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1. 发明授权

US06486372B1 Catalyst based on dealuminated mordenite containing at least one metal from groups VI, VII or VIII, and its use for dismutation and/or transalkylation of aromatic hydrocarbons 失效
标题翻译：基于含有至少一种VI，VII或VIII族金属的脱铝丝光沸石的催化剂及其用于芳族烃的歧化和/或烷基转移的用途
公开(公告)号：US06486372B1
公开(公告)日：2002-11-26
申请号：US09056741
申请日：1998-04-08
申请人： Elisabeth Merlen , Fabio Alario
发明人： Elisabeth Merlen , Fabio Alario
IPC分类号： C07C268
CPC分类号： C07C6/123 , B01J29/18 , C07C6/126 , C07C2521/02 , C07C2521/04 , C07C2521/06 , C07C2521/08 , C07C2521/10 , C07C2521/12 , C07C2521/16 , C07C2523/08 , C07C2523/14 , C07C2523/36 , C07C2523/42 , C07C2523/44 , C07C2523/755 , C07C2527/167 , C07C2529/22 , C07C2529/24 , Y02P20/52
摘要： A catalyst for transforming aromatic hydrocarbons, preferably for dismutation of toluene to produce benzene and xylenes and transalkylation of toluene and aromatic compounds containing at least 9 carbon atoms per molecule to produce xylenes, contains 40% to 90% by weight of a mordenite in its acid form in a proportion of and 10% to 60% by weight of binders. The mordenite comprises less than 0.1% by weight of sodium and has a Si02/A2O3 molar ratio of over 70. The catalyst also contains at least one metal from groups VI, VII or VIII and optionally an additional metal from groups III or IV.
摘要翻译：用于转化芳族烃的催化剂，优选用于歧化甲苯以产生苯和二甲苯，并且每分子含有至少9个碳原子的甲苯和芳族化合物的烷基转移以产生二甲苯，其在其酸中含有40重量％至90重量％的丝光沸石以10％至60％重量的粘合剂形式。丝光沸石包含小于0.1重量％的钠，SiO 2 / A 2 O 3的摩尔比为70以上。催化剂还含有至少一种VI，VII或VIII族金属和任选的III或IV族金属。

2. 发明授权

US06465705B1 Process for isomerizing aromatic C8 cuts in the presence of a catalyst based on mordenite containing at least one group VIII metal and at least one group III metal 有权
标题翻译：在基于含有至少一种VIII族金属和至少一种III族金属的丝光沸石的催化剂存在下异构化芳族C 8馏分的方法
公开(公告)号：US06465705B1
公开(公告)日：2002-10-15
申请号：US09630812
申请日：2000-08-02
申请人： Elisabeth Merlen , Fabio Alario
发明人： Elisabeth Merlen , Fabio Alario
IPC分类号： C07C522
CPC分类号： B01J29/20 , C07C5/2724 , C07C2521/04 , C07C2523/08 , C07C2523/14 , C07C2523/40 , C07C2523/42 , C07C2523/44 , C07C2523/74 , C07C2523/755 , C07C2529/22 , C07C2529/24 , Y02P20/52 , C07C15/067
摘要： The present invention relates to a process for isomerizing aromatic C8 cuts in the presence of a catalyst containing a mordenite which is slightly or not dealuminated and a binder. This mordenite is generally present at least in part in its acid form and its Si/Al atomic ratio is less than 20, preferably in the range 5 to 15, and more preferably in the range 5 to 10. The catalyst also contains at least one metal from group VIII of the periodic table, preferably selected from the group formed by palladium and platinum. Finally, the catalyst further contains at least one metal from group III of the periodic table, namely gallium, indium or thallium, preferably indium, and optionally at least one metal from group IV of the periodic table, namely germanium, tin or lead, preferably tin. The present invention also relates to the catalyst used in the isomerization process and to a process for its preparation.
摘要翻译：本发明涉及在含有轻微或不脱铝的丝光沸石的催化剂存在下使芳族C8馏分异构化的方法和粘合剂。该丝光沸石通常至少部分地以其酸形式存在，其Si / Al原子比小于20，优选在5至15范围内，更优选在5至10范围内。催化剂还含有至少一种元素周期表第VIII族的金属，优选选自钯和铂形成的基团。最后，催化剂还含有至少一种元素周期表III族金属，即镓，铟或铊，优选铟，以及任选的至少一种元素周期表IV族金属，即锗，锡或铅，优选锡。本发明还涉及用于异构化方法的催化剂及其制备方法。

3. 发明授权

US06313363B1 Process for isomerizing aromatic compounds containing eight carbon atoms 有权
标题翻译：异构化含有8个碳原子的芳族化合物的方法
公开(公告)号：US06313363B1
公开(公告)日：2001-11-06
申请号：US09289655
申请日：1999-04-12
申请人： Jean-François Joly , Julia Magne-Drisch , Fabio Alario , Elisabeth Merlen , Eric Benazzi , Sylvie Lacombe
发明人： Jean-François Joly , Julia Magne-Drisch , Fabio Alario , Elisabeth Merlen , Eric Benazzi , Sylvie Lacombe
IPC分类号： C07C522
CPC分类号： B01J29/7023 , B01J29/068 , B01J29/18 , B01J29/22 , B01J29/74 , B01J29/7446 , B01J33/00 , B01J37/20 , B01J2229/26 , B01J2229/42 , C07C5/2702 , Y02P20/52 , Y02P20/582 , Y10S585/906 , C07C15/08
摘要： The present invention relates to a process for isomerizing aromatic compounds containing 8 carbon atoms, the catalysts containing at least one group VIII metal, comprising at least one sulfurization step and at least one passivation step using ammonia.
摘要翻译：本发明涉及使含有8个碳原子的芳族化合物异构化的方法，含有至少一种第Ⅷ族金属的催化剂，其包括至少一个硫化步骤和至少一个使用氨的钝化步骤。

4. 发明授权

US06271429B1 Process for isomerizing and dehydrogenating aromatic compounds containing eight carbon atoms with different catalysts 有权
标题翻译：用不同催化剂异构化和脱氢含有8个碳原子的芳族化合物的方法
公开(公告)号：US06271429B1
公开(公告)日：2001-08-07
申请号：US09172290
申请日：1998-10-14
申请人： Jean-François Joly , Julia Magne-Drisch , Vincent Coupard , Fabio Alario , Gérard Miquel , Marc Reymond
发明人： Jean-François Joly , Julia Magne-Drisch , Vincent Coupard , Fabio Alario , Gérard Miquel , Marc Reymond
IPC分类号： C07C522
CPC分类号： C07C5/2724 , C07C2529/04 , C07C2529/06 , C07C15/067
摘要： A process for isomerising a feed comprising aromatic compounds containing 8 carbon atoms is carried out in two steps: an isomerisation step and a dehydrogenation step. In FIG. 1, the feed to be treated is introduced into isomerisation zone R1 via line 1. Substantially pure hydrogen is introduced into line 1 via line 12 and recycled hydrogen is introduced into line 1 via line 13. Hydrogen which circulates in line 13 is purged via line 15. The effluent from isomerisation zone R1 is sent to a separation zone S1 via line 2. In S1, hydrogen contained in the effluent is isolated and recycled to the inlet to isomerisation zone R1 via line 13, the remaining effluent being evacuated from this separation zone S1 via line 3. The fluid contained in line 3 is heated in an oven F1 then evacuated therefrom via line 4. The effluent leaving the oven is enriched in recycled hydrogen via line 14 then it is introduced into dehydrogenation zone R2. The effluent from zone R2 is sent via line 5 to separation zone S2. In S2, hydrogen contained in the effluent is isolated and recycled to the inlet to dehydrogenation zone R2 via line 14, the remainder of the effluent being evacuated from separation zone S2 via line 6. Hydrogen which circulates in line 14 is purged via line 16.
摘要翻译：异构化含有8个碳原子的芳族化合物的进料异构化方法分两步进行：异构化步骤和脱氢步骤。在图 1，待处理的进料通过管线1被引入异构化区域R1中。通过管线12将基本纯的氢气引入管线1中，再循环的氢气通过管线13引入管线1中。在管线13中循环的氢气通过管线来自异构化区域R1的流出物通过管线2被送到分离区域S1中。在S1中，流出物中包含的氢气被分离并通过管线13再循环到异构化区域R1的入口，剩余的流出物从该分离管线3中包含的流体在烘箱F1中加热，然后通过管线4从其中排出。离开烘箱的流出物经由管线14富集回收的氢气，然后将其引入脱氢区域R2。来自区域R2的流出物通过管线5输送到分离区域S2。在S2中，流出物中所含的氢被分离并通过管线14再循环到脱氢区R2的入口，剩余的流出物通过管线6从分离区S2排出。在管线14中循环的氢通过管线16被清除。

5. 发明授权

US06177604B1 Process for co-production and separation of ethylbenzene and paraxylene 有权
标题翻译：共同生产和分离乙苯和对二甲苯的方法
公开(公告)号：US06177604B1
公开(公告)日：2001-01-23
申请号：US09219392
申请日：1998-12-23
申请人： Gerard Hotier , Fabio Alario , Alain Methivier
发明人： Gerard Hotier , Fabio Alario , Alain Methivier
IPC分类号： C07C712
CPC分类号： C07C15/08 , B01D15/185 , B01D2215/023 , C07C5/2708 , C07C5/2737 , C07C7/13 , C07C15/073 , C07C2529/40 , C07C15/067
摘要： Paraxylene and ethylbenzene are produced from an aromatic hydrocarbon feedstock by using adsorption zones in a simulated fluid bed. The feedstock is first passed into a first adsorption zone to produce a first paraxylene-rich fraction and a second ethylbenzene-rich fraction. The second fraction is then passed into a second adsorption zone to produce a third fraction containing essentially pure ethylbenzene and a fourth fraction containing a majority of orthoxylene and metaxylene. The fourth stream is then passed into an isomerization zone to produce an isomerate which is then recycled back to the first adsorption zone.
摘要翻译：对二甲苯和乙苯由芳烃原料通过在模拟流化床中使用吸附区产生。原料首先进入第一吸附区以产生富含第二对二甲苯馏分和第二富含乙苯的级分。然后将第二级分进入第二吸附区以产生含有基本上纯的乙苯的第三级分和含有大部分邻二甲苯和间二甲苯的第四级分。然后将第四个物流进入异构化区以产生异构体，然后将其再循环回第一吸附区。

6. 发明授权

US06613709B1 Catalyst comprising at least one zeolite with structure type NES and rhenium, and its use for transalkylation of alkylaromatic hydrocarbons 有权
标题翻译：包含至少一种结构类型为NES和铼的沸石的催化剂及其用于烷基芳烃的烷基转移的用途
公开(公告)号：US06613709B1
公开(公告)日：2003-09-02
申请号：US09642020
申请日：2000-08-21
申请人： Elisabeth Merlen , Fabio Alario , Nathalie Ferrer , Olivia Martin
发明人： Elisabeth Merlen , Fabio Alario , Nathalie Ferrer , Olivia Martin
IPC分类号： B01J2906
CPC分类号： C07C6/126 , B01J29/74 , B01J29/78 , B01J2229/16 , B01J2229/26 , B01J2229/36 , B01J2229/40 , B01J2229/42 , C07C2529/70
摘要： The present invention concerns a catalyst which contain at least one zeolite with structure type NES, preferably NU-87, comprising silicon and at least one element T selected from the group formed by aluminium, iron, gallium and boron. Preferably, element T has been extracted so that the overall Si/T atomic ratio is more than 20. This zeolite is at least partially in its acid form. The binder is preferably alumina. The catalyst also contains at least one metal selected from the group formed by group VIIB, group VIB and iridium, preferably rhenium. Finally, the catalyst optionally also contains at least one metal selected from the group formed by elements from groups III and IV of the periodic table, preferably indium or tin. The present invention also concerns the use of the catalyst in a process for transalkylating alkylaromatic hydrocarbons such as toluene and alkylaromatic compounds containing at least 9 carbon atoms. In particular, this catalyst is highly effective in treating C9+ aromatic feeds containing more than 5% by weight of aromatic olefins containing 10 carbon atoms and more, this feed possibly also containing benzene.
摘要翻译：本发明涉及含有至少一种结构类型为NES，优选为NU-87的沸石的催化剂，其包含硅和选自由铝，铁，镓和硼形成的基团中的至少一种元素T. 优选地，提取元素T使得总Si / T原子比大于20.该沸石至少部分为其酸形式。粘合剂优选为氧化铝。该催化剂还含有选自由ⅦB族，ⅥB族和铱族，优选铼形成的族中的至少一种金属。最后，催化剂任选地还含有至少一种选自元素周期表III和IV族的元素形成的金属，优选为铟或锡。本发明还涉及催化剂在烷基化烷基芳烃如甲苯和含有至少9个碳原子的烷基芳族化合物的方法中的用途。特别地，该催化剂在处理含有大于5重量％的含有10个碳原子的芳族烯烃和更多的芳族烯烃的C9 +芳族原料方面是非常有效的，该进料还可能含有苯。

7. 发明授权

US06342200B1 Process for preparing a zeolite with structure type EUO 有权
标题翻译：制备结构型EUO的沸石的方法
公开(公告)号：US06342200B1
公开(公告)日：2002-01-29
申请号：US09432120
申请日：1999-11-02
申请人： Loic Rouleau , Sylvie Lacombe , Fabio Alario , Elisabeth Merlen , Frédéric Kolenda , Julia Magne-Drisch
发明人： Loic Rouleau , Sylvie Lacombe , Fabio Alario , Elisabeth Merlen , Frédéric Kolenda , Julia Magne-Drisch
IPC分类号： C01B3904
CPC分类号： B01J29/7023 , B01J20/18 , B01J29/04 , B01J2229/62 , C01B39/48 , C07C5/2708 , C07C2529/70 , C10G35/095 , C10G45/64 , Y02P20/588 , C07C15/067
摘要： The present invention concerns a process for preparing a zeolite with structure type EUO comprising at least one element X selected from silicon and germanium and at least one element T selected from iron, aluminium, gallium, boron, titanium, vanadium, zirconium, molybdenum, arsenic, antimony, chromium and manganese, characterized in that seeds of at least one zeolitic material are used comprising at least one element X′ selected from silicon and germanium and at least one element T′ selected from iron, aluminium, gallium, boron, titanium, vanadium, zirconium, molybdenum, arsenic, antimony, chromium and manganese with a ratio X′/T′ of less than 200, said seeds being different from the zeolite with structure type EUO being prepared. The present invention also concerns the use of the zeolite obtained as a catalyst in a process for converting hydrocarbon-containing feeds, as an adsorbent to control pollution and as a molecular sieve for separation, and more particularly as a catalyst in a process for isomerizing aromatic compounds containing 8 carbon atoms.
摘要翻译：本发明涉及一种制备具有结构型EUO的沸石的方法，该方法包括至少一种选自硅和锗的元素X和选自铁，铝，镓，硼，钛，钒，锆，钼，砷中的至少一种元素T ，锑，铬和锰，其特征在于使用至少一种沸石材料的种子，其包含至少一种选自硅和锗的元素X'和至少一种选自铁，铝，镓，硼，钛，钒，锆，钼，砷，锑，铬和锰，其比例X'/ T'小于200，所述种子与制备具有结构类型EUO的沸石不同。本发明还涉及在烃类进料转化方法中作为催化剂使用的沸石，作为用于控制污染的吸附剂和用于分离的分子筛，更特别地，作为用于异构化芳族化合物的方法中的催化剂含有8个碳原子的化合物。

8. 发明授权

US06218334B1 Catalysts which can be used in conversion reactions of hydrocarbons and containing silicon 失效
标题翻译：可用于烃和含硅转化反应的催化剂
公开(公告)号：US06218334B1
公开(公告)日：2001-04-17
申请号：US08973407
申请日：1997-12-15
申请人： Fabio Alario , Jean-Marie Deves , Patrick Euzen
发明人： Fabio Alario , Jean-Marie Deves , Patrick Euzen
IPC分类号： B01J2713
CPC分类号： C10G35/09 , B01J23/56 , B01J23/58 , B01J23/63 , B01J23/8933 , B01J27/13
摘要： The invention relates to a catalyst comprising: a matrix consisting of 0 and 100% by weight of &lgr; transition alumina, the complement up to 100% by weight of the matrix being in &ggr; transition alumina, and relative to the total weight of the catalyst, from 0.001 to 2% by weight of silicon, from 0.1 to 15% by weight of at least one halogen chosen from the group formed by fluorine, chlorine, bromine and iodine, from 0.01 to 2% by weight of at least one noble metal from the platinum group, from 0.005 to 10% by weight of at least one promoter metal chosen from the group formed by tin, germanium, indium, gallium, thallium, antimony, lead, rhenium, manganese, chromium, molybdenum and tungsten, and if required from 0.001 to 10% by weight of a doping metal.
摘要翻译：本发明涉及一种催化剂，其包括：由0和100重量％的羔羊酸过渡氧化铝组成的基体，所述基体的重量比率高达100重量％，并且相对于催化剂的总重量， 0.001至2重量％的硅，0.1至15重量％的至少一种选自氟，氯，溴和碘的卤素，0.01至2重量％的至少一种贵金属，选自0.005至10重量％的至少一种选自由锡，锗，铟，镓，铊，锑，铅，铼，锰，铬，钼和钨形成的助催化剂金属， 0.001〜10重量％的掺杂金属。

9. 发明授权

US6045689A Process for catalytic conversion of hydrocarbons into aromatic compounds with a catalyst containing silicon 失效
标题翻译：用含有催化剂的烃催化转化成芳族化合物的方法
公开(公告)号：US6045689A
公开(公告)日：2000-04-04
申请号：US973402
申请日：1997-12-15
申请人： Fabio Alario , Jean-Marie Deves , Patrick Euzen
发明人： Fabio Alario , Jean-Marie Deves , Patrick Euzen
IPC分类号： B01J23/56 , B01J23/63 , B01J23/64 , B01J27/13 , B01J27/135 , C10G35/09 , C10G35/06 , C10G35/085
CPC分类号： C10G35/09 , B01J23/56 , B01J23/63 , B01J27/13
摘要： A process for converting hydrocarbons into aromatic compounds, which entails contacting a composition containing hydrocarbons with a catalyst under temperature and pressure conditions to produce the aromatic compounds, the catalyst containing a matrix of .eta. transition alumina and/or .gamma. transition alumina. The catalyst contains 0.001 to 2 wt % of silicon, 0.1 to 15 wt % of at least one platinum group metal, and 0.005 to 10 wt % of at least one promoter metal. The promoter metals may be tin, germanium, indium, gallium, thallium, antimony, lead, rhenium, manganese, chromium, molybdenium or tungsten. The catalyst may also contain a doping metal.
摘要翻译： PCT No.PCT / FR96 / 00919 Sec。 371 1997年12月15日第 102（e）日期1997年12月15日PCT Filted 1996年6月14日PCT公布。出版物WO97 / 00306 日期1997年1月3日一种将烃转化为芳族化合物的方法，其需要在温度和压力条件下使含烃的组合物与催化剂接触以产生芳族化合物，所述催化剂含有等离子体氧化铝和/或γ过渡氧化铝。催化剂含有0.001〜2重量％的硅，0.1〜15重量％的至少一种铂族金属和0.005〜10重量％的至少一种助催化剂金属。助催化剂金属可以是锡，锗，铟，镓，铊，锑，铅，铼，锰，铬，钼或钨。催化剂也可以含有掺杂金属。

10. 发明申请

US20050256355A1 Catalyst comprising at least one zeolite with structure type NES and rhenium, and its use for transalkylation of alkylaromatic hydrocarbons 审中-公开
标题翻译：包含至少一种结构类型为NES和铼的沸石的催化剂及其用于烷基芳烃的烷基转移的用途
公开(公告)号：US20050256355A1
公开(公告)日：2005-11-17
申请号：US11048751
申请日：2005-02-03
申请人： Elisabeth Merlen , Fabio Alario , Nathalie Ferrer , Olivia Martin
发明人： Elisabeth Merlen , Fabio Alario , Nathalie Ferrer , Olivia Martin
IPC分类号： B01J29/06 , B01J29/78 , C07C6/12 , C10G45/64
CPC分类号： B01J29/78 , B01J2229/42 , C07C6/126 , C07C2523/28 , C07C2529/70 , C07C2529/78 , C10G45/64
摘要： The present invention concerns catalysts which contain at least one zeolite with structure type NES, preferably NU-87, comprising silicon and at least one element T selected from the group formed by aluminium, iron, gallium and boron. Preferably, element T has been extracted so that the overall Si/T atomic ratio is more than 20. This zeolite is at least partially in its acid form. The binder is preferably alumina. The catalyst also contains at least one metal selected from the group formed by group VIIB, group VIB and iridium, preferably molybdenum. Finally, the catalyst optionally also contains at least one metal selected from the group formed by elements from groups IIIA and IVA of the periodic table, preferably indium or tin. The present invention also concerns the use of the catalyst in a process for transalkylating alkylaromatic hydrocarbons such as toluene and alkylaromatic compounds containing at least 9 carbon atoms. In particular, this catalyst is highly effective in treating C9+ aromatic feeds containing more than 5% by weight of aromatic olefins containing 10 carbon atoms and more, this feed possibly also containing benzene.
摘要翻译：本发明涉及含有至少一种结构类型NES，优选NU-87的沸石的催化剂，其包含硅和至少一种选自由铝，铁，镓和硼形成的基团的元素T. 优选地，提取元素T使得总Si / T原子比大于20.该沸石至少部分为其酸形式。粘合剂优选为氧化铝。该催化剂还含有至少一种选自由ⅦB族，ⅥB族和铱族化合物形成的金属，优选为钼。最后，催化剂任选地还含有选自元素周期表IIIA和IVA族元素形成的族中的至少一种金属，优选为铟或锡。本发明还涉及催化剂在烷基化烷基芳烃如甲苯和含有至少9个碳原子的烷基芳族化合物的方法中的用途。特别地，该催化剂在处理含有大于5重量％的含有10个碳原子的芳族烯烃和更多的芳族烯烃的C9 +芳族原料方面是非常有效的，该进料还可能含有苯。

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