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1. 发明授权

US5917023A Reductive coupling of nitrobenzene or nitrobenzenes substituted on the nucleus to give the corresponding azobenzenes and azoxybenzenes by means of redox catalysts 失效
标题翻译：在核上取代的硝基苯或硝基苯的还原偶联，通过氧化还原催化剂得到相应的偶氮苯和偶氮氧苯
公开(公告)号：US5917023A
公开(公告)日：1999-06-29
申请号：US869760
申请日：1997-06-05
申请人： Alfred Hagemeyer , Daniel Heineke , Guido Voit , Tom Witzel
发明人： Alfred Hagemeyer , Daniel Heineke , Guido Voit , Tom Witzel
IPC分类号： B01J23/18 , C07B61/00 , C07C245/08 , C07C291/08
CPC分类号： C07C245/08 , C07C291/08
摘要： Nitrobenzene or a nitrobenzene substituted on the nucleus is subjected to reductive coupling to give the corresponding azobenzene and azoxybenzene under heterogeneous catalysis with substantial avoidance of overreduction to aniline derivatives by means of a redox catalyst in its reduced or partly reduced form, the redox catalyst containing at least one active metal component capable of a change of oxidation state.
摘要翻译：在核上取代的硝基苯或硝基苯进行还原偶联，在非均相催化下得到相应的偶氮苯和偶氮氧苯，基本上避免了通过其还原或部分还原形式的氧化还原催化剂将苯胺衍生物过度还原，至少一种能够改变氧化态的活性金属组分。

2. 发明授权

US6022999A Preparation of 3-aminomethyl-3,5,5-trimethylcyclohexylamine having a cis/trans isomer ratio of at least 70:30 有权
标题翻译：具有顺式/反式异构体比例为70:30以上的3-氨基甲基-3,5,5-三甲基环己胺的制备
公开(公告)号：US6022999A
公开(公告)日：2000-02-08
申请号：US207623
申请日：1998-12-09
申请人： Guido Voit , Tom Witzel , Boris Breitscheidel , Hermann Luyken , Karl-Heinz Ross , Peter Wahl
发明人： Guido Voit , Tom Witzel , Boris Breitscheidel , Hermann Luyken , Karl-Heinz Ross , Peter Wahl
IPC分类号： C07C209/26 , C07C209/48 , C07C209/52 , C07C211/36 , C07C209/22
CPC分类号： C07C209/26 , C07C209/48 , C07C209/52
摘要： A process for the preparation of 3-aminomethyl-3,5,5-trimethylcyclohexylamine having a cis/trans isomer ratio of at least 70:30 bya) imination of 3-cyano-3,5,5-trimethylcyclohexanone with ammonia in the presence of an imination catalyst at temperatures of from 20.degree. to 150.degree. C. and pressures of from 1.5 to 30 MPa to form 3-cyano-3,5,5-trimethylcyclo-hexanone imine followed byb) hydrogenation of the 3-cyano-3,5,5-trimethylcyclohexanone imine in the presence of ammonia over a catalyst containing copper and/or a Group VIII metal at a temperature of from 80.degree. to 160.degree. C. and under a pressure of from 5 to 30 MPa,wherein the catalytic hydrogenation of the 3-cyano-3,5,5-trimethylcyclohexanone imine is carried out in the presence of an acid used in an amount such as to give an acid number of from 0.1 to 2, based on 3-cyano-3,5,5-trimethylcyclohexanone used.
摘要翻译：一种制备顺式/反式异构体比例至少为70:30的3-氨基甲基-3,5,5-三甲基环己胺的制备方法，通过以下步骤：a）将3-氰基-3,5,5-三甲基环己酮与氨在在20至150℃的温度和1.5至30MPa的压力下存在仿制催化剂以形成3-氰基-3,5,5-三甲基环己酮亚胺，随后b）氢化3-氰基 -3,5,5-三甲基环己酮亚胺在含有铜和/或Ⅷ族金属的催化剂的存在下在80至160℃的温度和5至30MPa的压力下进行，其中 3-氰基-3,5,5-三甲基环己酮亚胺的催化氢化在酸的存在下进行，所用酸的用量使得酸值为0.1-2，基于3-氰基-3 ，使用5,5-三甲基环己酮。

3. 发明授权

US5756845A Preparation of 3-aminomethyl-3,5,5-trimethylcyclohexylamine 失效
标题翻译： 3-氨基甲基-3,5,5-三甲基环己胺的制备
公开(公告)号：US5756845A
公开(公告)日：1998-05-26
申请号：US608485
申请日：1996-02-28
申请人： Guido Voit , Tom Witzel , Boris Breitscheidel , Wolfgang Harder , Hermann Luyken , Axel Paul , Karl-Heinz Ross , Peter Wahl
发明人： Guido Voit , Tom Witzel , Boris Breitscheidel , Wolfgang Harder , Hermann Luyken , Axel Paul , Karl-Heinz Ross , Peter Wahl
IPC分类号： B01J23/46 , B01J23/75 , B01J23/755 , C07B61/00 , C07C209/48 , C07C211/36
CPC分类号： C07C209/48 , C07C2101/14
摘要： A process for the preparation of 3-aminomethyl-3,5,5-trimethylcyclohexylamine from 3-cyano-3,5,5-trimethylcyclohexanone which requires three spatially separated reaction spaces, in order to carry out the following three steps in sequence: a) reacting the 3-cyano-3,5,5-trimethylcyclohexanone with excess ammonia on acidic metal-oxide catalysts in a first reaction space at from 20.degree. to 150.degree. C. and from 50 to 300 bar, b) hydrogenating the resultant reaction products using hydrogen in a second reaction space in the presence of excess ammonia and preferably liquid ammonia on hydrogenation catalysts, optionally using basic components or on neutral or basic supports at from 50.degree. to 100.degree. C. and at from 50 to 300 bar, and c) hydrogenating the resultant reaction products in the presence of hydrogen and also ammonia in a third reaction space on hydrogenation catalysts, optionally using basic components or on neutral or basic supports at from 110.degree. to 160.degree. C. and at from 150 to 300 bar.These three steps in sequence provide a substantially complete reaction of the original 3-cyano-3,3,5-trimethylcyclohexanone reactant with a yield of 96% of the desired diamino product in which the cis-content of the diamine is 70%.
摘要翻译：从3-氰基-3,5,5-三甲基环己酮制备3-氨基甲基-3,5,5-三甲基环己胺的方法，其需要三个空间分离的反应空间，以便按顺序进行以下三个步骤：a ）在20至150℃和50至300巴的第一反应空间中使3-氰基-3,5,5-三甲基环己酮与过量的氨在酸性金属氧化物催化剂上反应，b）将所得反应物氢化在氢化催化剂存在下，在过量氨和优选液氨存在下在第二反应空间中使用氢的产物，任选使用碱性组分或在中性或碱性载体上在50至100℃和50至300巴条件下，以及 c）在氢化催化剂的第三反应空间中，在氢气和氨的存在下氢化所得反应产物，任选使用碱性组分或在中性或碱性载体上在110至160℃和150至300b ar。这三个步骤依次提供原始3-氰基-3,3,5-三甲基环己酮反应物的基本上完全的反应物，其中二胺的顺式含量为70％的所需二氨基产物的产率为96％。

4. 发明授权

US5679855A Preparation of benzophenone imines 失效
标题翻译：二苯甲酮亚胺的制备
公开(公告)号：US5679855A
公开(公告)日：1997-10-21
申请号：US561300
申请日：1995-11-21
申请人： Guido Voit , Martin Holderbaum , Tom Witzel , Alexander Aumuller
发明人： Guido Voit , Martin Holderbaum , Tom Witzel , Alexander Aumuller
IPC分类号： B01J21/06 , C07B61/00 , C07C249/02 , C07C251/16 , C07C251/24
CPC分类号： C07C251/16 , C07C249/02
摘要： A process for preparing benzophenone imines of the general formula I ##STR1## where R.sup.1 to R.sup.6 are hydrogen, C.sub.1 -to C.sub.4 -alkoxy, C.sub.1 -to C.sub.2 -alkylamine or C.sub.2 -to C.sub.4 -dialkylamine, by reacting benzophenones of the general formula II ##STR2## where R.sup.1 to R.sup.6 have the abovementioned meanings, in liquid ammonia in the presence of oxides of the elements boron, aluminum, gallium, indium, silicon, germanium, tin, lead, phosphorus, arsenic, antimony, bismuth, scandium, yttrium, titanium, zirconium, vanadium, niobium, tantalum or mixtures thereof at from 50.degree. to 150.degree. C. and from 50 to 350 bar is described.
摘要翻译：制备通式I的二苯甲酮亚胺的方法，其中R 1至R 6为氢，C 1至C 4 - 烷氧基，C 1至C 2 - 烷基胺或C 2至C 4 - 二烷基胺，通过使通式II其中R 1至R 6具有上述含义，在硼，铝，镓，铟，硅，锗，锡，铅，磷，砷，锑元素的氧化物存在下在液氨中描述了50至150℃和50至350巴的铋，钪，钇，钛，锆，钒，铌，钽或其混合物。

5. 发明授权

US5705699A Preparation of 3-aminomethyl-3,5,5-trimethylcyclohexylamine 失效
标题翻译： 3-氨基甲基-3,5,5-三甲基环己胺的制备
公开(公告)号：US5705699A
公开(公告)日：1998-01-06
申请号：US395323
申请日：1995-02-28
申请人： Tom Witzel , Guido Voit
发明人： Tom Witzel , Guido Voit
IPC分类号： C07B61/00 , C07C209/26 , C07C209/48 , C07C209/52 , C07C211/36 , C07C253/30 , C07C209/16
CPC分类号： C07C211/36 , C07C209/26 , C07C209/48 , C07C209/52 , C07C253/30 , C07C2101/14
摘要： 3-Aminomethyl-3,5,5-trimethylcyclohexylamine is prepared by reacting 3-cyano-3,5,5-trimethylcyclohexanone with 3-aminomethyl-3,5,5-trimethylcyclohexylamine and subsequently or simultaneously adding ammonia under a hydrogen pressure of from 50 to 300 bar in the presence of a hydrogenation catalyst at from 20.degree. to 150.degree. C., by a process in which the reaction is carried out without removing the water of reaction.
摘要翻译： 3-氨基甲基-3,5,5-三甲基环己胺通过3-氰基-3,5,5-三甲基环己酮与3-氨基甲基-3,5,5-三甲基环己基胺反应制备，随后或同时在氢气压力下加入氨在20〜150℃的氢化催化剂的存在下，通过不进行反应的水进行反应的方法制备。

6. 发明授权

US5696048A Cobalt catalysts 失效
标题翻译：钴催化剂
公开(公告)号：US5696048A
公开(公告)日：1997-12-09
申请号：US641278
申请日：1996-04-30
申请人： Boris Breitscheidel , Peter Polanek , Guido Voit , Tom Witzel , Gerd Linden , Michael Hesse
发明人： Boris Breitscheidel , Peter Polanek , Guido Voit , Tom Witzel , Gerd Linden , Michael Hesse
IPC分类号： B01J23/889 , B01J27/185 , B01J27/187 , C07B61/00 , C07C209/48 , C07C209/52 , C07C211/03
CPC分类号： B01J23/8892 , B01J27/1853 , B01J27/187 , C07C209/48
摘要： Cobalt catalysts whose catalytically active composition comprises from 55 to 98% by weight of cobalt, from 0.2 to 15% by weight of phosphorus, from 0.2 to 15% by weight of manganese and from 0.05 to 5% by weight of alkali metal, calculated as oxide, are prepared by calcining the catalyst composition, reducing it at final temperatures of from 200.degree. to 400.degree. C. in a stream of hydrogen and subsequently surface-oxidizing it by treatment in a stream of air at final temperatures of from 20.degree. to 60.degree. C. and can be used in a process for hydrogenating organic nitriles and/or imines.
摘要翻译：钴催化剂，其催化活性组合物包含55至98重量％的钴，0.2至15重量％的磷，0.2至15重量％的锰和0.05至5重量％的碱金属，计算为氧化物通过煅烧催化剂组合物，在氢气流中在200-400℃的最终温度下还原，然后在最终温度为20℃至大约20℃的空气流中进行表面氧化， 60℃，可用于氢化有机腈和/或亚胺的方法。

7. 发明授权

US5434291A Preparation of aminopropionitriles 失效
标题翻译：氨基丙腈的制备
公开(公告)号：US5434291A
公开(公告)日：1995-07-18
申请号：US251334
申请日：1994-06-01
申请人： Tom Witzel , Rudolf Kummer , Franz Merger , Guido Voit , Martin Brudermueller , Claus-Ulrich Priester , Wolfgang Harder
发明人： Tom Witzel , Rudolf Kummer , Franz Merger , Guido Voit , Martin Brudermueller , Claus-Ulrich Priester , Wolfgang Harder
IPC分类号： C07C253/18 , C07C253/30 , C07C255/24
CPC分类号： C07C253/30 , C07C255/24
摘要： A process for the preparation of aminopropionitriles of the general formula I ##STR1## in which R denotes hydrogen or methyl, wherein ammonia is caused to react with an acrylonitrile of the general formula II ##STR2## In which the substituent has the aforementioned meanings, in a molar ratio of from 1:1 to 500:1 over a heterogenic catalyst at temperatures ranging from 40.degree. to 180.degree. C. and pressures ranging from 10 to 350 bar.
摘要翻译：（I）的氨基丙腈的制备方法，其中R表示氢或甲基，其中使氨与通式II的丙烯腈反应（II）其中取代基具有上述含义，摩尔比为1：1至500：1，相对于异质催化剂，温度范围为40至180℃，压力范围为10至350巴。

8. 发明授权

US5917080A Preparation of 2-cyano-3,3-diarylacrylic esters 失效
标题翻译：制备2-氰基-3,3-二芳基丙烯酸酯
公开(公告)号：US5917080A
公开(公告)日：1999-06-29
申请号：US952667
申请日：1997-12-01
申请人： Martin Holderbaum , Karl Beck , Alexander Aumuller , Tom Witzel , Guido Voit
发明人： Martin Holderbaum , Karl Beck , Alexander Aumuller , Tom Witzel , Guido Voit
IPC分类号： C07C253/30 , C07C255/41 , C07C255/00
CPC分类号： C07C253/30
摘要： A process for preparing 2-cyano-3,3-diarylacrylic esters of the general formula I ##STR1## where R.sup.1 and R.sup.2 are hydrogen, C.sub.1 -C.sub.12 -alkyl groups, C.sub.- C.sub.12 -alkoxy groups or di(C.sub.1 -C.sub.4 -alkyl)amino groups and R.sup.3 is a C.sub.4 -C.sub.18 -alkyl group which can be interrupted by ether-functional oxygen atoms, by reacting a benzophenone imine of the general formula II ##STR2## with a cyanoacetic ester of the general formula III ##STR3## wherein the reaction is carried out at from 20 to 60.degree. C. and, during this, the liberated ammonia is continuously removed from the reaction mixture with the aid of a stream of gas or by reducing the pressure to from 900 to 100 mbar.
摘要翻译： PCT No.PCT / EP96 / 02238 Sec。 371 1997年12月1日第 102（e）日期1997年12月1日PCT提交1996年5月24日PCT公布。公开号WO96 / 38409 日期：1996年12月5日制备通式Ⅰ的2-氰基-3,3-二芳基丙烯酸酯的方法，其中R1和R2为氢，C1-C12-烷基，C-C12-烷氧基或二（C1-C4 - 烷基）氨基，R3是可以被醚官能的氧原子间隔的C4-C18-烷基，通过使通式II的二苯甲酮亚胺与通式III的氰基乙酸酯反应，其中反应进行在20至60℃范围内，并且在此期间，借助于气流或通过将压力降低至900至100毫巴，将释放的氨从反应混合物中连续除去。

9. 发明授权

US5536691A Cobalt catalysts and a process required for their preparation 失效
标题翻译：钴催化剂及其制备所需的工艺
公开(公告)号：US5536691A
公开(公告)日：1996-07-16
申请号：US269060
申请日：1994-06-30
申请人： Boris Breitscheidel , Peter Polanek , Matthias Irgang , Hermann Petersen , Gerd Linden , Guido Voit , Tom Witzel
发明人： Boris Breitscheidel , Peter Polanek , Matthias Irgang , Hermann Petersen , Gerd Linden , Guido Voit , Tom Witzel
IPC分类号： B01J23/889 , B01J27/185 , B01J27/187 , C07B61/00 , C07C209/48 , C07C209/50 , C07C211/36 , B01J23/04 , B01J23/34 , B01J23/78
CPC分类号： C07C209/50 , B01J23/8892 , B01J27/1853 , B01J27/187 , C07C2101/14
摘要： Cobalt catalysts whose catalytically active material comprises from 55 to 98 wt % of cobalt, from 0.2 to 15 wt % of phosphorus, from 0.2 to 15 wt % of manganese, and from 0.2 to 15 wt % of alkali metal, calculated as oxide, in which the catalyst material is calcined in a first step at final temperatures of from 550.degree. to 750.degree. C. and in a second step at final temperatures of from 800.degree. to 1000.degree. C., and a process for the hydrogenation of organic nitriles and/or imines, in which the novel cobalt catalyst is used.
摘要翻译：钴催化剂，其催化活性材料包含55至98重量％的钴，0.2至15重量％的磷，0.2至15重量％的锰和0.2至15重量％的以氧化物计算的碱金属，催化剂材料在最终温度为550℃至750℃的第一步骤中煅烧，第二步在最终温度为800至1000℃下煅烧，以及有机腈的氢化方法和 /或亚胺，其中使用新的钴催化剂。

10. 发明授权

US5801267A Preparation of aliphatic alpha, omega-aminonitriles 失效
标题翻译：脂肪族α，ω-氨基腈的制备
公开(公告)号：US5801267A
公开(公告)日：1998-09-01
申请号：US846239
申请日：1997-04-28
申请人： Klemens Flick , Johann-Peter Melder , Werner Schnurr , Klaus Ebel , Tom Witzel , Wolfgang Harder , Alwin Rehfinger , Rolf Fischer
发明人： Klemens Flick , Johann-Peter Melder , Werner Schnurr , Klaus Ebel , Tom Witzel , Wolfgang Harder , Alwin Rehfinger , Rolf Fischer
IPC分类号： B01J23/76 , B01J23/78 , B01J23/889 , B01J37/02 , C07C253/30 , C07C255/24 , C07C255/03
CPC分类号： B01J23/76 , B01J23/78 , B01J23/8892 , B01J23/8898 , B01J37/0201 , C07C253/30
摘要： Aliphatic alpha,omega-aminonitriles are prepared by partial hydrogenation of aliphatic alpha,omega-dinitriles at elevated temperatures and superatmospheric pressure in the presence of a solvent and of a catalyst by a process in which the catalyst (a) contains a compound based on a metal selected from the group consisting of nickel, cobalt, iron, ruthenium and rhodium and (b) contains from 0.01 to 25% by weight, based on (a), of a promoter based on a metal selected from the group consisting of palladium, platinum, iridium, osmium, copper, silver, gold, chromium, molybdenum, tungsten, manganese, rhenium, zinc, cadmium, lead, aluminum, tin, phosphorus, arsenic, antimony, bismuth and rare earth metals and (c) from 0 to 5% by weight, based on (a), of a compound based on an alkali metal or on an alkaline earth metal, with the proviso that the component (a) is not based on iron or iron and one of the metals selected from the group consisting of cobalt, ruthenium and rhodium when (b) is a promoter based on a metal selected from the group consisting of titanium, manganese, chromium and molybdenum, and with the further proviso that, when a compound based on only ruthenium or ruthenium and rhodium or nickel and rhodium is selected as component (a), the promoter (b) may be dispensed with.
摘要翻译：脂肪族α，ω-氨基腈通过脂肪族α，ω-二腈在升高的温度和超大气压下，在溶剂和催化剂存在下通过其中催化剂（a）含有基于选自镍，钴，铁，钌和铑的金属和（b）含有基于（a）0.01至25重量％的选自钯，铂，铱，锇，铜，银，金，铬，钼，钨，锰，铼，锌，镉，铅，铝，锡，磷，砷，锑，铋和稀土金属，（c）基于（a）的基于碱金属或碱土金属的化合物为5重量％，条件是组分（a）不以铁或铁为基准，并且其中一种金属选自（b）为舞会时由钴，钌和铑组成的组基于选自钛，锰，铬和钼的金属，另外条件是当仅选择仅钌，钌和铑或镍和铑的化合物作为组分（a）时，启动子（b）可以不用。

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