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1. 发明授权

US5684200A Process for the preparation of hydroxylamine ethers and their salts and intermediates for this purpose 失效
标题翻译：为此目的制备羟胺醚及其盐和中间体的方法
公开(公告)号：US5684200A
公开(公告)日：1997-11-04
申请号：US454371
申请日：1995-06-06
申请人： Albrecht Harreus , Norbert Goetz , Volker Maywald , Harald Rang , Ulf Misslitz , Ulrich Klein
发明人： Albrecht Harreus , Norbert Goetz , Volker Maywald , Harald Rang , Ulf Misslitz , Ulrich Klein
IPC分类号： C07C239/20 , C07C251/54 , C07C253/30 , C07C255/54 , C07C259/06 , C07C209/62 , C07C255/62
CPC分类号： C07C251/54
摘要： Hydroxylamine ethers I ##STR1## (where X is NO.sub.2, CN, halogen, alkyl or haloalkyl, Y is H, NO.sub.2, CN, halogen, alkyl or haloalkyl, n is 0-2 or 1-4 where Y and all radicals X are halogen and Alk is unsubstituted or substituted alkylene) and their salts with mineral acids or strong organic acids are prepared by reacting either a hydroximino compound II ##STR2## (where R.sup.1 is alkyl, R.sup.2 is alkyl or alkoxy or R.sup.1 +R.sup.2 form an alkylene chain) in the presence of an alkali metal hydroxide, alkali metal alcoholate, alkali metal bicarbonate or alkali metal carbonate as the base, or the corresponding anion II directly, with an alkylating agent III ##STR3## (where R.sup.3 is unsubstituted or substituted alkyl or unsubstituted or substituted phenyl) to give an oximino derivative IV ##STR4## said derivative is cleaved by means of a mineral acid or a strong organic acid to give the salt of I and, if desired, the latter is converted by means of a base into the free compound I. The hydroxylamine ethers I are intermediates for crop protection agents and drugs.
摘要翻译： PCT No.PCT / EP93 / 03597 371日期：1995年6月6日 102（e）日期1995年6月6日PCT提交1993年12月17日PCT公布。第WO94 / 14757号公报日期：1994年7月7日羟胺醚I（其中X为NO 2，CN，卤素，烷基或卤代烷基，Y为H，NO 2，CN，卤素，烷基或卤代烷基，n为0-2或1-4） Y和所有基团X是卤素，Alk是未取代的或取代的亚烷基），并且它们与无机酸或强有机酸的盐通过氢肟基化合物II（其中R 1是烷基，R 2是烷基或烷氧基或 R1 + R2形成亚烷基链）在碱金属氢氧化物，碱金属醇盐，碱金属碳酸氢盐或作为碱的碱金属碳酸盐或相应的阴离子II的存在下，与烷基化剂III（III R3是未取代或取代的烷基或未取代或取代的苯基），得到肟基衍生物IV所述衍生物通过无机酸或强有机酸裂解，得到I的盐，如果需要，将后者通过碱转化为游离化合物I.羟基氯胺醚我是作物保护剂和药物的中间体。

2. 发明授权

US5403812A Unsaturated cyclohexenone oxime ethers and herbicidal compositions thereof 失效
标题翻译：不饱和环己烯酮肟醚及其除草组合物
公开(公告)号：US5403812A
公开(公告)日：1995-04-04
申请号：US132119
申请日：1993-10-05
申请人： Juergen Kast , Norbert Meyer , Ulf Misslitz , Albrecht Harreus , Harald Rang , Matthias Gerber , Helmut Walter , Karl-Otto Westphalen
发明人： Juergen Kast , Norbert Meyer , Ulf Misslitz , Albrecht Harreus , Harald Rang , Matthias Gerber , Helmut Walter , Karl-Otto Westphalen
IPC分类号： A01N35/10 , A01N43/14 , A01N49/00 , C07C239/20 , C07C251/42 , C07C251/52 , C07C251/54 , C07C251/58 , C07C255/64 , C07C317/28 , C07C323/47 , C07D213/30 , C07D261/08 , C07D275/02 , C07D307/12 , C07D307/52 , C07D309/06 , C07D309/22 , C07D309/28 , C07D317/26 , C07D317/28 , C07D333/20 , C07D333/22 , C07D339/06 , C07D405/12 , C07D409/12 , C07D413/12 , A01N43/10 , A01N43/18 , C07D335/02
CPC分类号： C07D213/30 , A01N35/10 , A01N43/14 , A01N49/00 , C07C239/20 , C07C251/42 , C07C251/52 , C07C317/28 , C07C323/47 , C07D261/08 , C07D307/12 , C07D309/06 , C07D309/22 , C07D309/28 , C07D317/26 , C07D333/22 , C07D339/06 , C07D405/12 , C07D409/12 , C07D413/10 , C07D413/12 , C07C2101/02 , C07C2101/08 , C07C2101/14 , C07C2101/16
摘要： Unsaturated cyclohexenone oxime ethers I ##STR1## (Q=H, alkylcarbonyl, benzoyl, alkali metal or alkaline earth metal ion, substituted or unsubstituted ammonium ion, phosphonium ion, sulfonium ion, sulfoxonium ion, an equivalent of a transition metal cation;W=--C.ident.C-- or --CH=CH--;R.sup.1 =substituted or unsubstituted cycloalkyl, cycloalkenyl or 6-membered heterocyclic group which has 1-2 oxygen and/or sulfur atoms and can be saturated or partially unsaturated; substituted or unsubstituted 5-membered saturated heterocycle with 1-2 oxygen and/or sulfur atoms; substituted or unsubstituted 5-membered heteroaromatic group with 1-2 nitrogen atoms and/or 1 oxygen or sulfur atom; substituted or unsubstituted phenyl, pyridyl or R.sup.9 -X-substituted alkyl with X=O, S, --SO--, --SO.sub.2 -- andR.sup.9 =alkyl, phenyl, 5/6-membered hetaryl with 1-3 hetero atoms;R.sup.2 =alkyl;R.sup.3 =H, alkyl;R.sup.4 =H, halogen, alkyl;R.sup.5 =H, alkyl;or R.sup.3 +R.sup.4, R.sup.3 +R.sup.5 or R.sup.4 +R.sup.5 together form C.sub.2 -C.sub.4 -alkylene or C.sub.2 -C.sub.4 -alkenylene;R.sup.6 =H, alkyl, unsubstituted or phenyl-substituted haloalkyl, alkenyl, alkoxyalkyl, alkylthioalkyl, substituted or unsubstituted cycloalkyl or cycloalkenyl; substituted or unsubstituted phenyl or pyridyl) are suitable as herbicides.
摘要翻译：不饱和环己烯酮肟醚I（Q = H，烷基羰基，苯甲酰基，碱金属或碱土金属离子，取代或未取代的铵离子，鏻离子，锍离子，氧锍离子，当量的过渡金属阳离子; W = -C = C-或-CH = CH-; R 1 =具有1-2个氧和/或硫原子并且可以是饱和或部分不饱和的取代或未取代的环烷基，环烯基或6元杂环基;取代或未取代的5 具有1-2个氧和/或硫原子的饱和杂环;具有1-2个氮原子和/或1个氧或硫原子的取代或未取代的5元杂芳基;取代或未取代的苯基，吡啶基或R9-X取代的具有X = O，S，-SO - ， - SO 2 - 和R 9 =烷基的苯基，具有1-3个杂原子的5-6元杂芳基; R 2 =烷基; R 3 = H，烷基; R 4 = H，卤素，烷基; R5 = H，烷基或R3 + R4，R3 + R5或R4 + R5一起形成C 2 -C 4 - 亚烷基或C 2 -C 4 - 亚烯基; R 6 = H，烷基，未取代的或ph 烯基，烷氧基烷基，烷硫基烷基，取代或未取代的环烷基或环烯基; 取代或未取代的苯基或吡啶基）适合作为除草剂。

3. 发明授权

US6153759A Heterocyclic benzoyl intermediates for herbicidal compounds 失效
标题翻译：用于除草化合物的杂环苯甲酰中间体
公开(公告)号：US6153759A
公开(公告)日：2000-11-28
申请号：US226142
申请日：1999-01-07
申请人： Wolfgang von Deyn , Regina Luise Hill , Uwe Kardorff , Stefan Engel , Martina Otten , Marcus Vossen , Peter Plath , Harald Rang , Albrecht Harreus , Franz Rohl , Helmut Walter , Karl-Otto Westphalen , Ulf Misslitz
发明人： Wolfgang von Deyn , Regina Luise Hill , Uwe Kardorff , Stefan Engel , Martina Otten , Marcus Vossen , Peter Plath , Harald Rang , Albrecht Harreus , Franz Rohl , Helmut Walter , Karl-Otto Westphalen , Ulf Misslitz
IPC分类号： C07D239/26 , A01N43/08 , A01N43/10 , A01N43/74 , A01N43/80 , C07D207/333 , C07D213/50 , C07D213/57 , C07D213/63 , C07D213/70 , C07D213/74 , C07D215/14 , C07D231/12 , C07D231/14 , C07D231/20 , C07D235/18 , C07D261/04 , C07D261/08 , C07D263/14 , C07D263/32 , C07D271/06 , C07D271/10 , C07D275/02 , C07D277/10 , C07D277/20 , C07D277/26 , C07D277/30 , C07D277/32 , C07D277/34 , C07D277/36 , C07D277/66 , C07D279/06 , C07D285/00 , C07D285/08 , C07D285/125 , C07D285/13 , C07D307/46 , C07D317/26 , C07D319/06 , C07D327/06 , C07D333/22 , C07D333/28 , C07D335/02 , C07D339/06 , C07D405/10 , C07D407/10 , C07D409/10 , C07D413/10 , C07D417/10 , C07D307/42 , C07D261/12 , C07D263/20 , C07D271/08 , C07D333/32
CPC分类号： C07D271/06 , A01N43/08 , A01N43/10 , A01N43/74 , A01N43/80 , C07D261/04 , C07D261/08 , C07D263/14 , C07D263/32 , C07D277/26 , C07D307/46 , C07D333/22
摘要： Heterocyclic substituted benzoyl derivatives of the formula ##STR1## where Z is a 5-membered or 6-membered heterocyclic, saturated or unsaturated radical containing one to three hetero atoms selected from the group consisting of oxygen, sulfur and nitrogen, useful as intermediates for herbicidal compounds.
摘要翻译： Z是下式的杂环取代的苯甲酰基衍生物，其中Z是含有1至3个选自氧，硫和氮的杂原子的5元或6元杂环，饱和或不饱和基团，可用作除草化合物的中间体。

4. 发明授权

US5834402A Isoxazolylbenzoyl derivatives 失效
标题翻译：异恶唑基苯甲酰基衍生物
公开(公告)号：US5834402A
公开(公告)日：1998-11-10
申请号：US894481
申请日：1997-08-22
申请人： Wolfgang Von Deyn , Regina Luise Hill , Uwe Kardorff , Stefan Engel , Martina Otten , Marcus Vossen , Peter Plath , Harald Rang , Albrecht Harreus , Franz Rohl , Helmut Walter , Karl-Otto Westphalen , Ulf Misslitz
发明人： Wolfgang Von Deyn , Regina Luise Hill , Uwe Kardorff , Stefan Engel , Martina Otten , Marcus Vossen , Peter Plath , Harald Rang , Albrecht Harreus , Franz Rohl , Helmut Walter , Karl-Otto Westphalen , Ulf Misslitz
IPC分类号： A01N43/80 , C07D261/08 , C07D413/10 , C07D417/10 , C07D261/06 , C07D275/02
CPC分类号： C07D413/10 , A01N43/80 , C07D261/08 , C07D417/10
摘要： Isoxazol-4-ylbenzoyl derivatives of the formula I ##STR1## where the substituents have the meanings described in the specification; and agriculturally customary salts thereof.
摘要翻译： PCT No.PCT / EP96 / 00592 Sec。 371日期1997年8月22日 102（e）日期1997年8月22日PCT提交1996年2月13日PCT公布。出版物WO96 / 26192 日期：1996年8月29日式I的异恶唑-4-基苯甲酰基衍生物，其中取代基具有说明书中描述的含义; 及其农业惯用盐。

5. 发明授权

US6004903A 2-Anylocyclohexanediones having improved herbicidal properties 失效
标题翻译： 2-芳基环己酮具有改善的除草性能
公开(公告)号：US6004903A
公开(公告)日：1999-12-21
申请号：US894247
申请日：1997-08-14
申请人： Wolfgang von Deyn , Regina Luise Hill , Uwe Kardorff , Stefan Engel , Martina Otten , Marcus Vossen , Peter Plath , Harald Rang , Albrecht Harreus , Franz Rohl , Helmut Walter , Karl-Otto Westphalen , Ulf Misslitz
发明人： Wolfgang von Deyn , Regina Luise Hill , Uwe Kardorff , Stefan Engel , Martina Otten , Marcus Vossen , Peter Plath , Harald Rang , Albrecht Harreus , Franz Rohl , Helmut Walter , Karl-Otto Westphalen , Ulf Misslitz
IPC分类号： C07D239/26 , A01N43/08 , A01N43/10 , A01N43/74 , A01N43/80 , C07D207/333 , C07D213/50 , C07D213/57 , C07D213/63 , C07D213/70 , C07D213/74 , C07D215/14 , C07D231/12 , C07D231/14 , C07D231/20 , C07D235/18 , C07D261/04 , C07D261/08 , C07D263/14 , C07D263/32 , C07D271/06 , C07D271/10 , C07D275/02 , C07D277/10 , C07D277/20 , C07D277/26 , C07D277/30 , C07D277/32 , C07D277/34 , C07D277/36 , C07D277/66 , C07D279/06 , C07D285/00 , C07D285/08 , C07D285/125 , C07D285/13 , C07D307/46 , C07D317/26 , C07D319/06 , C07D327/06 , C07D333/22 , C07D333/28 , C07D335/02 , C07D339/06 , C07D405/10 , C07D407/10 , C07D409/10 , C07D413/10 , C07D417/10 , C07D307/54 , A01N43/28 , C07D333/24
CPC分类号： C07D271/06 , A01N43/08 , A01N43/10 , A01N43/74 , A01N43/80 , C07D261/04 , C07D261/08 , C07D263/14 , C07D263/32 , C07D277/26 , C07D307/46 , C07D333/22
摘要： Benzoyl derivatives of the formula I ##STR1## where Z is a 5-membered or 6-membered heterocyclic, saturated or unsaturated radical containing one to three hetero atoms selected from the group consisting of oxygen, sulfur and nitrogen,Q is a cyclohexane-1, 3-dione ring bonded in the 2-position and of the formula II, ##STR2## or conventional agricultural salts of the compounds I.
摘要翻译： PCT No.PCT / EP96 / 00593 Sec。 371日期1997年8月14日 102（e）日期1997年8月14日PCT提交1996年2月13日PCT公布。出版物WO96 / 2620000 日期：1996年8月29日式Ⅰ的苯甲酰衍生物，其中Z是含有1至3个选自氧，硫和氮的杂原子的5元或6元杂环饱和或不饱和基团，Q是环己烷 2-位和式II键合的1,3-二酮环，或化合物I的常规农用盐。

6. 发明授权

US5846906A Herbicidally active phenyldiketone compounds 失效
标题翻译：除草活性苯基二酮化合物
公开(公告)号：US5846906A
公开(公告)日：1998-12-08
申请号：US875659
申请日：1997-07-30
申请人： Wolfgang von Deyn , Regina Luise Hill , Uwe Kardorff , Stefan Engel , Martina Otten , Marcus Vossen , Peter Plath , Harald Rang , Albrecht Harreus , Hartmann Konig , Helmut Walter , Karl-Otto Westphalen , Ulf Misslitz
发明人： Wolfgang von Deyn , Regina Luise Hill , Uwe Kardorff , Stefan Engel , Martina Otten , Marcus Vossen , Peter Plath , Harald Rang , Albrecht Harreus , Hartmann Konig , Helmut Walter , Karl-Otto Westphalen , Ulf Misslitz
IPC分类号： A01N43/78 , A01N43/80 , C07D207/32 , C07D207/327 , C07D207/33 , C07D213/57 , C07D213/64 , C07D213/647 , C07D213/70 , C07D213/74 , C07D215/12 , C07D215/14 , C07D231/12 , C07D231/14 , C07D235/18 , C07D239/26 , C07D239/38 , C07D249/08 , C07D261/04 , C07D261/08 , C07D261/18 , C07D263/32 , C07D271/06 , C07D271/10 , C07D271/107 , C07D275/02 , C07D277/20 , C07D277/22 , C07D277/30 , C07D277/32 , C07D277/34 , C07D277/36 , C07D277/66 , C07D279/06 , C07D285/00 , C07D285/08 , C07D285/12 , C07D285/125 , C07D307/46 , C07D307/54 , C07D317/30 , C07D317/36 , C07D317/44 , C07D319/06 , C07D333/24 , C07D333/28 , C07D333/34 , C07D339/06 , C07D339/08 , A01N43/76 , C07D261/10 , C07D263/30 , C07D307/38 , C07D521/00
CPC分类号： C07D207/327 , A01N43/78 , A01N43/80 , C07D213/57 , C07D213/647 , C07D213/70 , C07D213/74 , C07D215/12 , C07D231/12 , C07D231/14 , C07D235/18 , C07D239/26 , C07D239/38 , C07D249/08 , C07D261/08 , C07D261/18 , C07D263/32 , C07D271/06 , C07D271/107 , C07D275/02 , C07D277/30 , C07D277/32 , C07D277/34 , C07D277/36 , C07D277/66 , C07D279/06 , C07D285/08 , C07D285/125 , C07D307/54 , C07D317/30 , C07D319/06 , C07D333/24 , C07D333/28 , C07D339/06 , C07D339/08
摘要： Herbicidally active phenyldiketone compounds of the formula I ##STR1## in which the substituents have the following meanings: L and M are hydrogen, C.sub.1 -C.sub.6 -alkyl, C.sub.2 -C.sub.6 -alkenyl, C.sub.2 -C.sub.6 -alkynyl, C.sub.1 -C.sub.4 -alkoxy, it being possible for these groups to be unsubstituted or substituted by one to five halogen atoms or C.sub.1 -C.sub.4 -alkoxy, or halogen, cyano, nitro, a group --(Y).sub.n --S(O).sub.m R.sup.7 or a group --(Y).sub.n --CO--R.sup.8, Z is a 5- or 6-membered heterocyclic saturated or unsaturated radical which has one to three hetero atoms selected from the group consisting of oxygen, sulfur or nitrogen and which is unsubstituted or substituted by halogen, cyano, nitro, a group --CO--R.sup.8, C.sub.1 -C.sub.4 -alkyl, C.sub.1 -C.sub.4 -haloalkyl, C.sub.3 -C.sub.8 -cycloalkyl, C.sub.1 -C.sub.4 -alkoxy, C.sub.1 -C.sub.4 -haloalkoxy, C.sub.1 -C.sub.4 -alkylthio, C.sub.1 -C.sub.4 -haloalkylthio, di-C.sub.1 -C.sub.4 -alkylamino or which forms a bicyclic system with a substituted or unsubstituted phenyl ring, a fused carbocycle or a fused second heterocycle, Y is O or NR.sup.9, n is zero or one, m is zero, one or two, R.sup.7 is C.sub.1 -C.sub.4 -alkyl, C.sub.1 -C.sub.4 -haloalkyl or NR.sup.9 R.sup.10, R.sup.8 is C.sub.1 -C.sub.4 -alkyl, C.sub.1 -C.sub.4 -haloalkyl, C.sub.1 -C.sub.4 -alkoxy or NR.sup.9 R.sup.10, R.sup.9 is hydrogen or C.sub.1 -C.sub.4 -alkyl, R.sup.10 is C.sub.1 -C.sub.4 -alkyl, R.sup.1 is cyclopropyl, 1-methylcyclopropyl, 1-methylthiocyclopropyl or tert-butyl; and agriculturally salts of the compounds I.
摘要翻译： PCT No.PCT / EP96 / 00624 Sec。 371日期1997年7月30日 102（e）1997年7月30日PCT PCT 1996年2月14日PCT公布。 WO96 / 26193 PCT出版物日期：1996年8月29日具有下列含义的式I的除草活性苯基二酮化合物其中取代基具有下列含义：L和M为氢，C 1 -C 6 - 烷基，C 2 -C 6 - 烯基，C 2 -C 6 - 炔基， C 1 -C 4 - 烷氧基，这些基团可以是未取代的或被一至五个卤素原子或C 1 -C 4 - 烷氧基取代，或卤素，氰基，硝基， - （Y）nS（O）m R 7或基团 - （Y）n -CO-R 8，Z是具有1至3个选自氧，硫或氮的杂原子的5或6元杂环饱和或不饱和基团，其未被取代或被卤素，氰基，硝基，-CO-R8，C1-C4-烷基，C1-C4卤代烷基，C3-C8-环烷基，C1-C4-烷氧基，C1-C4卤代烷氧基，C1-C4-烷硫基，C1 C 1-4卤代烷硫基，二-C 1 -C 4 - 烷基氨基或其形成具有取代或未取代的苯环，稠合碳环或稠合第二杂环的双环体系，Y为O或NR 9，n为0或1，m为0 一个或两个，R7是C C 1 -C 4烷基，C 1 -C 4卤代烷基或NR 9 R 10，R 8是C 1 -C 4烷基，C 1 -C 4卤代烷基，C 1 -C 4 - 烷氧基或NR 9 R 10，R 9是氢或C 1 -C 4烷基， C4烷基，R1是环丙基，1-甲基环丙基，1-甲硫基环丙基或叔丁基; 和化合物I的农业盐。

7. 发明授权

US5508412A Phthalimides useful as intermediate compounds 失效
标题翻译：邻苯二甲酰亚胺可用作中间体化合物
公开(公告)号：US5508412A
公开(公告)日：1996-04-16
申请号：US508044
申请日：1995-07-27
申请人： Juergen Kast , Norbert Meyer , Ulf Misslitz , Albrecht Harreus , Harald Rang , Matthias Gerber , Helmut Walter , Karl-Otto Westphalen
发明人： Juergen Kast , Norbert Meyer , Ulf Misslitz , Albrecht Harreus , Harald Rang , Matthias Gerber , Helmut Walter , Karl-Otto Westphalen
IPC分类号： A01N35/10 , A01N43/14 , A01N49/00 , C07C239/20 , C07C251/42 , C07C251/52 , C07C251/54 , C07C251/58 , C07C255/64 , C07C317/28 , C07C323/47 , C07D213/30 , C07D261/08 , C07D275/02 , C07D307/12 , C07D307/52 , C07D309/06 , C07D309/22 , C07D309/28 , C07D317/26 , C07D317/28 , C07D333/20 , C07D333/22 , C07D339/06 , C07D405/12 , C07D409/12 , C07D413/12 , C07D209/48
CPC分类号： C07D213/30 , A01N35/10 , A01N43/14 , A01N49/00 , C07C239/20 , C07C251/42 , C07C251/52 , C07C317/28 , C07C323/47 , C07D261/08 , C07D307/12 , C07D309/06 , C07D309/22 , C07D309/28 , C07D317/26 , C07D333/22 , C07D339/06 , C07D405/12 , C07D409/12 , C07D413/10 , C07D413/12 , C07C2101/02 , C07C2101/08 , C07C2101/14 , C07C2101/16
摘要： Unsaturated cyclohexenone oxime ethers I ##STR1## (Q.dbd.H, alkylcarbonyl, benzoyl, alkali metal or alkaline earth metal ion, substituted or unsubstituted ammonium ion, phosphonium ion, sulfonium ion, sulfoxonium ion, an equivalent of a transition metal cation;W=--C.tbd.C-- or --CH.dbd.CH--;R.sup.1 =substituted or unsubstituted cycloalkyl, cycloalkenyl or 6-membered heterocyclic group which has 1-2 oxygen and/or sulfur atoms and can be saturated or partially unsaturated; substituted or unsubstituted 5-membered saturated heterocycle with 1-2 oxygen and/or sulfur atoms; substituted or unsubstituted 5-membered heteroaromatic group with 1-2 nitrogen atoms and/or 1 oxygen or sulfur atom; substituted or unsubstituted phenyl, pyridyl or R.sup.9 -X-substituted alkyl with X=O, S, --SO--, --SO.sub.2 -- and R.sup.9 =alkyl, phenyl, 5/6-membered hetaryl with 1-3 hetero atoms;R.sup.2 =alkyl;R.sup.3 =H, alkyl;R.sup.4 =H, halogen, alkyl;R.sup.5 =H, alkyl;or R.sup.3 +R.sup.4, R.sup.3 +R.sup.5 or R.sup.4 +R.sup.5 together form C.sub.2 -C.sub.4 -alkylene or C.sub.2 -C.sub.4 -alkenylene;R.sup.6 =H, alkyl, unsubstituted or phenyl-substituted haloalkyl, alkenyl, alkoxyalkyl, alkylthioalkyl, substituted or unsubstituted cycloalkyl or cycloalkenyl; substituted or unsubstituted phenyl or pyridyl) are suitable as herbicides.
摘要翻译：不饱和环己烯酮肟醚I（Q = H，烷基羰基，苯甲酰基，碱金属或碱土金属离子，取代或未取代的铵离子，鏻离子，锍离子，氧锍离子，当量的过渡金属阳离子; W = -C 3BOND C-或-CH = CH-; R 1 =具有1-2个氧和/或硫原子并且可以是饱和或部分不饱和的取代或未取代的环烷基，环烯基或6元杂环基;取代或未取代的5 具有1-2个氧和/或硫原子的饱和杂环;具有1-2个氮原子和/或1个氧或硫原子的取代或未取代的5元杂芳基;取代或未取代的苯基，吡啶基或R9-X取代的具有X = O，S，-SO - ， - SO 2 - 和R 9 =烷基的苯基，具有1-3个杂原子的5-6元杂芳基; R 2 =烷基; R 3 = H，烷基; R 4 = H，卤素，烷基; R 5 = H，烷基或R 3 + R 4，R 3 + R 5或R 4 + R 5一起形成C 2 -C 4亚烷基或C 2 -C 4亚烯基; R 6 = H，或苯基取代的卤代烷基，烯基，烷氧基烷基，烷硫基烷基，取代或未取代的环烷基或环烯基; 取代或未取代的苯基或吡啶基）适合作为除草剂。

8. 发明授权

US5407896A Unsaturated cyclohexenone oxime ethers and herbicidal compositions thereof 失效
标题翻译：不饱和环己烯酮肟醚及其除草组合物
公开(公告)号：US5407896A
公开(公告)日：1995-04-18
申请号：US10318
申请日：1993-01-28
申请人： Juergen Kast , Norbert Meyer , Ulf Misslitz , Albrecht Harreus , Harald Rang , Matthias Gerber , Helmut Walter , Karl-Otto Westphalen
发明人： Juergen Kast , Norbert Meyer , Ulf Misslitz , Albrecht Harreus , Harald Rang , Matthias Gerber , Helmut Walter , Karl-Otto Westphalen
IPC分类号： A01N35/10 , A01N43/14 , A01N49/00 , C07C239/20 , C07C251/42 , C07C251/52 , C07C251/54 , C07C251/58 , C07C255/64 , C07C317/28 , C07C323/47 , C07D213/30 , C07D261/08 , C07D275/02 , C07D307/12 , C07D307/52 , C07D309/06 , C07D309/22 , C07D309/28 , C07D317/26 , C07D317/28 , C07D333/20 , C07D333/22 , C07D339/06 , C07D405/12 , C07D409/12 , C07D413/12 , A01N43/16 , C07D309/34
CPC分类号： C07D213/30 , A01N35/10 , A01N43/14 , A01N49/00 , C07C239/20 , C07C251/42 , C07C251/52 , C07C317/28 , C07C323/47 , C07D261/08 , C07D307/12 , C07D309/06 , C07D309/22 , C07D309/28 , C07D317/26 , C07D333/22 , C07D339/06 , C07D405/12 , C07D409/12 , C07D413/10 , C07D413/12 , C07C2101/02 , C07C2101/08 , C07C2101/14 , C07C2101/16
摘要： Unsaturated cyclohexenone oxime ethers I ##STR1## (Q=H, alkylcarbonyl, benzoyl, alkali metal or alkaline earth metal ion, substituted or unsubstituted ammonium ion, phosphonium ion, sulfonium ion, sulfoxonium ion, an equivalent of a transition metal cation;W=--C.tbd.C-- or --CH.dbd.CH--;R.sup.1 =substituted or unsubstituted cycloalkyl, cycloalkenyl or 6-membered heterocyclic group which has 1-2 oxygen and/or sulfur atoms and can be saturated or partially unsaturated; substituted or unsubstituted 5-membered saturated heterocycle with 1-2 oxygen and/or sulfur atoms; substituted or unsubstituted 5-membered heteroaromatic group with 1-2 nitrogen atoms and/or 1 oxygen or sulfur atom; substituted or unsubstituted phenyl, pyridyl or R.sup.9 --X-substituted alkyl with X=O, S, --SO--, --SO.sub.2 -- andR.sup.9 =alkyl, phenyl, 5/6-membered hetaryl with 1-3 hetero atoms;R.sup.2 =alkyl;R.sup.3 =H, alkyl;R.sup.4 =H, halogen, alkyl;R.sup.5 =H, alkyl;or R.sup.3 +R.sup.4, R.sup.3 +R.sup.5 or R.sup.4 +R.sup.5 together form C.sub.2 -C.sub.4 -alkylene or C.sub.2 -C.sub.4 -alkenylene;R.sup.6 =H, alkyl, unsubstituted or phenyl-substituted haloalkyl, alkenyl, alkoxyalkyl, alkylthioalkyl, substituted or unsubstituted cycloalkyl or cycloalkenyl; substituted or unsubstituted phenyl or pyridyl) are suitable as herbicides.
摘要翻译：不饱和环己烯酮肟醚I（Q = H，烷基羰基，苯甲酰基，碱金属或碱土金属离子，取代或未取代的铵离子，鏻离子，锍离子，氧锍离子，当量的过渡金属阳离子; W = -C 3BOND C-或-CH = CH-; R 1 =具有1-2个氧和/或硫原子并且可以是饱和或部分不饱和的取代或未取代的环烷基，环烯基或6元杂环基;取代或未取代的5 具有1-2个氧和/或硫原子的饱和杂环;具有1-2个氮原子和/或1个氧或硫原子的取代或未取代的5元杂芳基;取代或未取代的苯基，吡啶基或R9-X取代的具有X = O，S，-SO - ， - SO 2 - 和R 9 =烷基的苯基，具有1-3个杂原子的5-6元杂芳基; R 2 =烷基; R 3 = H，烷基; R 4 = H，卤素，烷基; R 5 = H，烷基或R 3 + R 4，R 3 + R 5或R 4 + R 5一起形成C 2 -C 4亚烷基或C 2 -C 4亚烯基; R 6 = H，或苯基取代的卤代烷基，烯基，烷氧基烷基，烷硫基烷基，取代或未取代的环烷基或环烯基; 取代或未取代的苯基或吡啶基）适合作为除草剂。

9. 发明授权

US5374609A Cyclohexenone oxime ethers and their use as herbicides 失效
标题翻译：环己烯酮肟醚及其作为除草剂的用途
公开(公告)号：US5374609A
公开(公告)日：1994-12-20
申请号：US65912
申请日：1993-05-25
申请人： Juergen Kast , Norbert Meyer , Ulf Misslitz , Albrecht Harreus , Thomas Kuekenhoehner , Harald Rang , Matthias Gerber , Karl-Otto Westphalen , Helmut Walter
发明人： Juergen Kast , Norbert Meyer , Ulf Misslitz , Albrecht Harreus , Thomas Kuekenhoehner , Harald Rang , Matthias Gerber , Karl-Otto Westphalen , Helmut Walter
IPC分类号： A01N35/10 , A01N37/22 , A01N37/34 , A01N43/08 , A01N43/10 , A01N43/14 , A01N43/16 , A01N43/28 , A01N43/80 , A01P13/00 , C07C239/20 , C07C249/08 , C07C251/42 , C07C251/52 , C07C251/54 , C07C251/58 , C07C251/60 , C07C255/62 , C07C323/47 , C07D213/30 , C07D261/08 , C07D275/02 , C07D307/10 , C07D309/06 , C07D309/08 , C07D309/20 , C07D317/14 , C07D333/06 , C07D335/02 , C07D339/06 , A01N33/24 , C07C251/50
CPC分类号： C07D213/30 , A01N35/10 , A01N43/14 , C07C239/20 , C07C251/42 , C07C251/52 , C07D261/08 , C07D309/06 , C07D309/08 , C07D335/02 , C07C2101/12 , C07C2101/14
摘要： Cyclohexenone oxime ethers I ##STR1## where R.sup.1 is C.sub.1 -C.sub.6 -alkyl, A is unsubstituted or substituted C.sub.3 -C.sub.6 -alkynylene, Z is unsubstituted or substituted phenyl or a 5-membered or 6-membered heteroaromatic and R.sup.2 is C.sub.1 -C.sub.4 -alkoxy-C.sub.1 -C.sub.6 -alkyl, C.sub.1 -C.sub.4 -alkylthio-C.sub.1 -C.sub.6 -alkyl, unsubstituted or substituted C.sub.3 -C.sub.7 -cycloalkyl or C.sub.5 -C.sub.7 -cycloalkenyl, an unsubstituted or substituted 5-membered saturated heterocyclic structure having one or two hetero atoms, an unsubstituted or substituted 6-membered or 7-membered saturated or monounsaturated or diunsaturated heterocyclic structure having one or two hetero atoms, an unsubstituted or substituted 5-membered heteroaromatic having one to three hetero atoms or unsubstituted or substituted phenyl or pyridyl, and their agriculturally useful salts and esters of C.sub.1 -C.sub.10 -carboxylic acids and inorganic acids, are suitable as herbicides.
摘要翻译：环己烯酮肟醚I（I）其中R1是C1-C6-烷基，A是未取代或取代的C3-C6-亚炔基，Z是未取代或取代的苯基或5元或6元杂芳族，R2是C1 C 1 -C 4 - 烷氧基-C 1 -C 6 - 烷基，C 1 -C 4 - 烷硫基-C 1 -C 6 - 烷基，未取代或取代的C 3 -C 7 - 环烷基或C 5 -C 7 - 环烯基，未取代或取代的5元饱和杂环结构，或两个杂原子，具有一个或两个杂原子的未取代或取代的6元或7元饱和或单不饱和或不饱和杂环结构，未取代或取代的具有1至3个杂原子的5元杂芳基或未取代或取代的苯基或吡啶基及其农业上有用的C1-C10-羧酸和无机酸的盐和酯类，适用作除草剂。

10. 发明授权

US5190573A Cyclohexenone oxime ethers, their preparation and their use as herbicides 失效
标题翻译：环己酮氧化物，其制备及其作为除草剂的用途
公开(公告)号：US5190573A
公开(公告)日：1993-03-02
申请号：US697050
申请日：1991-05-08
申请人： Ulf Misslitz , Norbert Meyer , Juergen Kast , Norbert Goetz , Albrecht Harreus , Bruno Wuerzer , Helmut Walter , Karl-Otto Westphalen , Matthias Gerber
发明人： Ulf Misslitz , Norbert Meyer , Juergen Kast , Norbert Goetz , Albrecht Harreus , Bruno Wuerzer , Helmut Walter , Karl-Otto Westphalen , Matthias Gerber
IPC分类号： A01N35/10 , A01N43/08 , A01N43/10 , A01N43/14 , A01N43/16 , A01N43/28 , A01P13/00 , C07C239/20 , C07C251/42 , C07C251/48 , C07C251/50 , C07C251/54 , C07C323/47 , C07D233/88 , C07D249/04 , C07D249/14 , C07D263/32 , C07D275/02 , C07D277/20 , C07D277/24 , C07D277/26 , C07D277/28 , C07D277/30 , C07D307/40 , C07D309/04 , C07D309/06 , C07D333/26 , C07D335/02 , C07D339/06 , C07D401/08 , C07D403/08 , C07D405/08 , C07D409/08 , C07D411/08 , C07D413/08 , C07D417/12
CPC分类号： A01N43/14 , A01N35/10 , C07C239/20 , C07D309/06 , C07D335/02 , C07C2101/16
摘要： Cyclohexenone oxime ethers ##STR1## where R.sup.1 is alkyl;A is substituted or unsubstituted alkylene or alkenylene, where methylene is replaced by an oxygen atom, a sulfur atom, a sulfoxyl group, a sulfonyl group or --NR.sup.a --,Z is phenyl or a 5- or 6-membered heteroaromatic structure;X is substituted or unsubstituted amino, nitro, cyano, halogen, alkyl, C.sub.1 -C.sub.4 -alkoxy, C.sub.1 -C.sub.4 -alkylthio, C.sub.1 -C.sub.4 -haloalkyl, C.sub.1 -C.sub.4 -haloalkoxy, carboxyl, C.sub.1 -C.sub.4 -alkoxycarbonyl, substituted or unsubstituted benzyloxycarbony or phenyl;n is 0 to 3, or 1 to 5 where X is halogen;R.sup.2 is alkoxyalkyl or alkylthioalkyl,substituted or unsubstituted cycloalkyl or cycloalkenyl,a substituted or unsubstituted 5-membered saturated heterocyclic structure with one or two heteroatoms,a substituted or unsubstituted 6- or 7-membered heterocyclic structure with 1-2 heteroatoms and 0-2 double bonds,a substituted or unsubstituted 5-membered heteroaromatic radical with 1-3 heteroatoms, orsubstituted or unsubstituted phenyl or pyridyl,and their agriculturally useful salts and esters of C.sub.1 -C.sub.10 -carboxylic acids and inorganic acids, processes for their manufacture, and their use as herbicides.
摘要翻译：环己烯酮肟醚（Ⅰ）其中R1为烷基; A是取代或未取代的亚烷基或亚烯基，其中亚甲基被氧原子，硫原子，亚砜基，磺酰基或-NR a - 取代，Z是苯基或5-或6-元杂芳族结构; X是取代或未取代的氨基，硝基，氰基，卤素，烷基，C 1 -C 4 - 烷氧基，C 1 -C 4 - 烷硫基，C 1 -C 4卤代烷基，C 1 -C 4卤代烷氧基，羧基，C 1 -C 4烷氧基羰基，苄氧基羰基或苯基; n为0至3，或1至5，其中X为卤素; R 2是烷氧基烷基或烷硫基烷基，取代或未取代的环烷基或环烯基，具有一个或两个杂原子的取代或未取代的5元饱和杂环结构，具有1-2个杂原子的取代或未取代的6或7元杂环结构和0-2 具有1-3个杂原子的取代或未取代的5元杂芳族基团，或取代或未取代的苯基或吡啶基，以及它们在农业上可用的C1-C10-羧酸和无机酸的盐和酯，其制备方法和它们用作除草剂。

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