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1. 发明授权

US06361901B1 Self-doped microphase separated block copolymer electrolyte 有权
标题翻译：自掺杂微相分离嵌段共聚物电解质
公开(公告)号：US06361901B1
公开(公告)日：2002-03-26
申请号：US09360427
申请日：1999-07-23
申请人： Anne M. Mayes , Donald R. Sadoway , Pallab Banerjee , Philip Soo , Biying Huang
发明人： Anne M. Mayes , Donald R. Sadoway , Pallab Banerjee , Philip Soo , Biying Huang
IPC分类号： H01M618
CPC分类号： H01M10/052 , H01M4/13 , H01M10/0525 , H01M10/054 , H01M10/0565
摘要： A polymer electrolyte includes a self-doped microphase separated block copolymer including at least one ionically conductive block and at least one second block that is immiscible in the ionically conductive block, an anion immobilized on the polymer electrolyte and a cationic species. The ionically conductive block provides a continuous ionically conductive pathway through the electrolyte. The electrolyte may be used as an electrolyte in an electrochemical cell.
摘要翻译：聚合物电解质包括自掺杂微相分离的嵌段共聚物，其包括至少一个离子导电嵌段和至少一个在离子导电嵌段中不混溶的第二嵌段，固定在聚合物电解质上的阴离子和阳离子物质。离子导电嵌段提供通过电解质的连续离子导电通路。电解质可以用作电化学电池中的电解质。

2. 发明授权

US07026071B2 Non-crosslinked, amorphous, block copolymer electrolyte for batteries 有权
公开(公告)号：US07026071B2
公开(公告)日：2006-04-11
申请号：US09862916
申请日：2001-05-22
申请人： Anne M. Mayes , Gerbrand Ceder , Yet-Ming Chiang , Donald R. Sadoway , Mehmet K. Aydinol , Philip P. Soo , Young-Il Jang , Biying Huang
发明人： Anne M. Mayes , Gerbrand Ceder , Yet-Ming Chiang , Donald R. Sadoway , Mehmet K. Aydinol , Philip P. Soo , Young-Il Jang , Biying Huang
IPC分类号： H01M6/00 , B32B27/30
CPC分类号： H01M4/133 , C01B13/14 , C01D15/02 , C01G45/1228 , C01G51/42 , C01G53/42 , C01P2002/02 , C01P2002/08 , C01P2002/20 , C01P2002/30 , C01P2002/52 , C01P2002/54 , C01P2002/72 , C01P2004/04 , C01P2006/40 , C01P2006/80 , H01B1/122 , H01M4/13 , H01M4/131 , H01M4/362 , H01M4/382 , H01M4/485 , H01M4/505 , H01M4/525 , H01M4/624 , H01M10/052 , H01M10/0525 , H01M10/0565 , H01M2300/0085 , H01M2300/0091 , Y10T428/31 , Y10T428/31935
摘要： Solid battery components are provided. A block copolymeric electrolyte is non-crosslinked and non-glassy through the entire range of typical battery service temperatures, that is, through the entire range of at least from about 0° C. to about 70° C. The chains of which the copolymer is made each include at least one ionically-conductive block and at least one second block immiscible with the ionically-conductive block. The chains form an amorphous association and are arranged in an ordered nanostructure including a continuous matrix of amorphous ionically-conductive domains and amorphous second domains that are immiscible with the ionically-conductive domains. A compound is provided that has a formula of LixMyNzO2. M and N are each metal atoms or a main group elements, and x, y and z are each numbers from about 0 to about 1. y and z are chosen such that a formal charge on the MyNz portion of the compound is (4-x). In certain embodiments, these compounds are used in the cathodes of rechargeable batteries. The present invention also includes methods of predicting the potential utility of metal dichalgogenide compounds for use in lithium intercalation compounds. It also provides methods for processing lithium intercalation oxides with the structure and compositional homogeneity necessary to realize the increased formation energies of said compounds. An article is made of a dimensionally-stable, interpenetrating microstructure of a first phase including a first component and a second phase, immiscible with the first phase, including a second component. The first and second phases define interphase boundaries between them, and at least one particle is positioned between a first phase and a second phase at an interphase boundary. When the first and second phases are electronically-conductive and ionically-conductive polymers, respectively, and the particles are ion host particles, the arrangement is an electrode of a battery.

3. 发明申请

US20080099734A1 Intercalation compounds for batteries and other devices 审中-公开
公开(公告)号：US20080099734A1
公开(公告)日：2008-05-01
申请号：US11732139
申请日：2007-04-02
申请人： Yet-Ming Chiang , Donald R. Sadoway , Young-Il Jang , Biying Huang
发明人： Yet-Ming Chiang , Donald R. Sadoway , Young-Il Jang , Biying Huang
IPC分类号： C01F7/00 , C01G45/00 , C01D15/00 , H01B1/02
摘要： Solid battery components are provided. A block copolymeric electrolyte is non-crosslinked and non-glassy through the entire range of typical battery service temperatures, that is, through the entire range of at least from about 0° C. to about 70° C. The chains of which the copolymer is made each include at least one ionically-conductive block and at least one second block immiscible with the ionically-conductive block. The chains form an amorphous association and are arranged in an ordered nanostructure including a continuous matrix of amorphous ionically-conductive domains and amorphous second domains that are immiscible with the ionically-conductive domains. A compound is provided that has a formula of LixMyNzO2. M and N are each metal atoms or a main group elements, and x, y and z are each numbers from about 0 to about 1. y and z are chosen such that a formal charge on the MyNportion of the compound is (4−x). In certain embodiments, these compounds are used in the cathodes of rechargeable batteries. The present invention also includes methods of predicting the potential utility of metal dichalgogenide compounds for use in lithium intercalation compounds. It also provides methods for processing lithium intercalation oxides with the structure and compositional homogeneity necessary to realize the increased formation energies of said compounds. An article is made of a dimensionally-stable, interpenetrating microstructure of a first phase including a first component and a second phase, immiscible with the first phase, including a second component. The first and second phases define interphase boundaries between them, and at least one particle is positioned between a first phase and a second phase at an interphase boundary. When the first and second phases are electronically-conductive and ionically-conductive polymers, respectively, and the particles are ion host particles, the arrangement is an electrode of a battery.

4. 发明申请

US20110300442A1 NOVEL NANOSCALE SOLUTION METHOD FOR SYNTHESIZING LITHIUM CATHODE ACTIVE MATERIALS 审中-公开
标题翻译：用于合成锂离子活性材料的新型纳米溶液方法
公开(公告)号：US20110300442A1
公开(公告)日：2011-12-08
申请号：US12792207
申请日：2010-06-02
申请人： Biying Huang
发明人： Biying Huang
IPC分类号： H01M4/131 , H01M4/60
CPC分类号： H01M4/5825 , H01M10/052
摘要： The present invention relates to a solution based method for preparing an nano scale electroactive metal polyanion or a mixed metal polyanion comprising reacting metal sulfate—M(SO4)x and/or other soluble metal salts, here M could be iron, cobalt, manganese, nickel or mixtures thereof, with a solution of sodium hydroxide with addition of solution of ammonium hydroxide, in the presence of water, drying the nano-intermediate M(OH)2 or M1M2(OH)2 or M1M2M3(OH)2, or MO(OH) or M1M2O(OH) or M1M2M3O(OH), mixing the dried intermediate with a soluble lithium precursor and soluble PO4 containing precursor and a soluble polymer carbon, well mixed the mixture, and then removing said solvent at a temperature and for a time sufficient to remove the solvent and form an essentially dried mixture; and heating said mixture at a temperature and for a time sufficient to produce an electroactive metal polyanion or electroactive mixed metal polyanion. It is another object of the invention to provide electrochemically active materials produced by said methods. The electrochemically active materials so produced are useful in making electrodes and batteries.
摘要翻译：本发明涉及一种制备纳米级电活性金属聚阴离子或混合金属聚阴离子的基于溶液的方法，其包括使金属硫酸盐-M（SO 4）x和/或其它可溶性金属盐反应，这里M可以是铁，钴，锰，镍或其混合物与氢氧化钠溶液加入氢氧化铵溶液，在水存在下，干燥纳米中间体M（OH）2或M1M2（OH）2或M1M2M3（OH）2或MO （OH）或M1M2O（OH）或M1M2M3O（OH），将干燥的中间体与可溶性锂前体和可溶的含PO4的前体和可溶性聚合物碳混合，将混合物充分混合，然后在一定温度下除去所述溶剂足以除去溶剂并形成基本上干燥的混合物的时间; 并在足以产生电活性金属聚阴离子或电活性混合金属聚阴离子的温度和时间下加热所述混合物。本发明的另一个目的是提供通过所述方法生产的电化学活性材料。所生产的电化学活性材料可用于制造电极和电池。

5. 发明授权

US08022009B2 Process for synthesizing LixFeMZO4/ carbon and LixMZO4/ carbon composite materials 有权
标题翻译：合成LixFeMZO4 /碳和LixMZO4 /碳复合材料的方法
公开(公告)号：US08022009B2
公开(公告)日：2011-09-20
申请号：US12686142
申请日：2010-01-12
申请人： Biying Huang , Xiongfei Shen , Yi-Qun Li
发明人： Biying Huang , Xiongfei Shen , Yi-Qun Li
IPC分类号： B01J21/18 , H01M4/02 , H01M4/58 , H01M4/34 , H01M4/54 , H01M10/32 , H01M4/00
CPC分类号： H01M4/5825 , H01M4/625 , H01M10/052
摘要： The present invention provides a cost effective process of generating LixMyZO4/carbon composite material. Further, this novel method of preparation can be modified by adding a dopant and the calcinations can be carried out using microwave heating to reduce the synthesis time and cost. The LixMyZO4/carbon composite material can be used as a cathode for a secondary electrochemical cell. Selection of one or more metals in the cathode material can be used change the voltage, the capacity, and the energy density of the electrochemical cell.
摘要翻译：本发明提供了生产LixMyZO4 /碳复合材料的成本有效的方法。此外，这种新的制备方法可以通过添加掺杂剂进行改性，并且可以使用微波加热进行煅烧以减少合成时间和成本。 LixMyZO4 /碳复合材料可用作二次电化学电池的阴极。可以使用阴极材料中的一种或多种金属的选择来改变电化学电池的电压，容量和能量密度。

6. 发明申请

US20120189896A1 ELECTRODE SEPARATOR 审中-公开
标题翻译：电极分离器
公开(公告)号：US20120189896A1
公开(公告)日：2012-07-26
申请号：US13259259
申请日：2010-03-17
申请人： Hongxia Zhou , George William Adamson , Biying Huang
发明人： Hongxia Zhou , George William Adamson , Biying Huang
IPC分类号： H01M2/16 , B32B37/06
CPC分类号： H01M2/1653 , H01M2/1686 , H01M10/32
摘要： The present invention provides a separator for use in an alkaline electrochemical cell comprising a QA polymer material, wherein the separator is substantially resistant to oxidation by silver oxide.
摘要翻译：本发明提供了一种用于包含QA聚合物材料的碱性电化学电池的隔板，其中所述隔板基本上不受氧化银的氧化。

7. 发明申请

US20080099720A1 SYNTHESIS OF CATHODE ACTIVE MATERIALS 审中-公开
标题翻译：阴极活性材料的合成
公开(公告)号：US20080099720A1
公开(公告)日：2008-05-01
申请号：US11968783
申请日：2008-01-03
申请人： Biying Huang , Jeffrey Swoyer , M. Saidi , Haitao Huang
发明人： Biying Huang , Jeffrey Swoyer , M. Saidi , Haitao Huang
IPC分类号： C01B25/30 , H01M4/48
CPC分类号： H01M4/5825 , C01B25/45 , H01M4/364 , H01M4/485 , H01M4/5815 , H01M4/622
摘要： The present invention relates to a method for preparing an electroactive metal polyanion or a mixed metal polyanion comprising forming a slurry comprising a polymeric material, a solvent, a polyanion source or alkali metal polyanion source and at least one metal ion source; heating said slurry at a temperature and for a time sufficient to remove the solvent and form an essentially dried mixture; and heating said mixture at a temperature and for a time sufficient to produce an electroactive metal polyanion or electroactive mixed metal polyanion. The electrochemically active materials so produced are useful in making electrodes and batteries.
摘要翻译：本发明涉及一种制备电活性金属聚阴离子或混合金属聚阴离子的方法，包括形成包含聚合材料，溶剂，聚阴离子源或碱金属聚阴离子源和至少一种金属离子源的浆料; 在足以除去溶剂并形成基本上干燥的混合物的温度和时间下加热所述浆料; 并在足以产生电活性金属聚阴离子或电活性混合金属聚阴离子的温度和时间下加热所述混合物。所生产的电化学活性材料可用于制造电极和电池。

8. 发明申请

US20120078853A1 SYSTEMS, METHODS, AND APPARATUS FOR FACILITATING CHEMICAL ANALYSES 有权
标题翻译：用于促进化学分析的系统，方法和装置
公开(公告)号：US20120078853A1
公开(公告)日：2012-03-29
申请号：US13239069
申请日：2011-09-21
申请人： Biying Huang , Scott G. Flicker , William B. Ballard , Robin Y. Smith , Sean G. Greenhow , Shadrack C. Frazier
发明人： Biying Huang , Scott G. Flicker , William B. Ballard , Robin Y. Smith , Sean G. Greenhow , Shadrack C. Frazier
IPC分类号： G06F17/30
CPC分类号： G06F17/30424 , G06F19/703 , G06F19/709
摘要： A knowledge management platform eliminates the trial and error process for analytical chemists in, for example, identifying appropriate methodologies for separating mixtures of chemical compounds. The platform allows the analytical chemists to perform a variety of searches on data existing from previous experiments, procedures, and/or processes. The platform may be employed to make faster decisions, and ultimately decreases the time taken in selecting an appropriate separation methodology.
摘要翻译：知识管理平台消除了分析化学家的试错过程，例如，确定分离化合物混合物的合适方法。该平台允许分析化学家对以前实验，程序和/或过程中存在的数据进行各种搜索。该平台可用于做出更快的决定，并最终减少选择合适的分离方法所需的时间。

9. 发明申请

US20110262803A1 Electrodes and Electrochemical Cells Employing the Same 审中-公开
标题翻译：电极和电化学电池使用它
公开(公告)号：US20110262803A1
公开(公告)日：2011-10-27
申请号：US12934283
申请日：2009-03-27
申请人： Biying Huang , Ximei Sun , Hongxia Zhou , George Adamson
发明人： Biying Huang , Ximei Sun , Hongxia Zhou , George Adamson
IPC分类号： H01M4/62 , H01M4/48 , H01M10/04 , H01M4/525 , H01M4/505 , H01M4/485 , H01M10/02 , H01M4/54
CPC分类号： H01M4/623 , H01M2/1653 , H01M2/1666 , H01M4/0433 , H01M4/244 , H01M4/30 , H01M4/34 , H01M4/42 , H01M4/48 , H01M4/54 , H01M10/26 , H01M10/28 , H01M10/287 , H01M10/32 , H01M2004/027 , H01M2004/028 , H01M2220/30 , Y10T29/49108
摘要： The present invention provides novel electrodes and electrochemical cells using these electrodes. Several embodiments presented by this invention provide novel cathodes that include an AgO active material and a PVDF binder. Furthermore, this invention also presents methods of manufacturing novel electrochemical cells and novel electrodes.
摘要翻译：本发明提供使用这些电极的新型电极和电化学电池。由本发明提出的几个实施方案提供了包括AgO活性材料和PVDF粘合剂的新型阴极。此外，本发明还提供了制造新型电化学电池和新型电极的方法。

10. 发明授权

US07338647B2 Synthesis of cathode active materials 有权
标题翻译：正极活性物质的合成
公开(公告)号：US07338647B2
公开(公告)日：2008-03-04
申请号：US10850003
申请日：2004-05-20
申请人： Biying Huang , Jeffrey Swoyer , M. Yazid Saidi , Haitao Huang
发明人： Biying Huang , Jeffrey Swoyer , M. Yazid Saidi , Haitao Huang
IPC分类号： C01B25/26 , C01B25/45 , C01B33/20 , C01B17/96 , C01G28/02 , C01G30/02 , C01G31/02
CPC分类号： H01M4/5825 , C01B25/45 , H01M4/364 , H01M4/485 , H01M4/5815 , H01M4/622
摘要： The present invention relates to a method for preparing an electroactive metal polyanion or a mixed metal polyanion comprising forming a slurry comprising a polymeric material, a solvent, a polyanion source or alkali metal polyanion source and at least one metal ion source; heating said slurry at a temperature and for a time sufficient to remove the solvent and form an essentially dried mixture; and heating said mixture at a temperature and for a time sufficient to produce an electroactive metal polyanion or electroactive mixed metal polyanion. In an alternative embodiment the present invention relates to a method for preparing a metal polyanion or a mixed metal polyanion which comprises mixing a polymeric material with a polyanion source or alternatively an alkali metal polyanion source and a source of at least one metal ion to produce a fine mixture and heating the mixture to a temperature higher than the melting point of the polymeric material, milling the resulting material and then heating the milled material. It is another object of the invention to provide electrochemically active materials produced by said methods. The electrochemically active materials so produced are useful in making electrodes and batteries.
摘要翻译：本发明涉及一种制备电活性金属聚阴离子或混合金属聚阴离子的方法，包括形成包含聚合材料，溶剂，聚阴离子源或碱金属聚阴离子源和至少一种金属离子源的浆料; 在足以除去溶剂并形成基本上干燥的混合物的温度和时间下加热所述浆料; 并在足以产生电活性金属聚阴离子或电活性混合金属聚阴离子的温度和时间下加热所述混合物。在替代实施方案中，本发明涉及一种制备金属聚阴离子或混合金属聚阴离子的方法，其包括将聚合材料与聚阴离子源或者碱金属聚阴离子源和至少一种金属离子源混合以产生精细混合物并将混合物加热到高于聚合物材料的熔点的温度，研磨所得材料，然后加热研磨的材料。本发明的另一个目的是提供通过所述方法生产的电化学活性材料。所生产的电化学活性材料可用于制造电极和电池。

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