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    • 4. 发明授权
    • Production method of Nb3Al superconducting multifilamentary wire
    • Nb3Al超导复丝的生产方法
    • US06570096B2
    • 2003-05-27
    • US09864228
    • 2001-05-25
    • Takao TakeuchiNobuya BannoToshihisa AsanoHitoshi Wada
    • Takao TakeuchiNobuya BannoToshihisa AsanoHitoshi Wada
    • H01B1200
    • H01L39/2409C30B25/105C30B29/04Y10S420/901Y10S505/806Y10S505/815Y10T29/49014
    • This invention provides a production method of Nb3Al superconducting multifilamentary wire based on rapid-heating, quenching and transformation method, capable of producing a high-performance Nb3Al superconducting multifilamentary wire by improving critical temperature thereof, upper critical field and critical current density. Upon a first stage heat treatment of beating a composite, in which bcc phase Nb—Al supersaturated solid solution is dispersed in Nb matrix, the bcc phase Nb—Al supersaturated solid solution ordered in temperature rise process is made disordered at an initial phase thereof and a non-reacting portion located adjacent is heated using a reaction heat generated when transforming this disordered bcc phase to A15 phase. Then, disordering of the bcc phase is promoted while propagating a high-temperature transformation region so as to automatically progress high-temperature beat treatment. As a result, a reaction-transformation is caused to block stacking fault from being generated in the A15 phase and crystal grain from being coarse and then, a second stage heat treatment for improving a long range ordering of the A15 phase is carried out.
    • 本发明提供了一种基于快速加热,淬火和转化方法的Nb3Al超导多丝线的制造方法,其能够通过改善其临界温度,上临界场和临界电流密度来生产高性能Nb3Al超导复丝。 在将bcc相Nb-Al过饱和固溶体分散在Nb基体中的复合材料的第一阶段热处理中,在升温过程中排列的bcc相Nb-Al过饱和固溶体在其初始阶段变得无序, 使用在将该无序bcc相变换为A15相时产生的反应热来加热位于相邻的非反应部分。 然后,在传播高温转化区域的同时促进bcc相的无序化,以自动进行高温节拍处理。 结果,导致反应转变阻止在A15相中产生的堆垛层错和晶粒粗糙化,然后进行用于改善A15相的长程排序的第二阶段热处理。
    • 9. 发明授权
    • Silver and silver alloy plating bath
    • 银和银合金电镀浴
    • US07628903B1
    • 2009-12-08
    • US09563479
    • 2000-05-02
    • Kiyotaka TsujiTetsuji NishikawaTakao TakeuchiKeigo ObataHidemi Nawafune
    • Kiyotaka TsujiTetsuji NishikawaTakao TakeuchiKeigo ObataHidemi Nawafune
    • C25D3/46C23C18/31
    • C25D3/46C25D3/64
    • A silver and silver alloy plating bath, includes (A) a soluble salt, having a silver salt or a mixture of a silver salt and a salt of a metal such as tin, bismuth, indium, lead, and the like; and (B) a particular aliphatic sulfide compound, such as thiobis(diethyleneglycol), dithiobis(triglycerol), 3,3′-thiodipropanol, thiodiglycerin, 3,6-dithiooctane-1,8-diol, and the like, which contain at least one or more of an ether oxygen atom, a 1-hydroxypropyl group, a hydroxypropylene group, or two or more of a sulfide bond in the molecule, and not containing a basic nitrogen atom. Compared to baths containing aliphatic monosulfide compounds, such as thiodiglycol or beta-thiodiglycol, which do not contain an ether oxygen atom, 1-hydroxypropyl group, a hydroxypropylene group, or two or more of a sulfide bond in the molecule, by having these particular compounds, the plating bath of the present invention has excellent stability over extended time, excellent co-deposition of silver and various metals, and excellent appearance of the electrodeposition coating.
    • 银和银合金电镀浴包括(A)可溶性盐,其具有银盐或银盐和金属如锡,铋,铟,铅等的盐的混合物; 和(B)特定的脂族硫醚化合物,例如硫代双(二甘醇),二硫代双(三甘油),3,3'-硫代二丙醇,硫二甘油,3,6-二硫辛烷-1,8-二醇等, 至少一个或多个醚氧原子,1-羟丙基,羟基亚丙基,或分子中的硫原子键中的两个或多个,并且不含碱性氮原子。 与分子中含有不含醚氧原子,1-羟丙基,羟基亚丙基或两个或多个硫键的脂族单硫醚化合物如硫二甘醇或β-硫二甘醇相比,具有这些特定 化合物,本发明的电镀浴在延长的时间内具有优异的稳定性,优异的银和各种金属的共沉积,以及优异的电沉积外观。