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1. 发明公开

EP3083722A2 CATALYST SYSTEM FOR POLYMERISATION OF AN OLEFIN 有权转让
标题翻译：热塑性聚氨酯润滑油
公开(公告)号：EP3083722A2
公开(公告)日：2016-10-26
申请号：EP14815753.0
申请日：2014-12-19
申请人： Saudi Basic Industries Corporation , SABIC Global Technologies B.V. , Zuideveld, Martin Alexander
发明人： ZUIDEVELD, Martin Alexander , BATINAS-GEURTS, Aurora Alexandra , GERLOFSMA, Raymond , STEENBAKKERS-MENTING, Henrica Norberta Alberta Maria
IPC分类号： C08F210/16 , C08F10/06 , C08F4/646 , C08F4/656
CPC分类号： C08F210/06 , C08F110/06 , C08L23/12 , C08L2207/02 , C08F210/02 , C08F2500/12 , C08F4/651 , C08F2/001 , C08F4/6565 , C08F4/6465 , C08L23/16
摘要： A process for the preparation of a catalyst system for olefin polymerization, including: A) providing said procatalyst obtainable via a process comprising: i) contacting a compound R4zMgX42-z with an alkoxy- or aryloxy-containing silane compound to give a first intermediate reaction product, ii) optionally contacting the solid product obtained in step i) with at least one activating compound selected from an activating electron donor or metal alkoxide compound; iii) contacting the first or second intermediate reaction product, with a halogen-containing Ti-compound and optionally an internal electron donor to obtain the procatalyst; and B) contacting the procatalyst with a co-catalyst and at least diethylaminotriethoxysilane as the external donor. Further disclosed is a catalyst system obtained by the process; a process for preparing a polyolefin by contacting at least one olefin with the catalyst system; a polyolefin obtained thereby; a composition comprising a propylene-ethylene copolymer; a shaped article thereof; and use of polyolefin.
摘要翻译：一种制备用于烯烃聚合的催化剂体系的方法，包括：A）提供可通过以下方法获得的所述主催化剂，所述方法包括：i）使化合物R4zMgX42-z与含烷氧基或芳氧基的硅烷化合物接触，得到第一中间反应产品，ii）任选地使步骤i）中获得的固体产物与选自活化电子给体或金属醇盐化合物的至少一种活化化合物接触; iii）使第一或第二中间反应产物与含卤素的Ti化合物和任选的内电子给体接触以获得前催化剂; 和B）使前催化剂与助催化剂和至少二乙基氨基三乙氧基硅烷作为外给体接触。进一步公开了通过该方法获得的催化剂体系; 通过使至少一种烯烃与催化剂体系接触来制备聚烯烃的方法; 由此获得的聚烯烃; 包含丙烯 - 乙烯共聚物的组合物; 其成型制品; 并使用聚烯烃。

2. 发明申请

WO2015091983A1 CATALYST SYSTEM FOR POLYMERIZATION OF AN OLEFIN 审中-公开
标题翻译：用于烯烃聚合的催化剂体系
公开(公告)号：WO2015091983A1
公开(公告)日：2015-06-25
申请号：PCT/EP2014/078797
申请日：2014-12-19
申请人： SAUDI BASIC INDUSTRIES CORPORATION , SABIC GLOBAL TECHNOLOGIES B.V. , ZUIDEVELD, Martin Alexander , BATINAS-GEURTS, Aurora Alexandra , BUKATOV, Gennadii Dimitrievich , SERGEEV, Sergei Andreevich , ZAKHAROV, Vladimir Aleksandrovich
发明人： ZUIDEVELD, Martin Alexander , BATINAS-GEURTS, Aurora Alexandra , BUKATOV, Gennadii Dimitrievich , SERGEEV, Sergei Andreevich , ZAKHAROV, Vladimir Aleksandrovich
IPC分类号： C08F110/06 , C08F4/651 , C08F4/655 , C08F4/656
CPC分类号： C08F110/06 , C08F4/651 , C08F2500/03 , C08F2500/12 , C08F2500/15 , C08F4/6557 , C08F4/6567
摘要： The present invention relates to The invention relates to a process for the preparation of a procatalyst suitable for preparing a catalyst composition for olefin polymerization. The present invention also relates to the procatalyst obtained or obtainable by the process. The composition further relates to a catalyst composition for olefin polymerization comprising the procatalyst. The invention also relates to the use of a benzamide as an activator in the preparation of a supported Ziegler-Natta type procatalyst. The invention further relates to a process for the preparation of polyolefins. The invention also relates to a polyolefin and a polypropylene homopolymer.
摘要翻译：本发明涉及一种制备适用于制备烯烃聚合催化剂组合物的前催化剂的方法。本发明还涉及通过该方法获得或可获得的前催化剂。组合物还涉及包含前催化剂的烯烃聚合催化剂组合物。本发明还涉及在制备负载齐格勒 - 纳塔型前催化剂中苯甲酰胺作为活化剂的用途。本发明还涉及一种制备聚烯烃的方法。本发明还涉及聚烯烃和聚丙烯均聚物。

3. 发明申请

WO2015091982A1 CATALYST SYSTEM FOR POLYMERISATION OF AN OLEFIN 审中-公开
标题翻译：用于聚合烯烃的催化剂体系
公开(公告)号：WO2015091982A1
公开(公告)日：2015-06-25
申请号：PCT/EP2014/078796
申请日：2014-12-19
申请人： SAUDI BASIC INDUSTRIES CORPORATION , SABIC GLOBAL TECHNOLOGIES B.V. , BATINAS-GEURTS, Aurora, Alexandra , ZUIDEVELD, Martin, Alexander
发明人： BATINAS-GEURTS, Aurora, Alexandra , ZUIDEVELD, Martin, Alexander
IPC分类号： C08F210/16 , C08F4/646 , C08F4/656
CPC分类号： C08F10/06 , C08F110/06 , C08F210/16 , C08F2410/01 , C08F2500/12 , C08F4/6565 , C08F4/6465 , C08F210/06
摘要： The present invention relates to a process for the preparation of a catalyst system suitable for olefin polymerization wherein the external electron donor is n-propyltriethoxysilane, and a catalyst system obtained or obtainable by said process. The invention also relates to a process for preparing a polyolefin using said catalyst system. The invention further relates to a polyolefin, in particular polyprolyene, obtainable by such a process, and shaped articles manufactured from such a polymer. The polymers produced using the catalyst system exhibit low volatiles and therefore have a reduced environmental and health impact.
摘要翻译：本发明涉及一种制备适用于烯烃聚合的催化剂体系的方法，其中外电子给体是正丙基三乙氧基硅烷，以及通过所述方法获得或可获得的催化剂体系。本发明还涉及使用所述催化剂体系制备聚烯烃的方法。本发明还涉及通过这种方法获得的聚烯烃，特别是聚丙烯烯，以及由这种聚合物制成的成型制品。使用催化剂体系生产的聚合物表现出低挥发性，因此具有降低的环境和健康影响。

4. 发明申请

WO2007071317A1 ZWITTERIONIC GUANIDINE CATALYST 审中-公开
标题翻译： ZWITTERICIC GUANIDINE催化剂
公开(公告)号：WO2007071317A1
公开(公告)日：2007-06-28
申请号：PCT/EP2006/011639
申请日：2006-12-05
申请人： DSM IP ASSETS B.V. , IJPEIJ, Edwin, Gerard , ZUIDEVELD, Martin, Alexander , ARTS, Henricus, Johannes , VAN DOREMAELE, Gerardus, Henricus, Josephus
发明人： IJPEIJ, Edwin, Gerard , ZUIDEVELD, Martin, Alexander , ARTS, Henricus, Johannes , VAN DOREMAELE, Gerardus, Henricus, Josephus
IPC分类号： C08F4/76 , C08F10/00 , C07F7/28
CPC分类号： C07F7/006 , C08F4/65916 , C08F10/00 , C08F4/16 , C08F4/76 , C08F4/659 , C08F4/64113
摘要： The invention relates to an organometallic compound according to formula (I), wherein M is a group 4 metal with valency v, with v being 3 or 4, preferably Ti, Y p is a monoanionic guanidine ligand with p ≥ 1, X m is an anionic ligand with m = ≥ 1, with m = v - p - 1 , and m being the number of anionic ligands and Q r is a coordinating ligand which is a Lewis base with r ≥ 0 being the number of ligands, and R 1 , R 2 , R 3 , R 4 , R 5 , R 6 , R 7 , R 8 and R 9 can be chosen independently from hydrogen atoms and optionally substituted alkyl or aryl groups having 1 to 20 carbon atoms. The invention further relates to the use of the compound according to Formula (I) as a catalyst for the preparation of polyolefins.
摘要翻译：本发明涉及一种根据式（I）的有机金属化合物，其中M是价态v的第4族金属，v为3或4，优选Ti，Y 1是单阴离子胍配体， p = 1，X m是具有m = = 1的阴离子配体，m = v-p-1，m是阴离子配体的数量和Q 是配位配体，其是具有r = 0的配位体数目的路易斯碱，R 1，R 2，R 3， R 4，R 5，R 6，R 7，R 8和R 8和 R 9可以独立于氢原子和任选取代的具有1至20个碳原子的烷基或芳基选择。本发明还涉及根据式（I）的化合物作为制备聚烯烃的催化剂的用途。

5. 发明申请

WO2005014666A1 PROCESS FOR THE PREPARATION OF A METAL-ORGANIC COMPOUND COMPRISING AT LEAST ONE IMINE LIGAND 审中-公开
标题翻译：制备包含至少一个IMINE LIGAND的金属有机化合物的方法
公开(公告)号：WO2005014666A1
公开(公告)日：2005-02-17
申请号：PCT/EP2004/008844
申请日：2004-08-03
申请人： DSM IP ASSETS B.V. , IJPEIJ, Edwin, Gerard , ARTS, Henricus, Johannes , VAN DOREMAELE, Gerardus, Henricus, Josephus , BEIJER, Felix, Hugo , VAN DER BURGT, Francis , ZUIDEVELD, Martin, Alexander
发明人： IJPEIJ, Edwin, Gerard , ARTS, Henricus, Johannes , VAN DOREMAELE, Gerardus, Henricus, Josephus , BEIJER, Felix, Hugo , VAN DER BURGT, Francis , ZUIDEVELD, Martin, Alexander
IPC分类号： C08F4/64
CPC分类号： C08F10/00 , C07F7/00 , C07F7/28 , C07F7/30 , C07F9/00 , C07F9/5355 , C07F17/00 , C07F19/00 , C08F4/65908 , C08F4/6592 , C08F210/06 , C08F210/16 , C08F2420/04 , C08F2500/17
摘要： A process for the preparation of a metal-organic compound, comprising at least one imine ligand, characterized in that an imine ligand according to formula (1) or the HA adduct thereof, wherein HA represents an acid, of which H represents its proton and A its conjugate base, is contacted with a metal-organic reagent of formula (2) in the presence of at least 1, respectively at least 2 equivalents of a base, with Y=N-R as formula (1), wherein Y is selected from a substituted carbon, or nitrogen atom and R represents a substituent, and with M v (L 1 )k(L 2 )I(L 3 )m(L 4 )n X as formula (2), wherein: M represents a group 4 or group 5 metal ion, V represents the valency of the metal ion, being 3, 4 or 5, L 1 , L 2 , L 3 , and L 4 represent a ligand or a group 17 halogen atom on M and may be equal or different, X represents a group 17 halogen atom, k, I, m, n = 0, 1, 2, 3, 4 with k+l+m+n+l=V. The invention further relates to a process for the preparation of a polyolefin by making a metal-organic compound according to the process of the invention, wherein the base is an olefin polymerisation compatible base, which metal- organic compound is activated anywhere in, or before a polymerisation reactor.
摘要翻译：一种制备包含至少一种亚胺配体的金属 - 有机化合物的方法，其特征在于根据式（1）的亚胺配体或其HA加合物，其中HA表示酸，其中H表示其质子，将其共轭碱与式（2）的金属有机试剂在至少1个分别具有至少2当量的碱，Y = NR的式（1）的存在下接触，其中Y选自取代的碳或氮原子，R表示取代基，M为（Ⅴ）（L1）k（L2）I（L3）m（L4）nⅩ，其中：M表示基团 4或5族金属离子，V表示金属离子的化合价，为3,4或5，L1，L2，L3和L4表示M上的配位体或17族卤素原子，可以相同或不同，X 代表17族卤素原子，k，I，m，n = 0,1,2,3,4，其中k + 1 + m + n + 1 = V。本发明还涉及通过制备根据本发明方法的金属 - 有机化合物来制备聚烯烃的方法，其中所述碱是烯烃聚合相容性碱，该金属 - 有机化合物在任何地方或之前被活化聚合反应器。

6. 发明申请

WO2005014601A2 PROCESS FOR THE PREPARATION OF A POLYOLEFIN 审中-公开
标题翻译：制备聚烯烃的方法
公开(公告)号：WO2005014601A2
公开(公告)日：2005-02-17
申请号：PCT/EP2004/008709
申请日：2004-08-03
申请人： DSM IP ASSETS B.V. , IJPEIJ, Edwin, Gerard , ARTS, Henricus, Johannes , VAN DOREMAELE, Gerardus, Henricus, Josephus , BEIJER, Felix, Hugo , VAN DER BURGT, Francis , ZUIDEVELD, Martin, Alexander
发明人： IJPEIJ, Edwin, Gerard , ARTS, Henricus, Johannes , VAN DOREMAELE, Gerardus, Henricus, Josephus , BEIJER, Felix, Hugo , VAN DER BURGT, Francis , ZUIDEVELD, Martin, Alexander
IPC分类号： C07F
CPC分类号： C08F10/00 , C07F7/00 , C07F7/28 , C07F7/30 , C07F9/00 , C07F9/5355 , C07F17/00 , C07F19/00 , C08F4/65908 , C08F4/6592 , C08F210/06 , C08F210/16 , C08F2420/04 , C08F4/65912 , C08F4/64044 , C08F2500/17
摘要： The invention related to a process for the polymerization of at least one aliphatic or aromatic hydrocarbyl C2-20 mono- or multiolefin in the presence of a catalyst and a boron comprising co-catalyst, wherein the catalyst comprises a composition of a metal-organic reagent, a spectator ligand and optionally at least one equivalent of a hydrocarbylating agent. The invention further relates to a polymer obtainable by the process of the invention.
摘要翻译：本发明涉及在催化剂和含硼助催化剂的存在下聚合至少一种脂族或芳族烃基C2-20单烯或多烯烃的方法，其中催化剂包含金属 - 有机试剂，旁观者配体和任选的至少一当量的烃基化剂。本发明还涉及可通过本发明的方法获得的聚合物。

7. 发明申请

WO2015091981A3 CATALYST SYSTEM FOR POLYMERISATION OF AN OLEFIN 审中-公开
标题翻译：用于聚合烯烃的催化剂体系
公开(公告)号：WO2015091981A3
公开(公告)日：2015-08-13
申请号：PCT/EP2014078795
申请日：2014-12-19
申请人： SAUDI BASIC IND CORP , SABIC GLOBAL TECHNOLOGIES BV , BATINAS-GEURTS AURORA ALEXANDRA , ZUIDEVELD MARTIN ALEXANDER , GERLOFSMA RAYMOND , STEENBAKKERS-MENTING HENRICA NORBERTA ALBERTA MARI
发明人： BATINAS-GEURTS AURORA ALEXANDRA , ZUIDEVELD MARTIN ALEXANDER , GERLOFSMA RAYMOND , STEENBAKKERS-MENTING HENRICA NORBERTA ALBERTA MARI
IPC分类号： C08F210/16 , C08F4/646 , C08F4/656 , C08F10/06
CPC分类号： C08F210/06 , C08F110/06 , C08L23/12 , C08L2207/02 , C08F210/02 , C08F2500/12 , C08F4/651 , C08F2/001 , C08F4/6565 , C08F4/6465 , C08L23/16
摘要： The present invention relates to a process for the preparation of a catalyst system suitable for olefin polymerization, wherein the process comprises the steps of: A) providing said procatalyst obtainable via a process comprising the steps of: i) contacting a compound R4 zMgX4 2-z with an alkoxy- or aryloxy-containing silane compound to give a first intermediate reaction product, ii) optionally contacting the solid product obtained in step i) with at least one activating compound selected from the group formed of activating electron donors and metal alkoxide compounds; iii) contacting the first or second intermediate reaction product, obtained respectively in step i) or ii), with a halogen-containing Ti-compound and optionally an internal electron donor to obtain said procatalyst; B) contacting said procatalyst with a co-catalyst and the at least diethylaminotriethoxysilane as the external donor. Moreover, the present invention relates to a catalyst system obtained or obtainable by the process of the present invention and to a process for preparing a polyolefin by contacting at least one olefin with the catalyst system according to the invention. In addition, the present invention relates to a polyolefin obtained or obtainable by the process for preparing a polyolefin according to the present invention and to a composition comprising a propylene-ethylene copolymer and a shaped article thereof. In addition, the invention relates to the use of said polyolefin.
摘要翻译：本发明涉及一种制备适用于烯烃聚合的催化剂体系的方法，其中该方法包括以下步骤：A）提供可通过包括以下步骤的方法获得的所述主催化剂：i）使化合物R4 zMgX4 2- z与含有烷氧基或芳氧基的硅烷化合物反应以产生第一中间反应产物，ii）任选地使步骤i）中获得的固体产物与至少一种活化化合物接触，所述活化化合物选自活化电子给体和金属醇盐化合物 ; iii）将分别在步骤i）或ii）中获得的第一或第二中间反应产物与含卤素的Ti化合物和任选的内电子给体接触以获得所述前催化剂; B）使所述前催化剂与助催化剂和所述至少二乙基氨基三乙氧基硅烷作为外部给体接触。此外，本发明涉及通过本发明的方法获得或可获得的催化剂体系，以及通过使至少一种烯烃与根据本发明的催化剂体系接触来制备聚烯烃的方法。此外，本发明涉及通过本发明的聚烯烃的制备方法获得或可获得的聚烯烃，以及包含丙烯 - 乙烯共聚物和其成型制品的组合物。此外，本发明涉及所述聚烯烃的用途。

8. 发明申请

WO2015091978A1 CATALYST COMPOSITION FOR POLYMERIZATION OF OLEFINS 审中-公开
标题翻译：用于烯烃聚合的催化剂组合物
公开(公告)号：WO2015091978A1
公开(公告)日：2015-06-25
申请号：PCT/EP2014/078790
申请日：2014-12-19
申请人： SAUDI BASIC INDUSTRIES CORPORATION , SABIC GLOBAL TECHNOLOGIES B.V. , TAFTAF, Mansour , SAINANI, Jaiprakash Brijlal , ZAKHAROV, Vladimir Aleksandrovich , BUKATOV, Gennadii Dimitrievich , PATEL, Vimalkumar Mahendrabhai , SERGEEV, Sergei Andreevich , ZUIDEVELD, Martin Alexander , BATINAS-GEURTS, Aurora Alexandra , GHALIT, Nourdin
发明人： TAFTAF, Mansour , SAINANI, Jaiprakash Brijlal , ZAKHAROV, Vladimir Aleksandrovich , BUKATOV, Gennadii Dimitrievich , PATEL, Vimalkumar Mahendrabhai , SERGEEV, Sergei Andreevich , ZUIDEVELD, Martin Alexander , BATINAS-GEURTS, Aurora Alexandra , GHALIT, Nourdin
IPC分类号： C08F4/651 , C08F110/06 , C07C233/69 , C08F4/656
CPC分类号： C07C233/69 , B01J31/0202 , B01J2231/64 , B01J2531/007 , C07C233/18 , C07C235/48 , C08F110/06 , C08F2410/01 , C08F4/651 , C08F2500/04 , C08F2500/12 , C08F2500/15 , C08F4/6565
摘要： The present invention relates to a catalyst composition comprising the compound represented by Formula (I) as an internal electron donor, Formula I wherein: R 1 , R 2 , R 3 , R 4 , R 5 and R 6 are the same or different and are independently selected from a group consisting of hydrogen, straight, branched and cyclic alkyl and aromatic substituted and unsubstituted hydrocarbyl having 1 to 20 carbon atoms; R 7 is selected from a group consisting of straight, branched and cyclic alkyl and aromatic substituted and unsubstituted hydrocarbyl having 1 to 20 carbon atoms; and R 8 is selected from a group consisting of aromatic substituted and unsubstituted hydrocarbyl having 6 to 20 carbon atoms; N is nitrogen atom; O is oxygen atom; and C is carbon atom. The present invention also relates to a process for preparing said polymerization catalyst composition and to a polymerization catalyst system comprising said catalyst composition, a co-catalyst and optionally an external electron donor. Furthermore, the present invention relates to a polyolefin obtainable by the process according to the present invention and to the use of the compound of Formula I as in internal electron donor in catalysts for polymerization of olefins.
摘要翻译：本发明涉及包含由式（I）表示的化合物作为内电子给体的催化剂组合物，式I其中：R 1，R 2，R 3，R 4，R 5和R 6相同或不同，并独立地选自由氢，直链，支链和环状烷基和芳族取代和未取代的具有1至20个碳原子的烃基组成; R 7选自直链，支链和环状烷基和芳族取代和未取代的具有1至20个碳原子的烃基; 并且R 8选自具有6至20个碳原子的芳族取代和未取代的烃基; N是氮原子; O是氧原子; C是碳原子。本发明还涉及制备所述聚合催化剂组合物的方法和包含所述催化剂组合物，助催化剂和任选的外电子给体的聚合催化剂体系。此外，本发明涉及通过本发明的方法获得的聚烯烃以及式I化合物在内电子给体中用于烯烃聚合的催化剂中的用途。

9. 发明申请

WO2015091966A1 CATALYST SYSTEM FOR POLYMERIZATION OF AN OLEFIN 审中-公开
标题翻译：用于烯烃聚合的催化剂体系
公开(公告)号：WO2015091966A1
公开(公告)日：2015-06-25
申请号：PCT/EP2014/078773
申请日：2014-12-19
申请人： SAUDI BASIC INDUSTRIES CORPORATION , SABIC GLOBAL TECHNOLOGIES B.V. , ZUIDEVELD, Martin Alexander , ZUIDEMA, Erik
发明人： ZUIDEVELD, Martin Alexander , ZUIDEMA, Erik
IPC分类号： C08F210/16 , C08F4/656 , C08F4/646 , C08F4/649
CPC分类号： C08F10/06 , C08F110/02 , C08F110/06 , C08F210/16 , C08F2410/00 , C08F2500/15 , C08F2500/12 , C08F4/6565 , C08F4/6465 , C08F4/6495 , C08F210/06
摘要： The present invention relates to a catalyst system comprising a procatalyst, a co-catalyst and an external electron donor, wherein the external electron donor comprises a compound having the structure according to Formula I': Si (L) n (OR 11 ) 4-n-m (R 12 ) m wherein, Si is a silicon atom with valency 4+; O is an oxygen atom with valency 2- and O is bonded to Si via a silicon-oxygen bond; n is 1, 2, 3 or 4; m is 0, 1, 2 or 3 n+m≤4 each R 11 group is independently selected from the group consisting of linear, branched and cyclic alkyl having at most 20 carbon atoms and aromatic substituted and unsubstituted hydrocarbyl having 6 to 20 carbon atoms; each R 12 group is independently selected from the group consisting of linear, branched and cyclic alkyl having at most 20 carbon atoms and aromatic substituted and unsubstituted hydrocarbyl having 6 to 20 carbon atoms; each L group is independently a group represented by the following structure, Formula II, wherein, L is bonded to the silicon atom via the nitrogen-silicon bond; L has a single substituent on the nitrogen atom, where this single substituent is an imine carbon atom; and X and Y are independently selected from the group consisting of a hydrogen atom; a heteroatom selected from group 13, 14, 15, 16 or 17 of the lUPAC Periodic Table of the Elements; a linear, branched and cyclic alkyl having at most 20 carbon atoms, optionally containing a heteroatom selected from group 13, 14, 15, 16 or 17 of the lUPAC Periodic Table of the Elements and an aromatic substituted and unsubstituted hydrocarbyl having 6 to 20 carbon atoms, optionally containing a heteroatom selected from group 13, 14, 15, 16 or 17 of the lUPAC Periodic Table of the Elements.
摘要翻译：本发明涉及包含前催化剂，助催化剂和外电子给体的催化剂体系，其中外电子给体包括具有式I'结构的化合物：Si（L）n（OR 11）4-nm （R 12）m，其中Si是4价的硅原子; O是具有2-价的氧原子，O经由硅 - 氧键与Si键合; n为1,2,3或4; m为0,1,2或3 n +m≤4，每个R 11基团独立地选自具有至多20个碳原子的直链，支链和环状烷基和具有6至20个碳原子的芳族取代和未取代的烃基; 每个R 12基团独立地选自具有至多20个碳原子的直链，支链和环状烷基和具有6至20个碳原子的芳族取代和未取代的烃基; 每个L基团独立地是由以下结构表示的基团，式II，其中L经由氮 - 硅键与硅原子键合; L在氮原子上具有单个取代基，其中该单取代基是亚胺碳原子; X和Y独立地选自氢原子; 选自元素周期表的第14,14,15,16或17号的杂原子; 含有至多20个碳原子的直链，支链和环状烷基，任选地含有选自元素周期表的LUPAC元素周期表第13,14,15,16或17族的杂原子和具有6至20个碳原子的芳族取代和未取代的烃基原子，任选地含有选自元素周期表的LUPAC元素的第13,14,15,16或17族的杂原子。

10. 发明申请

WO2011076775A1 TI CATALYST SYSTEM COMPRISING SUBSTITUTED CYCLOPENTADIENYL, AMIDINE AND DIENE LIGAND 审中-公开
标题翻译： TI催化剂系统，包括取代的环戊二烯基，氨基和二烯基配体
公开(公告)号：WO2011076775A1
公开(公告)日：2011-06-30
申请号：PCT/EP2010/070344
申请日：2010-12-21
申请人： DSM IP ASSETS B.V. , DOREMAELE, VAN, Gerardus, Henricus, Josephus , ZUIDEVELD, Martin, Alexander , MOUNTFORD, Philip , HEATH, Alex , SCOTT, Richard, T., W.
发明人： DOREMAELE, VAN, Gerardus, Henricus, Josephus , ZUIDEVELD, Martin, Alexander , MOUNTFORD, Philip , HEATH, Alex , SCOTT, Richard, T., W.
IPC分类号： C08F210/18 , C08F4/6592
CPC分类号： C08F4/76 , C08F4/65908 , C08F4/65912 , C08F4/6592 , C08F210/18 , C08F2410/01 , C08F2420/04 , Y10S526/943 , C08F210/06 , C08F236/20 , C08F2500/25
摘要： The invention relates to a catalyst system for the polymerization of olefins comprising a metal complex of formula CyLMD and an activating cocatalyst, wherein M is titanium, Cy is a cyclopentadienyl-type ligand, D is a diene, L is an amidinate-containing ligand of formula (1), wherein the amidinate-containing ligand is covalently bonded to the titanium via the imine nitrogen atom, Sub 1 is a substituent, which comprises a group 14 atom through which Sub 1 is bonded to the imine carbon atom, Sub 2 is a substituent, which comprises a nitrogen atom, through which Sub 2 is bonded to the imine carbon atom, and Cy is a mono- or polysubstituted cyclopentadienyl-type ligand, wherein the one or more substituents of Cy are selected from the group consisting of halogen, hydrocarbyl, silyl and germyl residues, optionally substituted with one or more halogen, amido, phosphido, alkoxy, or aryloxy residues. The invention further relates to a process for the preparation of a polymer comprising at least one aliphatic or aromatic hydrocarbyl C 2-20 olefin wherein the at least one aliphatic or aromatic olefin is contacted with the catalyst system of the present invention.
摘要翻译：本发明涉及一种用于烯烃聚合的催化剂体系，其包括式CyLMD的金属络合物和活化助催化剂，其中M为钛，Cy为环戊二烯基型配体，D为二烯，L为含有脒基的配体式（1）其中含脒基的配体通过亚胺氮原子与钛共价连接，Sub1是一个取代基，它包括Sub1与亚胺碳原子键合的第14族原子，Sub2是取代基，其包含氮原子，Sub2键合到亚胺碳原子上，Cy是单取代或多取代的环戊二烯基型配体，其中Cy的一个或多个取代基选自卤素，烃基，甲硅烷基和任选被一个或多个卤素，酰胺基，磷酰基，烷氧基或芳氧基残基取代的己基残基。本发明还涉及制备包含至少一种脂族或芳族烃基C 2-20烯烃的聚合物的方法，其中所述至少一种脂族或芳族烯烃与本发明的催化剂体系接触。

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