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1. 发明授权

US4572796A 1,1,4,7-Tetramethyl-3-indanone, product produced thereby and organoleptic uses thereof 失效
标题翻译： 1,1,4,7-四甲基-3-二氢茚酮，由此生产的产品及其感官用途
公开(公告)号：US4572796A
公开(公告)日：1986-02-25
申请号：US671407
申请日：1984-11-14
申请人： Augustinus G. van Loveren , Mark A. Sprecker , Patrick Whelan , Marie R. Hanna
发明人： Augustinus G. van Loveren , Mark A. Sprecker , Patrick Whelan , Marie R. Hanna
IPC分类号： C07C45/36 , C07C49/67 , C11B9/00 , A61K7/46
CPC分类号： C11B9/0049 , C07C45/36 , C07C49/67 , C07C2102/08
摘要： Described is a process for producing 1,1,4,7-tetramethyl-3-indanone defined according to the structure: ##STR1## the 1,1,4,7-tetramethyl-3-indanone per se and organoleptic uses thereof in augmenting or enhancing the aroma of perfume compositions, perfumed articles and colognes.
摘要翻译：描述了根据以下结构限定的1,1,4,7-四甲基-3-二氢茚酮的方法：本文所述的1,1,4,7-四甲基-3-二氢茚酮及其增感的感官用途或增强香水组合物，香水制品和古龙水的香气。

2. 发明授权

US4532357A Process for producing 1,1-dimethyl-3-indanones, products produced thereby and organoleptic uses thereof 失效
标题翻译：制备1,1-二甲基-3-茚满酮的方法，由此生产的产品及其感官用途
公开(公告)号：US4532357A
公开(公告)日：1985-07-30
申请号：US613570
申请日：1984-05-24
申请人： Augustinus G. van Loveren , Mark A. Sprecker , Patrick Whelan , Marie R. Hanna
发明人： Augustinus G. van Loveren , Mark A. Sprecker , Patrick Whelan , Marie R. Hanna
IPC分类号： C07C2/72 , C07C45/36 , C07C49/67 , C11B9/00 , C07C49/15 , A61K7/46
CPC分类号： C11B9/0049 , C07C2/72 , C07C45/36 , C07C49/67 , C07C2102/08
摘要： Described is a process for producing 1,1-dimethyl-3-indanones defined according to the structure: ##STR1## wherein R.sub.1 and R.sub.2 are the same or different and each represents hydrogen or methyl with the proviso that at least one of R.sub.1 and R.sub.2 methyl, products produced thereby and organoleptic uses thereof in augmenting or enhancing the aroma of perfume compositions, perfumed articles and colognes.
摘要翻译：描述了根据以下结构定义的1,1-二甲基-3-茚满酮的方法：其中R 1和R 2相同或不同，并且各自表示氢或甲基，条件是R 1和R 2中的至少一个甲基，由此产生的产品及其感官用途，以增强或增强香水组合物，香料制品和古龙水的香味。

3. 发明授权

US4549982A 1-Oxoalkyl-2-isopropylnorbornane derivatives, uses thereof in augmenting or enhancing the aroma of consumable materials and processes for preparing same 失效
标题翻译： 1-氧代烷基-2-异丙基降冰片烷衍生物，其用于增强或增强消耗材料的香气及其制备方法
公开(公告)号：US4549982A
公开(公告)日：1985-10-29
申请号：US644058
申请日：1984-08-24
申请人： John B. Hall , Mark A. Sprecker , Robert P. Belko , Augustinus G. Van Loveren , Marie R. Hanna
发明人： John B. Hall , Mark A. Sprecker , Robert P. Belko , Augustinus G. Van Loveren , Marie R. Hanna
IPC分类号： C07C31/137 , C07C33/12 , C07C45/62 , C07C45/69 , C07C49/323 , C07C49/553 , C11B9/00 , C07C49/115 , A61K7/46
CPC分类号： C11B9/0046 , C07C31/137 , C07C33/12 , C07C45/62 , C07C45/69 , C07C49/323 , C07C49/553
摘要： Described are 1-oxoalkyl-2-isopropylnorbornane derivatives defined according to the generic structure: ##STR1## wherein X represents a moiety selected from the group consisting of: ##STR2## wherein the dashed line represents a carbon-carbon double bond or a carbon-carbon single bond and wherein R.sub.1 and R.sub.2 represent hydrogen or methyl with the proviso that R.sub.1 and R.sub.2 are not both methyl, and uses thereof in augmenting or enhancing the aroma of consumable materials selected from the group consisting of perfume compositions, colognes and perfumed articles. Also described are processes for preparing said 1-oxoalkyl-2-isopropylnorbornane derivatives by means of a low temperature catalytic Diels Alder reaction or high temperature thermal Diels Alder reaction between a bicyclopentadiene derivative and 2-methyl-3- buten-5-one according to the reaction: ##STR3## wherein R represents methyl or hydrogen.
摘要翻译：描述根据以下通用结构定义的1-氧代烷基-2-异丙基降冰片烷衍生物：其中X表示选自以下的部分：其中虚线表示碳 - 碳双键或碳 - 碳单键，其中R 1和R 2表示氢或甲基，条件是R 1和R 2不是甲基，以及其用于增强或增强从由香料组合物，古龙水和香料制品组成的组中选择的可消耗材料的香气的用途。还描述了通过低温催化Diels Alder反应或双环戊二烯衍生物与2-甲基-3-丁烯-5-酮之间的高温热狄尔斯阿尔德反应制备所述1-氧代烷基-2-异丙基降冰片烷衍生物的方法，根据反应：其中R表示甲基或氢。

4. 发明授权

US4524020A Isopropyl substituted cyclohexenyl methyl ketones and perfumery uses thereof 失效
标题翻译：异丙基取代的环己烯基甲基酮及其香料用途
公开(公告)号：US4524020A
公开(公告)日：1985-06-18
申请号：US643827
申请日：1984-08-24
申请人： Mark A. Sprecker , Robert P. Belko , Augustinus G. Van Loveren , Marie R. Hanna
发明人： Mark A. Sprecker , Robert P. Belko , Augustinus G. Van Loveren , Marie R. Hanna
IPC分类号： C07C45/69 , C07C49/543 , C11B9/00 , A61K7/46 , C07C49/21
CPC分类号： C11B9/0034 , C07C45/69 , C07C49/543
摘要： Described are isopropyl substituted cyclohexenyl methyl ketones defined according to the structure: ##STR1## wherein R.sub.1, R.sub.2, R.sub.11 and R.sub.21 each represents hydrogen or methyl with the provisos that:(a) at least two of R.sub.1, R.sub.21, R.sub.2 and R.sub.11 represent hydrogen;(b) either R.sub.2 is methyl and R.sub.21 is hydrogen or R.sub.21 is methyl and R.sub.2 is hydrogen; and(c) R.sub.1 is methyl only when R.sub.2 is methyl and R.sub.11 is methyl only when R.sub.21 is methyl,as well as uses thereof in augmenting or enhancing the aroma of perfume compositions, colognes and perfumed articles including solid or liquid anionic, cationic, nonionic or zwitterionic detergents, fabric softener compositions, fabric softener articles, hair preparations and perfumed polymers.
摘要翻译：描述了根据以下结构定义的异丙基取代的环己烯基甲基酮：其中R 1，R 2，R 11和R 21各自表示氢或甲基，条件是：（a）R 1，R 21，R 2和R 11中的至少两个表示氢 ; （b）R2是甲基，R21是氢或R21是甲基，R2是氢; 和（c）仅当R 2为甲基时，R 1为甲基，R 21为甲基时，R 21为甲基时，R 11为甲基，以及其用于增强或增强香料组合物，古龙水和香料的芳香物质的用途，包括固体或液体阴离子，阳离子，非离子或两性离子洗涤剂，织物柔软剂组合物，织物柔软剂制品，头发制剂和加香聚合物。

5. 发明授权

US4622171A Polyhydroindan carboxaldehydes and uses thereof in augmenting or enhancing the aromas of perfume compositions, colognes and perfumed articles 失效
公开(公告)号：US4622171A
公开(公告)日：1986-11-11
申请号：US712164
申请日：1985-03-15
申请人： Mark A. Sprecker , William L. Schreiber , Futoshi Fujioka , Richard M. Boden , Manfred H. Vock , Patrick Whelan , Marie R. Hanna
发明人： Mark A. Sprecker , William L. Schreiber , Futoshi Fujioka , Richard M. Boden , Manfred H. Vock , Patrick Whelan , Marie R. Hanna
IPC分类号： C07C45/49 , C07C45/50 , C07C47/36 , C07C47/37 , C07C47/445 , C07C49/523 , C11B9/00 , A61K7/46
CPC分类号： C11B9/0042 , C07C45/49 , C07C45/50 , C07C47/36 , C07C47/37 , C07C47/445 , C07C49/523
摘要： Described is the genus of polyhydroindan carboxaldehydes defined according to the structure: ##STR1## wherein each of the dashed lines represent carbon-carbon single bonds or carbon-carbon double bonds with the proviso that at least one of the dashed lines represents a carbon-carbon single bond; wherein one of R.sub.1, R.sub.2 and R.sub.3 is hydrogen or methyl and each of the other of R.sub.1, R.sub.2 and R.sub.3 represents hydrogen; wherein one of R.sub.4, R.sub.5 and R.sub.6 represents hydrogen or methyl and each of the other of R.sub.4, R.sub.5 and R.sub.6 represents hydrogen; wherein m is 0 or 1 and n is 0 or 1 and the sum of m+n=1; wherein X' represents one of the moieties: ##STR2## wherein R.sub.7 represents C.sub.1 -C.sub.3 alkyl or acetyl; and wherein R.sub.8 represents C.sub.1 -C.sub.3 alkyl, with the proviso that when X' is methylene having the structure: ##STR3## then m is 0 and n is 1 and with the further proviso that when n is 0, one of the dashed lines is a carbon-carbon double bond; and one of R.sub.1, R.sub.2 and R.sub.3 represents methyl and one of R.sub.4, R.sub.5, and R.sub.6 represents methyl, and uses thereof in augmenting or enhancing the aroma of perfume compositions, colognes and perfumed articles (e.g., solid or liquid anionic, cationic, nonionic or zwitterionic detergents, fabric softener compositions, fabric softener articles, perfumed polymers and cosmetic powders). Also described is a process for preparing such polyhydroindan carboxaldehydes by reacting a tricyclic compound or mixture of compounds defined according to the structure: ##STR4## with carbon monoxide and hydrogen via an "oxo" reaction; wherein R.sub.1, R.sub.2, R.sub.3, R.sub.4 and R.sub.5 are defined, supra; wherein one of the dashed lines represents a carbon-carbon single bond and the other of the dashed lines represents a carbon-carbon double bond; wherein X" represents one of the moieties: with the proviso that when X' is methylene having the structure: ##STR5## then the line:+++++is a double bond and when X' is not methylene having the structure: ##STR6## then the line:+++++is a carbon-carbon single bond.

6. 发明授权

US4541949A Polyhydroindan carboxaldehydes 失效
标题翻译：聚氢化二氢甲醛
公开(公告)号：US4541949A
公开(公告)日：1985-09-17
申请号：US528568
申请日：1983-09-01
申请人： Mark A. Sprecker , William L. Schreiber , Futoshi Fujioka , Richard M. Boden , Manfred H. Vock , Patrick Whelan , Marie R. Hanna
发明人： Mark A. Sprecker , William L. Schreiber , Futoshi Fujioka , Richard M. Boden , Manfred H. Vock , Patrick Whelan , Marie R. Hanna
IPC分类号： C07C45/49 , C07C45/50 , C07C47/36 , C07C47/37 , C07C47/445 , C07C49/523 , C11B9/00 , A61K7/46
CPC分类号： C11B9/0042 , C07C45/49 , C07C45/50 , C07C47/36 , C07C47/37 , C07C47/445 , C07C49/523
摘要： Described is the composition of matter defined according to the structure: ##STR1## as well as components of such composition having the structures: ##STR2## and uses thereof in augmenting or enhancing the aroma of perfume compositions, colognes and perfumed articles.
摘要翻译：描述了根据以下结构定义的物质的组成：以及具有以下结构的这种组合物的组分：＆lt; IMAGE＆gt; + TR＆lt; IMAGE＆gt;＆gt;及其用于增强或增强香料组合物的香气，古龙水和香水文章。

7. 发明授权

US4636333A Alkoxy-substituted polyhydroindan carboxaldehydes 失效
标题翻译：烷氧基取代的多羟基茚满羧醛
公开(公告)号：US4636333A
公开(公告)日：1987-01-13
申请号：US837386
申请日：1986-03-07
申请人： Mark A. Sprecker , William L. Schreiber , Futoshi Fujioka , Richard M. Boden , Manfred H. Vock , Patrick Whelan , Marie R. Hanna
发明人： Mark A. Sprecker , William L. Schreiber , Futoshi Fujioka , Richard M. Boden , Manfred H. Vock , Patrick Whelan , Marie R. Hanna
IPC分类号： C07C45/49 , C07C45/50 , C07C47/36 , C07C47/37 , C07C47/445 , C07C49/523 , C11B9/00 , A61K7/46
CPC分类号： C11B9/0042 , C07C45/49 , C07C45/50 , C07C47/36 , C07C47/37 , C07C47/445 , C07C49/523
摘要： Described is a mixture of polyhydroindan carboxaldehydes defined according to the structure: ##STR1## wherein R.sub.7 represents a moiety selected from the group consisting of methyl and isopropyl prepared by means of reacting bicyclopentadiene with a lower alkanol in the presence of a Lewis acid in order to form a mixture of compounds defined according to the structure: ##STR2## and then reacting the resulting ether with carbon monoxide and hydrogen in the presence of an "oxo" reaction catalyst.
摘要翻译：描述了根据以下结构定义的多羟基茚基甲醛的混合物：其中R 7表示选自甲基和异丙基的部分，其通过在路易斯酸存在下通过双环戊二烯与低级链烷醇反应制备，以便形成根据以下结构定义的化合物的混合物：，然后在“氧代”反应催化剂存在下，使所得的醚与一氧化碳和氢气反应。

8. 发明授权

US4585582A Perfumery uses of 2-n-pentyl-2-cyclohexen-1-one 失效
标题翻译：香精使用2-正戊基-2-环己烯-1-酮
公开(公告)号：US4585582A
公开(公告)日：1986-04-29
申请号：US709917
申请日：1985-03-08
申请人： Augustinus G. van Loveren , Mark A. Sprecker
发明人： Augustinus G. van Loveren , Mark A. Sprecker
IPC分类号： C07C45/66 , C07C45/67 , C07C45/72 , C07C49/603 , C11B9/00 , A61K7/46
CPC分类号： C11B9/0034 , C07C45/66 , C07C45/67 , C07C45/72 , C07C49/603
摘要： Described is 2-n-pentyl-2-cyclohexen-1-one having the structure: ##STR1## useful in augmenting or enhancing the aroma of consumable materials including perfume compositions, colognes, and perfumed articles including solid or liquid anionic, cationic, nonionic or zwitterionic detergents, fabric softeners, fabric softener articles as well as hair sprays, shampoos, bath oils and perfumed polymers.
摘要翻译：描述了具有以下结构的2-正戊基-2-环己烯-1-酮：可用于增强或增强消耗材料的香气，包括香料组合物，古龙水和香料制品，包括固体或液体阴离子，阳离子，非离子表面活性剂或两性离子洗涤剂，织物柔软剂，织物柔软剂制品以及发胶，洗发剂，浴油和加香聚合物。

9. 发明授权

US07169747B2 Bicyclic lactones, perfumery uses thereof, processes for preparing same and intermediates therefor 有权
标题翻译：双环内酯，其香料用途，其制备方法及其中间体
公开(公告)号：US07169747B2
公开(公告)日：2007-01-30
申请号：US10705786
申请日：2003-11-10
申请人： Richard A. Weiss , Mark A. Sprecker , Marie R. Hanna , Charles E. J. Beck , Harold W. Jackson
发明人： Richard A. Weiss , Mark A. Sprecker , Marie R. Hanna , Charles E. J. Beck , Harold W. Jackson
IPC分类号： A61K7/46
CPC分类号： A61K8/498 , A61L9/01 , A61L9/012 , A61Q13/00 , C07D311/02 , C07D311/74 , C11B9/008 , C11D3/2096 , C11D3/50
摘要： Described are bicyclic lactones, both fused ring lactones defined according to the generic structure: and spiro lactones defined according to the generic structure: uses thereof in augmenting, enhancing or imparting aromas in or to perfume compositions, perfumed articles, colognes and perfumed polymers; processes for preparing such bicyclic lactones and intermediates therefor. In the structure: Z is one of the moieties: one of R1 or R3 is methyl and the other is hydrogen; and R4, R5, R6, R7, R8 and R9 hydrogen or nonadjacent C1–C3 alkyl. In the structure: Y represents C2–C12 substituted or unsubstituted alkylidenyl, alkenylidenyl or alkadienylidenyl having the structure: and completes a C5–C15 cycloalkyl, cycloalkadienyl or cycloalkenyl ring moiety; and wherein R12, R13, R14, R16, R17, R28, R29, R30 and R31 represent hydrogen or C1–C3 nonadjacent alkyl; wherein s is an integer of from 0 up to 10; t is an integer of from 0 up to 10; and v is an integer of 1 or 2; with the proviso that the sum of s and t is between 0 and 10 according to the inequalities: 0≦s+t≦10; 0≦S≦10; and 0≦t≦10.
摘要翻译：描述的是双环内酯，根据通用结构定义的稠环内酯和根据通用结构定义的螺内酯：用于增强，增强或赋予香料组合物，香料制品，古龙水和加香聚合物中的香气; 制备此类双环内酯的方法及其中间体。在结构中：Z是部分之一：R 1或R 3中的一个是甲基，另一个是氢; 和R 4，R 5，R 6，R 7，R 8，和R 9的氢或不相邻的C 1 -C 3烷基。在结构中：Y表示具有以下结构的取代或未取代的亚烷基，亚烯基或链二烯基的取代或未取代的C 1 -C 12 - C 15环烷基，环链二烯基或环烯基环部分; 并且其中R 12，R 13，R 14，R 16，R 17， >，R 28，R 29，R 30和R 31表示氢或C 1〜 N 3 -C 3不相邻的烷基; 其中s为0至10的整数; t是0到10的整数; v为1或2的整数; 条件是根据不等式，s和t之和在0和10之间：0 <= s + t <= 10; 0 <= S <= 10; 0 <= t <= 10。

10. 发明授权

US06310032B1 &agr;-Oxygen-substituted cyclohexane propionitriles, perfumery uses thereof and processes for preparing same 有权
标题翻译： α-氧代取代的环己烷丙腈，其香料用途及其制备方法
公开(公告)号：US06310032B1
公开(公告)日：2001-10-30
申请号：US09517603
申请日：2000-03-02
申请人： Mark A. Sprecker , Richard A. Weiss , Marie R. Hanna , Charles E. J. Beck
发明人： Mark A. Sprecker , Richard A. Weiss , Marie R. Hanna , Charles E. J. Beck
IPC分类号： A61K746
CPC分类号： C11B9/0061 , C11B9/0034
摘要： Described are &agr;-oxygen-substituted cyclohexane propionitriles having the structure: wherein R20 and R21 are the same or different C1-C3 lower alkoxy; or wherein R20 is hydrogen and R21 is hydroxy, C1-C3 lower alkoxy or C1-C3 lower acyloxy; and wherein R1, R2, R3, R4, R5, R6 and R7 are the same or different hydrogen or C1-C4 lower alkyl, and uses thereof for their organoleptic properties in augmenting or enhancing or imparting aromas in or to perfume compositions, colognes, microporous polymers or perfumed articles including solid or liquid anionic, cationic, nonionic or zwitterionic detergents, fabric softener compositions, fabric softener articles, hair care compositions and the like.
摘要翻译：描述的是具有以下结构的α-氧取代的环己烷丙腈：其中R20和R21是相同或不同的C1-C3低级烷氧基; 或其中R 20是氢，R 21是羟基，C 1 -C 3低级烷氧基或C 1 -C 3低级酰氧基; 并且其中R 1，R 2，R 3，R 4，R 5，R 6和R 7是相同或不同的氢或C 1 -C 4低级烷基，以及其用于增强或增强或赋予香料组合物或香水组合物中的香气的感官特性，包括固体或液体阴离子，阳离子，非离子或两性离子洗涤剂的微孔聚合物或加香制品，织物柔软剂组合物，织物柔软剂制品，护发组合物等。

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