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1. 发明授权

US07954528B2 Thermoplastic elastomer composition and process for producing same 有权
标题翻译：热塑性弹性体组合物及其制备方法
公开(公告)号：US07954528B2
公开(公告)日：2011-06-07
申请号：US12091333
申请日：2005-10-27
申请人： Andy Haishung Tsou , Yoshihiro Soeda , Yuichi Hara , Matthew Brian Measmer
发明人： Andy Haishung Tsou , Yoshihiro Soeda , Yuichi Hara , Matthew Brian Measmer
IPC分类号： C08L51/04 , C08L77/00 , C08L101/00 , B60C15/00 , C08K5/098
CPC分类号： C08L21/00 , C08L7/00 , C08L23/283 , C08L53/02 , C08L77/00 , Y10T152/10828 , Y10T152/10846 , C08L2666/08 , C08L2666/20 , C08L2666/06
摘要： A thermoplastic elastomer composition having excellent durability and flexibility while possessing superior air impermeability. In particular, a process for producing a thermoplastic elastomer composition having high rubber content by multistage addition of at least one vulcanizable rubber component, in which the time required to substantially cure the at least one rubber component preferably is less the mixer residence time. Such compositions are particularly useful in applications such as tire innerliners and barrier films or layers.
摘要翻译：一种热塑性弹性体组合物，具有优异的耐久性和柔韧性，同时具有优异的不透气性。特别地，通过多次添加至少一种可硫化橡胶组分来制备具有高橡胶含量的热塑性弹性体组合物的方法，其中基本上固化至少一种橡胶组分所需的时间优选较少是混合器停留时间。这样的组合物特别适用于诸如轮胎内衬和阻挡膜或层的应用。

2. 发明申请

US20130014880A1 CONSTRUCTION COMPRISING TIE LAYER 审中-公开
标题翻译：施工包括层层
公开(公告)号：US20130014880A1
公开(公告)日：2013-01-17
申请号：US13556248
申请日：2012-07-24
申请人： Andy Haishung TSOU , Yoshihiro Soeda , Matthew Brian Measmer , Arthur Joseph Sullivan , Yoshiaki Kirino , James Peter Stokes
发明人： Andy Haishung TSOU , Yoshihiro Soeda , Matthew Brian Measmer , Arthur Joseph Sullivan , Yoshiaki Kirino , James Peter Stokes
IPC分类号： B60C1/00
CPC分类号： B32B7/12 , B32B25/04 , B32B25/08 , B32B25/16 , B32B2307/724 , B32B2307/7265 , B32B2319/00 , B32B2377/00 , B32B2605/00 , B60C1/0008 , B60C1/0025 , B60C5/14 , C08L9/00 , C08L23/16 , C08L23/283 , C08L2312/00 , Y10T152/10495 , Y10T152/10855 , Y10T428/1386 , Y10T428/31721 , Y10T428/3175 , Y10T428/31797 , Y10T428/31826 , Y10T428/3183 , Y10T428/31917 , C08L2666/04 , C08L2666/06 , C08L2666/08 , C08L2666/02
摘要： A vulcanizable layered composition comprising at least two layers and at least one tie layer. The first layer of the two layers comprises an fluid permeation prevention layer, the second layer of the two layers comprises at least one high diene rubber, and the tie layer comprises about 50 to about 100 weight % of at least one halogenated isobutylene containing elastomer; up to about 50 weight % of at least one high diene elastomer; about 20 to about 50 weight % of at least one filler; up to about 30 weight % of at least one processing oil; about 1 to about 20 parts per hundred (phr) of at least one tackifier; and about 0.2 to about 15 parts per hundred of rubber (phr) of a curing system for the elastomers. The fluid permeation prevention layer preferably comprises a thermoplastic engineering resin component and an elastomer component.
摘要翻译：一种可硫化的层状组合物，其包含至少两层和至少一层粘结层。两层的第一层包括防止流体渗透的层，所述两层的第二层包含至少一种高二烯橡胶，并且所述粘结层包含约50至约100重量％的至少一种含卤代异丁烯的弹性体; 至多约50重量％的至少一种高二烯弹性体; 约20至约50重量％的至少一种填料; 至多约30重量％的至少一种加工油; 约1至约20份/ 100（phr）的至少一种增粘剂; 和约0.2至约15份/ 100份橡胶（phr）的弹性体固化体系。流体防渗层优选包含热塑性工程树脂组分和弹性体组分。

3. 发明授权

US07538158B2 Thermoplastic elastomer composition having viscosity-enhanced and vulcanized elastomer dispersions 有权
标题翻译：具有粘度增强和硫化弹性体分散体的热塑性弹性体组合物
公开(公告)号：US07538158B2
公开(公告)日：2009-05-26
申请号：US10548059
申请日：2003-03-06
申请人： Andy Haishung Tsou , Yoshihiro Soeda , Hsien-Chang Wang , Matthew Brian Measmer
发明人： Andy Haishung Tsou , Yoshihiro Soeda , Hsien-Chang Wang , Matthew Brian Measmer
IPC分类号： C08L51/04 , C08L77/00
CPC分类号： C08L23/283 , C08L77/00 , C08L2666/20
摘要： A thermoplastic elastomer composition having improved mechanical properties and fatigue resistance comprising (A) a halogenated isobutylene elastomer, (B) polyamide and (C) an amine component selected from tertiary amines and secondary diamines, wherein the elastomers are dispersed as a domain in a continuous phase of the polyamide.
摘要翻译：一种具有改进的机械性能和抗疲劳性的热塑性弹性体组合物，其包含（A）卤代异丁烯弹性体，（B）聚酰胺和（C）选自叔胺和仲二胺的胺组分，其中弹性体作为结构域分散在连续聚酰胺的相。

4. 发明申请

US20090218024A1 CONSTRUCTION COMPRISING TIE LAYER 审中-公开
标题翻译：施工包括层层
公开(公告)号：US20090218024A1
公开(公告)日：2009-09-03
申请号：US12091670
申请日：2006-09-29
申请人： Andy Haishung Tsou , Yoshihiro Soeda , Matthew Brian Measmer , Arthur Joseph Sullivan , Yoshiaki Kirino , James Peter Stokes
发明人： Andy Haishung Tsou , Yoshihiro Soeda , Matthew Brian Measmer , Arthur Joseph Sullivan , Yoshiaki Kirino , James Peter Stokes
IPC分类号： B60C5/00 , B32B27/08 , B32B27/32 , B32B27/06 , B32B1/08 , B29D30/08
CPC分类号： B32B7/12 , B32B25/04 , B32B25/08 , B32B25/16 , B32B2307/724 , B32B2307/7265 , B32B2319/00 , B32B2377/00 , B32B2605/00 , B60C1/0008 , B60C1/0025 , B60C5/14 , C08L9/00 , C08L23/16 , C08L23/283 , C08L2312/00 , Y10T152/10495 , Y10T152/10855 , Y10T428/1386 , Y10T428/31721 , Y10T428/3175 , Y10T428/31797 , Y10T428/31826 , Y10T428/3183 , Y10T428/31917 , C08L2666/04 , C08L2666/06 , C08L2666/08 , C08L2666/02
摘要： This disclosure relates to a vulcanizable layered composition comprising at least two layers and at least one tie layer, wherein the first layer of the two layers comprises an fluid permeation prevention layer, the second layer of the two layers comprises at least one high diene rubber, and the tie layer comprises a mixture of: (1) about 50 to about 100 weight % of at least one halogenated isobutylene containing elastomer; (2) about 0 to about 50 weight % of at least one high diene elastomer; (3) about 20 to about 50 weight % of at least one filler; (4) about 0 to about 30 weight % of at least one processing oil; (5) about 1 to about 20 parts per hundred (phr) of at least one tackifier; and (6) at least about 0.2 to about 15 parts per hundred of rubber (phr) of a curing system for the elastomers; wherein THE fluid permeation prevention layer preferably comprises: (A) at least 10% by weight, based on the total weight of the polymer composition, of at least one thermoplastic engineering resin component, preferably one or more nylon resins; and (B) at least 10% by weight, based on the total weight of the polymer composition, of at least one elastomer component, preferably a brominated isobutylene p-methylstyrene copolymer, and where the total amount of the component (A) and the component (B) is not less than 30% by weight based on the total weight of the polymer composition, wherein the elastomer component (B) is dispersed in a vulcanized or partially vulcanized state, as a discontinuous phase, in a matrix of the thermoplastic resin component (A) in the polymer composition.
摘要翻译：本公开涉及包含至少两层和至少一层粘结层的可硫化层状组合物，其中两层的第一层包含防止流体渗透的层，所述两层的第二层包含至少一种高二烯橡胶，所述粘结层包含以下混合物：（1）约50至约100重量％的至少一种含卤代异丁烯的弹性体; （2）约0至约50重量％的至少一种高二烯弹性体; （3）约20至约50重量％的至少一种填料; （4）约0至约30重量％的至少一种加工油; （5）约1至约20份/ 100（phr）的至少一种增粘剂; 和（6）至少约0.2至约15份/ 100份橡胶（phr）的弹性体固化体系; 其中，所述流体渗透防止层优选包含：（A）至少10重量％，基于所述聚合物组合物的总重量，至少一种热塑性工程树脂组分，优选一种或多种尼龙树脂; 和（B）至少10重量％，基于聚合物组合物的总重量，至少一种弹性体组分，优选溴化异丁烯对甲基苯乙烯共聚物，并且其中组分（A）和组分（B）基于聚合物组合物的总重量不小于30重量％，其中弹性体组分（B）作为不连续相以硫化或部分硫化的状态分散在热塑性塑料的基质中聚合物组合物中的树脂组分（A）。

5. 发明申请

US20080275187A1 Low Permeability Thermoplastic Elastomer Composition 有权
标题翻译：低渗透性热塑性弹性体组合物
公开(公告)号：US20080275187A1
公开(公告)日：2008-11-06
申请号：US12091535
申请日：2005-10-27
申请人： Andy Haishung Tsou , Yoshihiro Soeda , Yuichi Hara , Matthew Brian Measmer
发明人： Andy Haishung Tsou , Yoshihiro Soeda , Yuichi Hara , Matthew Brian Measmer
IPC分类号： C08L77/02
CPC分类号： B60C1/0008 , B60C1/00 , C08L23/26 , C08L23/28 , C08L77/00 , C08L77/02 , C08L77/06 , C08L2205/02 , C08L2205/03 , Y10T428/1352 , Y10T428/1386 , Y10T428/139 , Y10T428/1397 , C08L2666/20 , C08L2666/06
摘要： A thermoplastic elastomer composition possessing superior air impermeability, excellent durability and flexibility. In particular, the composition includes (A) at least one halogenated isobutylene-containing elastomer; and (B) at least one nylon resin having a melting point of about 170° C. to about 260° C.; and (C) a low molecular weight polymeric nylon plasticizer; wherein: (1) the at least one elastomer is present as a dispersed phase of small vulcanized particles in a continuous nylon phase; and (2) the elastomer particles are formed by dynamic vulcanization. Use of a low molecular weight nylon plasticizer provides for improved mixing and rubber dispersion while retaining the high levels of impermeability achievable by the use of nylon resin and halogenated isobutylene-containing elastomer in a dynamically vulcanized composition. Such compositions are particularly useful in applications such as tire innerliners and barrier films or layers as well as hoses.
摘要翻译：具有优异的防空气性，优异的耐久性和柔软性的热塑性弹性体组合物。特别地，组合物包括（A）至少一种含卤代异丁烯的弹性体; 和（B）至少一种熔点为约170℃至约260℃的尼龙树脂; 和（C）低分子量聚合尼龙增塑剂; 其中：（1）所述至少一种弹性体作为连续尼龙相中的小硫化颗粒的分散相存在; 和（2）弹性体颗粒通过动态硫化形成。使用低分子量尼龙增塑剂可提供改进的混合和橡胶分散体，同时保持在动态硫化组合物中使用尼龙树脂和含卤代异丁烯的弹性体可实现的高水平的不渗透性。这样的组合物在诸如轮胎内衬和阻隔膜或层以及软管的应用中特别有用。

6. 发明授权

US08021730B2 Low permeability thermoplastic elastomer composition 有权
标题翻译：低渗透性热塑性弹性体组合物
公开(公告)号：US08021730B2
公开(公告)日：2011-09-20
申请号：US12091535
申请日：2005-10-27
申请人： Andy Haishung Tsou , Yoshihiro Soeda , Yuichi Hara , Matthew Brian Measmer
发明人： Andy Haishung Tsou , Yoshihiro Soeda , Yuichi Hara , Matthew Brian Measmer
IPC分类号： C08L19/00 , C08L77/00 , B29D30/06 , B60C5/14
CPC分类号： B60C1/0008 , B60C1/00 , C08L23/26 , C08L23/28 , C08L77/00 , C08L77/02 , C08L77/06 , C08L2205/02 , C08L2205/03 , Y10T428/1352 , Y10T428/1386 , Y10T428/139 , Y10T428/1397 , C08L2666/20 , C08L2666/06
摘要： A thermoplastic elastomer composition possessing superior air impermeability, excellent durability and flexibility. In particular, the composition includes (A) at least one halogenated isobutylene-containing elastomer; and (B) at least one nylon resin having a melting point of about 170° C. to about 260° C.; and (C) a low molecular weight polymeric nylon plasticizer; wherein: (1) the at least one elastomer is present as a dispersed phase of small vulcanized particles in a continuous nylon phase; and (2) the elastomer particles are formed by dynamic vulcanization. Use of a low molecular weight nylon plasticizer provides for improved mixing and rubber dispersion while retaining the high levels of impermeability achievable by the use of nylon resin and halogenated isobutylene-containing elastomer in a dynamically vulcanized composition. Such compositions are particularly useful in applications such as tire innerliners and barrier films or layers as well as hoses.
摘要翻译：具有优异的防空气性，优异的耐久性和柔软性的热塑性弹性体组合物。特别地，组合物包括（A）至少一种含卤代异丁烯的弹性体; 和（B）至少一种熔点为约170℃至约260℃的尼龙树脂; 和（C）低分子量聚合尼龙增塑剂; 其中：（1）所述至少一种弹性体作为连续尼龙相中的小硫化颗粒的分散相存在; 和（2）弹性体颗粒通过动态硫化形成。使用低分子量尼龙增塑剂可提供改进的混合和橡胶分散体，同时保持在动态硫化组合物中使用尼龙树脂和含卤代异丁烯的弹性体可实现的高水平的不渗透性。这样的组合物在诸如轮胎内衬和阻隔膜或层以及软管的应用中特别有用。

7. 发明授权

US08580877B2 Construction comprising tie layer 有权
标题翻译：结构包括连结层
公开(公告)号：US08580877B2
公开(公告)日：2013-11-12
申请号：US12091608
申请日：2006-10-26
申请人： Andy Haishung Tsou , Yoshihiro Soeda , Matthew Brian Measmer , James Peter Stokes , Yoshiaki Kirino , Arthur Joseph Sullivan
发明人： Andy Haishung Tsou , Yoshihiro Soeda , Matthew Brian Measmer , James Peter Stokes , Yoshiaki Kirino , Arthur Joseph Sullivan
IPC分类号： C09J7/02
CPC分类号： B60C5/14 , B32B7/12 , B32B25/08 , B60C1/0008 , Y10T152/10495 , Y10T428/31797 , Y10T428/31855 , Y10T428/31909
摘要： A vulcanizable layered composition comprising at least two layers and at least one tie layer, wherein the first layer of the two layers is a fluid permeation prevention layer preferably comprising: (A) at least one thermoplastic engineering component and (B) at least one elastomer component; the second layer of the two layers comprises at least one high diene rubber and the tie layer comprises a mixture of: (1) at least one halogenated isobutylene containing elastomer; (2) up to 50 weight % of at least one high diene elastomer; (3) at least one filler; (4) up to 30 weight % of at least one processing oil; (5) at least one tackifier; and (6) a curing system for the elastomers.
摘要翻译：一种可硫化的层状组合物，其包含至少两个层和至少一个粘结层，其中所述两层的第一层是流体防渗层，优选包含：（A）至少一种热塑性工程组分和（B）至少一种弹性体零件; 所述两层的第二层包含至少一种高二烯橡胶，所述粘结层包含以下混合物：（1）至少一种含卤代异丁烯的弹性体; （2）至多50重量％的至少一种高二烯弹性体; （3）至少一种填料; （4）至多30重量％的至少一种加工油; （5）至少一种增粘剂; 和（6）弹性体的固化体系。

8. 发明申请

US20080314492A1 Construction Comprising Tie Layer 有权
标题翻译：构造包含层
公开(公告)号：US20080314492A1
公开(公告)日：2008-12-25
申请号：US12091608
申请日：2006-10-26
申请人： Andy Haishung Tsou , Yoshihiro Soeda , Matthew Brian Measmer , Arthur Joseph Sullivan , Yoshiaki Kirino , James Peter Stokes
发明人： Andy Haishung Tsou , Yoshihiro Soeda , Matthew Brian Measmer , Arthur Joseph Sullivan , Yoshiaki Kirino , James Peter Stokes
IPC分类号： B60C5/12 , B29D30/00 , B32B27/36 , B32B27/08
CPC分类号： B60C5/14 , B32B7/12 , B32B25/08 , B60C1/0008 , Y10T152/10495 , Y10T428/31797 , Y10T428/31855 , Y10T428/31909
摘要： This disclosure relates to a vulcanizable layered composition comprising at least two layers and at least one tie layer, wherein the first layer of the two layers comprises an fluid permeation prevention layer, the second layer of the two layers comprises at least one high diene rubber, and the tie layer comprises a mixture of: (1) about 50 to about 100 weight % of at least one halogenated isobutylene containing elastomer; (2) about 0 to about 50 weight % of at least one high diene elastomer; (3) about 20 to about 50 weight % of at least one filler; (4) about 0 to about 30 weight % of at least one processing oil; (5) about 1 to about 20 parts per hundred (phr) of at least one tackifier; and (6) at least about 0.2 to about 15 parts per hundred of rubber (phr) of a curing system for the elastomers; wherein THE fluid permeation prevention layer preferably comprises: (A) at least 10% by weight, based on the total weight of the polymer composition, of at least one thermoplastic engineering resin component, preferably one or more nylon resins, and (B) at least 10% by weight, based on the total weight of the polymer composition, of at least one elastomer component, preferably a brominated isobutylene p-methylstyrene copolymer, and where the total amount of the component (A) and the component (B) is not less than 30% by weight based on the total weight of the polymer composition, wherein the elastomer component (B) is dispersed in a vulcanized or partially vulcanized state, as a discontinuous phase, in a matrix of the thermoplastic resin component (A) in the polymer composition.
摘要翻译：本公开涉及包含至少两层和至少一层粘结层的可硫化层状组合物，其中两层的第一层包含防止流体渗透的层，所述两层的第二层包含至少一种高二烯橡胶，所述粘结层包含以下混合物：（1）约50至约100重量％的至少一种含卤代异丁烯的弹性体; （2）约0至约50重量％的至少一种高二烯弹性体; （3）约20至约50重量％的至少一种填料; （4）约0至约30重量％的至少一种加工油; （5）约1至约20份/ 100（phr）的至少一种增粘剂; 和（6）至少约0.2至约15份/ 100份橡胶（phr）的弹性体固化体系; 其中，所述流体渗透防止层优选包含：（A）至少10重量％，基于所述聚合物组合物的总重量，至少一种热塑性工程树脂组分，优选一种或多种尼龙树脂，和（B）至少10重量％，基于聚合物组合物的总重量，至少一种弹性体组分，优选溴化异丁烯对甲基苯乙烯共聚物，并且其中组分（A）和组分（B）的总量为不低于30重量％，其中弹性体组分（B）以硫化或部分硫化的状态作为不连续相分散在热塑性树脂组分（A）的基质中，在聚合物组合物中。

9. 发明申请

US20080255310A1 Thermoplastic Elastomer Composition and Process for Producing Same 有权
标题翻译：热塑性弹性体组合物及其制备方法
公开(公告)号：US20080255310A1
公开(公告)日：2008-10-16
申请号：US12091333
申请日：2005-10-27
申请人： Andy Haishung Tsou , Yoshihiro Soeda , Yuichi Hara , Matthew Brian Measmer
发明人： Andy Haishung Tsou , Yoshihiro Soeda , Yuichi Hara , Matthew Brian Measmer
IPC分类号： C08L27/00 , C08L77/06
CPC分类号： C08L21/00 , C08L7/00 , C08L23/283 , C08L53/02 , C08L77/00 , Y10T152/10828 , Y10T152/10846 , C08L2666/08 , C08L2666/20 , C08L2666/06
摘要： A thermoplastic elastomer composition having excellent durability and flexibility while possessing superior air impermeability. In particular, a process for producing a thermoplastic elastomer composition having high rubber content by multistage addition of at least one vulcanizable rubber component, in which the time required to substantially cure the at least one rubber component preferably is less the mixer residence time. Such compositions are particularly useful in applications such as tire innerliners and barrier films or layers.
摘要翻译：一种热塑性弹性体组合物，具有优异的耐久性和柔韧性，同时具有优异的不透气性。特别地，通过多次添加至少一种可硫化橡胶组分来制备具有高橡胶含量的热塑性弹性体组合物的方法，其中基本上固化至少一种橡胶组分所需的时间优选较少是混合器停留时间。这样的组合物特别适用于诸如轮胎内衬和阻挡膜或层的应用。

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