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    • 1. 发明授权
    • Low moisture permeability laminate construction
    • 低透湿层压结构
    • US08960250B2
    • 2015-02-24
    • US12446877
    • 2006-10-26
    • Andy Haishung TsouStephan Bertil OhlssonYoshihiro SoedaShusaku TomoiYuichi Hara
    • Andy Haishung TsouStephan Bertil OhlssonYoshihiro SoedaShusaku TomoiYuichi Hara
    • B60C1/00B32B25/08B60C5/14
    • B60C1/0008B32B1/08B32B7/12B32B25/08B32B2250/03B32B2250/24B32B2255/10B32B2255/26B32B2307/7265B32B2323/046B32B2355/00B32B2597/00B32B2605/00B60C5/14B60C2005/145Y10T428/1386Y10T428/1393Y10T428/265Y10T428/31515Y10T428/3154Y10T428/31663Y10T428/31721Y10T428/3175Y10T428/31797Y10T428/31855Y10T428/31917Y10T428/31924Y10T428/31931
    • An article having a fluid permeation prevention layer, such as a pneumatic tire or hose. A tire for example includes an outer tread layer, intermediate sidewall and carcass layers and an innermost air permeation prevention layer: (i) the air permeation prevention (APP) layer having an upper and a lower surface, the layer having a polymer composition exhibiting an air permeation coefficient (APC) of about 25×10′12 cc cm/cm2 sec cmHg (at 30° C.) or less and a Young's modulus of about 1 MPa to about 500 MPa, the polymer composition comprising: (A) at least 10 wt % of at least one. thermoplastic resin component having an APC of about 25×10″12 cc cm/cm2 sec cmHg (at 30° C.) or less and a Young's modulus of more than 500 MPa, which is preferably a polyamide resin or mixture, and (B) at least 10 wt % of at least one elastomer component having an APC of more than about 25×10″12 cc cm/cm2 sec cmHg (at 30° C.) and a Young's modulus of not more than 500 MPa, which elastomer component is preferably a halogen-containing rubber or mixture, the total amount (A)+(B) being not less than about 30 wt %, and the elastomer component is a dispersed vulcanized, discontinuous phase in the thermoplastic resin matrix; and (ii) at least one thermoplastic laminate layer bonded to at least said lower surface of the APP layer, the thermoplastic layer comprising a film-forming, semi-crystalline, substantially hydrophobic carbon chain polymer having a glass transition temperature, Tg, of less than about −200 C.
    • 具有防渗漏层的物品,例如充气轮胎或软管。 轮胎例如包括外胎面层,中间侧壁和胎体层以及最内部的防透气层:(i)具有上表面和下表面的防透气层(APP)层,所述层具有聚合物组合物, 大约25×10'12 cc cm / cm 2·sec·cmHg(30℃)或更低,杨氏模量为约1MPa至约500MPa的透气系数(APC),所述聚合物组合物包含:(A) 至少10重量%的至少一个。 具有约25×10 12 cc cm / cm 2·sec·cmHg(30℃)的APC和大于500MPa的杨氏模量的热塑性树脂组分(优选聚酰胺树脂或混合物)和(B )至少10重量%的至少一种具有APC大于约25×10 12 cc cm / cm 2·sec·cmHg(30℃)的APC和不大于500MPa的杨氏模量的弹性体组分,该弹性体 组分优选为含卤素橡胶或混合物,总量(A)+(B)不小于约30重量%,弹性体组分为热塑性树脂基体中分散的硫化不连续相; 和(ii)至少一层结合至所述APP层的至少所述下表面的热塑性层压层,所述热塑性层包含成膜,半结晶,基本疏水的碳链聚合物,其玻璃化转变温度Tg低于 比约-200℃
    • 7. 发明申请
    • THERMOPLASTIC ELASTOMER COMPOSITION AND PNEUMATIC TIRE USING SAME
    • 热塑性弹性体组合物和使用相同的气动轮胎
    • US20130025757A1
    • 2013-01-31
    • US13639337
    • 2011-05-17
    • Shusaku TomoiKoichi Kawaguchi
    • Shusaku TomoiKoichi Kawaguchi
    • B60C1/00C08L19/00
    • C08L77/00B60C1/0008C08L23/283Y10T152/10495C08L29/04C08L29/06C08L23/0861
    • Provided is a thermoplastic elastomer composition that can be suitably used for the inner liners of pneumatic tires and exhibits high air barrier properties and high fatigue durability. The present invention is a thermoplastic elastomer composition comprising a thermoplastic resin composition and a rubber composition dispersed in the thermoplastic resin composition, wherein the thermoplastic resin composition comprises a polyamide and an ethylene-vinyl alcohol copolymer or a poly(vinyl alcohol), the rubber composition comprises a halogenated isoolefin-p-alkylstyrene copolymer and is cross inked. The thermoplastic resin composition preferably comprises 1 to 25% by weight of the ethylene-vinyl alcohol copolymer or the poly(vinyl alcohol). The thermoplastic elastomer composition preferably comprises 100 parts by weight of the thermoplastic resin composition and 80 to 200 parts by weight of the halogenated isoolefin-p-alkylstyrene copolymer.
    • 提供一种热塑性弹性体组合物,其可以适用于充气轮胎的内衬,并且具有高空气阻隔性和高疲劳耐久性。 本发明是一种热塑性弹性体组合物,其包含热塑性树脂组合物和分散在热塑性树脂组合物中的橡胶组合物,其中热塑性树脂组合物包含聚酰胺和乙烯 - 乙烯醇共聚物或聚(乙烯醇),橡胶组合物 包括卤代异烯烃 - 对 - 烷基苯乙烯共聚物,并且是交联的。 热塑性树脂组合物优选包含1至25重量%的乙烯 - 乙烯醇共聚物或聚(乙烯醇)。 热塑性弹性体组合物优选包含100重量份的热塑性树脂组合物和80-200重量份的卤代异烯烃 - 对烷基苯乙烯共聚物。
    • 8. 发明授权
    • Pneumatic tire and method of production of same
    • 气动轮胎及其生产方法
    • US08202604B2
    • 2012-06-19
    • US12297240
    • 2007-04-26
    • Shusaku Tomoi
    • Shusaku Tomoi
    • B60C5/02B60C5/12B60C19/12B60C23/00B29D30/08B29D30/00
    • B29D30/3028B29D30/0681B29D2030/0682B60C5/14B60C2005/145Y10T428/24479Y10T428/24777
    • A pneumatic tire having an air permeation preventive layer formed by adhering a resin film containing thermoplastic resin as a main component thereof to a tire inner wall surface, wherein the resin film is laminated, as a narrow width slit film shape, with an elastomer and the resultant ribbon-shaped laminate is continuously and spirally wound in a tire circumferential direction so that the edges thereof partially overlap to thereby form the air permeation preventive layer, whereby a pneumatic tire having a light weight and superior air permeation preventive property, no splice openings of the air permeation preventive layer at the time of tire processing, and capable of shortening the processing time can be obtained as well as the production method thereof.
    • 一种充气轮胎,其特征在于,具有通过将含有热塑性树脂作为主要成分的树脂膜以轮胎内壁面的方式粘合而形成的透气防止层,所述轮胎内壁面通过弹性体将所述树脂膜层压成窄宽度狭缝膜, 所得到的带状层压体在轮胎周向上连续并螺旋地卷绕,使得其边缘部分重叠,从而形成防透气层,由此具有重量轻且优异的防透气性的充气轮胎,没有接合开口 可以获得轮胎加工时的防透气层,能够缩短加工时间的方法及其制造方法。
    • 10. 发明授权
    • Thermoplastic elastomer composition and pneumatic tire using same
    • 热塑性弹性体组合物和使用其的充气轮胎
    • US08940835B2
    • 2015-01-27
    • US13639337
    • 2011-05-17
    • Shusaku TomoiKoichi Kawaguchi
    • Shusaku TomoiKoichi Kawaguchi
    • B60C5/14C08L15/02C08L23/08C08L29/04C08L77/02C08L77/00B60C1/00
    • C08L77/00B60C1/0008C08L23/283Y10T152/10495C08L29/04C08L29/06C08L23/0861
    • Provided is a thermoplastic elastomer composition that can be suitably used for the inner liners of pneumatic tires and exhibits high air barrier properties and high fatigue durability. The present invention is a thermoplastic elastomer composition comprising a thermoplastic resin composition and a rubber composition dispersed in the thermoplastic resin composition, wherein the thermoplastic resin composition comprises a polyamide and an ethylene-vinyl alcohol copolymer or a poly(vinyl alcohol), the rubber composition comprises a halogenated isoolefin-p-alkylstyrene copolymer and is cross inked. The thermoplastic resin composition preferably comprises 1 to 25% by weight of the ethylene-vinyl alcohol copolymer or the poly(vinyl alcohol). The thermoplastic elastomer composition preferably comprises 100 parts by weight of the thermoplastic resin composition and 80 to 200 parts by weight of the halogenated isoolefin-p-alkylstyrene copolymer.
    • 提供一种热塑性弹性体组合物,其可以适用于充气轮胎的内衬,并且具有高空气阻隔性和高疲劳耐久性。 本发明是一种热塑性弹性体组合物,其包含热塑性树脂组合物和分散在热塑性树脂组合物中的橡胶组合物,其中热塑性树脂组合物包含聚酰胺和乙烯 - 乙烯醇共聚物或聚(乙烯醇),橡胶组合物 包括卤代异烯烃 - 对 - 烷基苯乙烯共聚物,并且是交联的。 热塑性树脂组合物优选包含1至25重量%的乙烯 - 乙烯醇共聚物或聚(乙烯醇)。 热塑性弹性体组合物优选包含100重量份的热塑性树脂组合物和80-200重量份的卤代异烯烃 - 对烷基苯乙烯共聚物。