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1. 发明申请

WO2015091983A1 CATALYST SYSTEM FOR POLYMERIZATION OF AN OLEFIN 审中-公开
标题翻译：用于烯烃聚合的催化剂体系
公开(公告)号：WO2015091983A1
公开(公告)日：2015-06-25
申请号：PCT/EP2014/078797
申请日：2014-12-19
申请人： SAUDI BASIC INDUSTRIES CORPORATION , SABIC GLOBAL TECHNOLOGIES B.V. , ZUIDEVELD, Martin Alexander , BATINAS-GEURTS, Aurora Alexandra , BUKATOV, Gennadii Dimitrievich , SERGEEV, Sergei Andreevich , ZAKHAROV, Vladimir Aleksandrovich
发明人： ZUIDEVELD, Martin Alexander , BATINAS-GEURTS, Aurora Alexandra , BUKATOV, Gennadii Dimitrievich , SERGEEV, Sergei Andreevich , ZAKHAROV, Vladimir Aleksandrovich
IPC分类号： C08F110/06 , C08F4/651 , C08F4/655 , C08F4/656
CPC分类号： C08F110/06 , C08F4/651 , C08F2500/03 , C08F2500/12 , C08F2500/15 , C08F4/6557 , C08F4/6567
摘要： The present invention relates to The invention relates to a process for the preparation of a procatalyst suitable for preparing a catalyst composition for olefin polymerization. The present invention also relates to the procatalyst obtained or obtainable by the process. The composition further relates to a catalyst composition for olefin polymerization comprising the procatalyst. The invention also relates to the use of a benzamide as an activator in the preparation of a supported Ziegler-Natta type procatalyst. The invention further relates to a process for the preparation of polyolefins. The invention also relates to a polyolefin and a polypropylene homopolymer.
摘要翻译：本发明涉及一种制备适用于制备烯烃聚合催化剂组合物的前催化剂的方法。本发明还涉及通过该方法获得或可获得的前催化剂。组合物还涉及包含前催化剂的烯烃聚合催化剂组合物。本发明还涉及在制备负载齐格勒 - 纳塔型前催化剂中苯甲酰胺作为活化剂的用途。本发明还涉及一种制备聚烯烃的方法。本发明还涉及聚烯烃和聚丙烯均聚物。

2. 发明申请

WO2015091978A1 CATALYST COMPOSITION FOR POLYMERIZATION OF OLEFINS 审中-公开
标题翻译：用于烯烃聚合的催化剂组合物
公开(公告)号：WO2015091978A1
公开(公告)日：2015-06-25
申请号：PCT/EP2014/078790
申请日：2014-12-19
申请人： SAUDI BASIC INDUSTRIES CORPORATION , SABIC GLOBAL TECHNOLOGIES B.V. , TAFTAF, Mansour , SAINANI, Jaiprakash Brijlal , ZAKHAROV, Vladimir Aleksandrovich , BUKATOV, Gennadii Dimitrievich , PATEL, Vimalkumar Mahendrabhai , SERGEEV, Sergei Andreevich , ZUIDEVELD, Martin Alexander , BATINAS-GEURTS, Aurora Alexandra , GHALIT, Nourdin
发明人： TAFTAF, Mansour , SAINANI, Jaiprakash Brijlal , ZAKHAROV, Vladimir Aleksandrovich , BUKATOV, Gennadii Dimitrievich , PATEL, Vimalkumar Mahendrabhai , SERGEEV, Sergei Andreevich , ZUIDEVELD, Martin Alexander , BATINAS-GEURTS, Aurora Alexandra , GHALIT, Nourdin
IPC分类号： C08F4/651 , C08F110/06 , C07C233/69 , C08F4/656
CPC分类号： C07C233/69 , B01J31/0202 , B01J2231/64 , B01J2531/007 , C07C233/18 , C07C235/48 , C08F110/06 , C08F2410/01 , C08F4/651 , C08F2500/04 , C08F2500/12 , C08F2500/15 , C08F4/6565
摘要： The present invention relates to a catalyst composition comprising the compound represented by Formula (I) as an internal electron donor, Formula I wherein: R 1 , R 2 , R 3 , R 4 , R 5 and R 6 are the same or different and are independently selected from a group consisting of hydrogen, straight, branched and cyclic alkyl and aromatic substituted and unsubstituted hydrocarbyl having 1 to 20 carbon atoms; R 7 is selected from a group consisting of straight, branched and cyclic alkyl and aromatic substituted and unsubstituted hydrocarbyl having 1 to 20 carbon atoms; and R 8 is selected from a group consisting of aromatic substituted and unsubstituted hydrocarbyl having 6 to 20 carbon atoms; N is nitrogen atom; O is oxygen atom; and C is carbon atom. The present invention also relates to a process for preparing said polymerization catalyst composition and to a polymerization catalyst system comprising said catalyst composition, a co-catalyst and optionally an external electron donor. Furthermore, the present invention relates to a polyolefin obtainable by the process according to the present invention and to the use of the compound of Formula I as in internal electron donor in catalysts for polymerization of olefins.
摘要翻译：本发明涉及包含由式（I）表示的化合物作为内电子给体的催化剂组合物，式I其中：R 1，R 2，R 3，R 4，R 5和R 6相同或不同，并独立地选自由氢，直链，支链和环状烷基和芳族取代和未取代的具有1至20个碳原子的烃基组成; R 7选自直链，支链和环状烷基和芳族取代和未取代的具有1至20个碳原子的烃基; 并且R 8选自具有6至20个碳原子的芳族取代和未取代的烃基; N是氮原子; O是氧原子; C是碳原子。本发明还涉及制备所述聚合催化剂组合物的方法和包含所述催化剂组合物，助催化剂和任选的外电子给体的聚合催化剂体系。此外，本发明涉及通过本发明的方法获得的聚烯烃以及式I化合物在内电子给体中用于烯烃聚合的催化剂中的用途。

3. 发明申请

WO2015091980A1 CATALYST SYSTEM FOR POLYMERIZATION OF AN OLEFIN 审中-公开
标题翻译：用于烯烃聚合的催化剂体系
公开(公告)号：WO2015091980A1
公开(公告)日：2015-06-25
申请号：PCT/EP2014/078794
申请日：2014-12-19
申请人： SAUDI BASIC INDUSTRIES CORPORATION , SABIC GLOBAL TECHNOLOGIES B.V. , ZUIDEVELD, Martin Alexander , BATINAS-GEURTS, Aurora Alexandra , BUKATOV, Gennadii Dimitrievich , SERGEEV, Sergei Andreevich , ZAKHAROV, Vladimir Aleksandrovich
发明人： ZUIDEVELD, Martin Alexander , BATINAS-GEURTS, Aurora Alexandra , BUKATOV, Gennadii Dimitrievich , SERGEEV, Sergei Andreevich , ZAKHAROV, Vladimir Aleksandrovich
IPC分类号： C08F110/06 , C08F4/651 , C08F4/656 , C08F4/655
CPC分类号： C08F110/06 , C08F4/651 , C08F2500/04 , C08F2500/15 , C08F4/6565
摘要： The invention relates to a process for the preparation of a procatalyst suitable for preparing a catalyst composition for olefin polymerization. The invention also relates to a procatalyst obtained or obtainable by the process. The invention further relates to the use of a benzamide as an activator in the preparation of a Ziegler-Natta procatalyst. The invention also relates to a process for the preparation of polyolefins. The invention also relates to a polyolefin. The invention further relates to a shaped article.
摘要翻译：本发明涉及一种制备适用于制备烯烃聚合催化剂组合物的前催化剂的方法。本发明还涉及通过该方法获得或可获得的主催化剂。本发明还涉及在制备齐格勒 - 纳塔前催化剂中苯甲酰胺作为活化剂的用途。本发明还涉及一种制备聚烯烃的方法。本发明还涉及一种聚烯烃。本发明还涉及成形制品。

4. 发明申请

WO2014118165A1 PROCESS FOR PREPARING A CATALYST COMPONENT FOR POLYMERIZATION OF OLEFINS 审中-公开
标题翻译：制备烯烃聚合催化剂组分的方法
公开(公告)号：WO2014118165A1
公开(公告)日：2014-08-07
申请号：PCT/EP2014/051610
申请日：2014-01-28
申请人： SAUDI BASIC INDUSTRIES CORPORATION , TAFTAF, Mansour , SAINANI, Jaiprakash Brijlal , ZAKHAROV, Vladimir Aleksandrovich , BUKATOV, Gennadii Dimitrievich , VIMALKUMAR, Mahendrabhai Patel , SERGEEV, Sergei Andreevich , ZUIDEVELD, Martin Alexander , BATINAS-GEURTS, Aurora Alexandra
发明人： TAFTAF, Mansour , SAINANI, Jaiprakash Brijlal , ZAKHAROV, Vladimir Aleksandrovich , BUKATOV, Gennadii Dimitrievich , VIMALKUMAR, Mahendrabhai Patel , SERGEEV, Sergei Andreevich , ZUIDEVELD, Martin Alexander , BATINAS-GEURTS, Aurora Alexandra
IPC分类号： C08F10/00 , C08F4/656
CPC分类号： C08F110/06 , C07C233/18 , C07C233/23 , C07C233/69 , C07C2601/14 , C08F4/649 , C08F4/6546 , C08F4/655 , C08F10/06 , C08F10/00 , C08F4/6565 , C08F4/651 , C08F2500/04 , C08F2500/12 , C08F2500/24
摘要： The present invention relates to a process for preparing a catalyst component for polymerization of an olefin comprising the steps of: i) contacting a compound R 9 z MgX 2-z wherein R 9 is aromatic, aliphatic or cyclo-aliphatic group containing up to 20 carbon atoms, X is a halide, and z is in a range of larger than 0 and smaller than 2, with an alkoxy- or aryloxy-containing silane compound to give a first intermediate reaction product; ii) contacting the first intermediate reaction product with at least one activating compound selected from the group formed by electron donors and compounds of formula M(OR 10 ) V - w (OR 11 ) w , wherein M can be Ti, Zr, Hf, Al or Si, and M(OR 10 ) V-W (R 11 ) W , wherein M is Si, each R 10 and R 11 , independently, represent an alkyl, alkenyl or aryl group, v is the valency of M, v being either 3 or 4, and w is smaller than v, to give a second intermediate reaction product; and iii) contacting the second intermediate reaction product with a halogen-containing Ti-compound, a monoester as activating agent, a 1,3-diether as an internal electron donor, and optionally a diester as an additional internal electron donor.
摘要翻译：本发明涉及一种制备烯烃聚合催化剂组分的方法，包括以下步骤：i）使化合物R9 zMgX2-z（其中R9是芳族的，含有至多20个碳原子的脂族或环脂族基团）与X 是卤化物，z在大于0且小于2的范围内，与含烷氧基或芳氧基的硅烷化合物反应得到第一中间反应产物; ii）使第一中间反应产物与选自由电子给体和式M（OR 10）V-w（OR 11）w形成的基团的至少一种活化化合物接触，其中M可以是Ti，Zr，Hf，Al或 Si和M（OR10）VW（R11）W，其中M是Si，每个R10和R11独立地表示烷基，烯基或芳基，v是M的化合价，v是3或4，w 小于v，得到第二中间反应产物; 和iii）使第二中间反应产物与含卤素的Ti化合物，单酯作为活化剂，作为内电子给体的1,3-二醚和任选的作为另外的内电子给体的二酯接触。

5. 发明申请

WO2014118164A1 CATALYST COMPOSITION FOR POLYMERIZATION OF OLEFINS 审中-公开
标题翻译：用于烯烃聚合的催化剂组合物
公开(公告)号：WO2014118164A1
公开(公告)日：2014-08-07
申请号：PCT/EP2014/051609
申请日：2014-01-28
申请人： SAUDI BASIC INDUSTRIES CORPORATION , TAFTAF, Mansour , SAINANI, Jaiprakash Brijlal , ZAKHAROV, Vladimir Aleksandrovich , BUKATOV, Gennadii Dimitrievich , VIMALKUMAR, Mahendrabhai Patel , SERGEEV, Sergei Andreevich , ZUIDEVELD, Martin Alexander , BATINAS-GEURTS, Aurora Alexandra
发明人： TAFTAF, Mansour , SAINANI, Jaiprakash Brijlal , ZAKHAROV, Vladimir Aleksandrovich , BUKATOV, Gennadii Dimitrievich , VIMALKUMAR, Mahendrabhai Patel , SERGEEV, Sergei Andreevich , ZUIDEVELD, Martin Alexander , BATINAS-GEURTS, Aurora Alexandra
IPC分类号： C08F10/00 , C08F4/656 , C08F4/651
CPC分类号： C08F110/06 , C07C233/18 , C07C233/23 , C07C233/69 , C07C2601/14 , C08F4/649 , C08F4/6546 , C08F4/655 , C08F10/06 , C08F10/00 , C08F4/6565 , C08F4/651 , C08F2500/04 , C08F2500/12 , C08F2500/24
摘要： The present invention relates to a catalyst composition comprising a monoester, the compound represented by formula (I) as an internal electron donor, and optionally an additional internal electron donor selected from a group consisting of diesters and diethers, Formula (I) wherein: R 1 , R 2 , R 3 , R 4 , R 5 and R 6 are the same or different and are independently selected from the group consisting of hydrogen, straight, branched and cyclic alkyl having at most 20 carbon atoms and aromatic substituted and unsubstituted hydrocarbyl having 6 to 20 carbon atoms; R 7 is selected from the group consisting of straight, branched and cyclic alkyl having at most 20 carbon atoms and aromatic substituted and unsubstituted hydrocarbyl having 6 to 20 carbon atoms; and R 8 is selected from the group consisting of aromatic substituted and unsubstituted hydrocarbyl having 6 to 20 carbon atoms. The present invention also relates to a process for preparing said polymerization catalyst composition and to a polymerization catalyst system comprising said catalyst composition, a co- catalyst and optionally an external electron donor. Furthermore, the present invention relates to use of said catalyst composition for polymerization of olefins.
摘要翻译：本发明涉及一种催化剂组合物，其包含单酯，由式（I）表示的作为内电子给体的化合物和任选的另外的选自二酯和二醚的内给电子体，式（I）其中：R 1 R 2，R 3，R 4，R 5和R 6相同或不同，独立地选自氢，直链，支链和环烷基，最多20个碳原子和芳族取代和未取代的碳原子数为6〜20的烃基 ; R 7选自具有至多20个碳原子的直链，支链和环状烷基和具有6至20个碳原子的芳族取代和未取代的烃基; 并且R 8选自具有6至20个碳原子的芳族取代的和未取代的烃基。本发明还涉及制备所述聚合催化剂组合物和包含所述催化剂组合物，助催化剂和任选的外电子给体的聚合催化剂体系的方法。此外，本发明涉及所述催化剂组合物用于烯烃聚合的用途。

6. 发明申请

WO2015185489A1 PROCATALYST FOR POLYMERIZATION OF OLEFINS 审中-公开
标题翻译： OLEFINS聚合方法
公开(公告)号：WO2015185489A1
公开(公告)日：2015-12-10
申请号：PCT/EP2015/062117
申请日：2015-06-01
申请人： SABIC GLOBAL TECHNOLOGIES B.V. , AL-BAHILY, Khalid Abdullah , SAINANI, Jaiprakash Brijlal , SHIRISH, Abhyankan , BUKATOV, Gennadii Dimitrievich , ZUIDEVELD, Martin Alexander , TAFTAF, Mansour , BATINAS-GEURTS, Aurora Alexandra , AL-HUMAIDAN, Osamah , ZAKHAROV, Vladimir Aleksandrovich , SERGEEV, Sergei Andreevich
发明人： AL-BAHILY, Khalid Abdullah , SAINANI, Jaiprakash Brijlal , SHIRISH, Abhyankan , BUKATOV, Gennadii Dimitrievich , ZUIDEVELD, Martin Alexander , TAFTAF, Mansour , BATINAS-GEURTS, Aurora Alexandra , AL-HUMAIDAN, Osamah , ZAKHAROV, Vladimir Aleksandrovich , SERGEEV, Sergei Andreevich
IPC分类号： C08F4/651 , C08F110/06
CPC分类号： C08F110/06 , C08F4/651 , C08F4/6565 , C08F2500/12 , C08F2500/04 , C08F2500/15 , C08F2500/03
摘要： The present invention relates to a procatalyst comprising the compound represented by formula A as an internal electron donor, wherein: R 81 , R 82 , R 83 , R 84 , R 85 , and R 86 are the same or different and are independently selected from a group consisting of hydrogen or a straight, branched and cyclic hydrocarbyl group, selected from alkyl, alkenyl, aryl, aralkyl or alkylaryl groups, and one or more combinations thereof, preferably having 1 to 20 carbon atoms; R 87 is a hydrogen or a linear, branched or cyclic hydrocarbyl group, selected from alkyl, alkenyl, aryl, aralkyl, alkoxycarbonyl or alkylaryl groups, and one or more combinations thereof, preferably having from 1 to 20 carbon atoms; and each R 80 group is independently a linear, branched or cyclic hydrocarbyl group selected from alkyl, alkenyl, aryl, aralkyl, or alkylaryl groups, and one or more combinations thereof, preferably having from 1 to 30 carbon atoms; N is nitrogen atom; O is oxygen atom; and C is carbon atom. The present invention also relates to a process for preparing said polymerization procatalyst and to a polymerization catalyst system comprising said procatalyst, a cocatalyst and optionally an external electron donor. Furthermore, the present invention relates to a polyolefin obtainable by the process according to the present invention and to the use of the compound of formula A as in internal electron donor in catalysts for polymerization of olefins.
摘要翻译：本发明涉及包含由式A表示的作为内电子给体的化合物的前催化剂，其中：R 81，R 82，R 83，R 84，R 85和R 86可以相同或不同，并且独立地选自氢或直链，支链和环状的烃基，选自烷基，烯基，芳基，芳烷基或烷基芳基，及其一种或多种组合，优选具有1至20个碳原子; R 87是氢或选自烷基，烯基，芳基，芳烷基，烷氧基羰基或烷基芳基的直链，支链或环状烃基，以及一种或多种组合，优选具有1至20个碳原子; 并且每个R 80基团独立地为选自烷基，烯基，芳基，芳烷基或烷基芳基的直链，支链或环状烃基，以及其一种或多种组合，优选具有1至30个碳原子; N是氮原子; O是氧原子; C是碳原子。本发明还涉及一种制备所述聚合前催化剂的方法以及包含所述主催化剂，助催化剂和任选的外电子给体的聚合催化剂体系。此外，本发明涉及通过本发明的方法获得的聚烯烃以及式A化合物在内电子给体中在烯烃聚合催化剂中的用途。

7. 发明申请

WO2013124063A1 CATALYST COMPONENT FOR THE POLYMERIZATION OF OLEFINS 审中-公开
标题翻译：用于烯烃聚合的催化剂组分
公开(公告)号：WO2013124063A1
公开(公告)日：2013-08-29
申请号：PCT/EP2013/000506
申请日：2013-02-21
申请人： SAUDI BASIC INDUSTRIES CORPORATION , TAFTAF, Mansour , GHALIT, Nourdin , BUKATOV, Gennadii Dimitrievich , SERGEEV, Sergei Andreevich , ZAKHAROV, Vladimir Aleksandrovich , SAINANI, Jaiprakash Brijlal , BATINAS-GEURTS, Aurora Alexandra
发明人： TAFTAF, Mansour , GHALIT, Nourdin , BUKATOV, Gennadii Dimitrievich , SERGEEV, Sergei Andreevich , ZAKHAROV, Vladimir Aleksandrovich , SAINANI, Jaiprakash Brijlal , BATINAS-GEURTS, Aurora Alexandra
IPC分类号： C08F110/06 , C08F4/651 , C08F4/656 , C08F10/00
CPC分类号： C08F110/06 , C08F10/00 , C08F4/651 , C08F4/6565
摘要： The present invention relates to a catalyst component for polymerization of an olefin comprising a compound represented by the Fischer projection of: wherein R 5 is substituted or unsubstituted hydrocarbyl having 1 to 20 carbon atoms; R 6 and R 7 are different and independently selected from the group consisting of hydrogen, halogen and substituted or unsubstituted hydrocarbyl having 1 to 20 carbon atoms; R 5 -R 7 optionally containing one or more hetero-atoms replacing one or more carbon atoms, one or more hydrogen atom or both, wherein said hetero-atom is selected from the group consisting of nitrogen, oxygen, sulfur, silicon, phosphorus and halogen; and wherein the compound of Formula (I) is the only internal electron donor in the catalyst component. The present invention also relates to a process for preparing a polymerization catalyst component comprising the steps of i) contacting a compound R 4 z MgX 2-z wherein R 4 is aromatic, aliphatic or cyclo-aliphatic group containing 1 to 20 carbon atoms, X is a halide, and z is in a range of larger than 0 and smaller than 2, with an alkoxy- or aryloxy-containing silane compound to give a first intermediate reaction product; ii) contacting the first intermediate reaction product with at least one activating compound selected from the group formed by internal electron donors and compounds of formula M(OR 2 ) v-w (R 3 ) w , wherein M can be Ti, Zr, Hf, Al or Si, each R 2 and R 3 , independently, represent an alkyl, alkenyl or aryl group, v is the valency of M and w is smaller than v and iii) contacting the second intermediate reaction product with a halogen-containing Ti- compound and an internal electron donor represented by the Fischer projection of formula (I); and optionally with at least one compound selected from a group comprising a monoester, a diester and a 1,3-diether.
摘要翻译：本发明涉及一种用于聚合烯烃的催化剂组分，其包含由Fischer投影表示的化合物：其中R5是取代或未取代的具有1至20个碳原子的烃基; R6和R7不同且独立地选自氢，卤素和具有1至20个碳原子的取代或未取代的烃基; 任选地含有一个或多个取代一个或多个碳原子的杂原子，一个或多个氢原子或两者的R 5 -R 7，其中所述杂原子选自氮，氧，硫，硅，磷和卤素; 并且其中式（I）的化合物是催化剂组分中唯一的内电子给体。本发明还涉及一种制备聚合催化剂组分的方法，包括以下步骤：i）使化合物R4zMgX2-z（其中R4是芳族的，含有1至20个碳原子的脂族或环脂族基团），X是卤化物， z为大于0且小于2的范围，与含烷氧基或芳氧基的硅烷化合物反应得到第一中间反应产物; ii）使第一中间反应产物与至少一种活化化合物接触，所述活化化合物选自由内部电子给体形成的基团和式M（OR 2）vw（R 3）w的化合物，其中M可以是Ti，Zr，Hf，Al或Si 每个R 2和R 3独立地表示烷基，烯基或芳基，v是M的化合价，w小于v，和iii）使第二中间反应产物与含卤素的Ti-化合物和内部电子由式（I）的费舍尔投影表示的供体; 和任选地与至少一种选自包含单酯，二酯和1,3-二醚的化合物。

8. 发明申请

WO2007134851A1 PROCESS FOR PREPARING A CATALYST COMPONENT FOR PROPYLENE POLYMERIZATION 审中-公开
标题翻译：制备用于丙烯聚合的催化剂组分的方法
公开(公告)号：WO2007134851A1
公开(公告)日：2007-11-29
申请号：PCT/EP2007/004572
申请日：2007-05-23
申请人： SAUDI BASIC INDUSTRIES CORPORATION , RAMJOIE, Yves Johann Elizabeth , VLAAR, Mark , FRIEDERICHS, Nicolaas Hendrika , SERGEEV, Sergei Andreevich , ZAKHAROV, Vladimir Aleksandrovich , BUKATOV, Gennadii Dimitrievich , TAFTAF, Mansour , ABURAQABAH, Atieh
发明人： RAMJOIE, Yves Johann Elizabeth , VLAAR, Mark , FRIEDERICHS, Nicolaas Hendrika , SERGEEV, Sergei Andreevich , ZAKHAROV, Vladimir Aleksandrovich , BUKATOV, Gennadii Dimitrievich , TAFTAF, Mansour , ABURAQABAH, Atieh
IPC分类号： C08F10/00 , C08F4/654
CPC分类号： C08F10/00 , C08F110/06 , C08F4/6545 , C08F2500/18 , C08F2500/24 , C08F2500/12 , C08F4/6548
摘要： The invention relates to a process for preparing a polymerization catalyst component wherein a solid compound with formula Mg(OR 1 ) x Cl 2-x wherein x is larger than O and smaller than 2, and each R 1 , independently, represents an alkyl group, said compound being obtained by reacting a Grignard compound with an alkoxy- or aryloxy-containing silane compound, is contacted with at least one activating compound selected from the group formed by internal electron donors and compounds of formula M(OR 2 ) V-W (R 3 ) W , wherein M can be Ti, Zr, Hf, Al or Si, each R 2 and R 3 , independently, represent an alkyl, alkenyl or aryl group, v is the valency of M and w is smaller than v, in the presence of an inert dispersant to give an intermediate reaction product, and wherein the intermediate reaction product is contacted with a halogen-containing Ti-compound. A catalyst system comprising said component shows improved performance in olefin polymerization. The invention also relates to a polymerization catalyst system comprising the catalyst component and to a process of making a polyolefin by contacting at least one olefin with a polymerization catalyst system comprising the catalyst component.
摘要翻译：本发明涉及一种制备聚合催化剂组分的方法，其中具有式Mg（OR 1）2 Cl 2-x X的固体化合物其中 x大于0且小于2，并且每个R 1独立地表示烷基，所述化合物是通过使格利雅化合物与含烷氧基或芳氧基的硅烷化合物反应得到的，为与至少一种活化化合物接触，所述活化化合物选自由内部电子给体形成的基团和式M（OR 2）V W（R 3））其中M可以是Ti，Zr，Hf，Al或Si，每个R 2和R 3独立地表示烷基，烯基或芳基，v是M的化合价，w小于v，在惰性分散剂存在下，得到中间体反应产物，其中中间体反应产物与含卤素的Ti化合物接触。包含所述组分的催化剂体系在烯烃聚合中显示出改进的性能。本发明还涉及包含催化剂组分的聚合催化剂体系和通过使至少一种烯烃与包含催化剂组分的聚合催化剂体系接触来制备聚烯烃的方法。

9. 发明公开

EP3083719A1 CATALYST SYSTEM FOR POLYMERIZATION OF AN OLEFIN 有权转让
标题翻译：烯烃聚合催化剂体系
公开(公告)号：EP3083719A1
公开(公告)日：2016-10-26
申请号：EP14827754.4
申请日：2014-12-19
申请人： Saudi Basic Industries Corporation , SABIC Global Technologies B.V.
发明人： ZUIDEVELD, Martin Alexander , BATINAS-GEURTS, Aurora Alexandra , BUKATOV, Gennadii Dimitrievich , SERGEEV, Sergei Andreevich , ZAKHAROV, Vladimir Aleksandrovich
IPC分类号： C08F110/06 , C08F4/651 , C08F4/655 , C08F4/656
CPC分类号： C08F110/06 , C08F4/651 , C08F2500/03 , C08F2500/12 , C08F2500/15 , C08F4/6557 , C08F4/6567
摘要： A process for the preparation of a procatalyst suitable for preparing a catalyst composition for olefin polymerization, the procatalyst obtained or obtainable by the process; and a catalyst composition for olefin polymerization comprising the procatalyst. In particular a benzamide can be used as an activator in the preparation of a supported Ziegler-Natta type procatalyst useful for a process for the preparation of polyolefins. The Polyolefins and polypropylene homopolymers are also disclosed.
摘要翻译：本发明涉及制备适用于制备用于烯烃聚合的催化剂组合物的前催化剂的方法。本发明还涉及通过该方法获得或可获得的主催化剂。该组合物还涉及包含原催化剂的用于烯烃聚合的催化剂组合物。本发明还涉及苯甲酰胺作为活化剂在制备负载型齐格勒 - 纳塔型前催化剂中的用途。本发明还涉及制备聚烯烃的方法。本发明还涉及聚烯烃和聚丙烯均聚物。

10. 发明公开

EP3083711A1 CATALYST COMPOSITION FOR POLYMERIZATION OF OLEFINS 有权转让
标题翻译：催化剂组合物聚合烯烃
公开(公告)号：EP3083711A1
公开(公告)日：2016-10-26
申请号：EP14827215.6
申请日：2014-12-19
申请人： Saudi Basic Industries Corporation , SABIC Global Technologies B.V.
发明人： TAFTAF, Mansour , SAINANI, Jaiprakash Brijlal , ZAKHAROV, Vladimir Aleksandrovich , BUKATOV, Gennadii Dimitrievich , PATEL, Vimalkumar Mahendrabhai , SERGEEV, Sergei Andreevich , ZUIDEVELD, Martin Alexander , BATINAS-GEURTS, Aurora Alexandra , GHALIT, Nourdin
IPC分类号： C08F4/651 , C08F110/06 , C07C233/69 , C08F4/656
CPC分类号： C07C233/69 , B01J31/0202 , B01J2231/64 , B01J2531/007 , C07C233/18 , C07C235/48 , C08F110/06 , C08F2410/01 , C08F4/651 , C08F2500/04 , C08F2500/12 , C08F2500/15 , C08F4/6565
摘要： The present invention relates to a catalyst composition comprising the compound represented by Formula (I) as an internal electron donor, Formula I wherein: R1, R2, R3, R4, R5 and R6 are the same or different and are independently selected from a group consisting of hydrogen, straight, branched and cyclic alkyl and aromatic substituted and unsubstituted hydrocarbyl having 1 to 20 carbon atoms; R7 is selected from a group consisting of straight, branched and cyclic alkyl and aromatic substituted and unsubstituted hydrocarbyl having 1 to 20 carbon atoms; and R8 is selected from a group consisting of aromatic substituted and unsubstituted hydrocarbyl having 6 to 20 carbon atoms; N is nitrogen atom; O is oxygen atom; and C is carbon atom. The present invention also relates to a process for preparing said polymerization catalyst composition and to a polymerization catalyst system comprising said catalyst composition, a co-catalyst and optionally an external electron donor. Furthermore, the present invention relates to a polyolefin obtainable by the process according to the present invention and to the use of the compound of Formula I as in internal electron donor in catalysts for polymerization of olefins.

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