss , Albert Hettche , Otto Kuehneweg
发明人： Franz Brandstetter , Walter Ziegler , Wolfram Dietsche , Stefan Weiss , Albert Hettche , Otto Kuehneweg
IPC分类号： C08L23/08 , C08L23/00 , C08L31/04 , C08L33/00 , C08L33/02 , C08L101/00 , C09D5/00 , C09D5/02 , C09D131/04 , C09G1/00 , C09G1/04 , C09G1/08 , C09G1/16
CPC分类号： C09G1/16 , C09G1/08
摘要： An aqueous wax dispersion for floor care contains a mixture of an aqueous secondary dispersion of an ethylene copolymer wax, having a specific MFI, and an aqueous primary dispersion together with plasticizers, leveling agents and water, and an ethylene copolymer wax in the form of an aqueous secondary dispersion is used for floor emulsions.
摘要翻译：用于地板护理的含水蜡分散体包含具有特定MFI的乙烯共聚物蜡的水性二次分散体和水性初级分散体与增塑剂，流平剂和水以及乙烯共聚物蜡的混合物，水性二次分散体用于地板乳液。

8. 发明授权

US4559159A Copolymers, their preparation and their use as assistants in detergents and cleansing agents 失效
标题翻译：共聚物，它们的制备及其作为洗涤剂和清洁剂助剂的用途
公开(公告)号：US4559159A
公开(公告)日：1985-12-17
申请号：US580806
申请日：1984-02-16
申请人： Walter Denzinger , Heinrich Hartmann , Wolfgang Trieselt , Richard Mueller , Paul Diessel , Albert Hettche
发明人： Walter Denzinger , Heinrich Hartmann , Wolfgang Trieselt , Richard Mueller , Paul Diessel , Albert Hettche
IPC分类号： C08F8/00 , C08F8/14 , C08F220/04 , C11D3/37 , D06L1/12 , D06M13/02 , D06M13/188 , D06M13/322 , D06M13/325 , D06M13/328 , D06M13/402 , D06M15/263 , C08F220/06 , D06L3/02
CPC分类号： C08F220/04 , C08F8/14 , C11D3/3757 , C11D3/3769 , C11D3/3773
摘要： Water-soluble copolymers which consist of from 40 to 90% by weight of one or more ethylenically unsaturated monocarboxylic acids of 3 to 5 carbon atoms, from 60 to 10% by weight of one or more ethylenically unsaturated dicarboxylic acids of 4 to 8 carbon atoms and/or of the corresponding dicarboxylic acid anhydride and, if required, not more than 15% by weight, based on the total weight of the carboxyl-containing monomers, of one or more carboxyl-free monomers, and which are esterified with from 2 to 60% by weight, based on the total weight of the carboxyl-containing monomers, of one or more compounds which contain a terminal hydroxyl group and one or more alkylene oxide groups of 2 to 4 carbon atoms, the preparation of such water-soluble copolymers and their use as assistants in detergents, cleansing and dishwashing agents.
摘要翻译：由40至90重量％的含有3-5个碳原子的一种或多种烯属不饱和一元羧酸组成的水溶性共聚物，60至10重量％的一种或多种4-8个碳原子的烯键式不饱和二羧酸和/或相应的二羧酸酐，并且如果需要，不超过15重量％，基于含羧基单体的总重量，一种或多种无羧基单体，并且用2 至60重量％，基于含羧基单体的总重量，一种或多种含有末端羟基和一个或多个2至4个碳原子的氧化烯基团的化合物，制备这种水溶性共聚物及其用作洗涤剂，清洁剂和餐具洗涤剂中的助剂。

9. 发明授权

US4183851A Pyrazoline compounds 失效
标题翻译：吡唑啉化合物
公开(公告)号：US4183851A
公开(公告)日：1980-01-15
申请号：US913949
申请日：1978-06-09
申请人： Manfred Patsch , Albert Hettche
发明人： Manfred Patsch , Albert Hettche
IPC分类号： C07D231/06 , C07D231/12 , C07D401/12
CPC分类号： C07D231/06 , C07D231/12
摘要： Pyrazoline compounds of the formula (I): ##STR1## in which each of B.sup.1 or B.sup.5 is hydrogen or C.sub.1 to C.sub.4 alkyl;R.sup.1 is hydrogen, alkyl or hydroxy;R.sup.2, R.sup.3, R.sup.5, R.sup.6 and R.sup.7 independently of one another are hydrogen, chloro, bromo, fluoro, methyl, ethyl, methoxy or ethoxy;R.sup.4 is hydrogen, alkyl, benzyl, phenylethyl or also phenyl optionally bearing chloro, bromo, methyl, ethyl, methoxy, ethoxy, cyano, dialkylamino or SO.sub.3 H as a substituent;X is --O--, --S--, --NR.sup.8 --, --NR.sup.8 CO--, --NR.sup.8 --SO.sub.2 --, --OSO.sub.3 -- or --SO.sub.3 --;R.sup.8 is hydrogen, alkyl or alkyl bearing hydroxy or C.sub.1 to C.sub.4 alkoxy as a sbustituent;A is hydrogen, sodium, potassium, unsubstituted or substituted ammonium, unsubstituted or substituted alkyl, cycloalkyl, aralkyl or aryl; and--NR.sup.8 -- and A together may be an optionally quaternized saturated or unsaturated heterocyclic ring.The compounds are eminently suitable as optical brighteners for example for acrylonitrile polymers, wool and polyamides.
摘要翻译：式（I）的吡唑啉化合物：其中B 1或B 5各自为氢或C 1至C 4烷基; R1是氢，烷基或羟基; R 2，R 3，R 5，R 6和R 7彼此独立地是氢，氯，溴，氟，甲基，乙基，甲氧基或乙氧基; R4是氢，烷基，苄基，苯基乙基，或者也可以是含有氯，溴，甲基，乙基，甲氧基，乙氧基，氰基，二烷基氨基或SO3H作为取代基的苯基; X是-O - ， - S - ， - NR 8 - ， - NR 8 CO-， - NR 8 -SO 2 - ， - SO 3 - 或-SO 3 - ; R8是氢，具有羟基的烷基或烷基或作为取代基的C1-C4烷氧基; A是氢，钠，钾，未取代或取代的铵，未取代或取代的烷基，环烷基，芳烷基或芳基; 并且-NR 8 - 和A一起可以是任选季铵化的饱和或不饱和杂环。该化合物特别适用于例如丙烯腈聚合物，羊毛和聚酰胺的荧光增白剂。

10. 发明授权

US4129563A Pyrazoline compounds 失效
标题翻译：吡唑啉化合物
公开(公告)号：US4129563A
公开(公告)日：1978-12-12
申请号：US702975
申请日：1976-07-06
申请人： Manfred Patsch , Albert Hettche
发明人： Manfred Patsch , Albert Hettche
IPC分类号： C07D231/06 , C07D231/12 , C09B57/00 , D21H21/30 , C07D401/12
CPC分类号： C07D231/06 , C07D231/12 , D21H21/30
摘要： Pyrazoline compounds of the formula (I): ##STR1## in which EACH OF B.sup.1 to B.sup.5 is hydrogen or C.sub.1 to C.sub.4 alkyl;R.sup.1 is hydrogen, alkyl or hydroxy;R.sup.2, r.sup.3, r.sup.5, r.sup.6 and R.sup.7 independently of one another are hydrogen, chloro, bromo, fluoro, methyl, ethyl, methoxy or ethoxy;R.sup.4 is hydrogen, alkyl, benzyl, phenylethyl or also phenyl optionally bearing chloro, bromo, methyl, ethyl, methoxy, ethoxy, cyano, dialkylamino or SO.sub.3 H as a substituent;X is --O--, --S--, --NR.sup.8 --, --NR.sup.8 CO--, --NR.sup.8 --SO.sub.2 --, --OSO.sub.3 -- or --SO.sub.3 --;R.sup.8 is hydrogen, alkyl or alkyl bearing hydroxy or C.sub.1 to C.sub.4 alkoxy as a substituent;A is hydrogen, sodium, potassium, unsubstituted or substituted ammonium, unsubstituted or substituted alkyl, cycloalkyl, aralkyl or aryl; and--NR.sup.8 -- and A together may be an optionally quaternized saturated or unsaturated heterocyclic ring.The compounds are eminently suitable as optical brighteners for example for acrylonitrile polymers, wool and polyamides.
摘要翻译：式（I）的吡唑啉化合物：其中每个B 1至B 5为氢或C 1至C 4烷基; R1是氢，烷基或羟基; R 2，R 3，R 5，R 6和R 7彼此独立地是氢，氯，溴，氟，甲基，乙基，甲氧基或乙氧基; R4是氢，烷基，苄基，苯基乙基，或者也可以是含有氯，溴，甲基，乙基，甲氧基，乙氧基，氰基，二烷基氨基或SO3H作为取代基的苯基; X是-O - ， - S - ， - NR 8 - ， - NR 8 CO-， - NR 8 -SO 2 - ， - SO 3 - 或-SO 3 - ; R8是氢，烷基或烷基，带有羟基或C1-C4烷氧基作为取代基; A是氢，钠，钾，未取代或取代的铵，未取代或取代的烷基，环烷基，芳烷基或芳基; 并且-NR 8 - 和A一起可以是任选季铵化的饱和或不饱和杂环。

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