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1. 发明授权

US09132414B2 Process for dehydration and isomerization of C4 alcohols using an amorphous solid with suitable porosity 有权
标题翻译：使用具有合适孔隙度的无定形固体使C4醇脱水和异构化的方法
公开(公告)号：US09132414B2
公开(公告)日：2015-09-15
申请号：US13703107
申请日：2011-05-27
申请人： Vincent Coupard , Sylvie Maury , Karine Surla
发明人： Vincent Coupard , Sylvie Maury , Karine Surla
IPC分类号： B01J21/04 , C07C1/24 , C07C5/27 , C07C11/08 , C07C11/09
CPC分类号： B01J21/04 , C07C1/24 , C07C5/2772 , C07C5/2775 , C07C11/08 , C07C11/09 , C07C2521/04 , C07C2521/06 , C07C2523/04 , C07C2523/06 , C07C2523/20 , C07C2523/22 , C07C2523/26 , C07C2523/28 , C07C2523/30
摘要： The present invention relates to a method of producing C4 olefins, from a feed of C4 monohydric alcohol, in which a reaction of dehydration of the monohydric alcohol to at least one olefin, and a reaction of skeletal isomerization of at least one of the olefins produced in one and the same reaction vessel, are carried out in the presence of an alumina-based catalyst with adapted porosity.
摘要翻译：本发明涉及从一元醇的进料中生产C4烯烃的方法，其中一元醇与至少一种烯烃的脱水反应和至少一种烯烃的骨架异构化的反应在同一反应容器中，在具有适应孔隙率的氧化铝基催化剂的存在下进行。

2. 发明授权

US08552241B2 Method of converting ethanol to base stock for diesel fuel 有权
标题翻译：将乙醇转化为柴油的原料的方法
公开(公告)号：US08552241B2
公开(公告)日：2013-10-08
申请号：US13205501
申请日：2011-08-08
申请人： Vincent Coupard , Sylvia Maury , Frédéric Capuano , Mohamed Bengrine
发明人： Vincent Coupard , Sylvia Maury , Frédéric Capuano , Mohamed Bengrine
IPC分类号： C07C1/24
CPC分类号： C10G3/50 , C10G3/45 , C10G3/47 , C10G3/62 , C10G2300/4018 , C10G2300/4081 , C10G2400/04 , Y02P30/20
摘要： A method of converting ethanol to a diesel fuel base stock comprises: a reaction stage (a) of contacting the ethanol with an acid catalyst, amorphous or structured, predominantly mesoporous, for example at a temperature of 300° C. to 500° C., at a pressure of 2 to 10 MPa and at a WHSV of 0.2 to 4 h−1, producing a gas phase, an organic liquid phase and an aqueous liquid phase, and a stage (b) of separating said gas phase, said organic liquid phase and said aqueous liquid phase at a pressure close to the reaction pressure. The method can involve recycling at least part of the gas phase separated in stage (b) to stage (a), and hydrogenating at least part of the organic liquid phase separated in stage (b).
摘要翻译：将乙醇转化为柴油燃料基料的方法包括：将乙醇与酸催化剂接触的反应阶段（a），其为无定形或结构化，主要是介孔的，例如在300℃至500℃的温度下。在2〜10MPa的压力和0.2〜4h -1的WHSV下，产生气相，有机液相和水性液相，以及分离所述气相的阶段（b），所述有机物液相和所述水性液相在接近反应压力的压力下进行。该方法可以包括将阶段（b）中分离的至少一部分气相再循环到阶段（a），并且将在阶段（b）中分离的至少部分有机液相氢化。

3. 发明申请

US20120048775A1 PROCESS FOR PRODUCING MIDDLE DISTILLATES BY HYDROISOMERIZATION AND HYDROCRACKING OF A HEAVY FRACTION DERIVED FROM A FISCHER-TROPSCH EFFLUENT EMPLOYING A RESIN 审中-公开
标题翻译：通过水解和水解从使用树脂的固化剂流出的重质馏分生产中间馏分的方法
公开(公告)号：US20120048775A1
公开(公告)日：2012-03-01
申请号：US13262681
申请日：2010-03-24
申请人： Aurelie Dandeu , Vincent Coupard
发明人： Aurelie Dandeu , Vincent Coupard
IPC分类号： C10G69/02 , C10G69/04
CPC分类号： C10G47/16 , B01J21/12 , B01J23/42 , B01J23/44 , B01J23/88 , B01J31/08 , B01J35/10 , B01J35/1019 , B01J35/1042 , B01J35/1061 , B01J35/108 , B01J39/04 , C10G2/30 , C10G7/00 , C10G25/02 , C10G25/05 , C10G45/32 , C10G45/34 , C10G45/58 , C10G45/60 , C10G47/00 , C10G65/12 , C10G67/06 , C10G2300/1011 , C10G2300/1022 , C10G2300/1025 , C10G2300/201 , C10G2300/301 , C10G2300/4006 , C10G2300/4012 , C10G2300/4018 , Y02P30/20
摘要： The present invention describes a process for producing middle distillates from a paraffinic feed produced by Fischer-Tropsch synthesis and divided into two fractions, a light fraction, termed the cold condensate, and a heavy fraction, termed the waxes, comprising a) fractionating said cold condensate fraction into a gaseous C4− fraction and an intermediate fraction with an initial boiling point in the range 15° C. to 40° C. and an end point in the range 300° C. to 450° C.; b) passing the intermediate fraction over at least one ion exchange resin; eliminating at least a portion of the water from the effluent derived from step b); decontaminating said heavy fraction termed the waxes by passage over a guard bed; recombining the purified intermediate fraction and the effluent derived from step d) to obtain a purified C5+ fraction; f) hydrogenating the unsaturated compounds of the purified C5+ fraction; g) hydroisomerization/hydrocracking of the effluent derived from step f); h) separating and recycling unreacted hydrogen and light gases to the hydroisomerization/hydrocracking step; and distilling the effluent derived from step h).
摘要翻译：本发明描述了一种由费 - 托合成生产的石蜡饲料生产中间馏分的方法，分为两部分，称为冷凝液的轻馏分，称为蜡的重质馏分，其包括a）将所述冷分馏冷凝物馏分进入气态C 4馏分和中间馏分，初始沸点在15℃至40℃，终点在300℃至450℃范围内。 b）使中间馏分通过至少一种离子交换树脂; 从来自步骤b）的流出物中除去至少一部分水; 通过在保护床上通过，将称为蜡的所述重质馏分去污; 将纯化的中间体馏分和来自步骤d）的流出物重组，得到纯化的C5 +级分; f）氢化纯化的C5 +级分的不饱和化合物; g）来自步骤f）的流出物的加氢异构化/加氢裂化; h）将未反应的氢气和轻质气体分离并循环到加氢异构化/加氢裂化步骤; 并蒸馏来自步骤h）的流出物。

4. 发明申请

US20110201857A1 Process For The Preparation Of Multimetallic Catalysts That Can Be Used In Reactions For Transformation Of Hydrocarbons 有权
标题翻译：可用于碳氢化合物转化反应的多金属催化剂的制备方法
公开(公告)号：US20110201857A1
公开(公告)日：2011-08-18
申请号：US13093587
申请日：2011-04-25
申请人： Vincent Coupard , Denis Uzio , Carine Petit-Clair , Lars Fischer , Frederic Portejoie
发明人： Vincent Coupard , Denis Uzio , Carine Petit-Clair , Lars Fischer , Frederic Portejoie
IPC分类号： C07C5/03
CPC分类号： B01J37/0211 , B01J21/04 , B01J23/50 , B01J23/62 , B01J23/622 , B01J23/626 , B01J23/892 , B01J23/8926 , B01J35/0013 , B01J35/006 , B01J35/008 , B01J37/0213 , C10G45/34 , C10G2300/1088 , C10G2300/4018 , C10G2400/20
摘要： The invention relates to a process for the preparation of a catalyst comprising: a) The preparation of a colloidal oxide suspension of a first metal M1 that consists in the neutralization of a basic solution by an acidic mineral solution that contains the precursor of the metal M1, b) Bringing into contact the precursor of the promoter M2, either directly in its crystallized form or after dissolution in aqueous phase, with the colloidal suspension that is obtained in stage a), c) Bringing into contact the colloidal suspension that is obtained in stage b) with the substrate, d) Drying at a temperature of between 30° C. and 200° C., under a flow of air. The invention also relates to a process for the treatment of an olefinic fraction that uses the catalyst prepared said preparation process.
摘要翻译：本发明涉及一种制备催化剂的方法，包括：a）第一金属M1的胶体氧化物悬浮液的制备，其包括通过含有金属M1前体的酸性矿物溶液中和碱性溶液 b）使步骤a）中获得的胶体悬浮液与促进剂M2的前体直接接触，其结晶形式或溶解于水相中，c）使得所得到的胶体悬浮液接触阶段b）与基材，d）在空气流下在30℃和200℃之间的温度下干燥。本发明还涉及一种处理使用所述制备方法制备的催化剂的烯烃级分的方法。

5. 发明授权

US07880048B2 Process for producing propylene in the presence of a macroporous catalyst in the form of spherical beads 有权
标题翻译：在球形珠形式的大孔催化剂存在下制备丙烯的方法
公开(公告)号：US07880048B2
公开(公告)日：2011-02-01
申请号：US11892561
申请日：2007-08-23
申请人： Brigitte Pigeat , Vincent Coupard , Sylvie Maury , Serge Drouet
发明人： Brigitte Pigeat , Vincent Coupard , Sylvie Maury , Serge Drouet
IPC分类号： C07C4/06
CPC分类号： B01J35/1038 , B01J29/40 , B01J35/08 , B01J35/1019 , B01J37/0018 , B01J37/0072 , B01J2229/42 , C07C4/06 , C07C2529/70 , C10G2300/1088 , C10G2400/20 , Y02P20/52 , C07C11/06
摘要： A process for once-through conversion of a hydrocarbon feed comprising at least olefins containing 4 carbon atoms and at least olefins containing 5 carbon atoms is described for the production of propylene, said process comprising passing said feed into at least one reaction unit provided with at least one catalyst in the form of spherical beads with a diameter in the range 1 to 3 mm, each of said spherical beads comprising at least one zeolite and at least one alumina-based support and having a pore distribution such that the macroporous volume, measured by mercury porosimetry, is in the range 0.10 to 0.20 ml/g and the mesoporous volume, measured by mercury porosimetry, is in the range 0.25 to 0.35 ml/g.
摘要翻译：描述了一种直接转化包含至少含有4个碳原子的烯烃和至少含有5个碳原子的烯烃的烃进料的方法，用于生产丙烯，所述方法包括使所述进料进入至少一个设置有至少一种直径在1至3mm范围内的球形珠粒形式的催化剂，每种所述球形珠粒包含至少一种沸石和至少一种氧化铝基载体，并且具有孔分布，以便测量大孔体积通过水银孔率测定法，在0.10至0.20ml / g的范围内，并且通过水银孔率法测量的介孔体积在0.25至0.35ml / g的范围内。

6. 发明申请

US20090192342A1 Process for Oligomerizing Olefins Using a Catalyst Based On Silica-Alumina 有权
标题翻译：使用基于二氧化硅 - 氧化铝的催化剂低聚烯烃的方法
公开(公告)号：US20090192342A1
公开(公告)日：2009-07-30
申请号：US12360231
申请日：2009-01-27
申请人： Vincent COUPARD , Alexandra Chaumonnot , Laurent Simon
发明人： Vincent COUPARD , Alexandra Chaumonnot , Laurent Simon
IPC分类号： C07C2/02 , B01J21/12
CPC分类号： C07C2/10 , C10G50/00 , C10G2300/1081 , C10G2300/1088 , C10G2300/1092 , C10G2400/22
摘要： A process for oligomerizing an olefinic hydrocarbon feed is described which consists of bringing said feed into contact with a catalyst comprising a silica-alumina, the silica content of said catalyst being in the range 5% to 95% by weight, said catalyst being prepared using a process comprising at least: a) mixing at least one alumina compound which is partially soluble in an acid medium with either at least one silica compound which is completely soluble in the reaction mixture or a combination formed by at least one silica compound and at least one alumina compound, said silica and alumina compounds being completely soluble in the reaction mixture, in order to form a solid precursor of said catalyst; b) hydrothermal treatment of the solid derived from step a) by calcining in moist air for a period in the range 4 to 7 hours.
摘要翻译：描述了一种使烯烃进料低聚的方法，其包括使所述进料与包含二氧化硅 - 氧化铝的催化剂接触，所述催化剂的二氧化硅含量在5重量％至95重量％的范围内，所述催化剂使用一种方法至少包括：a）将至少一种部分可溶于酸性介质的氧化铝化合物与至少一种完全可溶于反应混合物的二氧化硅化合物或由至少一种二氧化硅化合物形成的组合物和至少一种氧化铝化合物，所述二氧化硅和氧化铝化合物完全溶于反应混合物中，以形成所述催化剂的固体前体; b）通过在潮湿空气中煅烧4至7小时的时间段对来自步骤a）的固体进行水热处理。

7. 发明授权

US07329787B2 Process for transforming hydrocarbons into a fraction having an improved octane number and a fraction with a high cetane index 有权
$Process for transforming hydrocarbons into a fraction having an improved octane number and a fraction with a high cetane index$
标题翻译：将烃转化为具有改善的辛烷值的馏分和具有高十六烷指数的级分的方法
公开(公告)号：US07329787B2
公开(公告)日：2008-02-12
申请号：US10740685
申请日：2003-12-22
申请人： Patrick Briot , Vincent Coupard , Alain Forestiere , Eric Llido
发明人： Patrick Briot , Vincent Coupard , Alain Forestiere , Eric Llido
IPC分类号： C07C2/04 , C07C5/03 , C07C5/00
CPC分类号： C10L1/06 , C10G57/02 , C10G69/14 , C10L1/08
摘要： A process is described for transforming an initial hydrocarbon feed containing 4 to 15 carbon atoms, limits included, into a hydrocarbon fraction having an improved octane number and a hydrocarbon fraction with a high cetane number.
摘要翻译：描述了一种将含有4至15个碳原子的初始烃进料（包括限制）转化为具有改进的辛烷值的烃馏分和具有高十六烷值的烃馏分的方法。

8. 发明申请

US20070287873A1 METHOD OF CONVERTING ETHANOL TO BASE STOCK FOR DIESEL FUEL 有权
标题翻译：将乙醇转化为柴油燃料基料的方法
公开(公告)号：US20070287873A1
公开(公告)日：2007-12-13
申请号：US11754596
申请日：2007-05-29
申请人： Vincent Coupard , Sylvie Maury , Frederic Capuano , Mohamed Bengrine
发明人： Vincent Coupard , Sylvie Maury , Frederic Capuano , Mohamed Bengrine
IPC分类号： C07C1/00
CPC分类号： C10G3/50 , C10G3/45 , C10G3/47 , C10G3/62 , C10G2300/4018 , C10G2300/4081 , C10G2400/04 , Y02P30/20
摘要： A method of converting ethanol to a diesel fuel base stock comprises: a reaction stage (a) of contacting the ethanol with an acid catalyst, amorphous or structured, predominantly mesoporous, for example at a temperature of 300° C. to 500° C., at a pressure of 2 to 10 MPa and at a WHSV of 0.2 to 4 h−1, producing a gas phase, an organic liquid phase and an aqueous liquid phase, and a stage (b) of separating said gas phase, said organic liquid phase and said aqueous liquid phase at a pressure close to the reaction pressure. The method can involve recycling at least part of the gas phase separated in stage (b) to stage (a), and hydrogenating at least part of the organic liquid phase separated in stage (b).
摘要翻译：将乙醇转化为柴油燃料基料的方法包括：将乙醇与酸催化剂接触的反应阶段（a），其为无定形或结构化，主要是介孔的，例如在300℃至500℃的温度下。在2〜10MPa的压力和0.2〜4小时-1的WHSV下，产生气相，有机液相和含水液相，和阶段（b）在接近反应压力的压力下分离所述气相，所述有机液相和所述水性液相。该方法可以包括将阶段（b）中分离的至少一部分气相再循环到阶段（a），并且将在阶段（b）中分离的至少部分有机液相氢化。

9. 发明授权

US06824675B2 Distribution device for producing a polyphase mixture, and associated reactor 失效
标题翻译：用于生产多相混合物和相关反应器的分配装置
公开(公告)号：US06824675B2
公开(公告)日：2004-11-30
申请号：US09930201
申请日：2001-08-16
申请人： Christophe Boyer , Vincent Coupard , Bertrand Fanget
发明人： Christophe Boyer , Vincent Coupard , Bertrand Fanget
IPC分类号： C10G4502
CPC分类号： B01F5/0475 , B01D3/008 , B01F3/04496 , B01F5/0478 , B01F5/0493 , B01J8/0242 , B01J8/0278 , B01J8/0446 , B01J8/0492 , B01J2208/0084 , B01J2208/00849 , B01J2219/00006 , Y10S585/922 , Y10S585/923 , Y10T137/87652
摘要： A device for producing and distributing a polyphase mixture between two fluids comprises a chamber for the passage of a first fluid, said chamber being pierced by perforated tubes or conduits to pass a second fluid in a different physical state than the first fluid or not miscible with the first fluid through the chamber, said tubes being pierced by at least one orifice allowing passage of the first fluid and mixing between the fluids via the tubes. The second fluid is injected upstream of said device and the first fluid is injected into said device.
摘要翻译：用于在两种流体之间生产和分配多相混合物的装置包括用于第一流体通过的室，所述室被多孔管或导管刺穿，以使第二流体以不同于第一流体的物理状态传递或不与第一流体混合，所述第一流体通过所述室，所述管被至少一个孔刺穿，允许所述第一流体通过并经由所述管在所述流体之间混合。将第二流体注入所述装置的上游，并将第一流体注入所述装置。

10. 发明授权

US06350929B2 Process for isomerizing and dehydrogenating using a catalyst activated by sulfurization and passivation with ammonia or precursor thereof 有权
标题翻译：使用通过硫化活化的催化剂和用氨或其前体钝化的异构化和脱氢方法
公开(公告)号：US06350929B2
公开(公告)日：2002-02-26
申请号：US09392041
申请日：1999-09-09
申请人： Julia Magne-Drisch , Vincent Coupard , Jean-François Joly , Fabio Alario , Elisabeth Merlen
发明人： Julia Magne-Drisch , Vincent Coupard , Jean-François Joly , Fabio Alario , Elisabeth Merlen
IPC分类号： C07C522
CPC分类号： C10G45/60 , B01J2219/00006 , C10G59/02 , C10G65/043 , Y10S585/906
摘要： Process for isomerization of a feedstock that contains aromatic compounds with eight carbon atoms characterized in that it comprises at least one isomerization stage a) that is carried out in the presence of a catalyst that contains at least one metal of group VIII and that is activated according to an activation process that comprises at least one sulfurization stage and at least one stage for passivation with ammonia, and at least one dehydrogenation stage b).
摘要翻译：包含具有八个碳原子的芳族化合物的原料异构化方法，其特征在于其包含至少一个异构化阶段a），其在含有至少一种VIII族金属的催化剂存在下进行，并且根据涉及包含至少一个硫化阶段和至少一个用于用氨钝化的阶段和至少一个脱氢阶段b）的活化过程。

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