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1. 发明授权

US06827881B2 Conductive fluoropolymers 有权
标题翻译：导电氟聚合物
公开(公告)号：US06827881B2
公开(公告)日：2004-12-07
申请号：US10293686
申请日：2002-11-13
申请人： Attila Molnar , Steven R. Parsons , Thomas J. Blong
发明人： Attila Molnar , Steven R. Parsons , Thomas J. Blong
IPC分类号： H01B124
CPC分类号： H01B1/24 , C08F214/18 , C08L23/04 , C08L23/10 , C08L27/18 , C08L2666/04
摘要： The invention provides a melt-processable conductive fluorothermoplastic composition comprising three components. The first component is at least one melt-processable, thermoplastic fluoropolymer component having its interpolymerized units derived from (i) at least 50 wt % of TFE, and (ii) one or more ethylenically-unsaturated monomers represented by the formulas (a) CF2═CF—Rf, (b) CF2═CF—O—Rf′, and (c) CH2═CR2, wherein Rf is a perfluoroalkyl of 1 to 8 carbon atoms, Rf′ is Rf or a perfluoroalkoxy of 1 to 8 carbon atoms, and R is selected from H, F, Cl, or an aliphatic group having from 1 to 8 carbon atoms which may have F or Cl substituents. The thermoplastic fluoropolymer component is substantially free of interpolymerized units derived from VDF. The second component is from about 0.1 to about 10 weight percent of a hydrocarbon polymer, and the third component is from about 1 to about 20 weight percent of conductive filler. The invention also provides a method for making fluorothermoplastic compositions and shaped articles comprising a conductive fluorothermoplastic composition.
摘要翻译：本发明提供了包含三种组分的可熔融加工的导电性氟热塑性组合物。第一组分是至少一种可熔融加工的热塑性含氟聚合物组分，其具有衍生自（i）至少50重量％的TFE的共聚单元，和（ii）由式（a）CF 2表示的一种或多种烯键式不饱和单体 = CF-Rf，（b）CF 2 = CF-O-Rf'和（c）CH 2 = CR 2，其中Rf是1至8个碳原子的全氟烷基，Rf'是Rf或1至8个碳原子的全氟烷氧基并且R选自H，F，Cl或具有1至8个碳原子的可具有F或Cl取代基的脂族基团。热塑性含氟聚合物组分基本上不含衍生自VDF的共聚单元。第二组分为约0.1至约10重量％的烃聚合物，第三组分为约1至约20重量％的导电填料。本发明还提供了制备含氟热塑性组合物的方法和包含导电性氟热塑性组合物的成型制品。

2. 发明授权

US07387750B2 Conductive fluoropolymers 失效
标题翻译：导电氟聚合物
公开(公告)号：US07387750B2
公开(公告)日：2008-06-17
申请号：US10987777
申请日：2004-11-12
申请人： Attila Molnar , Steven R. Parsons , Thomas J. Blong
发明人： Attila Molnar , Steven R. Parsons , Thomas J. Blong
IPC分类号： H01B1/24
CPC分类号： H01B1/24 , C08F214/18 , C08L23/04 , C08L23/10 , C08L27/18 , C08L2666/04
摘要： The invention provides a melt-processable conductive fluorothermoplastic composition comprising three components. The first component is at least one melt-processable, thermoplastic fluoropolymer component having its interpolymerized units derived from (i) at least 50 wt % of TFE, and (ii) one or more ethylenically-unsaturated monomers represented by the formulas (a) CF2═CF—Rf, (b) CF2═CF—O—Rf′, and (c) CH2═CR2. The thermoplastic fluoropolymer component is substantially free of interpolymerized units derived from VDF. The second component is from about 0.1 to about 10 weight percent of a hydrocarbon polymer, and the third component is from about 1 to about 20 weight percent of conductive filler. The invention also provides a method for making fluorothermoplastic compositions and shaped articles comprising a conductive fluorothermoplastic composition.
摘要翻译：本发明提供了包含三种组分的可熔融加工的导电性氟热塑性组合物。第一组分是至少一种可熔融加工的热塑性含氟聚合物组分，其具有源自（i）至少50重量％的TFE的互聚单元，和（ii）由式（a）表示的一种或多种烯键式不饱和单体（b）CF 2 -CF-或F'，和（c ）CH 2 -CR 2 2。热塑性含氟聚合物组分基本上不含衍生自VDF的共聚单元。第二组分为约0.1至约10重量％的烃聚合物，第三组分为约1至约20重量％的导电填料。本发明还提供了一种制备含氟热塑性组合物和包含导电性氟热塑性组合物的成型制品的方法。

3. 发明授权

US06533955B1 Conductive fluoropolymers 有权
公开(公告)号：US06533955B1
公开(公告)日：2003-03-18
申请号：US09716806
申请日：2000-11-20
申请人： Attila Molnar , Steven R. Parsons , Thomas J. Blong
发明人： Attila Molnar , Steven R. Parsons , Thomas J. Blong
IPC分类号： H01B124
CPC分类号： H01B1/24 , C08F214/18 , C08L23/04 , C08L23/10 , C08L27/18 , C08L2666/04
摘要： The invention provides a melt-processable conductive fluorothermoplastic composition comprising three components. The first component is at least one melt-processable, thermoplastic fluoropolymer component having its interpolymerized units derived from (i) at least 50 wt % of TFE, and (ii) one or more ethylenically-unsaturated monomers represented by the formulas (a) CF2═CF—Rf, (b) CF2═CF—O—Rf′, and (c) CH2═CR2, wherein Rf is a perfluoroalkyl of 1 to 8 carbon atoms, Rf′ is Rf or a perfluoroalkoxy of 1 to 8 carbon atoms, and R is selected from H, F, Cl, or an aliphatic group having from 1 to 8 carbon atoms which may have F or Cl substituents. The thermoplastic fluoropolymer component is substantially free of interpolymerized units derived from VDF. The second component is from about 0.1 to about 10 weight percent of a hydrocarbon polymer, and the third component is from about 1 to about 20 weight percent of conductive filler. The invention also provides a method for making fluorothermoplastic compositions and shaped articles comprising a conductive fluorothermoplastic composition.

4. 发明申请

US20110249325A1 FLUOROPOLYMERIC MULTILAYER OPTICAL FILM AND METHODS OF MAKING AND USING THE SAME 审中-公开
标题翻译：氟聚合物多层光学膜及其制造和使用方法
公开(公告)号：US20110249325A1
公开(公告)日：2011-10-13
申请号：US13140503
申请日：2009-12-18
申请人： Sebastian F. Zehentmaier , Ludwig Mayer , Thomas J. Blong
发明人： Sebastian F. Zehentmaier , Ludwig Mayer , Thomas J. Blong
IPC分类号： G02B5/28 , B05D5/06 , B32B27/32 , B32B7/04 , G02B5/22 , B32B27/30
CPC分类号： B32B27/32 , B32B7/02 , B32B7/12 , B32B27/08 , B32B27/18 , B32B27/30 , B32B27/322 , B32B27/325 , B32B27/36 , B32B27/365 , B32B27/40 , B32B2255/10 , B32B2255/26 , B32B2264/108 , B32B2270/00 , B32B2274/00 , B32B2307/3065 , B32B2307/402 , B32B2307/5825 , B32B2307/584 , B32B2307/71 , B32B2307/712 , B32B2307/714 , B32B2307/75 , B32B2551/00 , B32B2551/08 , G02B5/0841 , G02B5/287 , G02B5/305 , Y10T428/3154 , Y10T428/31544
摘要： A multilayer optical film is provided comprising first optical layers of a first fluoropolymeric material and second optical layers of a second fluoropolymeric material wherein at least a portion of the first layers and at least a portion of the second layers are in intimate contact
摘要翻译：提供了一种多层光学膜，其包括第一含氟聚合物材料的第一光学层和第二含氟聚合物材料的第二光学层，其中第一层的至少一部分和第二层的至少一部分紧密接触

5. 发明申请

US20100051188A1 FLUOROPOLYMER CONTAINING LAMINATES 有权
标题翻译：含氟聚合物的层压板
公开(公告)号：US20100051188A1
公开(公告)日：2010-03-04
申请号：US12618837
申请日：2009-11-16
申请人： Dennis E. Hull , Joseph G. Walton , Maria P. Dillon , David B. Redmond , Mark W. Muggli , Thomas J. Blong
发明人： Dennis E. Hull , Joseph G. Walton , Maria P. Dillon , David B. Redmond , Mark W. Muggli , Thomas J. Blong
IPC分类号： B32B38/00 , B32B37/00
CPC分类号： C09J4/06 , B32B27/08 , B32B27/28 , B32B27/32 , B32B27/322 , B32B27/36 , B32B2250/24 , B32B2307/51 , B32B2307/554 , B32B2457/12 , H01L31/0203 , H01L31/0216 , H01L31/048 , H01L31/049 , Y10T156/10 , Y10T428/2495 , Y10T428/26 , Y10T428/31511 , Y10T428/3154 , Y10T428/31544 , Y10T428/31565 , Y10T428/31663 , Y10T428/31725 , Y10T428/31736 , Y10T428/3175 , Y10T428/31786 , Y10T428/31797 , Y10T428/31855 , Y10T428/31938
摘要： The multilayer film serves as a laminate. The film is a multilayered structure that, in its base form, encompasses an intermediate layer with first and second outer layer affixed to opposing sides of the intermediate layer. The first outer layer is a semi-crystalline fluoropolymer. The intermediate layer includes a polyester and the second outer layer is an olefinic polymer. The layers are bonded together in the noted order to provide the multilayer film.
摘要翻译：多层膜用作层压体。该膜是一种多层结构，其基体形式包含一中间层，其中第一外层和第二外层固定在中间层的相对侧上。第一外层是半结晶含氟聚合物。中间层包括聚酯，第二外层是烯烃聚合物。这些层以指定的顺序结合在一起以提供多层膜。

6. 再颁专利

USRE40902E1 Tetrafluoroethylene/hexafluoropropylene copolymers with higher drawability 有权
标题翻译：具有较高拉伸性的四氟乙烯/六氟丙烯共聚物
公开(公告)号：USRE40902E1
公开(公告)日：2009-09-01
申请号：US11930397
申请日：2007-10-31
申请人： Ralph Kaulbach , Albert Killich , Friedrich Kloos , Gernot Loehr , Ludwig Mayer , Erik Peters , Thomas J. Blong , Denis Duchesne
发明人： Ralph Kaulbach , Albert Killich , Friedrich Kloos , Gernot Loehr , Ludwig Mayer , Erik Peters , Thomas J. Blong , Denis Duchesne
IPC分类号： C08F214/26 , C08F214/28 , C08F214/18
CPC分类号： C08F214/26 , B29C47/0004 , B29C47/0016 , B29C47/0021 , B29C47/0023 , B29K2027/18 , B29L2031/3462 , C08F8/22
摘要： A tetrafluoroethylene/hexafluoropropylene copolymer with high drawability is provided. Also provided is a process employing the polymer and an article coated with the polymer.
摘要翻译：提供了具有高拉伸性的四氟乙烯/六氟丙烯共聚物。还提供了使用聚合物和涂覆有聚合物的制品的方法。

7. 再颁专利

USRE40516E1 Composite articles including a fluoropolymer blend 有权
标题翻译：包括含氟聚合物共混物的复合制品
公开(公告)号：USRE40516E1
公开(公告)日：2008-09-23
申请号：US10241660
申请日：2002-09-11
申请人： Edward E. Parsonage , Thomas J. Blong
发明人： Edward E. Parsonage , Thomas J. Blong
IPC分类号： B32B27/00 , B32B27/38 , B32B27/30 , B32B27/34 , C08L27/12
CPC分类号： B32B27/08 , B32B1/02 , B32B1/08 , B32B27/20 , B32B27/28 , B32B27/281 , B32B27/288 , B32B27/30 , B32B27/302 , B32B27/304 , B32B27/308 , B32B27/32 , B32B27/34 , B32B27/36 , B32B27/365 , B32B27/40 , B32B2270/00 , B32B2327/12 , B32B2439/00 , B32B2597/00 , Y10T428/1393 , Y10T428/24942 , Y10T428/31504 , Y10T428/31507 , Y10T428/3154 , Y10T428/31544
摘要： A composite article is provided which includes a blend component comprising a vinylidene fluoride containing fluoropolymer and a substantially non-vinylidene fluoride containing fluoropolymer, and a component including a substantially non-fluorinated polymer having pendant amine groups intimately bonded to the blend component. Increased adhesion is observed by a greater peel strength value between the blend component and a substantially non-vinylidene fluoride containing fluoropolymer when compared to a peel strength value between a substantially non-vinylidene fluoride containing fluoropolymer and the substantially non-fluorinated polymer having pendant amine groups.
摘要翻译：提供了一种复合制品，其包括包含含偏二氟乙烯的含氟聚合物和基本上不含偏氟乙烯的含氟聚合物的共混组分，以及包含基本上非氟化的聚合物的组分，所述聚合物具有与共混组分紧密结合的侧胺基团。与基本上不含偏氟乙烯的含氟聚合物和具有侧基胺基本上非氟化聚合物之间的剥离强度值相比，共混组分和基本上不含偏二氟乙烯的含氟聚合物之间的较大的剥离强度值观察到增加的附着力。

8. 发明授权

US07342081B2 Fluoropolymer compositions, coated articles, and method of making the same 失效
标题翻译：含氟聚合物组合物，涂覆制品及其制备方法
公开(公告)号：US07342081B2
公开(公告)日：2008-03-11
申请号：US11024131
申请日：2004-12-28
申请人： Blake E. Chandler , Thomas J. Blong , Dale E. Hutchens
发明人： Blake E. Chandler , Thomas J. Blong , Dale E. Hutchens
IPC分类号： C08F16/24
CPC分类号： C08J3/12 , C08J2327/12 , C09D5/031 , C09D5/037
摘要： A fluoropolymer composition comprising a fluoropolymer with a particle size distribution having a ratio of the mode to D95 of 0.75 or greater and wherein when the fluoropolymer is a copolymer consisting of interpolymerized units derived from tetrafluoroethylene and perfluoro(propyl vinyl) ether, the fluoropolymer has less than 60 unstable endgroups per million carbon atoms; coated articles comprising the fluoropolymer; and methods for making the same.
摘要翻译：一种氟聚合物组合物，其含有具有模式与D95的比率为0.75以上的粒度分布的含氟聚合物，并且其中当所述含氟聚合物是由衍生自四氟乙烯和全氟（丙基乙烯基）醚的共聚单元组成的共聚物时，所述含氟聚合物具有较少的每百万个碳原子超过60个不稳定的端基; 包含含氟聚合物的涂层制品; 和制作相同的方法。

9. 发明授权

US06693164B2 High purity fluoropolymers 失效
标题翻译：高纯度氟聚合物
公开(公告)号：US06693164B2
公开(公告)日：2004-02-17
申请号：US09864649
申请日：2001-05-23
申请人： Thomas J. Blong , Denis Duchesne , Gernot Loehr , Albert Killich , Tilman Zipplies , Ralph Kaulbach , Herbert Strasser
发明人： Thomas J. Blong , Denis Duchesne , Gernot Loehr , Albert Killich , Tilman Zipplies , Ralph Kaulbach , Herbert Strasser
IPC分类号： C08F616
CPC分类号： C08F6/06 , C08F6/22 , C08L27/12
摘要： The invention relates to high purity fluoropolymers and processes for making such materials. These polymers are particularly suited for applications in the semiconductor industry. The process comprises removal of unstable polymer end groups by fluorination and removal of heavy metal impurities by extraction with an aqueous acid medium.
摘要翻译：本发明涉及高纯度氟聚合物及其制备方法。这些聚合物特别适用于半导体工业中的应用。该方法包括通过用含水酸性介质萃取氟化和除去重金属杂质来除去不稳定的聚合物端基。

10. 发明授权

US06361641B1 Composite articles including fluoropolymers and non-fluorinated polymers and method for making the same 失效
标题翻译：包括含氟聚合物和非氟化聚合物的复合制品及其制备方法
公开(公告)号：US06361641B1
公开(公告)日：2002-03-26
申请号：US09495769
申请日：2000-02-01
申请人： Thomas J. Blong , Edward E. Parsonage
发明人： Thomas J. Blong , Edward E. Parsonage
IPC分类号： B32B3100
CPC分类号： B32B27/08 , B32B1/08 , B32B7/10 , B32B27/281 , B32B27/288 , B32B27/302 , B32B27/308 , B32B27/32 , B32B27/34 , B32B27/36 , B32B27/365 , B32B27/40 , B32B2270/00 , B32B2327/12 , B32B2597/00 , C08L27/12 , C08L77/00 , F16L11/04 , F16L2011/047 , Y10T428/31507 , Y10T428/3154 , Y10T428/31544 , Y10T428/31725 , C08L2666/14
摘要： A composite article is provided which includes a blend component having first and second surfaces and a substantially non-fluorinated polymer component adhered to the first surface of the blend component, wherein the substantially non-fluorinated polymer component has an exposed surface. The blend component includes a first hydrogen containing fluoropolymer, and a substantially non-fluorinated polymer having one or more pendant primary or secondary amine groups. Increased adhesion is observed by a peel strength value between the blend component and the substantially non-fluorinated polymer component when compared to a peel strength value between a component consisting of a fluoropolymer and a component consisting of a substantially non-fluorinated polymer having pendant primary or secondary amine groups.
摘要翻译：提供了一种复合制品，其包括具有第一和第二表面的共混组分和粘附到共混组分的第一表面的基本上非氟化的聚合物组分，其中基本上未氟化的聚合物组分具有暴露的表面。共混组分包括第一含氢含氟聚合物和具有一个或多个伯胺基或仲胺基侧基的基本上非氟化的聚合物。当与由氟聚合物组成的组分和由基本上无氟聚合物组成的组分之间的剥离强度值相比较时，通过共混组分和基本上非氟化的聚合物组分之间的剥离强度值观察到增加的粘附性，仲胺基团。

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