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1. 发明授权

US4390737A Process for the ortho-alkylation of phenolic compounds 失效
标题翻译：酚类化合物的邻烷基化方法
公开(公告)号：US4390737A
公开(公告)日：1983-06-28
申请号：US316781
申请日：1981-10-30
申请人： Akihide Kudoh , Motoo Kawamata , Kazushi Ohshima , Makoto Kotani , Takeshi Tsuda , Satoshi Morita
发明人： Akihide Kudoh , Motoo Kawamata , Kazushi Ohshima , Makoto Kotani , Takeshi Tsuda , Satoshi Morita
IPC分类号： B01J23/00 , B01J23/32 , C07B61/00 , C07C27/00 , C07C37/16 , C07C39/06 , C07C67/00
CPC分类号： B01J23/32 , C07C37/16
摘要： This invention relates to a process for the selective ortho-alkylation of a phenolic compound having at least one ortho-positioned hydrogen atom by catalytically reacting the phenolic compound with an alcohol in the vapor phase. In this process, the reaction of the phenolic compound with the alcohol is carried out at a temperature of from 300.degree. to 550.degree. C. in the presence of a catalyst containing manganese oxide, silicon oxide and one or more additives selected from group (A) consisting of germanium oxide, tin oxide and lead oxide, or a catalyst containing manganese oxide, silicon oxide, one or more additives selected from the aforesaid group (A), and one or more additives selected from group (B) consisting of alkali metal oxides and alkaline earth metal oxides. The catalyst used in this invention exhibits not only excellent catalytic activity in the selective ortho-alkylation of phenols, continuous stability of the activity, good shapability, and good mechanical strength but also effective utilization of alcohols.
摘要翻译：本发明涉及一种通过使酚类化合物与气相中的醇催化反应，使具有至少一个邻位氢原子的酚类化合物选择性正烷基化的方法。在该方法中，酚类化合物与醇的反应在含有氧化锰，氧化硅和选自组（A）的一种或多种添加剂的催化剂存在下，在300-550℃的温度下进行。），或者含有氧化锰，氧化硅，选自上述组（A）的一种或多种添加剂的一种或多种添加剂和选自由碱金属（B）组成的组分（B））的一种或多种添加剂组成的催化剂，由氧化锗，氧化锡和氧化铅组成的催化剂，氧化物和碱土金属氧化物。用于本发明的催化剂不仅在酚的选择性邻烷基化中具有优异的催化活性，活性的连续稳定性，良好的成型性和良好的机械强度，而且还有效地利用醇。

2. 发明授权

US4375566A Process for producing ortho-alkylated phenols from anisoles 失效
标题翻译：从苯甲醚生产邻烷基化酚的方法
公开(公告)号：US4375566A
公开(公告)日：1983-03-01
申请号：US264391
申请日：1981-05-18
申请人： Motoo Kawamata , Kazushi Ohshima , Mitsuo Onofusa , Akihide Kudoh , Makoto Kotani , Takeshi Tsuda
发明人： Motoo Kawamata , Kazushi Ohshima , Mitsuo Onofusa , Akihide Kudoh , Makoto Kotani , Takeshi Tsuda
IPC分类号： C07C37/00 , B01J23/00 , C07B61/00 , C07C27/00 , C07C37/055 , C07C37/06 , C07C37/16 , C07C39/06 , C07C39/07 , C07C67/00
CPC分类号： C07C37/055 , C07C37/16 , C07C37/48
摘要： A process for producing selectively o-alkylated phenols wherein an anisole having at least one ortho positioned hydrogen atom is contacted with a mixed oxide catalyst in the vapor phase.
摘要翻译：一种生产选择性邻烷基化酚的方法，其中具有至少一个邻位氢原子的苯甲醚与气相中的混合氧化物催化剂接触。

3. 发明授权

US4388478A Process for the ortho-alkylation of phenolic compounds 失效
标题翻译：酚类化合物的邻烷基化方法
公开(公告)号：US4388478A
公开(公告)日：1983-06-14
申请号：US316800
申请日：1981-10-30
申请人： Akihide Kudoh , Motoo Kawamata , Kazushi Ohshima , Makoto Kotani , Takeshi Tsuda , Fukuichi Aoki
发明人： Akihide Kudoh , Motoo Kawamata , Kazushi Ohshima , Makoto Kotani , Takeshi Tsuda , Fukuichi Aoki
IPC分类号： B01J23/00 , B01J23/32 , B01J23/34 , C07B61/00 , C07C27/00 , C07C37/16 , C07C39/06 , C07C67/00
CPC分类号： B01J23/32 , C07C37/16
摘要： This invention relates to a process for the selective ortho-alkylation of a phenolic compound having at least one ortho-positioned hydrogen atom by catalytically reacting the phenolic compound with an alcohol in the vapor phase. In this process, the reaction of the phenolic compound with the alcohol is carried out at a temperature of from 300.degree. to 550.degree. C. in the presence of a catalyst containing manganese oxide and one or more additives selected from group (A) consisting of germanium oxide, tin oxide and lead oxide, or a catalyst containing manganese oxide, one or more additives selected from the aforesaid group (A), and one or more additives selected from group (B) consisting of alkali metal oxides and alkaline earth metal oxides. The catalyst used in this invention exhibits not only excellent catalytic activity in the selective ortho-alkylation of phenols, continuous stability of the activity, good shapeability and good mechanical strength but also effective utilization of alcohols.
摘要翻译：本发明涉及一种通过使酚类化合物与气相中的醇催化反应，使具有至少一个邻位氢原子的酚类化合物选择性正烷基化的方法。在该方法中，酚类化合物与醇的反应在含有氧化锰和一种或多种选自（A）组成的催化剂的催化剂存在下，在300〜550℃的温度下进行。或者含有氧化锰的催化剂，选自上述组（A）的一种或多种添加剂和选自由碱金属氧化物和碱土金属氧化物组成的组（B）的一种或多种添加剂。用于本发明的催化剂不仅在酚的选择性邻烷基化中表现出优异的催化活性，活性的连续稳定性，良好的成型性和良好的机械强度，而且有效地利用醇。

4. 发明授权

US4361709A Process for the production of o-alkylated phenols 失效
标题翻译：邻烷基化酚的制备方法
公开(公告)号：US4361709A
公开(公告)日：1982-11-30
申请号：US265600
申请日：1981-05-20
申请人： Motoo Kawamata , Kazushi Ohshima , Mitsuo Onofusa , Akihide Kudoh , Makoto Kotani , Takeshi Tsuda
发明人： Motoo Kawamata , Kazushi Ohshima , Mitsuo Onofusa , Akihide Kudoh , Makoto Kotani , Takeshi Tsuda
IPC分类号： B01J23/00 , C07B61/00 , C07C27/00 , C07C37/16 , C07C39/06 , C07C39/07 , C07C67/00 , C07C37/11
CPC分类号： C07C37/16
摘要： A process for the production of alkyl phenols having at least one o-alkyl radical comprising catalytically reacting a phenolic compound having at least one o-positioned hydrogen atom with an alcohol in the vapor phase in the presence of a manganese oxide containing catalyst modified with a compound of at least one of the alkali metals.
摘要翻译：一种制备具有至少一个邻 - 烷基基团的烷基酚的方法，该方法包括在含有氧化锰的催化剂的存在下，使具有至少一个邻位氢原子的酚化合物与醇在气相中催化反应至少一种碱金属的化合物。

5. 发明授权

US4916236A Preparation of indoles by cyclization 失效
标题翻译：通过环化制备吲哚
公开(公告)号：US4916236A
公开(公告)日：1990-04-10
申请号：US270067
申请日：1988-11-14
申请人： Akihide Kudoh , Tadatoshi Honda , Makoto Kotani , Kazuhiro Terada , Takeshi Tsuda , Shinji Kiyono
发明人： Akihide Kudoh , Tadatoshi Honda , Makoto Kotani , Kazuhiro Terada , Takeshi Tsuda , Shinji Kiyono
IPC分类号： C07D209/04 , B01J21/00 , B01J23/00 , B01J27/00 , C07B61/00 , C07D209/08
CPC分类号： C07D209/08
摘要： Disclosed herein is a preparation process for an indole, which process comprises subjecting an N-(.beta.-hydroxy)-alkylaniline, in the presence of a catalyst and at a super-atmospheric pressure, to a gas-phase catalytic reaction. The present process improves the selectivity of the reaction and the service life of the catalyst.
摘要翻译：本文公开了吲哚的制备方法，该方法包括在催化剂存在下和在超大气压下将N-（β-羟基） - 烷基苯胺进行气相催化反应。本方法提高了反应的选择性和催化剂的使用寿命。

6. 发明授权

US4937353A Preparation process for indoles 失效
标题翻译：吲哚的制备方法
公开(公告)号：US4937353A
公开(公告)日：1990-06-26
申请号：US267708
申请日：1988-11-03
申请人： Akihide Kudoh , Tadatoshi Honda , Makoto Kotani , Kazuhiro Terada , Takeshi Tsuda , Shinji Kiyono
发明人： Akihide Kudoh , Tadatoshi Honda , Makoto Kotani , Kazuhiro Terada , Takeshi Tsuda , Shinji Kiyono
IPC分类号： C07D209/08
CPC分类号： C07D209/08
摘要： Disclosed herein is to react an aniline and an ethylene glycol at a superatmospheric pressure in preparing an indole by subjecting the aniline and ethylene glycol to a gas-phase catalytic reaction in the presence of a catalyst, thereby improving the selectivity of the reaction and the service life of the catalyst.
摘要翻译：本文公开了通过在催化剂存在下使苯胺和乙二醇进行气相催化反应，在超大气压下使苯胺和乙二醇反应来制备吲哚，从而提高反应的选择性和使用寿命催化剂的寿命。

7. 发明授权

US09897992B2 Numerical control apparatus 有权
公开(公告)号：US09897992B2
公开(公告)日：2018-02-20
申请号：US14400879
申请日：2012-05-22
申请人： Takeshi Tsuda , Keiichiro Suzuki
发明人： Takeshi Tsuda , Keiichiro Suzuki
IPC分类号： G05B19/19 , G05B19/4103
CPC分类号： G05B19/19 , G05B19/4103 , G05B2219/37618 , G05B2219/41188
摘要： A numerical control apparatus that controls a machine tool including a plurality of linear axes and rotation axes, and controls a relative tool posture with respect to work on a table includes a program reading unit that sequentially reads a tool posture with respect to the work from a machining program, a determining unit that determines whether the read tool posture is within a predetermined tool posture range, a tool-posture control unit that determines control content of the tool posture according to the determination by the determining unit, and an interpolation/acceleration and deceleration processing unit that controls the linear and rotation axes according to the control content of the tool posture. When the read tool posture is within the predetermined range, the tool-posture control unit determines rotation axis angles of the rotation axes such that a change of tool posture from the last tool posture is limited.

8. 发明授权

US09678500B2 Machining program creating device numerical control device, machining system, machining program creating method, numerical control method, and machining program 有权
公开(公告)号：US09678500B2
公开(公告)日：2017-06-13
申请号：US14342989
申请日：2011-09-15
申请人： Takeshi Tsuda , Tsuyoshi Kumazawa , Munetaka Wakizaka
发明人： Takeshi Tsuda , Tsuyoshi Kumazawa , Munetaka Wakizaka
IPC分类号： G05B19/416
CPC分类号： G05B19/416 , G05B2219/35221 , G05B2219/36249
摘要： A numerical control device reads a machining program and causes a machine tool to operate based on the machining program. The numerical control device includes: an acceleration-deceleration determining unit; and a position-command generating unit. The numerical control device is configured to set the acceleration and the deceleration as acceleration-deceleration data when the acceleration and the deceleration satisfy tolerances decided based on actual mechanical dynamic characteristics, and set the tolerances as acceleration-deceleration data when the acceleration and deceleration do not satisfy the tolerances. The position-command generating unit is configured to generate a position command based on the moving command, the acceleration-deceleration data, and the speed at the end of the command route and the superimposition amount subjected to processing by the acceleration-deceleration determining unit.

9. 发明申请

US20140173981A1 AGRICULTURAL COVERING MATERIAL 审中-公开
标题翻译：农业覆盖材料
公开(公告)号：US20140173981A1
公开(公告)日：2014-06-26
申请号：US14237506
申请日：2012-08-08
申请人： Taro Ichikawa , Takeshi Tsuda
发明人： Taro Ichikawa , Takeshi Tsuda
IPC分类号： A01G13/00 , B32B27/32 , B32B5/26
CPC分类号： A01G13/0268 , A01G9/1438 , B32B5/022 , B32B5/26 , B32B27/32 , B32B2250/03 , B32B2250/20 , B32B2262/0253 , B32B2307/412 , B32B2307/724 , B32B2410/00 , D04H1/4291 , D04H1/4374 , D04H1/559 , D04H1/56 , D04H3/16 , Y02A40/252 , Y10T428/24942
摘要： The purpose of the present invention is to provide an agricultural covering material which has a high light transmittance so that it accelerates the growth of crops and has visual confirmation properties to the inside thereof for cultivators, which has a good growth acceleration effect due to heat retention of soil temperature, can suppress ingress of excess amounts of rainwater, has excellent evenness such as a low unevenness in strength and effective prevention of harmful insects which will fly and gather, and which has proper air-permeability. The agricultural covering material of the present invention includes a nonwoven fabric laminate having (i) a light transmittance of 80% or more, (ii) an air-permeability of 50 to 400 cm3/cm2/sec and (iii) a basis weight of 10 to 30 g/cm2.
摘要翻译：本发明的目的是提供一种农业覆盖材料，其具有高的透光率，从而加速作物的生长，并且对于其具有由于保温而具有良好生长加速效应的耕作机的内部具有目视确认性的土壤温度，可以抑制过量的雨水进入，具有优良的均匀性，如强度不均匀性低，有效防止会飞，聚集的有害昆虫，具有适当的透气性。本发明的农业用覆盖材料包括：（i）透光率为80％以上，（ii）透气度为50〜400cm 3 / cm 2 / sec的无纺布叠层体，（iii） 10〜30g / cm 2。

10. 发明申请

US20120271446A1 NUMERICAL CONTROLLER 有权
标题翻译：数控系统
公开(公告)号：US20120271446A1
公开(公告)日：2012-10-25
申请号：US13511848
申请日：2009-11-26
申请人： Tomonori Sato , Naoki Nakamura , Takeshi Tsuda , Shunro Ono
发明人： Tomonori Sato , Naoki Nakamura , Takeshi Tsuda , Shunro Ono
IPC分类号： G05B19/19
CPC分类号： G05B19/4166 , G05B2219/43156
摘要： When performing the processing while changing the position and the posture of the tool relative to the work, if the speed of the tool tip point relative to the work is regularly controlled while greatly changing the tool posture, the speed of each driving shaft of the machine is increased, whereby the interference may be generated. In order to solve the problem, in the numerical controller which obtains the position of each driving shaft of the machine performing the determination of the feeding speed, the interpolation and the coordinate conversion according to the relative instruction path and the instruction speed of the tool tip point relative to the work instructed to the processing program, when determining the feeding speed, the reference point is provided on the tool or the table, the translation speed of the reference point viewed from the mechanical coordinate system is set to the observation target speed, the reference feeding speed is obtained so that the observation target speed is a predetermined reference speed, and the smaller of the reference feeding speed and the instruction feeding speed is set to the feeding speed.
摘要翻译：当在改变工具相对于工件的位置和姿态的同时进行处理时，如果在大大改变工具姿势的同时，相对于工件的刀尖点的速度被定期地控制，则机器的每个驱动轴的速度从而可能产生干扰。为了解决这个问题，在获得进给速度确定的机器的每个驱动轴的位置的数值控制器中，根据相对指令路径和刀尖指令速度的插值和坐标转换相对于处理程序指示的工作点，当确定进给速度时，将参考点设置在工具或工作台上，将从机械坐标系观察到的参考点的平移速度设定为观察目标速度，获得基准进给速度，使得观察目标速度为预定的基准速度，并且将基准进给速度和指令进给速度的较小值设定为进给速度。

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