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1. 发明申请

US20100312018A1 Processes for Producing Levosandal and Levosandol 审中-公开
标题翻译：产生左旋糖和左旋糖酐的方法
公开(公告)号：US20100312018A1
公开(公告)日：2010-12-09
申请号：US12753279
申请日：2010-04-02
申请人： Avelino Corma Canos , Sara Iborra Chornet , Alexandra Velty
发明人： Avelino Corma Canos , Sara Iborra Chornet , Alexandra Velty
IPC分类号： C07C45/74 , C07C29/159
CPC分类号： C07C29/14 , C07C45/74 , C07C2601/10 , C07C33/12 , C07C47/225
摘要： The present invention relates to processes for producing 2-ethyl-4-(2,2,3-trimethyl-3-cyclopenten-1-yl)-2-butenal and 2-ethyl-4-(2,2,3-trimethyl-3-cyclopenten-1-yl)-2-buten-1-ol using heterogeneous bifunctional catalysts with a good yield. There is provided a process for producing 2-ethyl-4-(2,2,3-trimethyl-3-cyclopenten-1-yl)-2-butenal by the cross-aldol condensation between campholenic aldehyde and butanal using bifunctional heterogeneous catalysts in the presence of controlled amounts of an aliphatic alcohol; and a process for producing 2-ethyl-4-(2,2,3-trimethyl-3-cyclopenten-1-yl)-2-buten-1-ol useful as perfume, starting from 2-ethyl-4-(2,2,3-trimethyl-3-cyclopenten-1-yl)-2-butenal through a MPV reduction using an acid-base bifunctional heterogeneous catalyst. Both process can be coupled in a cascade process which involves the cross-aldol condensation between campholenic aldehyde and butanal followed by the Meerwein-Ponndorf-Verley (MPV) reduction in the presence of a secondary alcohol using the same heterogeneous bifunctional catalyst for obtaining (2-ethyl-4-(2,2,3-trimethyl-3-cyclopenten-1-yl)-2-buten-1-ol).
摘要翻译：本发明涉及2-乙基-4-（2,2,3-三甲基-3-环戊烯-1-基）-2-丁烯醛和2-乙基-4-（2,2,3-三甲基 -3-环戊烯-1-基）-2-丁烯-1-醇，使用异构双官能催化剂，产率很高。提供了一种通过使用双功能非均相催化剂在camp醛和丁醛之间的交换醛醇缩合产生2-乙基-4-（2,2,3-三甲基-3-环戊烯-1-基）-2-丁烯醛的方法存在受控量的脂族醇; 和用作香料的2-乙基-4-（2,2,3-三甲基-3-环戊烯-1-基）-2-丁烯-1-醇的制备方法，由2-乙基-4-（2 ，2,3-三甲基-3-环戊烯-1-基）-2-丁烯醛，通过使用酸碱双功能多相催化剂的MPV还原。这两种方法可以在级联方法中偶合，其涉及在醛醇和丁醛之间的交叉醛醇缩合，随后在仲醇存在下使用相同的异构双功能催化剂还原Meerwein-Ponndorf-Verley（MPV）以获得（2 - 乙基-4-（2,2,3-三甲基-3-环戊烯-1-基）-2-丁烯-1-醇）。

2. 发明申请

US20070092439A1 Method of preparing monoesters of polyhydroxyl alcohols 审中-公开
标题翻译：制备多羟基醇单酯的方法
公开(公告)号：US20070092439A1
公开(公告)日：2007-04-26
申请号：US11489252
申请日：2006-07-19
申请人： Avelino Corma Canos , Sara Iborra Chornet , Alexandra Velty , Sharifah Bee Abd Hamid
发明人： Avelino Corma Canos , Sara Iborra Chornet , Alexandra Velty , Sharifah Bee Abd Hamid
IPC分类号： C01B39/00
CPC分类号： C07D493/04 , C07D307/20
摘要： The invention relates to a method of preparing monoesters of polyhydroxyl alcohols. The inventive method comprises a first step consisting in protecting the hydroxyl groups of a polyhydroxyl alcohol by means of acetalisation and a second step comprising the sterification of said acetalised polyhydroxyl alcohol with a fatty acid in the presence of one or more solid acid catalysts.
摘要翻译：本发明涉及一种制备多羟基醇单酯的方法。本发明的方法包括第一步，通过缩醛化保护多羟基醇的羟基，第二步包括在一种或多种固体酸催化剂存在下用脂肪酸灭菌所述缩醛化的多羟基醇。

3. 发明申请

US20100099894A1 Method for the Synthesis of Cyclic Acetals by the Reactive Extraction of a Polyol in a Concentrated Solution 审中-公开
标题翻译：通过多元醇在浓缩溶液中反应萃取合成环缩醛的方法
公开(公告)号：US20100099894A1
公开(公告)日：2010-04-22
申请号：US12445030
申请日：2007-10-08
申请人： Jean-Luc Dubois , Sara Iborra Chornet , Alexandra I. Lucienne Velty , Avelino Corma Canos
发明人： Jean-Luc Dubois , Sara Iborra Chornet , Alexandra I. Lucienne Velty , Avelino Corma Canos
IPC分类号： C07D319/06 , C07D317/10
CPC分类号： C07D317/20 , C07D319/06
摘要： A method for the synthesis of cyclic acetals comprises reacting at least one carbonyl-function compound selected from aldehydes, ketones, and/or linear acetals, on a polyol in a concentrated aqueous solution exceeding 20 wt % in a reactor containing an acidic catalyst. The carbonyl-function compound is selected so that the cyclic acetal obtained has a water solubility lower than 20000 mg/kg. During the catalytic reaction for the cyclic acetal synthesis, at least one portion of the organic phase containing the cyclic acetal is separated. The acidic catalysis is either homogeneous when using a water-soluble strong acid, or heterogeneous when using a solid acid such as a resin, a zeolite, or any appropriately acidified solid. The extractive reaction method can be used for obtaining high conversions and selectivity.
摘要翻译：合成环状缩醛的方法包括在含有酸性催化剂的反应器中，使至少一种选自醛，酮和/或直链缩醛的羰基官能化合物在多元醇上浓缩超过20重量％的浓缩水溶液中。选择羰基官能化合物，使得得到的环状缩醛的水溶解度低于20000mg / kg。在环缩醛合成的催化反应期间，分离含有环缩醛的至少一部分有机相。当使用水溶性强酸时，酸性催化剂是均匀的，或当使用固体酸如树脂，沸石或任何适当酸化的固体时是非均相的。萃取反应方法可用于获得高转化率和选择性。

4. 发明授权

US07087779B2 Aldehyde conversion method using a molecular sieve and the use of the molecular sieve as a catalyst in said method 失效
标题翻译：使用分子筛的醛转化方法和在所述方法中使用分子筛作为催化剂
公开(公告)号：US07087779B2
公开(公告)日：2006-08-08
申请号：US10932564
申请日：2004-09-02
申请人： Avelino Corma Canos , María Mifsud Grau , Sara Iborra Chornet , Michael Renz
发明人： Avelino Corma Canos , María Mifsud Grau , Sara Iborra Chornet , Michael Renz
IPC分类号： C07D331/02 , C07D301/12 , C07C69/76
CPC分类号： C07C51/285 , B01J29/0308 , B01J29/035 , B01J29/04 , B01J29/7057 , C01B37/005 , C01B39/085 , C07C51/235 , C07C67/39 , C07C63/04 , C07C65/21 , C07C69/017 , C07C69/08 , C07C69/10
摘要： The invention relates to an aldehyde conversion method comprising putting an aldehyde into contact with oxygenated water and with a catalyst, under oxidation conditions, wherein the catalyst is a molecular sieve with pores of a diameter of at least 0.52 nm and has an empirical formula in a calcined and dehydrated form of (SnxTiySi1-x-y-zGez)O2 wherein x is a molar fraction of the tin and has a value between 0.001 and 0.1; y is a molar fraction of titanium and has a value from zero to 0.1; and z is the molar fraction molar of the germanium and has a value from zero to 0.08.
摘要翻译：本发明涉及醛转化方法，其包括在氧化条件下将醛与含氧水和催化剂接触，其中催化剂是直径为至少0.52nm的孔的分子筛，并且具有经验式煅烧和脱水形式的<？in-line-formula description =“In-line Formulas”end =“lead”？（Sn x x Ti x Si x Si α-in-line-formula description =“In-line Formulas”end =“tail”？>其中x（x，y）是锡的摩尔分数，其值在0.001和0.1之间; y是钛的摩尔分数，其值为0至0.1; z是锗的摩尔分数摩尔，其值为零至0.08。

5. 发明授权

US6114587A Process and catalyst for the selective production of .alpha.-alkylcinnamaldehyde 失效
标题翻译：用于选择性生产α-烷基肉桂醛的方法和催化剂
公开(公告)号：US6114587A
公开(公告)日：2000-09-05
申请号：US171158
申请日：1999-02-02
申请人： M.sup.a Jose Climent Olmedo , Rut Guil Lopez , Sara Iborra Chornet , Jaime Primo Millo , Avelino Corma Canos
发明人： M.sup.a Jose Climent Olmedo , Rut Guil Lopez , Sara Iborra Chornet , Jaime Primo Millo , Avelino Corma Canos
IPC分类号： B01J29/06 , B01J29/04 , C07B61/00 , C07C45/51 , C07C45/68 , C07C47/232 , C07C45/45
CPC分类号： C07C45/515 , B01J29/04
摘要： The selective obtainment of .alpha.-alkyl cinnamaldehydes, such as Jasmine aldehyde is carried out by a process that involves two consecutive reactions: acetalization of an n-alkyl aldehyde by direct reaction with an alcohol or by transacetalization followed by the reaction between said acetal and aromatic aldehyde such as benzaldehyde using molecular sieves with regular pore distribution in the range of micro and mesopores and between 6 and 100 .ANG. as acid catalysts.
摘要翻译： PCT No.PCT / ES98 / 00017 Sec。 371日期1998年2月2日 102（e）1998年2月2日PCT 1998年1月23日PCT PCT。出版物WO98 / 3592800 日期1998年8月20日选择性获得α-烷基肉桂醛如茉莉醛通过涉及两个连续反应的方法进行：通过与醇的直接反应缩醛化正烷基醛或通过反式缩合反应在所述缩醛和芳族醛之间，例如苯甲醛，使用在微孔和介孔范围内具有规则孔分布的分子筛和作为酸催化剂的6至100安格姆。

6. 发明授权

US10005073B2 Process for manufacture of a zeolite based catalyst for the conversion of methanol to olefins 有权
公开(公告)号：US10005073B2
公开(公告)日：2018-06-26
申请号：US14005325
申请日：2012-03-15
申请人： Manfred Frauenrath , Stefan Klingelhofer , Gotz Burgfels , Avelino Corma Canos , Joaquin Martinez Triguero , Elena Corresa Mateu
发明人： Manfred Frauenrath , Stefan Klingelhofer , Gotz Burgfels , Avelino Corma Canos , Joaquin Martinez Triguero , Elena Corresa Mateu
IPC分类号： B01J29/40 , C07C1/22 , B01J37/00 , C07C1/20
CPC分类号： B01J29/40 , B01J37/0018 , B01J37/0036 , B01J2229/18 , B01J2229/20 , B01J2229/37 , B01J2229/42 , C07C1/20 , C07C1/22 , C07C2529/70 , Y02P20/52 , C07C11/02 , C07C11/06
摘要： The present invention relates to a process for preparing phosphorus containing zeolite type catalysts based on crystalline aluminosilicates, the catalysts of this process and the use of these catalysts for the conversion of methanol to olefins.

7. 发明申请

US20140142353A1 METHOD FOR EXTRACTING BIOCHEMICAL PRODUCTS OBTAINED FROM A PROCESS OF HYDROTHERMAL CARBONIZATION OF BIOMASS 有权
标题翻译：从生物质热水碳酸化过程中提取生物化学产品的方法
公开(公告)号：US20140142353A1
公开(公告)日：2014-05-22
申请号：US14114818
申请日：2011-12-22
申请人： Martin Hitzl , Michael Renz , Avelino Corma Canos
发明人： Martin Hitzl , Michael Renz , Avelino Corma Canos
IPC分类号： C10G1/00
CPC分类号： C10G1/002 , C10G1/008 , C10G1/02 , C10G2300/1011 , C10L9/086 , C10L2290/54 , Y02E50/13 , Y02P30/20
摘要： The invention relates to a method for extracting biochemical products obtained from a process of hydrothermal carbonization of biomass, which includes feeding an aqueous mixture of biomass from a preheating tube for the aqueous mixture of biomass to a vertical reactor with a predetermined level of floatation and an area for accumulation of steam and gases in the upper part thereof, wherein said method for extracting biochemical products is characterized in that it includes (a) heating the aqueous mixture of biomass to, or above, evaporation temperature in said vertical reactor and/or in a previous stage of preheating the aqueous mixture of biomass, increasing the generation of stream and/or gases at the predetermined flotation level of the vertical reactor, (b) extracting the steam and/or gases generated in the previous stage and accumulated in the upper part of the vertical reactor, and (c) cooling the gases and/or condensing the steam extracted in the previous stage at different levels of temperature and pressure. The invention likewise relates to the biochemical product obtainable from said method, as well as to a system for implementing said method.
摘要翻译：本发明涉及一种从生物质水热碳化过程中提取生物化学产品的方法，其包括将生物质的水混合物从用于生物质的含水混合物的预热管中提供至具有预定水平浮选的垂直反应器，其中所述用于提取生物化学产物的方法的特征在于其包括（a）将所述生物质的水混合物加热至或高于所述垂直反应器中的蒸发温度和/或在预热生物质水混合物的先前阶段，在垂直反应器的预定浮选水平增加流和/或气体的产生，（b）提取先前阶段产生的并积聚在上层的蒸汽和/或气体垂直反应器的一部分，和（c）在不同的水平下冷却气体和/或冷凝在前一阶段提取的蒸汽 ls的温度和压力。本发明同样涉及可从所述方法获得的生物化学产品，以及用于实施所述方法的系统。

8. 发明授权

US08115001B2 Zeolite ITQ-30 有权
标题翻译：沸石ITQ-30
公开(公告)号：US08115001B2
公开(公告)日：2012-02-14
申请号：US11597808
申请日：2005-05-25
申请人： Avelino Corma Canos , María José Díaz Cabañas
发明人： Avelino Corma Canos , María José Díaz Cabañas
IPC分类号： C07D221/18
CPC分类号： C01B39/48 , B01J29/035 , B01J29/70 , C01B37/02 , C10G11/05 , C10G49/08 , C10G2300/1092 , C10G2300/1096 , C10G2400/30
摘要： The invention relates to a laminar microporous crystalline zeolite material known as ITQ-30 which, as when synthesized, has a chemical composition in the anhydrous state with the following molar relations: x (M1/n XO2):y YO2:SiO2:z R, wherein: x represents a value less than 0.1, which can be equal to zero; y has a value of less than 0.1, which can be equal to zero; z has a value of less than 0.1; M is selected from among H+, NH4+, one or more +n inorganic cations and combinations of same; X represents one or more +3 oxidation state chemical elements; Y represents one or more +4 oxidation state chemical elements; and R represents one or more organic compounds. The invention also relates to the method of preparing said zeolite, involving the use of one or more organic additives in a reaction mixture which is crystallized by means of heating, and to the use thereof in processes for the separation and transformation of organic compounds.
摘要翻译：本发明涉及一种称为ITQ-30的层状微孔结晶沸石材料，其当合成时具有以下摩尔关系的无水状态的化学组成：x（M1 / n XO2）：y YO2：SiO2：zR ，其中：x表示小于0.1的值，其可以等于零; y的值小于0.1，可以等于零; z的值小于0.1; M选自H +，NH4 +，一种或多种+ n种无机阳离子及其组合; X表示一种或多种+3氧化态化学元素; Y表示一个或多个+4氧化态化学元素; R表示一种或多种有机化合物。本发明还涉及制备所述沸石的方法，涉及在通过加热结晶的反应混合物中使用一种或多种有机添加剂，以及其用于分离和转化有机化合物的方法中的用途。

9. 发明申请

US20110282099A1 PROCESS FOR THE PRODUCTION OF METHYLENE-BRIDGED POLYPHENYL POLYAMINES 有权
标题翻译：制备亚甲基桥联聚苯胺的方法
公开(公告)号：US20110282099A1
公开(公告)日：2011-11-17
申请号：US13133410
申请日：2009-11-26
申请人： Christopher John Mitchell , Avelino Corma Canos , Robert Henry Carr , Pablo Botella Asuncion
发明人： Christopher John Mitchell , Avelino Corma Canos , Robert Henry Carr , Pablo Botella Asuncion
IPC分类号： C07C211/51
CPC分类号： C07C209/60 , C07C209/78 , C07C211/50
摘要： A process for providing methylene-bridged polyphenyl polyamines from aniline and formaldehyde according to the invention comprises the subsequent steps ofa) condensing aniline and formaldehyde, providing a condensate, the molar ratio of aniline to formaldehyde being chosen in the range of 2 to 3.5;b) reacting, in a first catalytic reaction step, at a reaction temperature within the range of about 30° C. to about 100° C., said condensate over a solid catalyst being chosen from the group consisting of clays, silicates, silica-aluminas and ion exchange resins, whereby an intermediate mixture is provided, the intermediate mixture comprising amino benzyl amines;c) converting, in a subsequent catalytic reaction step, at a temperature within the range of about 70° C. to about 250° C., the reaction temperature in said subsequent catalytic reaction step is higher than the reaction temperature in said first catalytic reaction step, said intermediate mixture into methylene-bridged polyphenyl polyamines in presence of a subsequent solid catalyst being chosen from the group consisting of zeolites, delaminated zeolites and ordered mesoporous materials, thereby providing said methylene-bridged polyphenyl polyamines.
摘要翻译：根据本发明的由苯胺和甲醛提供亚甲基桥接的聚苯胺的方法包括以下步骤：a）使苯胺和甲醛缩合，提供缩合物，苯胺与甲醛的摩尔比选择在2至3.5的范围内; b）在第一催化反应步骤中，在约30℃至约100℃范围内的反应温度下使所述缩合物在固体催化剂上选自粘土，硅酸盐，二氧化硅 - 氧化铝和离子交换树脂，由此提供中间体混合物，所述中间体混合物包含氨基苄基胺; c）在随后的催化反应步骤中，在约70℃至约250℃的温度范围内转化，所述后续催化反应步骤中的反应温度高于所述第一催化反应中的反应温度在随后的固体催化剂存在下将所述中间体混合物形成亚甲基桥连的聚苯胺，所述固体催化剂选自沸石，分层沸石和有序介孔材料，从而提供所述亚甲基桥连的聚苯基多胺。

10. 发明申请

US20110014103A1 PREPARATION OF DESULPHURISATION MATERIALS 有权
标题翻译：脱硫材料的制备
公开(公告)号：US20110014103A1
公开(公告)日：2011-01-20
申请号：US12922347
申请日：2009-02-25
申请人： Norman Macleod , Antonio Chica Lara , Avelino Corma Canos , Yonhy Saavedra Lopez
发明人： Norman Macleod , Antonio Chica Lara , Avelino Corma Canos , Yonhy Saavedra Lopez
IPC分类号： B01D53/52 , B01J27/236
CPC分类号： B01J23/007 , B01D53/8609 , B01D53/8612 , B01D2255/2092 , B01D2257/304 , B01D2257/306 , B01D2257/308 , B01D2258/06 , B01J23/80 , C01F7/002 , C01F7/005 , C01G9/00 , C01G9/02 , C01P2002/22 , C01P2002/52 , C01P2002/54 , C01P2002/72 , C01P2004/82 , C01P2006/12 , C10G25/003 , C10G45/04 , C10L3/10
摘要： A process for the preparation of a desulphurisation material includes:forming a zinc/aluminium hydrotalcite composition, and (ii) calcining the composition to form a zinc oxide/alumina material, in which one or more nickel compounds are included in the hydrotalcite formation step, and/or are impregnated onto the hydrotalcite composition and/or the calcined zinc oxide/alumina material, and the resulting composition dried and recovered.
摘要翻译：制备脱硫材料的方法包括：形成锌/铝水滑石组合物，和（ii）煅烧所述组合物以形成氧化锌/氧化铝材料，其中在水滑石形成步骤中包括一种或多种镍化合物，和/或浸渍在水滑石组合物和/或煅烧氧化锌/氧化铝材料上，并将所得组合物干燥和回收。

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