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1. 发明申请

US20060057837A1 Treating agent materials 有权
标题翻译：处理剂材料
公开(公告)号：US20060057837A1
公开(公告)日：2006-03-16
申请号：US11203558
申请日：2005-08-12
申请人： Anil Bhanap , Boris Korolev , Roger Leung , Beth Munoz
发明人： Anil Bhanap , Boris Korolev , Roger Leung , Beth Munoz
IPC分类号： H01L21/4763
CPC分类号： H01L21/02216 , H01L21/02126 , H01L21/316 , H01L21/31695 , H01L21/76814 , H01L21/76826
摘要： A treating agent composition for increasing the hydrophobicity of an organosilicate glass dielectric film when applied to said film. It includes a component capable of alkylating or arylating silanol moieties of the organosilicate glass dielectric film via silylation, and an activating agent which may be an acid, a base, an onium compound, a dehydrating agent, and combinations thereof, and a solvent or mixture of a main solvent and a co-solvent.
摘要翻译：一种用于在施加到所述膜上时增加有机硅酸盐玻璃介电膜的疏水性的处理剂组合物。它包括能够通过甲硅烷基化将有机硅酸盐玻璃介电膜的硅烷醇部分烷基化或芳基化的组分，以及可以是酸，碱，鎓化合物，脱水剂及其组合的活化剂，以及溶剂或混合物的主要溶剂和共溶剂。

2. 发明授权

US07307137B2 Low dielectric constant materials and methods of preparation thereof 有权
标题翻译：低介电常数材料及其制备方法
公开(公告)号：US07307137B2
公开(公告)日：2007-12-11
申请号：US10466651
申请日：2001-10-18
申请人： Kreisler Lau , Feng Quan Liu , Paul Apen , Boris Korolev , Emma Brouk , Ruslan Zherebin , David Nalewajek , Roger Leung
发明人： Kreisler Lau , Feng Quan Liu , Paul Apen , Boris Korolev , Emma Brouk , Ruslan Zherebin , David Nalewajek , Roger Leung
IPC分类号： C08G63/78
CPC分类号： C08G61/12 , C07C13/615 , C07C13/64 , C07C15/54 , C07C17/10 , C07C17/269 , C07C2603/74 , C07C2603/90 , C07F7/0805 , C08F238/00 , C08G61/02 , H01L2924/0002 , C07C23/46 , C07C25/22 , H01L2924/00
摘要： The present invention is directed to low dielectric polymers and to methods of producing these low dielectric constant polymers, dielectric materials and layers, and electronic components. In one aspect of the present invention, an isomeric mixture of thermosetting monomers, wherein the monomers have a core structure and a plurality of arms, is provided, and the isomeric mixture of thermosetting monomers is polymerized, wherein polymerization comprises a reaction of an ethynyl group that is located in at least one arm of a monomer. In yet another aspect of the inventive subject matter, spin-on low dielectric constant materials are formed having a first backbone with an aromatic moiety and a first reactive group, and a second backbone with an aromatic moiety and a second reactive group, wherein the first and second backbone are crosslinked via the first and second reactive groups in a crosslinking reaction preferably without an additional crosslinker, and wherein a cage structure having at least eight (8) atoms is covalently bound to at least one of the first and second backbone.
摘要翻译：本发明涉及低介电聚合物以及生产这些低介电常数聚合物，介电材料和层以及电子元件的方法。在本发明的一个方面，提供其中单体具有核心结构和多个臂的热固性单体的异构体混合物，并且热固性单体的异构体混合物聚合，其中聚合包括乙炔基其位于单体的至少一个臂中。在本发明主题的另一方面，形成旋涂低介电常数材料，其具有具有芳族部分和第一反应性基团的第一主链和具有芳族部分和第二反应性基团的第二主链，其中第一并且第二主链在交联反应中通过第一和第二反应性基团交联，优选不含另外的交联剂，并且其中具有至少八个（8）原子的笼结构共价结合至第一和第二主链中的至少一个。

3. 发明授权

US06849696B2 Low dielectric constant organic dielectrics based on cage-like structures 失效
标题翻译：基于笼状结构的低介电常数有机电介质
公开(公告)号：US06849696B2
公开(公告)日：2005-02-01
申请号：US10293024
申请日：2002-11-12
申请人： Kreisler Lau , Feng Quan Liu , Boris Korolev , Emma Brouk , Roger Leung
发明人： Kreisler Lau , Feng Quan Liu , Boris Korolev , Emma Brouk , Roger Leung
IPC分类号： C08G65/40 , C08F8/00 , C08F257/02 , C08F277/00 , C08F281/00 , C08G61/12 , C08G81/00 , C08J3/24 , C08L1/00 , C08L51/00 , C08L67/00 , C08L67/06 , C08L71/12 , H01L20060101 , H01L21/312
CPC分类号： C08J3/246 , C08F257/02 , C08G61/12 , C08L51/003 , Y10S977/902 , Y10S977/963 , C08L2666/02
摘要： A low dielectric constant material has a first backbone with an aromatic moiety and a first reactive group, and a second backbone with an aromatic moiety and a second reactive group, wherein the first and second backbones are crosslinked via the first and second reactive groups in a crosslinking reaction without an additional crosslinker, and wherein a cage structure having at least 10 atoms is covalently bound to at least one of the first and second backbone.
摘要翻译：低介电常数材料具有具有芳族部分和第一反应性基团的第一主链和具有芳族部分和第二反应性基团的第二主链，其中第一和第二主链通过第一和第二反应性基团在交联反应而没有额外的交联剂，并且其中具有至少10个原子的笼状结构与第一和第二主链中的至少一个共价结合。

4. 发明授权

US06509415B1 Low dielectric constant organic dielectrics based on cage-like structures 失效
公开(公告)号：US06509415B1
公开(公告)日：2003-01-21
申请号：US09545058
申请日：2000-04-07
申请人： Kreisler Lau , Feng Quan Liu , Boris Korolev , Emma Brouk , Rusian Zherebin , Roger Leung
发明人： Kreisler Lau , Feng Quan Liu , Boris Korolev , Emma Brouk , Rusian Zherebin , Roger Leung
IPC分类号： C08F28100
CPC分类号： C08J3/246 , C08F257/02 , C08G61/12 , C08L51/003 , Y10S977/902 , Y10S977/963 , C08L2666/02
摘要： A low dielectric constant material has a first backbone with an aromatic moiety and a first reactive group, and a second backbone with an aromatic moiety and a second reactive group, wherein the first and second backbones are crosslinked via the first and second reactive groups in a crosslinking reaction without an additional crosslinker, and wherein a cage structure having at least 10 atoms is covalently bound to at least one of the first and second backbone.

5. 发明授权

US06797777B2 Low dielectric constant organic dielectrics based on cage-like structures 失效
标题翻译：基于笼状结构的低介电常数有机电介质
公开(公告)号：US06797777B2
公开(公告)日：2004-09-28
申请号：US09902924
申请日：2001-07-10
申请人： Kreisler Lau , Feng Quan Liu , Boris Korolev , Emma Brouk , Rusian Zherebin , Roger Leung
发明人： Kreisler Lau , Feng Quan Liu , Boris Korolev , Emma Brouk , Rusian Zherebin , Roger Leung
IPC分类号： C08F28100
CPC分类号： C08F257/02 , C08F8/00 , C08G61/02 , C08G61/12 , C08G81/00 , C08L51/003 , H01B3/307 , H01B3/427 , C08L2666/02
摘要： A low dielectric constant material has a first backbone with an aromatic moiety and a first reactive group, and a second backbone with an aromatic moiety and a second reactive group, wherein the first and second backbones are crosslinked via the first and second reactive groups in a crosslinking reaction without an additional crosslinker, and wherein a cage structure having at least 10 atoms is covalently bound to at least one of the first and second backbone.
摘要翻译：低介电常数材料具有具有芳族部分和第一反应性基团的第一主链和具有芳族部分和第二反应性基团的第二主链，其中第一和第二主链通过第一和第二反应性基团在交联反应而没有额外的交联剂，并且其中具有至少10个原子的笼状结构与第一和第二主链中的至少一个共价结合。

6. 发明申请

US20050090596A1 Organic composition 审中-公开
标题翻译：有机成分
公开(公告)号：US20050090596A1
公开(公告)日：2005-04-28
申请号：US10404676
申请日：2003-04-02
申请人： Paul Apen , Kreisler Lau , Boris Korolev , Bo Li , Ruslan Zherebin , Edward Sullivan , Christian Werner , Sonja Demel , Bernd Kellermeier , Andreas Kanschik-Conradsen
发明人： Paul Apen , Kreisler Lau , Boris Korolev , Bo Li , Ruslan Zherebin , Edward Sullivan , Christian Werner , Sonja Demel , Bernd Kellermeier , Andreas Kanschik-Conradsen
IPC分类号： C08G61/02 , C08G61/12 , C08K5/01
CPC分类号： C08G61/02 , C08G61/12
摘要： The present invention provides adamantane or diamantane compositions that are useful as a dielectric material in microelectronic applications such as microchips.
摘要翻译：本发明提供金刚烷或二金刚烷组合物，其可用作微电子应用如微芯片中的电介质材料。

7. 发明授权

US06987147B2 Low dielectric constant materials with improved thermo-mechanical strength and processability 失效
标题翻译：低介电常数材料，具有改善的热机械强度和加工性能
公开(公告)号：US06987147B2
公开(公告)日：2006-01-17
申请号：US10263204
申请日：2002-10-01
申请人： Kreisler Lau , Bo Li , Boris Korolev , Edward Sullivan , Ruslan Zherebin
发明人： Kreisler Lau , Bo Li , Boris Korolev , Edward Sullivan , Ruslan Zherebin
IPC分类号： C08G65/30 , C08G65/38 , C08F8/00
CPC分类号： H01L21/02118 , B32B27/06 , C08G61/02 , H01L21/02203 , H01L21/02282 , H01L21/312 , Y10T428/24851
摘要： A polymeric network comprises a plurality of monomers that include a cage compound with at least three arms, wherein at least one of the arms has two or more branches, and wherein each of the branches further comprises a reactive group. Monomers in contemplated polymeric networks are covalently coupled to each other via the reactive groups. Particularly contemplated cage compounds include adamantane and diamantane, and especially contemplated branched arms comprise ortho-bis(phenylethynyl)phenyl. Especially contemplated polymeric networks have a dielectric constant of no more than 3.0, and are formed on the surface of a substrate.
摘要翻译：聚合物网络包括多个单体，其包括具有至少三个臂的笼形化合物，其中至少一个臂具有两个或更多个分支，并且其中每个分支还包含反应性基团。预期聚合物网络中的单体通过反应性基团共价偶联。特别预期的笼形化合物包括金刚烷和金刚烷，特别是预期的支链包括邻 - 双（苯基乙炔基）苯基。特别考虑的聚合物网络具有不超过3.0的介电常数，并且形成在基底的表面上。

8. 发明授权

US06713590B2 Low dielectric constant materials with polymeric networks 失效
标题翻译：低介电常数材料与聚合网络
公开(公告)号：US06713590B2
公开(公告)日：2004-03-30
申请号：US10004584
申请日：2001-12-03
申请人： Kreisler S. Lau , Feng Quan Liu , Boris Korolev , Emma Brouk , Ruslan Zherebin , David Nalewajek
发明人： Kreisler S. Lau , Feng Quan Liu , Boris Korolev , Emma Brouk , Ruslan Zherebin , David Nalewajek
IPC分类号： C08G802
CPC分类号： C08G69/48 , C08G61/02 , C08G61/12 , C08G65/4012 , C08G2650/20 , C08G2650/60 , C08L2312/00
摘要： A low dielectric constant material has a polymeric network that is fabricated from a first and a second component. The first component comprises a polymeric strand, and the second component comprises a molecule having a central portion with at least three arms extending from the central portion, wherein each of the arms includes a backbone with a reactive group. The first component and the second component form the polymeric network in a reaction that involves at least one of the reactive groups when the first and second components are thermally activated. Contemplated low dielectric constant materials are advantageously employed in the fabrication of electronic devices, and particularly contemplated devices include integrated circuits.
摘要翻译：低介电常数材料具有由第一和第二组分制成的聚合物网络。第一组分包含聚合物链，并且第二组分包含具有至少三个从中心部分延伸的臂的中心部分的分子，其中每个臂包括具有反应性基团的主链。当第一和第二组分被热活化时，第一组分和第二组分在涉及至少一个反应性基团的反应中形成聚合物网络。考虑的低介电常数材料有利地用于制造电子器件，并且特别预期的器件包括集成电路。

9. 发明授权

US6156812A Nanoporous material fabricated using polymeric template strands 失效
标题翻译：使用聚合物模板链制造的纳米多孔材料
公开(公告)号：US6156812A
公开(公告)日：2000-12-05
申请号：US544723
申请日：2000-04-06
申请人： Kreisler Lau , Tian-An Chen , Boris Korolev
发明人： Kreisler Lau , Tian-An Chen , Boris Korolev
IPC分类号： C08J9/26 , C08J9/02
CPC分类号： C08J9/26 , C08J2201/046
摘要： Compositions and methods are provided in which nanoporous polymeric materials are produced via stable, polymeric template strands having reactive groups that can be used for forming crosslinking functionalities and/or adding thermolabile groups, wherein at least some of the thermolabile groups are thermolyzed to produce voids. The template strands preferably comprise aromatic systems and vicinal keto groups, such as a polybenzil formed from fluorene bisphenol or 3,3'-dihydroxytolane with 4,4'-difluorobenzil. At least some of the reactive groups preferably react using an addition-elimination reaction. Especially preferred thermolabile groups comprise poly(propylene oxide), and especially preferred crosslinkers comprise ethynyl-moiety and tetracyclone moieties.
摘要翻译：提供了组合物和方法，其中纳米多孔聚合物材料通过具有可用于形成交联官能团和/或添加不耐热基团的反应性基团的稳定的聚合物模板链产生，其中至少一些不耐热基团被热分解以产生空隙。模板链优选包含芳族体系和连位酮基，例如由芴双酚或3,3'-二羟基乙内酯与4,4'-二氟苯甲醛形成的聚苯乙烯。至少一些反应性基团优选使用加成 - 消除反应进行反应。特别优选的热不稳定基团包括聚（环氧丙烷），并且特别优选的交联剂包括乙炔基部分和四环酮部分。

10. 发明授权

US06803441B2 Compositions and methods for thermosetting molecules in organic compositions 失效
标题翻译：有机组合物中热固性分子的组成和方法
公开(公告)号：US06803441B2
公开(公告)日：2004-10-12
申请号：US10267380
申请日：2002-10-08
申请人： Kreisler Lau , Feng Quan Liu , Boris Korolev , Emma Brouk , Ruslan Zherebin , David Nalewajek
发明人： Kreisler Lau , Feng Quan Liu , Boris Korolev , Emma Brouk , Ruslan Zherebin , David Nalewajek
IPC分类号： C08G6378
CPC分类号： C08G61/12 , C08G61/02 , C08G2650/60
摘要： In a method of producing a low dielectric constant polymer, a thermosetting monomer is provided, wherein the thermosetting monomer has a cage compound or aryl core structure, and a plurality of arms that are covalently bound to the cage compound or core structure. In a subsequent step, the thermosetting monomer is incorporated into a polymer to form the low dielectric constant polymer, wherein the incorporation into the polymer comprises a chemical reaction of a triple bond that is located in at least one of the arms. Contemplated cage compounds and core structures include adamantane, diamantane, silicon, a phenyl group and a sexiphenylene group, while preferred arms include an arylene, a branched arylene, and an arylene ether. The thermosetting monomers may advantageously be employed to produce low-k dielectric material in electronic devices, and the dielectric constant of the polymer can be controlled by varying the overall length of the arms.
摘要翻译：在制造低介电常数聚合物的方法中，提供了一种热固性单体，其中该热固性单体具有笼形化合物或芳基核心结构，以及共价结合笼形化合物或核心结构的多个臂。在随后的步骤中，将热固性单体引入聚合物中以形成低介电常数聚合物，其中掺入聚合物中包含位于至少一个臂中的三键的化学反应。考虑的笼状化合物和核心结构包括金刚烷，二金刚烷，硅，苯基和亚噻吩基，而优选的臂包括亚芳基，支链亚芳基和亚芳基醚。热固性单体可以有利地用于在电子器件中产生低k介电材料，并且聚合物的介电常数可以通过改变臂的整个长度来控制。

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