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    • 2. 发明申请
    • EFFICIENT MIXING PROCESS FOR PRODUCING THERMOPLASTIC ELASTOMER COMPOSITION
    • 用于生产热塑性弹性体组合物的高效混合方法
    • US20100331452A1
    • 2010-12-30
    • US12682490
    • 2007-10-11
    • Andy Haishung TsouYuichi HaraMichael Kenneth LyonYoshihiro Soeda
    • Andy Haishung TsouYuichi HaraMichael Kenneth LyonYoshihiro Soeda
    • C08J3/20C08L77/00
    • C08J3/005B29C47/0011B29C47/40C08J2377/00C08L15/00C08L23/28C08L23/283C08L77/00C08L2666/02C08L2666/06
    • A durable, flexible, impermeable thermoplastic elastomer composition is produced using a dynamic vulcanization process conducted in a high shear mixer at elevated temperature. The composition comprises cured particles of a first halogenated isobutylene-containing elastomer and particles of a second elastomer having at least one functional group capable of reacting with and grafting to a polyamide, the particles of the first and second elastomers dispersed in a continuous thermoplastic polyamide matrix, said process comprising: (1) dispersing a curative in the halogenated elastomer and forming a pre-compounded, preferably pelletized composition; (2) introducing polyamide resin and optional stabilizers into the mixer and shearing and heating to melt the polyamide and form a mixture; (3) introducing a nylon plasticizer to reduce the viscosity of the polyamide mixture to substantially match that of the pre-compounded elastomer under mixing conditions; (4) introducing pellets of the pre-compounded elastomer into the mixer and initiating dynamic vulcanization of the elastomer and polyamide components; (5) introducing the second elastomer and continuing heating and shearing to disperse the second elastomer and substantially complete dynamic vulcanization; and delivering the thermoplastic elastomer composition from the mixer. Such compositions are particularly useful in applications such as tire innerliners and barrier films or layers.
    • 使用在高剪切混合器中在高温下进行的动态硫化方法制备耐用的,柔性的,不渗透的热塑性弹性体组合物。 该组合物包含含有第一卤代异丁烯的弹性体的固化颗粒和具有至少一个能够与聚酰胺反应和接枝到聚酰胺上的官能团的第二弹性体颗粒,第一和第二弹性体的颗粒分散在连续的热塑性聚酰胺基质 所述方法包括:(1)将固化剂分散在卤化弹性体中并形成预混合的,优选颗粒状的组合物; (2)将聚酰胺树脂和任选的稳定剂引入混合器中并剪切和加热以熔化聚酰胺并形成混合物; (3)在混合条件下引入尼龙增塑剂以降低聚酰胺混合物的粘度与预混合弹性体的粘度基本一致; (4)将预混合弹性体的颗粒引入混合器中并引发弹性体和聚酰胺组分的动态硫化; (5)引入第二弹性体并继续加热和剪切以分散第二弹性体并基本上完成动态硫化; 并从混合器中输送热塑性弹性体组合物。 这样的组合物特别适用于诸如轮胎内衬和阻挡膜或层的应用。
    • 8. 发明授权
    • Low moisture permeability laminate construction
    • 低透湿层压结构
    • US08960250B2
    • 2015-02-24
    • US12446877
    • 2006-10-26
    • Andy Haishung TsouStephan Bertil OhlssonYoshihiro SoedaShusaku TomoiYuichi Hara
    • Andy Haishung TsouStephan Bertil OhlssonYoshihiro SoedaShusaku TomoiYuichi Hara
    • B60C1/00B32B25/08B60C5/14
    • B60C1/0008B32B1/08B32B7/12B32B25/08B32B2250/03B32B2250/24B32B2255/10B32B2255/26B32B2307/7265B32B2323/046B32B2355/00B32B2597/00B32B2605/00B60C5/14B60C2005/145Y10T428/1386Y10T428/1393Y10T428/265Y10T428/31515Y10T428/3154Y10T428/31663Y10T428/31721Y10T428/3175Y10T428/31797Y10T428/31855Y10T428/31917Y10T428/31924Y10T428/31931
    • An article having a fluid permeation prevention layer, such as a pneumatic tire or hose. A tire for example includes an outer tread layer, intermediate sidewall and carcass layers and an innermost air permeation prevention layer: (i) the air permeation prevention (APP) layer having an upper and a lower surface, the layer having a polymer composition exhibiting an air permeation coefficient (APC) of about 25×10′12 cc cm/cm2 sec cmHg (at 30° C.) or less and a Young's modulus of about 1 MPa to about 500 MPa, the polymer composition comprising: (A) at least 10 wt % of at least one. thermoplastic resin component having an APC of about 25×10″12 cc cm/cm2 sec cmHg (at 30° C.) or less and a Young's modulus of more than 500 MPa, which is preferably a polyamide resin or mixture, and (B) at least 10 wt % of at least one elastomer component having an APC of more than about 25×10″12 cc cm/cm2 sec cmHg (at 30° C.) and a Young's modulus of not more than 500 MPa, which elastomer component is preferably a halogen-containing rubber or mixture, the total amount (A)+(B) being not less than about 30 wt %, and the elastomer component is a dispersed vulcanized, discontinuous phase in the thermoplastic resin matrix; and (ii) at least one thermoplastic laminate layer bonded to at least said lower surface of the APP layer, the thermoplastic layer comprising a film-forming, semi-crystalline, substantially hydrophobic carbon chain polymer having a glass transition temperature, Tg, of less than about −200 C.
    • 具有防渗漏层的物品,例如充气轮胎或软管。 轮胎例如包括外胎面层,中间侧壁和胎体层以及最内部的防透气层:(i)具有上表面和下表面的防透气层(APP)层,所述层具有聚合物组合物, 大约25×10'12 cc cm / cm 2·sec·cmHg(30℃)或更低,杨氏模量为约1MPa至约500MPa的透气系数(APC),所述聚合物组合物包含:(A) 至少10重量%的至少一个。 具有约25×10 12 cc cm / cm 2·sec·cmHg(30℃)的APC和大于500MPa的杨氏模量的热塑性树脂组分(优选聚酰胺树脂或混合物)和(B )至少10重量%的至少一种具有APC大于约25×10 12 cc cm / cm 2·sec·cmHg(30℃)的APC和不大于500MPa的杨氏模量的弹性体组分,该弹性体 组分优选为含卤素橡胶或混合物,总量(A)+(B)不小于约30重量%,弹性体组分为热塑性树脂基体中分散的硫化不连续相; 和(ii)至少一层结合至所述APP层的至少所述下表面的热塑性层压层,所述热塑性层包含成膜,半结晶,基本疏水的碳链聚合物,其玻璃化转变温度Tg低于 比约-200℃
    • 9. 发明授权
    • Efficient mixing process for producing thermoplastic elastomer composition
    • 用于生产热塑性弹性体组合物的高效混合方法
    • US08450396B2
    • 2013-05-28
    • US12682490
    • 2007-10-11
    • Andy Haishung TsouYuichi HaraMichael Kenneth LyonYoshihiro Soeda
    • Andy Haishung TsouYuichi HaraMichael Kenneth LyonYoshihiro Soeda
    • C08J3/20
    • C08J3/005B29C47/0011B29C47/40C08J2377/00C08L15/00C08L23/28C08L23/283C08L77/00C08L2666/02C08L2666/06
    • A durable, flexible, impermeable thermoplastic elastomer composition is produced using a dynamic vulcanization process conducted in a high shear mixer at elevated temperature. The composition comprises cured particles of a first halogenated isobutylene-containing elastomer and particles of a second elastomer having at least one functional group capable of reacting with and grafting to a polyamide, the particles of the first and second elastomers dispersed in a continuous thermoplastic polyamide matrix, said process comprising: (1) dispersing a curative in the halogenated elastomer and forming a pre-compounded, preferably pelletized composition; (2) introducing polyamide resin and optional stabilizers into the mixer and shearing and heating to melt the polyamide and form a mixture; (3) introducing a nylon plasticizer to reduce the viscosity of the polyamide mixture to substantially match that of the pre-compounded elastomer under mixing conditions; (4) introducing pellets of the pre-compounded elastomer into the mixer and initiating dynamic vulcanization of the elastomer and polyamide components; (5) introducing the second elastomer and continuing heating and shearing to disperse the second elastomer and substantially complete dynamic vulcanization; and delivering the thermoplastic elastomer composition from the mixer. Such compositions are particularly useful in applications such as tire innerliners and barrier films or layers.
    • 使用在高剪切混合器中在高温下进行的动态硫化方法制备耐用的,柔性的,不渗透的热塑性弹性体组合物。 该组合物包含含有第一卤代异丁烯的弹性体的固化颗粒和具有至少一个能够与聚酰胺反应和接枝到聚酰胺上的官能团的第二弹性体颗粒,第一和第二弹性体的颗粒分散在连续的热塑性聚酰胺基质 所述方法包括:(1)将固化剂分散在卤化弹性体中并形成预混合的,优选颗粒状的组合物; (2)将聚酰胺树脂和任选的稳定剂引入混合器中并剪切和加热以熔化聚酰胺并形成混合物; (3)在混合条件下引入尼龙增塑剂以降低聚酰胺混合物的粘度与预混合弹性体的粘度基本一致; (4)将预混合弹性体的颗粒引入混合器中并引发弹性体和聚酰胺组分的动态硫化; (5)引入第二弹性体并继续加热和剪切以分散第二弹性体并基本上完成动态硫化; 并从混合器中输送热塑性弹性体组合物。 这样的组合物特别适用于诸如轮胎内衬和阻挡膜或层的应用。