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    • 2. 发明申请
    • ADAMANTANE DERIVATIVE, PROCESS FOR PRODUCTION THEREOF, RESIN COMPOSITION, AND CURED PRODUCT OF THE RESIN COMPOSITION
    • 衍生物衍生物,其生产方法,树脂组合物和树脂组合物的固化产物
    • US20100048757A1
    • 2010-02-25
    • US12447308
    • 2007-10-24
    • Yasunari OkadaHideki YamaneKatsuki ItoNobuaki Matsumoto
    • Yasunari OkadaHideki YamaneKatsuki ItoNobuaki Matsumoto
    • C08F2/46C07C69/54C08L31/02
    • G03F7/027C07C67/08C07C69/54C07C2603/74C08F20/20C08F20/28
    • Disclosed herein is an adamantane derivative represented by the following general formula (I): (wherein R represents a hydrogen atom, a fluorine atom, a methyl group or a trifluoromethyl group; Y represents a hydrogen atom, a hydroxyl group, ═O formed by two Ys together, a carboxyl group, or a hydrocarbon group having 1 to 20 carbon atoms or a cyclic hydrocarbon group having 3 to 20 carbon atoms; m is 13 and n is 3, or m is 12 and n is 4; and p is an integer of one or more), a production method thereof, a resin composition containing the adamantane derivative, and a cured product thereof. The present invention provides a cured product advantageous as various coating agents, a microlens, a film condenser, a colored composition for a liquid crystal color filter, a pattern organizer formed in nanoimprinting, and the like, having transparency, heat resistance, good mechanical properties, low volume shrinkage, and low coefficient of linear expansion, as well as liquid adamantyl group-containing (meth)acrylates to produce the cured product, the production method thereof, and the resin composition.
    • 本文公开了由以下通式(I)表示的金刚烷衍生物:其中R表示氢原子,氟原子,甲基或三氟甲基; Y表示氢原子,羟基,由式 两个Y一起,一个羧基或一个碳原子数1〜20的烃基或碳原子数3〜20的环状烃基,m为13,n为3,m为12,n为4,p为 1个以上的整数),其制造方法,含有金刚烷衍生物的树脂组合物及其固化物。 本发明提供了作为各种涂布剂,微透镜,薄膜冷凝器,液晶滤色器着色组合物,纳米压印等形成的图案组织器等有利的固化产物,具有透明性,耐热性,良好的机械性能 ,低体积收缩率和低的线性膨胀系数,以及含有金刚烷基的(甲基)丙烯酸酯以制备固化产物,其制备方法和树脂组合物。
    • 4. 发明申请
    • ADAMANTANE DERIVATIVE, METHOD FOR PRODUCING THE SAME, AND RESIN COMPOSITION CONTAINING ADAMANTANE DERIVATIVE
    • 亚胺衍生物,其制备方法和含有衍生物的树脂组合物
    • US20100056663A1
    • 2010-03-04
    • US12516102
    • 2007-11-21
    • Katsuki ItoYasunari OkadaHideki YamaneAkio Kojima
    • Katsuki ItoYasunari OkadaHideki YamaneAkio Kojima
    • C08F2/46C07C39/04C07D303/02C08G65/08C07C69/52
    • C08F20/30C07C39/17C07C67/26C07C2603/74C07D303/30C08G59/3218H05K3/287C07C69/54
    • The present invention is an adamantane derivative which provides optical characteristics such as transparency, (long term) light resistance and the like, long term heat resistance, electric characteristics such as dielectric constant and the like, and good mechanical properties; a production method thereof; and a resin composition containing the above-mentioned adamantane derivative that is an adamantane derivative represented by general formulae (I) to (III); for example, a production method of an adamantane derivative represented by the general formula (III) by reacting an adamantane derivative represented by the general formula (II) with acrylates, a resin composition containing an adamantane derivative represented by the general formula (II) and an epoxy resin curing agent, and a resin composition containing an adamantane derivative represented by the general formula (III) and a thermopolymerization initiator or a photopolymerization initiator.In the formula, R1 represents CnH2n+1 (n is an integer of 1 to 10); R2 represents H, CH3, F or CF3; j is an integer of 1 to 4; k is an integer of 0 to 3; m is an integer of 2 to 5; and j+k+m≦6.
    • 本发明是提供透明性,长期耐光性等长期耐热性,介电常数等电特性等良好的机械特性的光学特性的金刚烷衍生物。 其制造方法; 和含有上述通式(I)〜(III)所示的金刚烷衍生物的金刚烷衍生物的树脂组合物; 例如通过使通式(II)表示的金刚烷衍生物与丙烯酸酯反应的通式(III)表示的金刚烷衍生物的制造方法,含有通式(II)表示的金刚烷衍生物的树脂组合物和 环氧树脂固化剂和含有由通式(III)表示的金刚烷衍生物和热聚合引发剂或光聚合引发剂的树脂组合物。 在该式中,R 1表示C n H 2n + 1(n为1〜10的整数)。 R2代表H,CH3,F或CF3; j为1〜4的整数, k为0〜3的整数, m为2〜5的整数, 和j + k + m≦̸ 6。