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1. 发明申请

US20120252993A1 CATALYSTS 失效
标题翻译：催化剂
公开(公告)号：US20120252993A1
公开(公告)日：2012-10-04
申请号：US13493080
申请日：2012-06-11
申请人： Alexander Zelmanovich VOSKOBOYNIKOV , Andrei Fyodorovich Asachenko , Dmitry Konanovich , Mikhail V. Nikulin , Alexey Tzarev , Janne Maaranen , Tiina Vanne , Jyrki Kauhanen , Erik Mansner , Esa Kokko , Laura Saarinen
发明人： Alexander Zelmanovich VOSKOBOYNIKOV , Andrei Fyodorovich Asachenko , Dmitry Konanovich , Mikhail V. Nikulin , Alexey Tzarev , Janne Maaranen , Tiina Vanne , Jyrki Kauhanen , Erik Mansner , Esa Kokko , Laura Saarinen
IPC分类号： C08F4/76 , C07F19/00 , C08F10/14 , C07C13/70 , C07C13/465 , C08F10/02 , C07F17/00 , C07F7/08
CPC分类号： C07F17/00 , C08F4/65912 , C08F4/65916 , C08F10/00 , C08F110/02 , C08F210/16 , C08F4/65927 , C08F2500/07 , C08F2500/12 , C08F2500/03 , C08F2500/18 , C08F210/14
摘要： A complex containing a ligand of formula (I): useful in the formation of olefin polymerization catalysts and their use in olefin polymerization.
摘要翻译：含有式（I）配体的络合物：可用于形成烯烃聚合催化剂及其在烯烃聚合中的应用。

2. 发明申请

US20100305286A1 CATALYSTS 审中-公开
标题翻译：催化剂
公开(公告)号：US20100305286A1
公开(公告)日：2010-12-02
申请号：US12675545
申请日：2008-08-27
申请人： Alexander Zelmanovich Voskoboynikov , Andrei Fyodorovich Asachenko , Dmitry Konanovich , Mikhail V. Nikulin , Alexey Tzarev , Janne Maaranen , Tiina Vanne , Jyrki Kauhanen , Erik Mansner , Esa Kokko , Laura Saarinen
发明人： Alexander Zelmanovich Voskoboynikov , Andrei Fyodorovich Asachenko , Dmitry Konanovich , Mikhail V. Nikulin , Alexey Tzarev , Janne Maaranen , Tiina Vanne , Jyrki Kauhanen , Erik Mansner , Esa Kokko , Laura Saarinen
IPC分类号： C08F4/76 , C07F7/08 , C07F17/00 , B01J31/22 , C08F4/58
CPC分类号： C07F17/00 , C08F4/65912 , C08F4/65916 , C08F10/00 , C08F110/02 , C08F210/16 , C08F4/65927 , C08F2500/07 , C08F2500/12 , C08F2500/03 , C08F2500/18 , C08F210/14
摘要： A complex comprising a ligand of formula (I), wherein each R1, which may be the same or different, is hydrogen, an optionally substituted C1-20 hydrocarbyl group, N(R5)2, silyl, siloxy; an optionally substituted heteroaryl group, an optionally substituted heterocyclyl group or two R1 groups on adjacent carbon atoms taken together may form an optionally substituted 5- to 8-membered fused ring; each R2, which may be the same or different is hydrogen, is hydrogen, an optionally substituted C1-20 hydrocarbyl group, N(R5)2, silyl, siloxy; an optionally substituted heteroaryl group, or an optionally substituted heterocyclyl group; R3, which binds to the 6-membered ring of the indenyl group, is —(Si(R5)2)p—, where p is 1 or 2, —(C(R5)2)n- where n is an integer of 2 or more; each R4 which may be the same or different, is hydrogen, an optionally substituted C1-20 hydrocarbyl group, N(R5)2, silyl, siloxy, an optionally substituted heteroaryl group, an optionally substituted heterocyclyl group or two R4 groups on adjacent carbon atoms taken together can form an optionally substituted 5- to 8-membered fused carbon ring; each R5, which may be the same or different, is hydrogen, an optionally substituted C1-20 hydrocarbyl group, or two R5 groups taken together can form an optionally substituted 5- to 8-membered ring; a is 0 to 3; b is 0 to 3; c is 0 to 4; complexed to a metal ion, M.
摘要翻译：包含式（I）的配体的络合物，其中每个R 1可以相同或不同，为氢，任选取代的C 1-20烃基，N（R 5）2，甲硅烷基，甲硅烷氧基; 任选取代的杂芳基，任选取代的杂环基或相邻碳原子上的两个R 1基团可以一起形成任选取代的5-至8-元稠环; 每个R 2可以相同或不同，为氢，为氢，任选取代的C 1-20烃基，N（R 5）2，甲硅烷基，甲硅烷氧基; 任选取代的杂芳基，或任选取代的杂环基; 结合茚基的6元环的R 3是 - （Si（R 5）2）p - ，其中p是1或2， - （C（R 5）2）n - ，其中n是 2以上; 每个R 4可以相同或不同，为氢，任选取代的C 1-20烃基，N（R 5）2，甲硅烷基，甲硅烷氧基，任选取代的杂芳基，任选取代的杂环基或相邻碳上的两个R 4基团一起取代的原子可以形成任选取代的5至8元稠合碳环; 每个R 5可以相同或不同，为氢，任选取代的C 1-20烃基或两个R 5基团可以形成任选取代的5至8元环; a是0到3; b为0〜3; c为0〜4; 与金属离子络合

3. 发明授权

US08569532B2 Catalysts 失效
标题翻译：催化剂
公开(公告)号：US08569532B2
公开(公告)日：2013-10-29
申请号：US13493080
申请日：2012-06-11
申请人： Alexander Zelmanovich Voskoboynik , Andrei Fyodorovich Asachenko , Dmitry Konanovich , Mikhail V. Nikulin , Alexey Tzarev , Janne Maaranen , Tiina Vanne , Jyrki Kauhanen , Erik Mansner , Esa Kokko , Laura Saarinen
发明人： Alexander Zelmanovich Voskoboynik , Andrei Fyodorovich Asachenko , Dmitry Konanovich , Mikhail V. Nikulin , Alexey Tzarev , Janne Maaranen , Tiina Vanne , Jyrki Kauhanen , Erik Mansner , Esa Kokko , Laura Saarinen
IPC分类号： C07F17/00 , B01J31/22 , C08F4/6592
CPC分类号： C07F17/00 , C08F4/65912 , C08F4/65916 , C08F10/00 , C08F110/02 , C08F210/16 , C08F4/65927 , C08F2500/07 , C08F2500/12 , C08F2500/03 , C08F2500/18 , C08F210/14
摘要： A complex containing a ligand of formula (I): useful in the formation of olefin polymerization catalysts and their use in olefin polymerization.
摘要翻译：含有式（I）配体的络合物：可用于形成烯烃聚合催化剂及其在烯烃聚合中的应用。

4. 发明授权

US08546595B2 Halogen substituted heteroatom-containing metallocene compounds for olefin polymerization 有权
标题翻译：用于烯烃聚合的卤素取代的含杂原子的茂金属化合物
公开(公告)号：US08546595B2
公开(公告)日：2013-10-01
申请号：US13424782
申请日：2012-03-20
申请人： Alexander Z. Voskoboynikov , Alexey N. Ryabov , Mikhail V. Nikulin , Alexander V. Lygin , Dmitry V. Uborsky , Catalina L. Coker , Jo Ann M. Canich
发明人： Alexander Z. Voskoboynikov , Alexey N. Ryabov , Mikhail V. Nikulin , Alexander V. Lygin , Dmitry V. Uborsky , Catalina L. Coker , Jo Ann M. Canich
IPC分类号： C07F17/00 , C08F4/6592
CPC分类号： C08F10/00 , C08F4/65912 , C08F4/65925 , C08F2420/02 , C08F2420/06 , Y10S526/943 , C08F4/65927 , C08F4/6592 , C08F110/06 , C08F2500/02 , C08F2500/03 , C08F210/16 , C08F210/14 , C08F110/02
摘要： Halogen substituted metallocene compounds are described and comprise one or more monocyclic or polycyclic ligands that are pi-bonded to the metal atom and include at least one halogen substituent directly bonded to an sp2 carbon atom at a bondable ring position of the ligand, wherein the or at least one ligand has one or more ring heteroatoms in its cyclic structure. When combined with a suitable activator, these compounds show activity in the polymerization of olefins, such as ethylene and propylene.
摘要翻译：描述了卤素取代的茂金属化合物，并且包含一个或多个单键或多环配体，其与金属原子π键合，并且包括至少一个与配体的可键合环位置上的sp2碳原子键合的卤素取代基，其中或至少一个配体在其环状结构中具有一个或多个环杂原子。当与合适的活化剂组合时，这些化合物在烯烃如乙烯和丙烯的聚合中显示出活性。

5. 发明授权

US08541522B2 Catalyst compounds and use thereof 失效
标题翻译：催化剂化合物及其用途
公开(公告)号：US08541522B2
公开(公告)日：2013-09-24
申请号：US12908268
申请日：2010-10-20
申请人： Garth R. Giesbrecht , Timothy M. Boller , Alexander Z. Voskoboynikov , Andrey F. Asachenko , Mikhail V. Nikulin , Alexey A. Tsarev
发明人： Garth R. Giesbrecht , Timothy M. Boller , Alexander Z. Voskoboynikov , Andrey F. Asachenko , Mikhail V. Nikulin , Alexey A. Tsarev
IPC分类号： C08F4/76 , C08F4/64 , C07F7/00
CPC分类号： C07F7/00
摘要： This invention relates to Group 4 catalyst compounds containing di-anionic tridentate nitrogen/oxygen based ligands. The catalyst compounds are useful, with or without activators, to polymerize olefins, particularly α-olefins, or other unsaturated monomers. Systems and processes to oligomerize and/or polymerize one or more unsaturated monomers using the catalyst compound, as well as the oligomers and/or polymers produced therefrom are also provided.
摘要翻译：本发明涉及含有二阴离子三齿氮/氧基配体的第4族催化剂化合物。催化剂化合物可用于或不使用活化剂聚合烯烃，特别是α-烯烃或其它不饱和单体。还提供了使用催化剂化合物低聚和/或聚合一种或多种不饱和单体的系统和方法，以及由其制备的低聚物和/或聚合物。

6. 发明申请

US20110098430A1 Catalyst Compounds and Use Thereof 失效
标题翻译：催化剂化合物及其用途
公开(公告)号：US20110098430A1
公开(公告)日：2011-04-28
申请号：US12908550
申请日：2010-10-20
申请人： Garth R. GIESBRECHT , Timothy M. Boller , Alexander Z. Voskoboynikov , Andrey F. Asachenko , Mikhail V. Nikulin , Alexey A. Tsarev
发明人： Garth R. GIESBRECHT , Timothy M. Boller , Alexander Z. Voskoboynikov , Andrey F. Asachenko , Mikhail V. Nikulin , Alexey A. Tsarev
IPC分类号： C08F4/76 , C07F7/00 , C07D213/30 , B01J31/12
CPC分类号： C07F7/00
摘要： This invention relates to Group 4 catalyst compounds containing di-anionic tridentate nitrogen/oxygen based ligands. The catalyst compounds are useful, with or without activators, to polymerize olefins, particularly α-olefins, or other unsaturated monomers. Systems and processes to oligomerize and/or polymerize one or more unsaturated monomers using the catalyst compound, as well as the oligomers and/or polymers produced therefrom are also provided.
摘要翻译：本发明涉及含有二阴离子三齿氮/氧基配体的第4族催化剂化合物。催化剂化合物在有或没有活化剂的情况下可用于聚合烯烃，特别是α-烯烃或其它不饱和单体。还提供了使用催化剂化合物低聚和/或聚合一种或多种不饱和单体的系统和方法，以及由其制备的低聚物和/或聚合物。

7. 发明授权

US07910783B2 Preparation of substituted bridged indenyl and related ligands 失效
标题翻译：取代的桥连茚基和相关配体的制备
公开(公告)号：US07910783B2
公开(公告)日：2011-03-22
申请号：US11302846
申请日：2005-12-14
申请人： Alexander Z. Voskoboynikov , Mikhail V. Nikulin , Alexey N. Ryabov , Alexander V. Lygin , Catalina L. Coker , Jo Ann M. Canich
发明人： Alexander Z. Voskoboynikov , Mikhail V. Nikulin , Alexey N. Ryabov , Alexander V. Lygin , Catalina L. Coker , Jo Ann M. Canich
IPC分类号： C07C13/28 , C07C13/32 , C07C13/465 , C07C13/567
CPC分类号： C07F17/00
摘要： A process for preparing a chelating ligand of the formula (II) from a chelating ligand of the formula (I) via an sp2-sp2 or sp2-sp3 coupling reaction with an organometallic compound of the formula (III). wherein B is a bridging group that is bonded to L1 and L2 in formula (I) and to L3 and L4 in formula (II); L1 is a substituted monocyclic or polycyclic ligand that comprises at least one chlorine, bromine, iodine, or sulfonate substituent, directly bonded to an sp2 carbon atom of the ring structure of the ligand; L2 is a monoanionic ligand; or L2 may, independently, be defined as L1; L3 is the same group as L1, but said at least one chlorine, bromine, iodine, or sulfonate substituent is replaced with a hydrocarbyl, substituted hydrocarbyl, halocarbyl, or substituted halocarbyl fragment; L4 is the same group as L2, though, when L2 is defined as L1, L4 may be the same as L3 or L1; R1 is a hydrocarbyl, substituted hydrocarbyl, halocarbyl, or substituted halocarbyl; M1 is an element of group 1, 2, 12, 13 or 14 of the Periodic Table of the Elements; each X2, if present, is selected independently from the group consisting of halogen atoms, the hydroxyl group, alkoxy groups, aryloxy groups, mesylate, tosylate and triflate; r is 1, 2 or 3, and t is 0, 1 or 2, where r+t corresponds to the oxidation number of M1.
摘要翻译：通过与式（III）的有机金属化合物的sp2-sp2或sp2-sp3偶联反应从式（I）的螯合配体制备式（II）的螯合配体的方法。其中B是与式（I）中的L1和L2键合并且在式（II）中与L3和L4键合的桥连基团; L1是取代的单环或多环配体，其包含直接键合到配体的环结构的sp2碳原子上的至少一个氯，溴，碘或磺酸盐取代基; L2是单阴离子配体; 或L2可以独立地定义为L1; L3是与L1相同的基团，但是所述至少一个氯，溴，碘或磺酸酯取代基被烃基取代的烃基，卤代烃基或取代的卤代烃基片段代替; L4与L2相同，但当L2定义为L1时，L4可以与L3或L1相同; R 1是烃基，取代的烃基，卤代烃基或取代的卤代烃基; M1是元素周期表第1,2,12,13或14族的元素; 每个X 2如果存在，独立地选自卤素原子，羟基，烷氧基，芳氧基，甲磺酸酯，甲苯磺酸酯和三氟甲磺酸酯; r为1,2或3，t为0,1或2，其中r + t对应于M1的氧化数。

8. 发明授权

US07550544B2 Halogen substituted metallocene compounds for olefin polymerization 有权
标题翻译：用于烯烃聚合的卤素取代的金属茂化合物
公开(公告)号：US07550544B2
公开(公告)日：2009-06-23
申请号：US11302821
申请日：2005-12-14
申请人： Alexander Z. Voskoboynikov , Alexey N. Ryabov , Mikhail V. Nikulin , Alexander V. Lygin , Catalina L. Coker , Jo Ann M. Canich
发明人： Alexander Z. Voskoboynikov , Alexey N. Ryabov , Mikhail V. Nikulin , Alexander V. Lygin , Catalina L. Coker , Jo Ann M. Canich
IPC分类号： C08F4/64 , C08F4/76 , C07F17/00
CPC分类号： C07F17/00 , Y10S526/941 , Y10S526/943
摘要： A metallocene compound is represented by the formula (1): wherein: M is a Group 3, 4, 5 or 6 transition metal atom, or a lanthanide metal atom, or actinide metal atom, preferably a Group 4 transition metal atom selected from titanium, zirconium or hafnium; E is a substituted or unsubstituted monocyclic or polycyclic arenyl ligand pi-bonded to M; A is a substituted or unsubstituted polycyclic arenyl ligand that is pi-bonded to M and has a different ring structure than the E ligand; at least one of the A and E ligands includes at least one halogen substituent directly bonded to an sp2 carbon at a bondable ring position; Y is a bridging group containing at least one Group 13, 14, 15, or 16 element and any single position of the ring structure of A and to any single position of the ring structure of E; and y is zero or 1, indicating the absence (y=0) or presence (y=1) of Y; and each X is a univalent anionic ligand, or two X are joined and bound to the metal atom to form a metallocycle ring, or two X are joined to form a chelating ligand, a diene ligand, or an alkylidene ligand; provided that when E is an unsubstituted cyclopentadienyl ligand, either y is one or A is not 2-bromofluorenyl or 2,7-dibromofluorenyl.
摘要翻译：金属茂化合物由式（1）表示：其中：M是第3,4,5或6族过渡金属原子，或镧系元素金属原子或锕系金属原子，优选选自钛的第4族过渡金属原子，锆或铪; E是与M键合的取代或未取代的单环或多环的烷基配体; A是取代或未取代的与M配体结合并具有不同于E配体的环结构的多环烷基配体; A和E配体中的至少一个配体包括至少一个卤素取代基，直接键合到可结合的环位置上的sp2碳; Y是含有至少一个第13,14,15或16族元素和A的环结构的任何单个位置和E的环结构的任何单个位置的桥连基团; y为0或1，表示Y不存在（y = 0）或存在（y = 1）; 并且每个X是一价阴离子配体，或两个X连接并结合到金属原子以形成金属环，或者两个X连接形成螯合配体，二烯配体或亚烷基配体; 条件是当E是未取代的环戊二烯基配体时，y是1或A不是2-溴芴基或2,7-二溴芴基。

9. 发明授权

US08557936B2 Catalyst compounds and use thereof 失效
公开(公告)号：US08557936B2
公开(公告)日：2013-10-15
申请号：US12908522
申请日：2010-10-20
申请人： Garth R. Giesbrecht , Timothy M. Boller , Alexander Z. Voskoboynikov , Andrey F. Asachenko , Mikhail V. Nikulin , Alexey A. Tsarev
发明人： Garth R. Giesbrecht , Timothy M. Boller , Alexander Z. Voskoboynikov , Andrey F. Asachenko , Mikhail V. Nikulin , Alexey A. Tsarev
IPC分类号： C08F4/76 , C08F4/64 , C07F7/00
CPC分类号： C07F7/00
摘要： This invention relates to Group 4 catalyst compounds containing di-anionic tridentate nitrogen/oxygen based ligands. The catalyst compounds are useful, with or without activators, to polymerize olefins, particularly α-olefins, or other unsaturated monomers. Systems and processes to oligomerize and/or polymerize one or more unsaturated monomers using the catalyst compound, as well as the oligomers and/or polymers produced therefrom are also provided.

10. 发明授权

US08546501B2 Catalyst compounds and use thereof 失效
公开(公告)号：US08546501B2
公开(公告)日：2013-10-01
申请号：US12908550
申请日：2010-10-20
申请人： Garth R. Giesbrecht , Timothy M. Boller , Alexander Z. Voskoboynikov , Andrey F. Asachenko , Mikhail V. Nikulin , Alexey A. Tsarev
发明人： Garth R. Giesbrecht , Timothy M. Boller , Alexander Z. Voskoboynikov , Andrey F. Asachenko , Mikhail V. Nikulin , Alexey A. Tsarev
IPC分类号： C08F4/76 , C08F4/64 , C07F7/00
CPC分类号： C07F7/00
摘要： This invention relates to Group 4 catalyst compounds containing di-anionic tridentate nitrogen/oxygen based ligands. The catalyst compounds are useful, with or without activators, to polymerize olefins, particularly α-olefins, or other unsaturated monomers. Systems and processes to oligomerize and/or polymerize one or more unsaturated monomers using the catalyst compound, as well as the oligomers and/or polymers produced therefrom are also provided.

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