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1. 发明授权

US08067354B2 Softening detergent composition 有权
标题翻译：软化洗涤剂组合物
公开(公告)号：US08067354B2
公开(公告)日：2011-11-29
申请号：US12086291
申请日：2006-12-26
申请人： Teruo Kubota , Yohei Ozeki , Wataru Ueno , Motomitsu Hasumi
发明人： Teruo Kubota , Yohei Ozeki , Wataru Ueno , Motomitsu Hasumi
IPC分类号： C11D1/83
CPC分类号： C11D1/83 , C11D3/046 , C11D3/08 , C11D3/10 , C11D3/126 , C11D3/128 , C11D3/3761 , D06M11/79
摘要： [PROBLEMS] To provide a softening detergent composition capable of washing a fibrous manufactured article having softening ability, and at the same time allowing a clay mineral to be less likely to remain on clothes.
摘要翻译： [问题]提供能够洗涤具有软化能力的纤维制品的软化洗涤剂组合物，同时允许粘土矿物不太可能留在衣服上。

2. 发明申请

US20090170746A1 Softening Detergent Composition 有权
标题翻译：软化洗涤剂组合物
公开(公告)号：US20090170746A1
公开(公告)日：2009-07-02
申请号：US12086291
申请日：2006-12-26
申请人： Teruo Kubota , Yohei Ozeki , Wataru Ueno , Motomitsu Hasumi
发明人： Teruo Kubota , Yohei Ozeki , Wataru Ueno , Motomitsu Hasumi
IPC分类号： C11D3/12
CPC分类号： C11D1/83 , C11D3/046 , C11D3/08 , C11D3/10 , C11D3/126 , C11D3/128 , C11D3/3761 , D06M11/79
摘要： [Problems] To provide a softening detergent composition capable of washing a fibrous manufactured article having softening ability, and at the same time allowing a clay mineral to be less likely to remain on clothes.[Solving Means] A softening detergent composition containing (a) 1 to 20% by mass of clay granules containing as a main component a smectite clay mineral represented by the following general formula (I), provided that a Na/Ca mass ratio in the granules is less than 1.0: [Si8(MgaAlb)O20(OH)4]X−.X/n [Me]n (I), wherein a, b, and x satisfy the formulas 0
摘要翻译： [问题]提供能够洗涤具有软化能力的纤维制品的软化洗涤剂组合物，同时允许粘土矿物不太可能留在衣服上。 [解决方案]一种软化洗涤剂组合物，其含有（a）1〜20质量％的以下述通式（I）表示的蒙皂石粘土矿物作为主要成分的粘土颗粒，其中，所述粘土颗粒的Na / Ca质量比颗粒小于1.0：[Si8（MgaAlb）O20（OH）4] X-X / n [Me] n（I）其中a，b和x满足式0

3. 发明授权

US07098177B1 Process for producing detergent particles 有权
标题翻译：生产洗涤剂颗粒的方法
公开(公告)号：US07098177B1
公开(公告)日：2006-08-29
申请号：US09581594
申请日：1999-10-14
申请人： Teruo Kubota , Hitoshi Takaya , Hiroyuki Yamashita
发明人： Teruo Kubota , Hitoshi Takaya , Hiroyuki Yamashita
IPC分类号： C11D11/00
CPC分类号： C11D17/06 , C11D11/0082 , C11D17/065
摘要： A process for preparing detergent particles containing step (I): mixing a base particle for supporting a surfactant ((a) component), and a surfactant composition ((b) component), under mixing conditions wherein the (a) component does not substantially undergo breakdown, to give a mixture; wherein the base particle is obtained by spray-drying an aqueous slurry, wherein the mixing operation is carried out by using a mixer containing agitation impellers, and where the mixer further contains disintegration impellers, the mixing operation step (I) is carried out without substantially rotating the disintegration impellers; and step (II): mixing the mixture obtained in step (I) with 5 to 100 parts by weight of fine powder, while substantially maintaining the shape of the (a) component containing (b) component, to give detergent particles, having a degree of particle growth of 1.3 or less, and a bulk density of 500 g/L or more.
摘要翻译：一种制备含有步骤（I）的洗涤剂颗粒的方法：在（a）成分基本上不含有（a）成分的混合条件下混合表面活性剂（（a）成分）和表面活性剂组合物（（b）成分）进行分解，给出混合物; 其特征在于，所述基础颗粒是通过喷雾干燥含水浆料而获得的，其中所述混合操作是通过使用含有搅拌叶轮的混合器进行的，并且其中所述混合器还包含崩解叶轮，所述混合操作步骤（I）旋转分解叶轮; 和步骤（II）：在基本保持含（b）成分的（a）成分的形状的同时，将步骤（I）中获得的混合物与5至100重量份的细粉末混合，得到具有粒子生长度为1.3以下，堆积密度为500g / L以上。

4. 发明申请

US20050256023A1 Detergent particles 有权
标题翻译：洗涤剂颗粒
公开(公告)号：US20050256023A1
公开(公告)日：2005-11-17
申请号：US10523606
申请日：2003-09-02
申请人： Yoshinobu Imaizumi , Hiroyuki Yamashita , Teruo Kubota
发明人： Yoshinobu Imaizumi , Hiroyuki Yamashita , Teruo Kubota
IPC分类号： C11D11/02 , C11D11/04 , C11D17/06 , C11D17/00
CPC分类号： C11D11/04 , C11D11/02 , C11D17/06
摘要： Detergent particles obtained by a process comprising the step of dryneutralizing base particles comprising a water-soluble solid alkali inorganic substance (A) with a liquid acid precursor (B) of a non-soap anionic surfactant, wherein the base particles are obtained by a spray-drying method, and wherein the base particles contain the component (A) in an amount of equal to or greater than 4 times the amount equivalent for neutralizing the component (B) and have an average particle size of from 150 to 400 μm; base particles having an average particle size of from 150 to 400 μm, comprising 20 to 80% by weight of a water-soluble solid alkali inorganic substance; a process for preparing detergent particles comprising the steps of (a) preparing a slurry comprising a water-soluble solid alkali inorganic substance (A) in an amount equal to or greater than 4 times the amount equivalent for neutralizing a liquid acid precursor (B) of a non-soap anionic surfactant to be added in step (c); (b) spray-drying the slurry obtained in step (a) to give base particles; and (c) mixing the liquid acid precursor (B) with the base particles obtained in step (b) and dry-neutralizing the resulting mixture; and a detergent composition comprising the detergent particles as defined above. The detergent particles can be used for laundry detergents, dishwashing detergents and the like.
摘要翻译：通过包括将包含水溶性固体碱性无机物质（A）的基础颗粒与非皂性阴离子表面活性剂的液体酸前体（B）中和的步骤获得的洗涤剂颗粒，其中所述基础颗粒通过喷雾并且其中所述基础颗粒含有等于或大于中和组分（B）的当量的4倍量的组分（A），并且平均粒度为150-400μm; 平均粒径为150〜400μm的碱性粒子，含有20〜80重量％的水溶性固体碱无机物质; 一种制备洗涤剂颗粒的方法，包括以下步骤：（a）制备含有等于或大于中和液体酸性前体（B）的当量的4倍量的水溶性固体碱性无机物质（A）的浆料，的步骤（c）中加入的非皂性阴离子表面活性剂; （b）喷雾干燥步骤（a）中获得的浆料，得到基础颗粒; 和（c）将液体酸前体（B）与步骤（b）中获得的基础颗粒混合并干燥中和所得混合物; 以及包含如上所述的洗涤剂颗粒的洗涤剂组合物。洗涤剂颗粒可用于衣物洗涤剂，餐具洗涤剂等。

5. 发明授权

US5945395A Method for producing nonionic detergent granules 失效
标题翻译：生产非离子洗涤剂颗粒的方法
公开(公告)号：US5945395A
公开(公告)日：1999-08-31
申请号：US937586
申请日：1997-09-29
申请人： Hiroyuki Yamashita , Koji Toyoda , Masaaki Sakaue , Yasuji Yamada , Teruo Kubota , Hiroshi Kogurusu
发明人： Hiroyuki Yamashita , Koji Toyoda , Masaaki Sakaue , Yasuji Yamada , Teruo Kubota , Hiroshi Kogurusu
IPC分类号： C11D1/14 , C11D1/28 , C11D1/29 , C11D1/72 , C11D1/83 , C11D11/00 , C11D17/00 , C11D17/06
CPC分类号： C11D17/0034 , C11D1/83 , C11D11/0082 , C11D17/065 , C11D1/146 , C11D1/28 , C11D1/29 , C11D1/72
摘要： The method for producing nonionic detergent granules includes the steps of (I) blending the following (i) to (iii): (i) at least one of a nonionic surfactant and an aqueous nonionic surfactant solution; (ii) an acid precursor of an anionic surfactant capable of having a lamellar orientation; (iii) at least one of an alkali builder and an alkali, porous oil-absorbing carrier, to give a mixture of detergent starting materials containing the nonionic surfactant as a main surfactant component; and (II) heating the mixture obtained in step (I) at least up to a temperature capable of neutralizing the acid precursor of the anionic surfactant in an agitating mixer, and granulating while tumbling the agitating mixer thereby increasing a bulk density, to give nonionic detergent granules having a bulk density of from 0.6 to 1.2 g/ml.
摘要翻译：制备非离子洗涤剂颗粒的方法包括以下步骤：（I）将以下（i）至（iii）共混：（i）非离子表面活性剂和非离子表面活性剂水溶液溶液中的至少一种; （ii）能够具有层状取向的阴离子表面活性剂的酸前体; （iii）碱助洗剂和碱性多孔吸油性载体中的至少一种，得到含有非离子表面活性剂作为主要表面活性剂组分的洗涤剂原料的混合物; 和（II）在搅拌混合器中将步骤（I）中获得的混合物加热到至少达到能够中和阴离子表面活性剂的酸前体的温度，并在搅拌混合器翻转时进行造粒，从而提高堆积密度，得到非离子表面活性剂洗涤剂颗粒的堆积密度为0.6〜1.2g / ml。

6. 发明申请

US20100093593A1 Softening Detergent Composition 有权
标题翻译：软化洗涤剂组合物
公开(公告)号：US20100093593A1
公开(公告)日：2010-04-15
申请号：US11989780
申请日：2006-07-31
申请人： Yohei Ozeki , Teruo Kubota , Motomitsu Hasumi
发明人： Yohei Ozeki , Teruo Kubota , Motomitsu Hasumi
IPC分类号： C11D3/04
CPC分类号： C11D3/001 , C11D1/83 , C11D3/126 , C11D17/06 , D06M11/79 , D06M2200/50
摘要： [PROBLEMS] To provide a softening detergent composition capable of washing a fibrous manufactured article or the like having softening ability, and at the same time allowing a clay mineral to be less likely to remain on clothes.[SOLVING MEANS] A softening detergent composition containing (a) 2 to 20% by mass of clay granules containing as a main component a smectite clay mineral represented by the following general formula (I), provided that a Na/Ca mass ratio in the granules is 1.0 or more: [Si8(MgaAlb)O20(OH)4]X−.X/n [Me]n+ (I), wherein a, b, and x satisfy the formulas 0
摘要翻译： [问题]提供能够洗涤具有软化能力的纤维制品等的软化洗涤剂组合物，同时允许粘土矿物不太可能留在衣服上。 [解决方案]一种软化洗涤剂组合物，其含有（a）2〜20质量％的以下述通式（I）表示的蒙皂石粘土矿物作为主要成分的粘土颗粒，其中，所述粘土颗粒中的Na / Ca质量比颗粒为1.0以上：[Si8（MgaAlb）O20（OH）4] X-X / n [Me] n +（I）其中a，b和x满足式0

7. 发明申请

US20050272629A1 Detergent particle 审中-公开
标题翻译：洗涤剂颗粒
公开(公告)号：US20050272629A1
公开(公告)日：2005-12-08
申请号：US10524029
申请日：2003-08-13
申请人： Motomitsu Hasumi , Toshiki Nishi , Teruo Kubota , Shu Yamaguchi , Hideichi Nitta , Hiroyuki Yamashita
发明人： Motomitsu Hasumi , Toshiki Nishi , Teruo Kubota , Shu Yamaguchi , Hideichi Nitta , Hiroyuki Yamashita
IPC分类号： C11D3/12 , C11D3/37 , C11D11/00 , C11D17/00 , C11D17/06
CPC分类号： C11D11/0088 , C11D17/0039 , C11D17/06
摘要： A detergent particle comprising a base detergent particle, a base layer comprising a fine powder, prepared by treating a surface of the base detergent particle with a fine powder dispersion, in which a fine powder is dispersed in a binder, wherein the base layer is formed on the surface of the base detergent particle, and a surface coating comprising a surface modifier, which is formed on the base layer; a process for preparing a detergent particle, comprising the steps of treating a surface of a base detergent particle with a fine powder dispersion in which the fine powder is dispersed in a binder as a dispersion medium to form a base layer on the surface of the base detergent particle; and surface-coating the base layer with a surface modifier; and a fine powder dispersion for forming a base layer comprising a binder and a fine powder, wherein the fine powder is dispersed in the binder. The detergent composition comprising the detergent particle of the present invention can be used as laundry detergents, laundry bleaching agents, cleaning agents for hard surfaces such as detergents for automatic dishwashers, pipe cleaners, and the like.
摘要翻译：一种洗涤剂颗粒，其包含基础洗涤剂颗粒，包含细粉末的基底层，其通过用细粉末分散体处理基础洗涤剂颗粒的表面而制备，其中细粉末分散在粘合剂中，其中形成基底层在基础洗涤剂颗粒的表面上，以及包含表面改性剂的表面涂层，其形成在基底层上; 一种制备洗涤剂颗粒的方法，包括以细粉分散体处理基础洗涤剂颗粒表面的步骤，其中细粉末作为分散介质分散在粘合剂中以在基材的表面上形成基层洗涤剂颗粒; 并用表面改性剂表面涂覆基层; 以及用于形成包含粘合剂和细粉末的基底层的细粉末分散体，其中细粉末分散在粘合剂中。包含本发明的洗涤剂颗粒的洗涤剂组合物可用作衣物洗涤剂，衣物漂白剂，硬表面清洁剂，例如用于自动洗碗机的洗涤剂，管道清洁剂等。

8. 发明授权

US06818605B1 Granulated detergent composition 失效
标题翻译：颗粒状洗涤剂组合物
公开(公告)号：US06818605B1
公开(公告)日：2004-11-16
申请号：US10009684
申请日：2001-12-13
申请人： Takeshi Ban , Teruo Kubota , Shu Yamaguchi , Hiroyuki Saijo , Hiroyuki Yamashita
发明人： Takeshi Ban , Teruo Kubota , Shu Yamaguchi , Hiroyuki Saijo , Hiroyuki Yamashita
IPC分类号： C11D1700
CPC分类号： C11D3/046 , C11D3/08 , C11D3/10 , C11D3/12 , C11D3/128 , C11D17/065
摘要： The present invention relates to a granular detergent composition having easy measurability and distributivity suitable for spoon measurement, a bulk density thereof being 500 g/L or more, containing a surfactant, a water-insoluble inorganic compound and a water-soluble salt, wherein the granular detergent composition has a variance of powder dropping rate V of 1.0 or less, an inserting pressure P of 80 gf/cm or less, a &Dgr; dropping ratio D of 14% of les, and an index K of from 30 to 230, the index K being represented by the equation: K=P×exp (0.135×D), wherein P stands for an inserting pressure (gf/cm), and D stands for a &Dgr; dropping ratio (%); and a process for preparing the same.
摘要翻译：本发明涉及一种粒状洗涤剂组合物，其具有容易测量和分布适用于勺子测量，其堆积密度为500g / L或更高，含有表面活性剂，水不溶性无机化合物和水溶性盐，其中颗粒状洗涤剂组合物的粉末滴下速度V的变化为1.0以下，插入压力P为80gf / cm以下，Δ滴加比D为14％，指数K为30〜230，指数K由下式表示：K = Pxexp（0.135×D），其中P表示插入压力（gf / cm），D表示Δ下降率（％）。及其制备方法。

9. 发明授权

US08034760B2 Softening detergent composition 有权
标题翻译：软化洗涤剂组合物
公开(公告)号：US08034760B2
公开(公告)日：2011-10-11
申请号：US11989780
申请日：2006-07-31
申请人： Yohei Ozeki , Teruo Kubota , Motomitsu Hasumi
发明人： Yohei Ozeki , Teruo Kubota , Motomitsu Hasumi
IPC分类号： C11D1/83
CPC分类号： C11D3/001 , C11D1/83 , C11D3/126 , C11D17/06 , D06M11/79 , D06M2200/50
摘要： [PROBLEMS] To provide a softening detergent composition capable of washing a fibrous manufactured article or the like having softening ability, and at the same time allowing a clay mineral to be less likely to remain on clothes.[SOLVING MEANS] A softening detergent composition containing (a) 2 to 20% by mass of clay granules containing as a main component a smectite clay mineral represented by the following general formula (I), provided that a Na/Ca mass ratio in the granules is 1.0 or more: [Si8(MgaAlb)O20(OH)4]X−.X/n [Me]n+ (I), wherein a, b, and x satisfy the formulas 0
摘要翻译： [问题]提供能够洗涤具有软化能力的纤维制品等的软化洗涤剂组合物，同时允许粘土矿物不太可能留在衣服上。 [解决方案]一种软化洗涤剂组合物，其含有（a）2〜20质量％的以下述通式（I）表示的蒙皂石粘土矿物作为主要成分的粘土颗粒，其中，所述粘土颗粒中的Na / Ca质量比颗粒为1.0以上：[Si8（MgaAlb）O20（OH）4] X-X / n [Me] n +（I）其中a，b和x满足式0

10. 发明授权

US06849590B1 Process for producing granules for supporting surfactant 失效
标题翻译：生产用于支撑表面活性剂的颗粒的方法
公开(公告)号：US06849590B1
公开(公告)日：2005-02-01
申请号：US09869359
申请日：1999-12-28
申请人： Hiroki Yamaboshi , Shuji Takana , Teruo Kubota , Hitoshi Takaya , Hiroyuki Yamashita , Hideichi Nitta
发明人： Hiroki Yamaboshi , Shuji Takana , Teruo Kubota , Hitoshi Takaya , Hiroyuki Yamashita , Hideichi Nitta
IPC分类号： B01J2/00 , C11D11/00 , C11D17/00 , C11D17/06
CPC分类号： B01J2/006 , C11D11/0082 , C11D17/0039 , C11D17/06
摘要： The present invention relates to a process for preparing particles for supporting a surfactant, comprising a step of giving a defect to a coating film containing a water-soluble component, wherein the coating film is formed on surfaces of raw material particles; and a process for preparing detergent particles comprising a step of mixing a surfactant composition and the particles for supporting a surfactant obtained by the above process, under conditions that the surfactant composition shows a liquid state. By using the process of the present invention, there can be obtained particles for supporting a surfactant, in which the supporting ability of the particles is improved, without lowering the detergency. In addition, by using the particles for supporting a surfactant, there can be obtained detergent particles having excellent detergency.
摘要翻译：本发明涉及一种制备用于支撑表面活性剂的颗粒的方法，包括对含有水溶性组分的涂膜产生缺陷的步骤，其中在原料颗粒的表面上形成涂膜; 以及制备洗涤剂颗粒的方法，包括在表面活性剂组合物显示液态的条件下，混合表面活性剂组合物和用于负载由上述方法得到的表面活性剂的颗粒的步骤。通过使用本发明的方法，可以获得支撑表面活性剂的颗粒，其中颗粒的支持能力得到改善，而不降低去污力。另外，通过使用支撑表面活性剂的粒子，可以得到洗涤性优异的洗涤剂粒子。

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