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1. 发明申请

US20100099894A1 Method for the Synthesis of Cyclic Acetals by the Reactive Extraction of a Polyol in a Concentrated Solution 审中-公开
标题翻译：通过多元醇在浓缩溶液中反应萃取合成环缩醛的方法
公开(公告)号：US20100099894A1
公开(公告)日：2010-04-22
申请号：US12445030
申请日：2007-10-08
申请人： Jean-Luc Dubois , Sara Iborra Chornet , Alexandra I. Lucienne Velty , Avelino Corma Canos
发明人： Jean-Luc Dubois , Sara Iborra Chornet , Alexandra I. Lucienne Velty , Avelino Corma Canos
IPC分类号： C07D319/06 , C07D317/10
CPC分类号： C07D317/20 , C07D319/06
摘要： A method for the synthesis of cyclic acetals comprises reacting at least one carbonyl-function compound selected from aldehydes, ketones, and/or linear acetals, on a polyol in a concentrated aqueous solution exceeding 20 wt % in a reactor containing an acidic catalyst. The carbonyl-function compound is selected so that the cyclic acetal obtained has a water solubility lower than 20000 mg/kg. During the catalytic reaction for the cyclic acetal synthesis, at least one portion of the organic phase containing the cyclic acetal is separated. The acidic catalysis is either homogeneous when using a water-soluble strong acid, or heterogeneous when using a solid acid such as a resin, a zeolite, or any appropriately acidified solid. The extractive reaction method can be used for obtaining high conversions and selectivity.
摘要翻译：合成环状缩醛的方法包括在含有酸性催化剂的反应器中，使至少一种选自醛，酮和/或直链缩醛的羰基官能化合物在多元醇上浓缩超过20重量％的浓缩水溶液中。选择羰基官能化合物，使得得到的环状缩醛的水溶解度低于20000mg / kg。在环缩醛合成的催化反应期间，分离含有环缩醛的至少一部分有机相。当使用水溶性强酸时，酸性催化剂是均匀的，或当使用固体酸如树脂，沸石或任何适当酸化的固体时是非均相的。萃取反应方法可用于获得高转化率和选择性。

2. 发明授权

US6114587A Process and catalyst for the selective production of .alpha.-alkylcinnamaldehyde 失效
标题翻译：用于选择性生产α-烷基肉桂醛的方法和催化剂
公开(公告)号：US6114587A
公开(公告)日：2000-09-05
申请号：US171158
申请日：1999-02-02
申请人： M.sup.a Jose Climent Olmedo , Rut Guil Lopez , Sara Iborra Chornet , Jaime Primo Millo , Avelino Corma Canos
发明人： M.sup.a Jose Climent Olmedo , Rut Guil Lopez , Sara Iborra Chornet , Jaime Primo Millo , Avelino Corma Canos
IPC分类号： B01J29/06 , B01J29/04 , C07B61/00 , C07C45/51 , C07C45/68 , C07C47/232 , C07C45/45
CPC分类号： C07C45/515 , B01J29/04
摘要： The selective obtainment of .alpha.-alkyl cinnamaldehydes, such as Jasmine aldehyde is carried out by a process that involves two consecutive reactions: acetalization of an n-alkyl aldehyde by direct reaction with an alcohol or by transacetalization followed by the reaction between said acetal and aromatic aldehyde such as benzaldehyde using molecular sieves with regular pore distribution in the range of micro and mesopores and between 6 and 100 .ANG. as acid catalysts.
摘要翻译： PCT No.PCT / ES98 / 00017 Sec。 371日期1998年2月2日 102（e）1998年2月2日PCT 1998年1月23日PCT PCT。出版物WO98 / 3592800 日期1998年8月20日选择性获得α-烷基肉桂醛如茉莉醛通过涉及两个连续反应的方法进行：通过与醇的直接反应缩醛化正烷基醛或通过反式缩合反应在所述缩醛和芳族醛之间，例如苯甲醛，使用在微孔和介孔范围内具有规则孔分布的分子筛和作为酸催化剂的6至100安格姆。

3. 发明申请

US20100312018A1 Processes for Producing Levosandal and Levosandol 审中-公开
标题翻译：产生左旋糖和左旋糖酐的方法
公开(公告)号：US20100312018A1
公开(公告)日：2010-12-09
申请号：US12753279
申请日：2010-04-02
申请人： Avelino Corma Canos , Sara Iborra Chornet , Alexandra Velty
发明人： Avelino Corma Canos , Sara Iborra Chornet , Alexandra Velty
IPC分类号： C07C45/74 , C07C29/159
CPC分类号： C07C29/14 , C07C45/74 , C07C2601/10 , C07C33/12 , C07C47/225
摘要： The present invention relates to processes for producing 2-ethyl-4-(2,2,3-trimethyl-3-cyclopenten-1-yl)-2-butenal and 2-ethyl-4-(2,2,3-trimethyl-3-cyclopenten-1-yl)-2-buten-1-ol using heterogeneous bifunctional catalysts with a good yield. There is provided a process for producing 2-ethyl-4-(2,2,3-trimethyl-3-cyclopenten-1-yl)-2-butenal by the cross-aldol condensation between campholenic aldehyde and butanal using bifunctional heterogeneous catalysts in the presence of controlled amounts of an aliphatic alcohol; and a process for producing 2-ethyl-4-(2,2,3-trimethyl-3-cyclopenten-1-yl)-2-buten-1-ol useful as perfume, starting from 2-ethyl-4-(2,2,3-trimethyl-3-cyclopenten-1-yl)-2-butenal through a MPV reduction using an acid-base bifunctional heterogeneous catalyst. Both process can be coupled in a cascade process which involves the cross-aldol condensation between campholenic aldehyde and butanal followed by the Meerwein-Ponndorf-Verley (MPV) reduction in the presence of a secondary alcohol using the same heterogeneous bifunctional catalyst for obtaining (2-ethyl-4-(2,2,3-trimethyl-3-cyclopenten-1-yl)-2-buten-1-ol).
摘要翻译：本发明涉及2-乙基-4-（2,2,3-三甲基-3-环戊烯-1-基）-2-丁烯醛和2-乙基-4-（2,2,3-三甲基 -3-环戊烯-1-基）-2-丁烯-1-醇，使用异构双官能催化剂，产率很高。提供了一种通过使用双功能非均相催化剂在camp醛和丁醛之间的交换醛醇缩合产生2-乙基-4-（2,2,3-三甲基-3-环戊烯-1-基）-2-丁烯醛的方法存在受控量的脂族醇; 和用作香料的2-乙基-4-（2,2,3-三甲基-3-环戊烯-1-基）-2-丁烯-1-醇的制备方法，由2-乙基-4-（2 ，2,3-三甲基-3-环戊烯-1-基）-2-丁烯醛，通过使用酸碱双功能多相催化剂的MPV还原。这两种方法可以在级联方法中偶合，其涉及在醛醇和丁醛之间的交叉醛醇缩合，随后在仲醇存在下使用相同的异构双功能催化剂还原Meerwein-Ponndorf-Verley（MPV）以获得（2 - 乙基-4-（2,2,3-三甲基-3-环戊烯-1-基）-2-丁烯-1-醇）。

4. 发明授权

US07312355B2 Method of preparing fatty acid monoesters 有权
公开(公告)号：US07312355B2
公开(公告)日：2007-12-25
申请号：US11403142
申请日：2006-04-12
申请人： Avelino Corma Canòs , Sara Iborra Chornet , Alexandra Isabelle Velty , Sharifah Bee Abd Hamid
发明人： Avelino Corma Canòs , Sara Iborra Chornet , Alexandra Isabelle Velty , Sharifah Bee Abd Hamid
IPC分类号： C07C67/02
CPC分类号： C11C3/04 , C07C67/03 , C07C69/24 , C07C69/52
摘要： The invention relates to a method of producing fatty acid monoesters and polyhydroxylic alcohols by means of transesterification between a polyhydroxylic alcohol and a compound that is selected from a fat of animal origin, a fat of vegetable origin, and a fatty acid methyl ester. The invention is characterised in that the transesterification reaction is performed in the presence of basic solid catalysts, said basic solids being oxides that are selected from mixed oxides of one or more monovalent metals and one or more trivalent metals, mixed oxides of one or more divalent metals and one or more trivalent metals, and mixtures of same.

5. 发明申请

US20070092439A1 Method of preparing monoesters of polyhydroxyl alcohols 审中-公开
标题翻译：制备多羟基醇单酯的方法
公开(公告)号：US20070092439A1
公开(公告)日：2007-04-26
申请号：US11489252
申请日：2006-07-19
申请人： Avelino Corma Canos , Sara Iborra Chornet , Alexandra Velty , Sharifah Bee Abd Hamid
发明人： Avelino Corma Canos , Sara Iborra Chornet , Alexandra Velty , Sharifah Bee Abd Hamid
IPC分类号： C01B39/00
CPC分类号： C07D493/04 , C07D307/20
摘要： The invention relates to a method of preparing monoesters of polyhydroxyl alcohols. The inventive method comprises a first step consisting in protecting the hydroxyl groups of a polyhydroxyl alcohol by means of acetalisation and a second step comprising the sterification of said acetalised polyhydroxyl alcohol with a fatty acid in the presence of one or more solid acid catalysts.
摘要翻译：本发明涉及一种制备多羟基醇单酯的方法。本发明的方法包括第一步，通过缩醛化保护多羟基醇的羟基，第二步包括在一种或多种固体酸催化剂存在下用脂肪酸灭菌所述缩醛化的多羟基醇。

6. 发明授权

US07087779B2 Aldehyde conversion method using a molecular sieve and the use of the molecular sieve as a catalyst in said method 失效
标题翻译：使用分子筛的醛转化方法和在所述方法中使用分子筛作为催化剂
公开(公告)号：US07087779B2
公开(公告)日：2006-08-08
申请号：US10932564
申请日：2004-09-02
申请人： Avelino Corma Canos , María Mifsud Grau , Sara Iborra Chornet , Michael Renz
发明人： Avelino Corma Canos , María Mifsud Grau , Sara Iborra Chornet , Michael Renz
IPC分类号： C07D331/02 , C07D301/12 , C07C69/76
CPC分类号： C07C51/285 , B01J29/0308 , B01J29/035 , B01J29/04 , B01J29/7057 , C01B37/005 , C01B39/085 , C07C51/235 , C07C67/39 , C07C63/04 , C07C65/21 , C07C69/017 , C07C69/08 , C07C69/10
摘要： The invention relates to an aldehyde conversion method comprising putting an aldehyde into contact with oxygenated water and with a catalyst, under oxidation conditions, wherein the catalyst is a molecular sieve with pores of a diameter of at least 0.52 nm and has an empirical formula in a calcined and dehydrated form of (SnxTiySi1-x-y-zGez)O2 wherein x is a molar fraction of the tin and has a value between 0.001 and 0.1; y is a molar fraction of titanium and has a value from zero to 0.1; and z is the molar fraction molar of the germanium and has a value from zero to 0.08.
摘要翻译：本发明涉及醛转化方法，其包括在氧化条件下将醛与含氧水和催化剂接触，其中催化剂是直径为至少0.52nm的孔的分子筛，并且具有经验式煅烧和脱水形式的<？in-line-formula description =“In-line Formulas”end =“lead”？（Sn x x Ti x Si x Si α-in-line-formula description =“In-line Formulas”end =“tail”？>其中x（x，y）是锡的摩尔分数，其值在0.001和0.1之间; y是钛的摩尔分数，其值为0至0.1; z是锗的摩尔分数摩尔，其值为零至0.08。

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