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    • 1. 发明授权
    • Flame retarded polystyrenic resin composition and molded article of a
polystyrenic resin
    • 阻燃聚苯乙烯树脂组合物和聚苯乙烯树脂的模塑制品
    • US5929154A
    • 1999-07-27
    • US793922
    • 1997-04-07
    • Akitoshi MasuyamaTohru IwashitaShinobu YamaoMasami Mihara
    • Akitoshi MasuyamaTohru IwashitaShinobu YamaoMasami Mihara
    • C08K3/22C08K3/00C08K3/24C08K5/00C08K5/03C08L25/04C08L25/06C08L53/02C08L101/00C08K3/10
    • C08L25/06C08K5/03C08L53/02
    • A flame retarded polystyrenic resin composition comprising: (A) 100 parts by weight of a resin which comprises (a-1) 1 to 100% by weight of a styrenic polymer having the syndiotactic configuration, (a-2) 0 to 10% by weight of a polymer having compatibility or affinity with component (a-1) and having a polar group, and (a-3) 0 to 99% by weight of a thermoplastic resin and/or a rubbery elastomer other than components (a-1) and (a-2), (B) 2 to 100 parts by weight of a brominated diphenyl compound, (C) 0.5 to 50 parts by weight of at least one compound selected from antimony oxides, sodium antimonate, iron oxides, and zinc oxide, the ratio by weight of component (B) to component (C) being in the range of 1 to 10; a flame retarded polystyrenic resin composition comprising (D) an inorganic filler in addition to the above components; and a molded article of a polystyrenic resin prepared by using the compositions as a material. The flame retarded polystyrenic resin composition has an improved flame retarding property while the proper characteristics of syndiotactic polystyrene such as excellent heat stability, chemical resistance, and mechanical strength are maintained, realizes suppressed generation of gases and decreased attachment of-materials to molds during heat molding, and exhibits excellent heat stability so that the molded product is provided with little change in color and mechanical strength.
    • PCT No.PCT / JP96 / 01987 Sec。 371日期1997年4月7日 102(e)1997年4月7日PCT PCT 1996年7月17日PCT公布。 出版物WO97 / 04027 日期:1997年2月6日一种阻燃聚苯乙烯树脂组合物,其包含:(A)100重量份的树脂,其包含(a-1)1至100重量%的具有间同立构构型的苯乙烯聚合物,(a-2) 0〜10重量%的与组分(a-1)具有相容性或亲和性且具有极性基团的聚合物,和(a-3)0至99重量%的热塑性树脂和/或除橡胶弹性体之外的橡胶状弹性体 组分(a-1)和(a-2),(B)2至100重量份溴化二苯基化合物,(C)0.5至50重量份的至少一种选自氧化锑,锑酸钠, 氧化铁和氧化锌,组分(B)与组分(C)的重量比在1至10的范围内; 阻燃聚苯乙烯树脂组合物,除了上述组分外还包含(D)无机填料; 和通过使用该组合物作为材料制备的聚苯乙烯树脂的模塑制品。 阻燃型聚苯乙烯树脂组合物具有改进的阻燃性能,同时保持诸如优异的热稳定性,耐化学性和机械强度的间规聚苯乙烯的适当特性,实现了热成型期间抑制气体的产生和减少材料与模具的附着。 并且表现出优异的热稳定性,使得模制产品的颜色和机械强度几乎没有变化。
    • 10. 发明授权
    • Polyarylene sulfide resin compositions
    • 聚芳硫醚树脂组合物
    • US6117950A
    • 2000-09-12
    • US412987
    • 1999-10-06
    • Shinobu YamaoWataru Kosaka
    • Shinobu YamaoWataru Kosaka
    • C08G75/02C08L63/00C08L77/00C08L77/02C08L77/06C08L81/02C08F283/00
    • C08L77/06C08G75/0222C08G75/029C08L63/00C08L77/00C08L77/02C08L81/02
    • A polyarylene sulfide resin composition contains a polyarylene sulfide containing at least one group selected from a group consisting of an amino group and an amide group, a polyamide resin, an epoxy resin and, as needed, a filler. A further composition contains 100 parts by weight of the polyarylene sulfide, 0.05 to 5 parts of the epoxy resin, and 5 to 400 parts of the filler. Another type of the resin composition contains the polyarylene sulfide, the polyamide, a compound selected from an acid, an acid anhydride and an acid halide, each having in its molecule not less than two functional groups reactive with the amino group or the amide group, and, as needed, the filler. A further type of the resin composition contains the polyarylene sulfide, the compound and, as needed, an inorganic filler subjected to surface treatment with a silane type coupling agent. A still further type of the resin composition contains the polyarylene sulfide and the compound. A still further type of the resin composition contains the polyarylene sulfide and the inorganic filler subjected to surface treatment with an epoxysilane type coupling agent.
    • 聚芳硫醚树脂组合物包含含有选自氨基和酰胺基中的至少一个基团的聚芳硫醚,聚酰胺树脂,环氧树脂和根据需要的填料。 另外的组合物含有聚芳撑硫醚100重量份,环氧树脂0.05〜5重量份,填料5〜400重量份。 另一种类型的树脂组合物含有聚亚芳基硫醚,聚酰胺,选自酸,酸酐和酰卤的化合物,其分子中不少于两个与氨基或酰胺基反应的官能团, 并根据需要填充。 另一种类型的树脂组合物包含聚芳硫醚,该化合物和根据需要的用硅烷型偶联剂进行表面处理的无机填料。 另一种类型的树脂组合物含有聚芳硫醚和该化合物。 另一种类型的树脂组合物包含用环氧硅烷型偶联剂进行表面处理的聚芳硫醚和无机填料。