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    • 6. 发明授权
    • Multiunsaturates removal process
    • 多重删除过程
    • US5520722A
    • 1996-05-28
    • US375434
    • 1995-01-18
    • Frank HershkowitzGabor Kiss
    • Frank HershkowitzGabor Kiss
    • B01D53/14C07C45/50
    • C07C45/50B01D53/1487Y02P20/582
    • The invention is a process for the preferential removal of a variable amount of alkynes and multiunsaturates from a gas stream containing at least hydrogen, olefins, alkynes, and multiunsaturates by contacting a gas stream containing H.sub.2, olefins, alkynes and multiunsaturates with a metal complex-containing stream selected from the group consisting of liquids and slurries, at conditions sufficient to form multiunsaturate adducts of the metal complex, by introducing the metal complex stream at a rate sufficient to form stoichiometric adducts of the alkynes and multiunsaturates to be removed, and removing the alkyne and multiunsaturate adducts of the metal complex. The invention has utility for removal of multiunsaturates from multicomponent syngas streams.
    • 本发明是一种通过使包含H 2,烯烃,炔和多不饱和化合物的气流与金属络合物的气流接触,优选从至少包含氢,烯烃,炔和多不饱和物的气流中除去可变量的炔和多不饱和物的方法, 在足以形成金属络合物的多不饱和加合物的条件下,通过以足以形成待除去的炔和多不饱和化合物的化学计量加合物的速率引入金属络合物流,将含有物流选自由液体和浆料组成的组中, 炔和多不饱和的金属络合物的加合物。 本发明可用于从多组分合成气流中除去多不饱和物。
    • 8. 发明授权
    • Unsaturates recovery and recycle process
    • 不饱和的回收和回收过程
    • US5516965A
    • 1996-05-14
    • US375432
    • 1995-01-18
    • Frank HershkowitzGabor Kiss
    • Frank HershkowitzGabor Kiss
    • C07C7/11C07C45/50C07C45/78C07C7/00
    • C07C45/783C07C45/50C07C7/11Y02P20/582
    • The invention relates to a process for recovering unreacted unsaturated hydrocarbons from an effluent stream of a process for synthesizing oxygenated hydrocarbons from unsaturated hydrocarbons, said stream containing unreacted unsaturated hydrocarbons, oxygenated reaction products, and low-boiling gaseous components selected from the group including CO, H.sub.2, CO.sub.2, H.sub.2 O, C.sub.1 -C.sub.5 alkanes, nitrogen, helium, and argon by absorbing the unreacted unsaturated hydrocarbons and the oxygenated hydrocarbons of the synthesis process effluent stream in a solvent wherein said solvent is an unsaturates-depleted stream of the oxygenated product of said synthesis process, and stripping the unsaturated hydrocarbons from the solvent to produce a first stream concentrated in unsaturates and a second stream of oxygenated product depleted in unsaturates, wherein said unsaturates-depleted stream is the absorption solvent and the synthesis process product.
    • 本发明涉及从不饱和烃合成含氧烃的方法的流出物流中回收未反应的不饱和烃的方法,所述物流含有未反应的不饱和烃,含氧反应产物和选自CO, H 2,CO 2,H 2 O,C 1 -C 5烷烃,氮,氦和氩,通过在溶剂中吸收合成过程流出物流中的未反应的不饱和烃和氧化烃,其中所述溶剂是贫氧产物的不饱和物流 所述合成方法,以及从所述溶剂中除去不饱和烃以产生浓缩在不饱和化合物中的第一物流和贫化的不饱和化合物的第二氧化产物流,其中所述不饱和物流是吸收溶剂和合成过程产物。
    • 9. 发明授权
    • Direct hydroformylation of a multi-component synthesis gas containing
carbon monoxide, hydrogen, ethylene, and acetylene
    • 含有一氧化碳,氢气,乙烯和乙炔的多组分合成气的直接加氢甲酰化
    • US5675041A
    • 1997-10-07
    • US573052
    • 1995-12-15
    • Gabor KissFrank HershkowitzHarry W. DeckmanMichael Gerard MatturroIstvan T. HorvathAnthony M. DeanRaymond A. Cook
    • Gabor KissFrank HershkowitzHarry W. DeckmanMichael Gerard MatturroIstvan T. HorvathAnthony M. DeanRaymond A. Cook
    • C07C45/50
    • C07C45/50Y02P20/582
    • The invention is a process for production of C.sub.3 to C.sub.6 aldehydes by hydroformylating a mixture containing: (a) C.sub.2 to C.sub.5 olefins and mixtures thereof, and (b) (i) C.sub.2 to C.sub.5 alkynes and mixtures thereof or (ii) C.sub.3 to C.sub.5 cumulated dienes and mixtures thereof or (iii) mixtures of (i) and (ii), with CO, H.sub.2 and a solution of a rhodium complex catalyst produced by complexing Rh and an organophosphorus compound at a concentration of Rh in solution from 1 to 1000 ppm by weight. Alternatively, the solution of rhodium complex catalyst can have a P/Rh atom ratio of at least 30. Alternatively, the solution of rhodium complex catalyst can have a P/Rh atom ratio greater than the value R.sub.L defined by the formula: ##EQU1## in which R.sub.B is the P/Rh ratio sufficient for a catalytically active Rh complex, pKa.sub.TPP is the pKa value for triphenylphosphine, pKa.sub.L is the pKa value for the triorganophosphorus compound, R is the gas constant, and .DELTA.S.sub.B is 35(N-1) cal/mole/.degree.K., N is the number of P-Rh attachments per ligand molecule. The process has utility for the hydroformylation of streams that contain olefins and alkynes.
    • 本发明是通过加氢甲酰化含有:(a)C 2〜C 5烯烃及其混合物的混合物,和(b)(ⅰ)C2〜C5炔烃及其混合物或(ⅱ)C3〜C5 累积的二烯及其混合物,或(iii)(ⅰ)和(ⅱ)的混合物与CO,H 2和铑络合物催化剂的溶液形成,所述铑配合物催化剂是通过使Rh和溶液中Rh浓度为1〜1000的有机磷化合物 重量ppm。 或者,铑络合物催化剂的溶液的P / Rh原子比可以至少为30.另外,铑络合物催化剂的溶液可以具有大于由下式定义的值RL的P / Rh原子比: 其中RB是催化活性Rh配合物的P / Rh比,pKaTPP是三苯基膦的pKa值,pKaL是三有机磷化合物的pKa值,R是气体常数,DELTA SB是35(N-1 )cal / mole / DEGK,N是每个配体分子的P-Rh附着物的数目。 该方法可用于含有烯烃和炔烃的物流的加氢甲酰化。