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1. 发明申请

WO2013087185A2 A CATALYST SYSTEM FOR THE PRODUCTION OF ULTRA-HIGH MOLECULAR WEIGHT POLYETHYLENE 审中-公开
标题翻译：用于生产超高分子量聚乙烯的催化剂体系
公开(公告)号：WO2013087185A2
公开(公告)日：2013-06-20
申请号：PCT/EP2012/005089
申请日：2012-12-10
申请人： SAUDI BASIC INDUSTRIES CORPORATION (SABIC) , BATINAS-GEURTS, Aurora Alexandra , FRIEDERICHS, Nicolaas Hendrika , SCHOFFELEN, Tom , ZUIDEMA, Erik
发明人： BATINAS-GEURTS, Aurora Alexandra , FRIEDERICHS, Nicolaas Hendrika , SCHOFFELEN, Tom , ZUIDEMA, Erik
IPC分类号： C08F4/651 , C08F4/649 , C08F4/656 , C08F110/02
CPC分类号： C08F110/02 , C08F4/651 , C08F4/6494 , C08F4/6567 , C08F2500/01 , C08F2500/18 , C08F2500/24
摘要： The invention relates to a catalyst system for the production of ultrahigh molecular weight polyethylene comprising I. a solid reaction product obtained by reaction of: (a) a hydrocarbon solution comprising (1) an organic oxygen containing magnesium compound or a halogen containing magnesium compound and (2) an organic oxygen containing titanium compound and (b) a mixture comprising a metal compound having the formula MeR n X 3-n wherein X is a halogenide, Me is a metal of Group III of Mendeleev's Periodic System of Chemical Elements, R is a hydrocarbon radical containing 1 - 10 carbon atoms and 0 ≤ n ≤ 3 and a silicon compound of formula R m SiCI 4.m wherein 0 ≤ m ≤ 2 and R is a hydrocarbon radical containing 1 - 10 carbon atoms wherein the molar ratio of metal from (b): titanium from (a) is lower than 1:1 II. an organo aluminium compound having the formula AIR 3 in which R is a hydrocarbon radical containing 1 - 10 carbon atoms and III. an external electron donor selected from the group of 1,2- dialkoxyalkanes, 1,2-dialkoxyalkenes or an external polymeric electron donor.
摘要翻译：本发明涉及一种用于生产超高分子量聚乙烯的催化剂体系，其包括I.通过以下反应获得的固体反应产物：（a）烃溶液，其包含（1）含有机氧的镁化合物或含卤素的镁化合物和（2）含有机氧的钛化合物和（b）包含具有式MeRnX3-n的金属化合物的混合物，其中X是卤化物，Me是Mendeleev的化学元素周期系统的III族金属，R是烃含有1-10个碳原子且0 <= n <3的基团和式RmSiCl 4 m的硅化合物，其中0≤m≤2且R是含有1-10个碳原子的烃基，其中金属的摩尔比来自（b）：（a）的钛低于1:1。具有式AIR3的有机铝化合物，其中R是含有1-10个碳原子的烃基和III。选自1,2-二烷氧基烷烃，1,2-二烷氧基羰基或外部聚合电子给体的外部电子给体。

2. 发明申请

WO2013087185A3 A CATALYST SYSTEM AND A PROCESS FOR THE PRODUCTION OF ULTRA HIGH MOLECULAR WEIGHT POLYETHYLENE IN PRESENCE OF THIS CATALYST SYSTEM 审中-公开
标题翻译：催化剂体系及其制备超高分子量聚乙烯在本催化剂体系中的应用
公开(公告)号：WO2013087185A3
公开(公告)日：2013-08-08
申请号：PCT/EP2012005089
申请日：2012-12-10
申请人： SAUDI BASIC IND CORP SABIC , BATINAS-GEURTS AURORA ALEXANDRA , FRIEDERICHS NICOLAAS HENDRIKA , SCHOFFELEN TOM , ZUIDEMA ERIK
发明人： BATINAS-GEURTS AURORA ALEXANDRA , FRIEDERICHS NICOLAAS HENDRIKA , SCHOFFELEN TOM , ZUIDEMA ERIK
IPC分类号： C08F4/651 , C08F4/649 , C08F4/656 , C08F110/02
CPC分类号： C08F110/02 , C08F4/651 , C08F4/6494 , C08F4/6567 , C08F2500/01 , C08F2500/18 , C08F2500/24
摘要： The invention relates to a catalyst system for the production of ultrahigh molecular weight polyethylene comprising I. a solid reaction product obtained by reaction of: (a) a hydrocarbon solution comprising (1) an organic oxygen containing magnesium compound or a halogen containing magnesium compound and (2) an organic oxygen containing titanium compound and (b) a mixture comprising a metal compound having the formula MeRnX3-n wherein X is a halogenide, Me is a metal of Group III of Mendeleev's Periodic System of Chemical Elements, R is a hydrocarbon radical containing 1 - 10 carbon atoms and 0
摘要翻译：本发明涉及一种用于生产超高分子量聚乙烯的催化剂体系，其包括I.通过以下反应获得的固体反应产物：（a）烃溶液，其包含（1）含有机氧的镁化合物或含卤素的镁化合物和（2）含有机氧的钛化合物和（b）包含具有式MeRnX3-n的金属化合物的混合物，其中X是卤化物，Me是Mendeleev的化学元素周期系统的III族金属，R是烃含有1-10个碳原子且0 <= n <3的基团和式RmSiCl 4 m的硅化合物，其中0≤m≤2且R是含有1-10个碳原子的烃基，其中金属的摩尔比来自（b）：（a）的钛低于1:1。具有式AIR3的有机铝化合物，其中R是含有1-10个碳原子的烃基和III。选自1,2-二烷氧基烷烃，1,2-二烷氧基羰基或外部聚合电子给体的外部电子给体。

3. 发明申请

WO2013087167A3 A PROCESS FOR THE PRODUCTION OF BIMODAL POLYETHYLENE IN THE PRESENCE OF THIS CATALYST SYSTEM 审中-公开
公开(公告)号：WO2013087167A3
公开(公告)日：2013-06-20
申请号：PCT/EP2012/005031
申请日：2012-12-06
申请人： SAUDI BASIC INDUSTRIES CORPORATION , BATINAS-GEURTS, Aurora Alexandra , FRIEDERICHS, Nicolaas Hendrika , SCHOFFELEN, Tom , ZUIDEMA, Erik , GARG, Priya
发明人： BATINAS-GEURTS, Aurora Alexandra , FRIEDERICHS, Nicolaas Hendrika , SCHOFFELEN, Tom , ZUIDEMA, Erik , GARG, Priya
IPC分类号： C08F210/16 , C08F2/00 , C08F4/651 , C08F4/649 , C08F4/655
摘要： The invention relates to a process for the production of bimodal polyethylene in a two-step polymerisation process in the presence of a catalyst system comprising: (I) the solid reaction product obtained by reacting of: a) a hydrocarbon solution containing 1) an organic oxygen containing magnesium compound or a halogen containing magnesium compound and 2) an organic oxygen containing titanium compound and b) an aluminium halogenide having the formula AIR n X 3-n in which R is a hydrocarbon radical containing 1 − 10 carbon atoms, X is halogen and 0 3 in which R is a hydrocarbon radical containing 1 − 10 carbon atom and (III) an electron donor selected from the group of 1,2-dialkoxyalkanes and 1,2- dialkoxyalkenes wherein in the first step a low molecular weight polyethylene is produced which has a MFI 190/1,2 is between 1 and 200 dg/min, and in the second step a high molecular weight ethylene copolymer is produced in which the MFI 190/5 of the total product is between 0.1 and 5 dg/min, and the weight fraction of the material produced in the first step is between 40 wt% and 60 wt% of the total product.

4. 发明申请

WO2015091966A1 CATALYST SYSTEM FOR POLYMERIZATION OF AN OLEFIN 审中-公开
标题翻译：用于烯烃聚合的催化剂体系
公开(公告)号：WO2015091966A1
公开(公告)日：2015-06-25
申请号：PCT/EP2014/078773
申请日：2014-12-19
申请人： SAUDI BASIC INDUSTRIES CORPORATION , SABIC GLOBAL TECHNOLOGIES B.V. , ZUIDEVELD, Martin Alexander , ZUIDEMA, Erik
发明人： ZUIDEVELD, Martin Alexander , ZUIDEMA, Erik
IPC分类号： C08F210/16 , C08F4/656 , C08F4/646 , C08F4/649
CPC分类号： C08F10/06 , C08F110/02 , C08F110/06 , C08F210/16 , C08F2410/00 , C08F2500/15 , C08F2500/12 , C08F4/6565 , C08F4/6465 , C08F4/6495 , C08F210/06
摘要： The present invention relates to a catalyst system comprising a procatalyst, a co-catalyst and an external electron donor, wherein the external electron donor comprises a compound having the structure according to Formula I': Si (L) n (OR 11 ) 4-n-m (R 12 ) m wherein, Si is a silicon atom with valency 4+; O is an oxygen atom with valency 2- and O is bonded to Si via a silicon-oxygen bond; n is 1, 2, 3 or 4; m is 0, 1, 2 or 3 n+m≤4 each R 11 group is independently selected from the group consisting of linear, branched and cyclic alkyl having at most 20 carbon atoms and aromatic substituted and unsubstituted hydrocarbyl having 6 to 20 carbon atoms; each R 12 group is independently selected from the group consisting of linear, branched and cyclic alkyl having at most 20 carbon atoms and aromatic substituted and unsubstituted hydrocarbyl having 6 to 20 carbon atoms; each L group is independently a group represented by the following structure, Formula II, wherein, L is bonded to the silicon atom via the nitrogen-silicon bond; L has a single substituent on the nitrogen atom, where this single substituent is an imine carbon atom; and X and Y are independently selected from the group consisting of a hydrogen atom; a heteroatom selected from group 13, 14, 15, 16 or 17 of the lUPAC Periodic Table of the Elements; a linear, branched and cyclic alkyl having at most 20 carbon atoms, optionally containing a heteroatom selected from group 13, 14, 15, 16 or 17 of the lUPAC Periodic Table of the Elements and an aromatic substituted and unsubstituted hydrocarbyl having 6 to 20 carbon atoms, optionally containing a heteroatom selected from group 13, 14, 15, 16 or 17 of the lUPAC Periodic Table of the Elements.
摘要翻译：本发明涉及包含前催化剂，助催化剂和外电子给体的催化剂体系，其中外电子给体包括具有式I'结构的化合物：Si（L）n（OR 11）4-nm （R 12）m，其中Si是4价的硅原子; O是具有2-价的氧原子，O经由硅 - 氧键与Si键合; n为1,2,3或4; m为0,1,2或3 n +m≤4，每个R 11基团独立地选自具有至多20个碳原子的直链，支链和环状烷基和具有6至20个碳原子的芳族取代和未取代的烃基; 每个R 12基团独立地选自具有至多20个碳原子的直链，支链和环状烷基和具有6至20个碳原子的芳族取代和未取代的烃基; 每个L基团独立地是由以下结构表示的基团，式II，其中L经由氮 - 硅键与硅原子键合; L在氮原子上具有单个取代基，其中该单取代基是亚胺碳原子; X和Y独立地选自氢原子; 选自元素周期表的第14,14,15,16或17号的杂原子; 含有至多20个碳原子的直链，支链和环状烷基，任选地含有选自元素周期表的LUPAC元素周期表第13,14,15,16或17族的杂原子和具有6至20个碳原子的芳族取代和未取代的烃基原子，任选地含有选自元素周期表的LUPAC元素的第13,14,15,16或17族的杂原子。

5. 发明申请

WO2013087167A2 A PROCESS FOR THE PRODUCTION OF BIMODAL POLYETHYLENE IN THE PRESENCE OF THIS CATALYST SYSTEM 审中-公开
标题翻译：在该催化剂体系存在下生产双峰聚乙烯的方法
公开(公告)号：WO2013087167A2
公开(公告)日：2013-06-20
申请号：PCT/EP2012005031
申请日：2012-12-06
申请人： SAUDI BASIC IND CORP , BATINAS-GEURTS AURORA ALEXANDRA , FRIEDERICHS NICOLAAS HENDRIKA , SCHOFFELEN TOM , ZUIDEMA ERIK , GARG PRIYA
发明人： BATINAS-GEURTS AURORA ALEXANDRA , FRIEDERICHS NICOLAAS HENDRIKA , SCHOFFELEN TOM , ZUIDEMA ERIK , GARG PRIYA
IPC分类号： C08F4/651 , C08F4/649 , C08F4/655 , C08F210/16
CPC分类号： C08F110/02 , C08F210/16 , C08F4/651 , C08F4/6494 , C08F4/6555 , C08F2500/04 , C08F2500/12 , C08F2/001 , C08F210/08 , C08F2500/07
摘要： The invention relates to a process for the production of bimodal polyethylene in a two-step polymerisation process in the presence of a catalyst system comprising: (I) the solid reaction product obtained by reacting of: a) a hydrocarbon solution containing 1) an organic oxygen containing magnesium compound or a halogen containing magnesium compound and 2) an organic oxygen containing titanium compound and b) an aluminium halogenide having the formula AIRnX3-n in which R is a hydrocarbon radical containing 1 - 10 carbon atoms, X is halogen and 0
摘要翻译：本发明涉及在催化剂体系存在下在两步聚合过程中生产双峰聚乙烯的方法，所述催化剂体系包含：（I）通过以下反应获得的固体反应产物：a）烃溶液，其含有1）有机物含氧镁化合物或含卤素镁化合物和2）含有机氧的钛化合物和b）通式为AlR n X 3-n的卤化铝，其中R为含有1-10个碳原子的烃基，X为卤素和0 （II）具有通式为AIR3的铝化合物，其中R为含有1-10个碳原子的烃基和（III）选自1,2-二烷氧基烷烃和1,2-二烷氧基烯烃的电子给体其中在第一步骤中生产MFI 190/2为1至200dg / min的低分子量聚乙烯，并且在第二步中生产高分子量乙烯共聚物，其中MFI 190 / 总产品中的5个是在0.1和5dg / min之间，并且第一步中产生的材料的重量分数在总产品的40wt％和60wt％之间。

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